沥青混合料的黏弹性性能与温度、时间及其胶结料的状态等参数密切相关,而在路面的使用过程中沥青容易受到老化的影响,进一步影响沥青混合料的黏弹性性能。为了让路面设计过程中的参数更为具体,在实验室内对不同老化状态下的SBS改性沥青...沥青混合料的黏弹性性能与温度、时间及其胶结料的状态等参数密切相关,而在路面的使用过程中沥青容易受到老化的影响,进一步影响沥青混合料的黏弹性性能。为了让路面设计过程中的参数更为具体,在实验室内对不同老化状态下的SBS改性沥青混合料进行多个频率及温度下的单轴动态模量试验。采用William, Landel and Ferry(WLF)公式对不同温度下的频率进行时温等效转换,然后基于分数阶模型(2S2P1D模型)建立了动态模量及相位角主曲线,分析老化对沥青混合料黏弹性能的影响特征。研究结果表明:2S2P1D模型能够较好地拟合不同老化状态下的SBS改性沥青混合料的动态模量的数据,相关系数大于0.9;沥青混合料的2S2P1D模型中的玻璃态模量Eg和与粘度相关的β参数随着老化程度的增加显著增大。然而,静态模量E0、分数阶指数k及h随着老化程度的增加而减小。基于该模型建立的储存模量及损失模量的主曲线表明:低频时老化对于沥青混合料的储存模量及损失模量具有不同的影响,当频率趋近于0时,老化对储存模量的影响基本不存在,但是随着老化程度的加深损失模量会显著增强。展开更多
Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices.This work successfully synthesized a new thiophosphate phase ofβ-Pb_(3)P_(2)S_(8)thr...Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices.This work successfully synthesized a new thiophosphate phase ofβ-Pb_(3)P_(2)S_(8)through the high-temperature solid-state spontaneous crystallization method.Different from the cubicα-Pb_(3)P_(2)S_(8),theβ-Pb_(3)P_(2)S_(8)crystallizes in the orthorhombic Pbcn space group.Notably,β-Pb_(3)P_(2)S_(8)shows a large band gap of 2.37 e V in lead-based chalcogenides,wide infrared transparent window(2.5-15μm),and excellent thermal stability.Importantly,the experimental birefringence shows the largest value of0.26@550 nm in chalcogenides,even larger than the commercialized oxide materials.The Barder charge analysis result indicates that the exceptional birefringence effect is mainly from the Pb^(2+)and S^(2-)in the[Pb S_n]polyhedrons.Meanwhile,the parallelly arranged polyhedral layers could improve the structural anisotropic.Therefore,this work supports a new method for designing chalcogenides with exceptional birefringence effect in the infrared region.展开更多
The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle dif...The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle diffraction method.The crystal belongs to triclinic,space group Pi,crystal cell parameters:a=9 009(2),b=10 437(2),c=18 858(4)?,α=80 99(3),β=88 55(3),γ=82 01(3)°,V=1734 3(6)? 3,Z=2,Mr=698 7,Dc=1 338g·cm -3 ,μ=1 022mm -1 ,F(000)=732,R=0 0342,Rw=0 0812.The structural analysis showed that six sulfur atoms from three ligands 〔S 2P(O- i -C 3H 7) 2〕 coordinate with a cobalt atom,CoS 6 framework in molecular stucture approximately octahedral.The complex was also characterized by IR? 1H NMR? 31 P NMR and MS.展开更多
文摘沥青混合料的黏弹性性能与温度、时间及其胶结料的状态等参数密切相关,而在路面的使用过程中沥青容易受到老化的影响,进一步影响沥青混合料的黏弹性性能。为了让路面设计过程中的参数更为具体,在实验室内对不同老化状态下的SBS改性沥青混合料进行多个频率及温度下的单轴动态模量试验。采用William, Landel and Ferry(WLF)公式对不同温度下的频率进行时温等效转换,然后基于分数阶模型(2S2P1D模型)建立了动态模量及相位角主曲线,分析老化对沥青混合料黏弹性能的影响特征。研究结果表明:2S2P1D模型能够较好地拟合不同老化状态下的SBS改性沥青混合料的动态模量的数据,相关系数大于0.9;沥青混合料的2S2P1D模型中的玻璃态模量Eg和与粘度相关的β参数随着老化程度的增加显著增大。然而,静态模量E0、分数阶指数k及h随着老化程度的增加而减小。基于该模型建立的储存模量及损失模量的主曲线表明:低频时老化对于沥青混合料的储存模量及损失模量具有不同的影响,当频率趋近于0时,老化对储存模量的影响基本不存在,但是随着老化程度的加深损失模量会显著增强。
基金supported in part by the National Natural Science Foundation of China(No.52102218)the National Key Research and Development Program of China(No.2020YFA0710303)+2 种基金the Fujian Science&Technology Innovation Laboratory for Op-toelectronic Information of China(No.2021ZZ127)the Minjiang Scholar Professorship(No.GXRC-21004)the Natural Science Foundation of Fujian Province of China(No.2021J01594)。
文摘Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices.This work successfully synthesized a new thiophosphate phase ofβ-Pb_(3)P_(2)S_(8)through the high-temperature solid-state spontaneous crystallization method.Different from the cubicα-Pb_(3)P_(2)S_(8),theβ-Pb_(3)P_(2)S_(8)crystallizes in the orthorhombic Pbcn space group.Notably,β-Pb_(3)P_(2)S_(8)shows a large band gap of 2.37 e V in lead-based chalcogenides,wide infrared transparent window(2.5-15μm),and excellent thermal stability.Importantly,the experimental birefringence shows the largest value of0.26@550 nm in chalcogenides,even larger than the commercialized oxide materials.The Barder charge analysis result indicates that the exceptional birefringence effect is mainly from the Pb^(2+)and S^(2-)in the[Pb S_n]polyhedrons.Meanwhile,the parallelly arranged polyhedral layers could improve the structural anisotropic.Therefore,this work supports a new method for designing chalcogenides with exceptional birefringence effect in the infrared region.
文摘The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle diffraction method.The crystal belongs to triclinic,space group Pi,crystal cell parameters:a=9 009(2),b=10 437(2),c=18 858(4)?,α=80 99(3),β=88 55(3),γ=82 01(3)°,V=1734 3(6)? 3,Z=2,Mr=698 7,Dc=1 338g·cm -3 ,μ=1 022mm -1 ,F(000)=732,R=0 0342,Rw=0 0812.The structural analysis showed that six sulfur atoms from three ligands 〔S 2P(O- i -C 3H 7) 2〕 coordinate with a cobalt atom,CoS 6 framework in molecular stucture approximately octahedral.The complex was also characterized by IR? 1H NMR? 31 P NMR and MS.
