The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurr...The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurry with ferrous sulfate and sulfuric acidsolution was filled into a vertical tube(9m in height)and air was blown from the bottom of the reactor.The effects of initial acidconcentration,temperature,particle size,initial zinc sulfate concentration,pulp density and the concentration of Fe on the leachingkinetics were investigated.Results of the kinetic analysis indicate that direct leaching of zinc sulfide concentrate follows shrinkingcore model(SCM).This process was controlled by a chemical reaction with the apparent activation energy of49.7kJ/mol.Furthermore,a semi-empirical equation is obtained,showing that the order of the iron,sulfuric acid and zinc sulfate concentrationsand particle radius are0.982,0.189,-0.097and-0.992,respectively.Analysis of the unreacted and reacted sulfide particles bySEM-EDS shows that insensitive agitation in the reactor causes detachment of the sulfur layer from the particles surface in lowerthan60%Zn conversion and lixiviant in the face with sphalerite particles.展开更多
多尺度非均匀背景为不同尺度和形状且在空间上分布不均匀的粗糙结构。本文针对多尺度非均匀粗糙背景散射特性快速计算问题,提出了基于散射中心方法的参数化表征模型。多尺度非均匀背景的散射场一般由地表大尺度表面所产生的镜反射分量...多尺度非均匀背景为不同尺度和形状且在空间上分布不均匀的粗糙结构。本文针对多尺度非均匀粗糙背景散射特性快速计算问题,提出了基于散射中心方法的参数化表征模型。多尺度非均匀背景的散射场一般由地表大尺度表面所产生的镜反射分量、大尺度表面几何不连续处所产生的绕射分量和地表小尺度粗糙面引起的漫散射分量共同组成。传统雷达目标散射中心建模采用分布型、局部型和滑动型散射中心模型(scattering center model, SCM)表征目标的反射和绕射散射;但是,传统散射中心表征形式仅能描述大尺度光滑表面、几何不连续处的散射场,无法描述小尺度粗糙面的散射效应。本文结合粗糙面的相干-非相干散射理论,在大尺度地形散射中心表征模型的基础上,利用相干模型修正小尺度粗糙面对大尺度表面散射场幅度的影响;利用双向反射分布函数(bidirectional reflectance distribution function, BRDF)建立非相干散射的参数化表征形式。对两种非均匀多尺度背景的散射特性进行参数化表征,并采用商业软件高频求解器对计算结果的精度和效率进行了校验,证明了粗糙背景散射中心参数化建模方法的可行性。展开更多
基金the Zanjan Zinc Khalessazan Industries Company (ZZKICO) for the financial and technical support of this work
文摘The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurry with ferrous sulfate and sulfuric acidsolution was filled into a vertical tube(9m in height)and air was blown from the bottom of the reactor.The effects of initial acidconcentration,temperature,particle size,initial zinc sulfate concentration,pulp density and the concentration of Fe on the leachingkinetics were investigated.Results of the kinetic analysis indicate that direct leaching of zinc sulfide concentrate follows shrinkingcore model(SCM).This process was controlled by a chemical reaction with the apparent activation energy of49.7kJ/mol.Furthermore,a semi-empirical equation is obtained,showing that the order of the iron,sulfuric acid and zinc sulfate concentrationsand particle radius are0.982,0.189,-0.097and-0.992,respectively.Analysis of the unreacted and reacted sulfide particles bySEM-EDS shows that insensitive agitation in the reactor causes detachment of the sulfur layer from the particles surface in lowerthan60%Zn conversion and lixiviant in the face with sphalerite particles.
文摘多尺度非均匀背景为不同尺度和形状且在空间上分布不均匀的粗糙结构。本文针对多尺度非均匀粗糙背景散射特性快速计算问题,提出了基于散射中心方法的参数化表征模型。多尺度非均匀背景的散射场一般由地表大尺度表面所产生的镜反射分量、大尺度表面几何不连续处所产生的绕射分量和地表小尺度粗糙面引起的漫散射分量共同组成。传统雷达目标散射中心建模采用分布型、局部型和滑动型散射中心模型(scattering center model, SCM)表征目标的反射和绕射散射;但是,传统散射中心表征形式仅能描述大尺度光滑表面、几何不连续处的散射场,无法描述小尺度粗糙面的散射效应。本文结合粗糙面的相干-非相干散射理论,在大尺度地形散射中心表征模型的基础上,利用相干模型修正小尺度粗糙面对大尺度表面散射场幅度的影响;利用双向反射分布函数(bidirectional reflectance distribution function, BRDF)建立非相干散射的参数化表征形式。对两种非均匀多尺度背景的散射特性进行参数化表征,并采用商业软件高频求解器对计算结果的精度和效率进行了校验,证明了粗糙背景散射中心参数化建模方法的可行性。
