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Assessment of Super Absorbent Polymer (SAP) on Plant Available Water (PAW) in Dry Lands
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作者 Vincent Ng’eno Christian Omuto +1 位作者 Duncan Mbuge Vitalis Too 《Engineering(科研)》 CAS 2023年第2期90-105,共16页
One of the ways of overcoming the cost of irrigation is through in-situ water harvesting at the plant roots. Super absorbent polymer (SAP) can facilitate water harvesting at the plant roots. This study attempted to as... One of the ways of overcoming the cost of irrigation is through in-situ water harvesting at the plant roots. Super absorbent polymer (SAP) can facilitate water harvesting at the plant roots. This study attempted to assess the effect of SAP on plant available water (PAW) of different soils. In this study, SAP was sequentially added at the rate of 0.2%, 0.3% and 0.5% of the soil weight and its impact assessed in clay, sandy clay and sandy loam soils. The moisture retention characteristics of the original and SAP treated soils were studied using soil water retention curves (SWRC) and results modelled using Gardner model. PAW was estimated from SWRC as the difference between moisture content at 1.5 and 3 bar in all soils. The difference in PAW between original and treated soils was assessed at 5% level of significance. The WRC of all the samples was adequately found to be described by the Gardner model (Coefficient of determination R<sup>2</sup> ≥ 98% and residual standard error (RSE) ≤ 0.04). SWRC changed with increase in SAP percentage in clay, sandy clay and sandy loam soils. Clay had a higher change in water retention then sandy clay and lastly sandy loam. Plant available water content (PAW) in all soils increased. In clay soil it increased with increase in SAP from 0.3291 at zero SAP to 0.6223 at 0.5% SAP. Sandy clay soil increased in PAW from 0.2721 at zero SAP to 0.5335 at 0.5% SAP and Sandy loam soils from 0.1691 at zero SAP to 0.3461 at 0.5% SAP. Hence, from the study SAP can be used to conserve irrigation water in the plant roots and therefore reducing the cost since PAW has been increased. 展开更多
关键词 Plant Available Water (PAW) Soil Water Retention Curve (SWRC) SOIL Super Absorbent polymer (sap)
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Fabric changes induced by super-absorbent polymer on cementelime stabilized excavated clayey soil 被引量:7
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作者 Xia Bian Lingling Zeng +3 位作者 Xiaozhao Li Xiusong Shi Shuming Zhou Fuqing Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2021年第5期1124-1135,共12页
This paper studies the microstructure variation induced by super-absorbent polymer(SAP)to understand the mechanism of macroscopic strength improvement of stabilized soil.The fabric changes of cement elime stabilized s... This paper studies the microstructure variation induced by super-absorbent polymer(SAP)to understand the mechanism of macroscopic strength improvement of stabilized soil.The fabric changes of cement elime stabilized soil were analyzed with respect to the variation of SAP content,water content,lime content and curing time,using mercury intrusion porosimetry(MIP)tests.It can be observed that the delimitation pore diameter between inter-and intra-aggregate pores was 0.2 mm for the studied soil,determined through the intrusion/extrusion cycles.Experimental results showed that fabric in both inter-and intra-aggregate pores varied significantly with SAP content,lime content,water content and curing time.Two main changes in fabric due to SAP are identified as:(1)an increase in intra-aggregate pores(<0.2 mm)due to the closer soilecementelime cluster space at higher SAP content;and(2)a decrease in inter-aggregate pores represented by a reduction in small-pores(0.2e2 mm)due to the lower pore volume of soil mixture after water absorption by SAP,and a slight increase in large-pores(>2 mm)due to the shrinkage of SAP particle during the freezeedry process of MIP test.Accordingly,the strength gain due to SAP for cementelime stabilized soil was mainly due to a denser fabric with less interaggregate pores.The cementitious products gradually developed over time,leading to an increase in intra-aggregate pores with an increasing proportion of micro-pores(0.006e0.2 mm).Meanwhile,the inter-aggregate pores were filled by cementitious products,resulting in a decrease in total void ratio.Hence,the strength development over time is attributable to the enhancement of cementation bonding and the refinement of fabric due to the increasing cementitious compounds. 展开更多
关键词 FABRIC Soil stabilization Microstructure Super-absorbent polymer(sap)
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Effect of SAP on Properties of High Performance Concrete under Marine Wetting and Drying Cycles 被引量:4
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作者 Ouattara Coumoin Cherel WANG Fazhou +1 位作者 YANG Jin LIU Zhichao 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2019年第5期1136-1142,共7页
The internal curing effect of superabsorbent polymer(SAP) on the properties of high performance concrete(HPC) under marine wetting and drying cycles(WD cycles) was investigated. Compressive strength, hydration and chl... The internal curing effect of superabsorbent polymer(SAP) on the properties of high performance concrete(HPC) under marine wetting and drying cycles(WD cycles) was investigated. Compressive strength, hydration and chloride migration were experimentally investigated and the results were evaluated by compasison with those under fresh water curing(FW). Water absorption and porosity were also evaluated only under WD cycles. The results showed the important influence of wetting and drying cycles on the properties of SAP modified HPC properties. Carefully designed, SAP minimized the long-term compressive strength of HPC under marine WD cycles. The hydration rate was faster in the initial curing, but became lower as compared with that cured in FW. In addition, SAP improved the long-term water absorption resistance and chloride migration resistance of HPC under marine WD cycles. The examination of the porosity showed a lower increase of the volume of capillary pores in SAP modified HPC under long term WD cycles compared with that without SAP. Therefore, internal curing by SAP could improve the durability properties of HPC under marine WD cycles. 展开更多
关键词 SUPERABSORBENT polymer(sap) high performance concrete WETTING and DRYING cycles internal CURING
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Effects of superabsorbent polymer particles on flexural properties and self-healing behavior of ECC 被引量:5
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作者 Deng Hanwen 《Journal of Southeast University(English Edition)》 EI CAS 2018年第1期95-103,共9页
In order to improve the self-healing behavior and the recovery of mechanical properties of engineered cementitious composites(ECC),the approach of incorporating superabsorbent polymer(SAP)in mixtures is investigated.T... In order to improve the self-healing behavior and the recovery of mechanical properties of engineered cementitious composites(ECC),the approach of incorporating superabsorbent polymer(SAP)in mixtures is investigated.The rapid water penetration test and four-point bending test were conducted to evaluate the effects of self-healing on the water permeability and mechanical properties of pre-damaged ECC.The self-healing process and self-healing products were observed by the environment scanning electron microscope(ESEM)and energy dispersive X-ray spectroscopy(EDS).The experimental results show that all ECC mixtures exhibit excellent flexural capacity,meanwhile maintaining a crack width below 50μm.The incorporation of SAP particles in ECC can apparently improve the mechanical recovery of ECC mixtures after 10 healing curing cycles,such as flexural deformation and flexural stiffness.The flexural stiffness of ECC containing 4%SAP particles after self-healing can be recovered to 80%.The self-healing test results show that when the water permeability of ECC mixtures incorporating SAP particles is close to zero,only three healing cycles are needed.When ECC incorpora ting more SAP particles,the accelerated self-healing process can be finished in the first three cycles,and self-healing product is mixed Ca(OH)2/CaCO 3 with CaCO 3 being a major component in the later stage.It is,therefore,feasible to produce ECC materials incorporating SAP particles,while simultaneously maintaining higher material ductility and self-healing behavior. 展开更多
关键词 engineered cementitious composites(ECC) SELF-HEALING superabsorbent polymer(sap) mechanical property
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Effects of different concentrations of super-absorbent polymers on soil structure and hydro-physical properties following continuous wetting and drying cycles 被引量:1
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作者 JI Bing-yi ZHAO Chi-peng +3 位作者 WU Yue HAN Wei SONG Ji-qing BAI Wen-bo 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2022年第11期3368-3381,共14页
Super-absorbent polymers(SAPs)are widely used chemical water-saving materials,which play an active role in the accumulation of soil water and the improvement of soil structure.Little is known about their performance w... Super-absorbent polymers(SAPs)are widely used chemical water-saving materials,which play an active role in the accumulation of soil water and the improvement of soil structure.Little is known about their performance with repeated usage or about factors influencing their efficiency under alternate wetting and drying cycles.In this study,various concentrations of SAP(0,0.1,0.2 and 0.3%)in soil following three continuous wetting and drying cycles(T1,T2 and T3),were studied to determine effects on soil structure stability and hydro-physical properties.The results indicated that the SAP improved soil water supply capacity under conditions of mild drought(T2)and sufficient irrigation(T3)at concentrations of 0.2 and 0.3%,but a reduction was observed under severe drought conditions(T1),which was negatively correlated with the SAP concentration.The physical adsorption of the SAP by soil and the chemical connection between the SAP and soil mineral colloids as Si-O-Si bonds,-OH bonds and different crystalline silica were the important factors that directly lead to the reduction of water retention capacities of the SAP with alternating wet and dry conditions.Compared with the control,the soil liquid phase ratios of the SAP treatments were increased by8.8-202.7%in the T1 and T2 cycles,which would have led to a decrease in the soil air phase ratios.After repeated wetting and drying cycles,the SAP treatments increased the amount of>0.25 mm soil aggregates and the contents of water-stable macro-aggregate(R_(0.25)),and decreased the amount of<0.053 mm soil aggregates,especially with higher concentrations of the SAP.Increases in mean weight diameter(MWD)and geometric mean diameter(GMD),and declines in fractal dimension(D)and unstable aggregates index(E_(LT))were all observed with the SAP treatments,which indicated an improvement in soil stability and structure.It was concluded that the distribution and stability of soil aggregates and soil water supply capacity was closely related to SAP concentration,soil moisture condition and the interaction between the SAP and soil particles. 展开更多
关键词 super-absorbent polymer(sap) soil water soil structure soil aggregate soil colloid
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Super absorbent fiber: 200:1 water absorption ratio
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作者 Zhao Xinhua 《China Textile》 2025年第3期19-19,共1页
In today's era of continuous advancement in materials science,the properties of materials are constantly being enhanced,and their application fields are also expanding continuously.SAF(Super Absorbent Fiber),one s... In today's era of continuous advancement in materials science,the properties of materials are constantly being enhanced,and their application fields are also expanding continuously.SAF(Super Absorbent Fiber),one such material,stands out.Compared to traditional SAP(Super Absorbent Polymer),SAF boasts a unique fibrous form and exceptional performance,presenting broad application prospects. 展开更多
关键词 materials science fibrous form super absorbent fiber sap super absorbent polymer saf super absorbent polymer performance absorbent fiber one water absorption ratio
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岩藻多糖生物保水剂的合成及应用研究
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作者 熊国美 林俊健 +4 位作者 王思瑶 许志敏 顾红艳 常可鑫 彭红波 《华南农业大学学报》 北大核心 2025年第4期509-519,共11页
【目的】以富含L-岩藻糖和硫酸基等亲水结构的天然岩藻多糖为原料合成保水剂,以期提高保水剂的降解和可再生能力。【方法】以过硫酸铵(Ammonium persulfate,APS)为引发剂,N,N′-亚甲基双丙烯酰胺(N,N'-Methylenebis acrylamide,MBA... 【目的】以富含L-岩藻糖和硫酸基等亲水结构的天然岩藻多糖为原料合成保水剂,以期提高保水剂的降解和可再生能力。【方法】以过硫酸铵(Ammonium persulfate,APS)为引发剂,N,N′-亚甲基双丙烯酰胺(N,N'-Methylenebis acrylamide,MBA)为交联剂,采用水溶液聚合技术将天然岩藻多糖接枝在丙烯酸(Arylic acid,AA)上进行共聚反应合成岩藻多糖生物保水剂。通过单因素试验优化产品制备工艺。采用傅里叶变换红外光谱仪(Fourier-transform infrared spectroscopy,FT-IR)和扫描电子显微镜(Scanning electron microscope,SEM)表征产物;通过盆栽试验检测保水剂对白菜生长的影响。【结果】岩藻多糖和AA的最佳质量比为1.0∶7.5,中和度为70%,APS和MBA用量分别为AA质量的3.0%和0.2%。SEM结果表明,产物具有多孔疏松的网状结构;FTIR分析表明,产物为岩藻多糖与AA的接枝共聚物。保水剂在去离子水、9 g·L^(-1)NaCl溶液中吸水倍率分别为420.9和63.8 g·g^(-1);且在重复吸水、干燥6次后,吸水倍率仍为初始的70.8%。此外,每千克土壤中添加6 g保水剂的白菜生长状况最佳,植株总生物量显著增加105.5%,土壤含水量提高8.98%(P<0.05)。【结论】岩藻多糖生物保水剂吸水和重复使用性能良好,在土壤中添加该保水剂能够显著促进植物生长。该研究为藻类保水剂的研发及其在农业中的推广应用提供了基础数据。 展开更多
关键词 岩藻多糖 保水剂 岩藻多糖生物保水剂 吸水性能 水溶液聚合技术
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淀粉接枝共聚丙烯酸型超强吸水剂的快速合成研究 被引量:10
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作者 曹宏梅 陆钊 赖红伟 《吉林化工学院学报》 CAS 2007年第3期23-26,共4页
用过硫酸钾为引发剂,N,N′-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合方法,使淀粉接枝共聚丙烯酸(单体)经一步快速合成出固体超强吸水剂.考察了交联剂用量、引发剂用量、单体中和度、淀粉的用量及其理化状态、共聚合温度等对产品的吸水... 用过硫酸钾为引发剂,N,N′-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合方法,使淀粉接枝共聚丙烯酸(单体)经一步快速合成出固体超强吸水剂.考察了交联剂用量、引发剂用量、单体中和度、淀粉的用量及其理化状态、共聚合温度等对产品的吸水率的影响.结果表明,当淀粉的用量为26%,交联剂用量为0.06%(占丙烯酸单体的质量分数),引发剂的用量为0.08%,丙烯酸的中和度为48%(丙烯酸占丙烯酸钠的摩尔分数)时,该吸水剂在1 min内可完全吸水膨胀,吸蒸馏水率最大为1300 mL/g,且具有优良的保水性能. 展开更多
关键词 淀粉 丙烯酸 接枝聚合 超强吸水剂
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多孔型高吸水树脂对水泥净浆流动性能的影响 被引量:9
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作者 李婉文 赖俊英 +2 位作者 林学智 钱匡亮 钱晓倩 《建筑材料学报》 EI CAS CSCD 北大核心 2022年第2期171-177,共7页
为稳定掺入高吸水树脂(SAP)水泥基材料的流动性能,采用反相悬浮聚合法制备了多孔型聚丙烯酸/丙烯酰胺SAP.利用扫描电子显微镜(SEM)观测SAP的微观形貌,通过傅里叶红外光谱(FTIR)分析SAP的分子结构,用“茶袋法”测试SAP的吸液性能,并通过... 为稳定掺入高吸水树脂(SAP)水泥基材料的流动性能,采用反相悬浮聚合法制备了多孔型聚丙烯酸/丙烯酰胺SAP.利用扫描电子显微镜(SEM)观测SAP的微观形貌,通过傅里叶红外光谱(FTIR)分析SAP的分子结构,用“茶袋法”测试SAP的吸液性能,并通过流动度试验研究了非多孔型及多孔型SAP对水泥净浆流动度经时变化的影响.结果表明:多孔型SAP具有微米级连通孔结构,能够有效促进吸水速率,达到吸水平衡只需1 min内;当通过额外引水保持水泥净浆初始流动度相同时,多孔型SAP的掺入对水泥净浆流动度的经时损失影响最小. 展开更多
关键词 水泥净浆 反向悬浮聚合 高吸水树脂 多孔型 流动性能
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反相乳液聚合法制备P(AA-AMPS)高吸水树脂的合成及其性能结构研究 被引量:4
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作者 李振华 郭三维 《广东化工》 CAS 2013年第22期35-36,48,共3页
文章以2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、丙烯酸(AA)为共聚功能单体,过硫酸钾(KPS),过氧化苯甲酰(BPO)为引发剂,聚乙二醇双丙烯酸酯(PEGDA)(Mw=700)为交联剂,以Span-60,Triton X-100为复配乳化剂,通过反相乳液聚合法制备两性离子型高... 文章以2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、丙烯酸(AA)为共聚功能单体,过硫酸钾(KPS),过氧化苯甲酰(BPO)为引发剂,聚乙二醇双丙烯酸酯(PEGDA)(Mw=700)为交联剂,以Span-60,Triton X-100为复配乳化剂,通过反相乳液聚合法制备两性离子型高吸水树脂,研究了SAP的合成条件,详细探讨了聚合过程中各种因素对SAP性能的影响,SAP结构与性能的关系等。 展开更多
关键词 反相乳液聚合 高吸水树脂 吸水倍率 耐盐性 结构
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废弃木材纤维制备高吸水树脂研究 被引量:6
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作者 杨永启 目仁更 +4 位作者 杜帅 闫友军 宋继梅 张英超 高辉玉 《广东化工》 CAS 2020年第17期32-34,共3页
本论文以废弃木材纤维为原料,经粉碎、浸泡,氢氧化钠碱化、氯乙酸醚化处理,烘干后得到水溶性大大增强的羧甲基纤维素。然后以此为母体,以丙烯酸和丙烯酸钠为单体,以过硫酸钾为引发剂,以N,N’亚甲基双丙烯酰胺为交联剂,在高温下发生接枝... 本论文以废弃木材纤维为原料,经粉碎、浸泡,氢氧化钠碱化、氯乙酸醚化处理,烘干后得到水溶性大大增强的羧甲基纤维素。然后以此为母体,以丙烯酸和丙烯酸钠为单体,以过硫酸钾为引发剂,以N,N’亚甲基双丙烯酰胺为交联剂,在高温下发生接枝聚合反应制备高吸水树脂。制备过程进行了单因素变量实验,在此基础上筛选条件进行了正交实验探究,得出最佳原料质量比为:羧甲基纤维素质量∶丙烯酸质量∶氢氧化钠质量∶交联剂质量∶引发剂的质量=1∶6∶2∶0.021∶0.042,其最大吸水率可达2535 g/g。实验证明本论文制备的高吸水树脂吸水率高,性能优良。 展开更多
关键词 高吸水树脂 木材纤维 羧甲基纤维素 接枝聚合 吸水性能
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高吸水树脂的合成
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作者 邹凌凯 《福建建筑》 2015年第8期101-103,共3页
高吸水树脂(SAP)是一种具有优异的吸水性和保水性的新型高分子材料。采用水溶液聚合法合成高吸水树脂,实验结果表明,不同的聚合反应温度、交联剂、引发剂的用量和单体浓度直接影响高吸水树脂的产品性能指标,优化后合成的高吸水树脂吸水... 高吸水树脂(SAP)是一种具有优异的吸水性和保水性的新型高分子材料。采用水溶液聚合法合成高吸水树脂,实验结果表明,不同的聚合反应温度、交联剂、引发剂的用量和单体浓度直接影响高吸水树脂的产品性能指标,优化后合成的高吸水树脂吸水性能可以达到510g/g。 展开更多
关键词 高吸水树脂 聚合反应 引发剂 交联剂 吸水性能
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