为强化三维电极生物膜(3DBER)工艺深度脱氮除磷性能,提高污水厂尾水质量,将硫磺和海绵铁作为混合填料,构建硫铁复合填料三维电极生物膜(3DBER-S-Fe)脱氮除磷工艺;在不同ρ(C)/ρ(N)、I和水力停留时间(HRT)运行条件下,探究工艺深度脱氮...为强化三维电极生物膜(3DBER)工艺深度脱氮除磷性能,提高污水厂尾水质量,将硫磺和海绵铁作为混合填料,构建硫铁复合填料三维电极生物膜(3DBER-S-Fe)脱氮除磷工艺;在不同ρ(C)/ρ(N)、I和水力停留时间(HRT)运行条件下,探究工艺深度脱氮除磷效果.分别从反应器填料和阴极上取生物膜,通过Miseq高通量测序,构建细菌16S rRNA基因克隆文库.结果表明:在运行条件为ρ(C)/ρ(N)=2、I=150 m A和HRT=4 h时,3DBER-SFe对总氮和总磷的去除率分别可达85.59%和97.43%;适当增加ρ(C)/ρ(N)、I和HRT均能不同程度提高系统脱氮除磷效率.在填料和阴极上丰度最大的均为具有硫自养反硝化功能的Thiobacillus,分别占40.62%和44.75%;具有氢自养反硝化功能的Rhodocyclaceae在阴极的分布明显多于填料.因此,3DBER-S-Fe具有较高的脱氮性能主要是硫自养反硝化和氢自养反硝化共同作用的结果,且氢自养反硝化过程主要发生在阴极.展开更多
There are a wide range of magmatism and mineralization in the Yunkai area of South China during the Late Yanshanian Period, including the newly discovered Michang, Youmapo, Sanchaehong and Songwang porphyry-skarn W-Mo...There are a wide range of magmatism and mineralization in the Yunkai area of South China during the Late Yanshanian Period, including the newly discovered Michang, Youmapo, Sanchaehong and Songwang porphyry-skarn W-Mo deposits. In this study, we obtained zircon U-Pb ages of the ore-bearing biotite granites and their mafic enclaves from 884-1 to 1104-1 Ma. Zircons from the granites show Hf isotopic compositions with negative C-Hf（t） values of -5.9 to -0.6 and calculated Hf model ages （TvM2） of 1.5-1.2 Ga; indicating that the Middle Proterozoic crustal materials may have provided an important source for the magmatic rocks in this district during the Late Yanshanian Period, whereas zircons from the mafic enclaves show positive era（t） values of 1.3 to 10.1 with younger Hf model ages （TDM2） of 0.5-1.1 Ga, suggesting a mantle component may have involved in the granitic magma generation. Sulfur isotope study of the sulfide minerals from the W-Mo deposits show a narrow 834S distribution with most data ranging from -4.2%0 to 5.2‰. In addition, this study reports the first Fe isotopic compositions of pyrite in the W-Mo deposits, which show a uniform distribution range with the values near zero （656Fe=0.16‰-0.58‰, average 0.35‰; 657Fe=0.02‰-0.54‰, average 0.48‰）. These data indicate that the ore-forming materials may come from the deep-sourced granitic magma, and the mineralizations show a close relationship with the granitic magmatism during the Late Yanshanian Period. Combining with previous results, we suggest that there is a widespread porphyry-skarn W-Mo mineralization in the Yunkai area during the Late Cretaceous （80-110 Ma）, which has a close relationship with the Late Yanshanian magmatism that may have formed during the rollback of the subducted Pacific Plate.展开更多
The destruction of hydrocarbon in deep carbonate diagenetic environment is one of problems on the formation of oil and gas. Organic-inorganic reactions in the process of TSR(Thermochemical Sulfate Reduction) are the m...The destruction of hydrocarbon in deep carbonate diagenetic environment is one of problems on the formation of oil and gas. Organic-inorganic reactions in the process of TSR(Thermochemical Sulfate Reduction) are the main reason to make disappearance of the hydrocarbons. The work in this field has often been the subject of much research work in recent years. In this paper, the thermodynamics of CH4-CaSO4 and H2S-Fe2O3 systems is discussed to investigate the possibility of reactions. It is found that these two reactions can proceed spontaneously.Increasing temperature is favorite for CH4-CaSO4 system but disfavorite for H2S-Fe2O3 system. Thermal simulation experiments were carried out using autoclave at high temperature and high pressure. The properties of the products were characterized by microcoulometry, FT-IR and XRD methods. On the basis of the experimental data, a reaction kinetic model is developed and kinetic parameters are determined.展开更多
The evaporation kinetics of SnS from SnSCu2SFeS teruary system was investigated against matte grade, tetnperature and carrier gas flow rate. It was demonstrated that the evapomtion process is controlled by gas-phase m...The evaporation kinetics of SnS from SnSCu2SFeS teruary system was investigated against matte grade, tetnperature and carrier gas flow rate. It was demonstrated that the evapomtion process is controlled by gas-phase mass transport. The increases of the flow rote of carrier gas and the temperature could increase the gas-phase mass transport coefficient and the Partial pressure of SnS over the melts, respectively, and hence would appreciably promote the evaporation process. An increase of matte grade could lower the activitv coefficient of SnS in the melts, which in turn would cause the reduction of the evapomtion rate of SnS展开更多
文摘为强化三维电极生物膜(3DBER)工艺深度脱氮除磷性能,提高污水厂尾水质量,将硫磺和海绵铁作为混合填料,构建硫铁复合填料三维电极生物膜(3DBER-S-Fe)脱氮除磷工艺;在不同ρ(C)/ρ(N)、I和水力停留时间(HRT)运行条件下,探究工艺深度脱氮除磷效果.分别从反应器填料和阴极上取生物膜,通过Miseq高通量测序,构建细菌16S rRNA基因克隆文库.结果表明:在运行条件为ρ(C)/ρ(N)=2、I=150 m A和HRT=4 h时,3DBER-SFe对总氮和总磷的去除率分别可达85.59%和97.43%;适当增加ρ(C)/ρ(N)、I和HRT均能不同程度提高系统脱氮除磷效率.在填料和阴极上丰度最大的均为具有硫自养反硝化功能的Thiobacillus,分别占40.62%和44.75%;具有氢自养反硝化功能的Rhodocyclaceae在阴极的分布明显多于填料.因此,3DBER-S-Fe具有较高的脱氮性能主要是硫自养反硝化和氢自养反硝化共同作用的结果,且氢自养反硝化过程主要发生在阴极.
基金supported by the Fundamental Research Funds for the Central Universities (No. CUG120702)
文摘There are a wide range of magmatism and mineralization in the Yunkai area of South China during the Late Yanshanian Period, including the newly discovered Michang, Youmapo, Sanchaehong and Songwang porphyry-skarn W-Mo deposits. In this study, we obtained zircon U-Pb ages of the ore-bearing biotite granites and their mafic enclaves from 884-1 to 1104-1 Ma. Zircons from the granites show Hf isotopic compositions with negative C-Hf（t） values of -5.9 to -0.6 and calculated Hf model ages （TvM2） of 1.5-1.2 Ga; indicating that the Middle Proterozoic crustal materials may have provided an important source for the magmatic rocks in this district during the Late Yanshanian Period, whereas zircons from the mafic enclaves show positive era（t） values of 1.3 to 10.1 with younger Hf model ages （TDM2） of 0.5-1.1 Ga, suggesting a mantle component may have involved in the granitic magma generation. Sulfur isotope study of the sulfide minerals from the W-Mo deposits show a narrow 834S distribution with most data ranging from -4.2%0 to 5.2‰. In addition, this study reports the first Fe isotopic compositions of pyrite in the W-Mo deposits, which show a uniform distribution range with the values near zero （656Fe=0.16‰-0.58‰, average 0.35‰; 657Fe=0.02‰-0.54‰, average 0.48‰）. These data indicate that the ore-forming materials may come from the deep-sourced granitic magma, and the mineralizations show a close relationship with the granitic magmatism during the Late Yanshanian Period. Combining with previous results, we suggest that there is a widespread porphyry-skarn W-Mo mineralization in the Yunkai area during the Late Cretaceous （80-110 Ma）, which has a close relationship with the Late Yanshanian magmatism that may have formed during the rollback of the subducted Pacific Plate.
基金Supported by the National Natural Science Foundation of China (No.40172047) and National Major Fundamental Research & Development Project(No.G19990433)
文摘The destruction of hydrocarbon in deep carbonate diagenetic environment is one of problems on the formation of oil and gas. Organic-inorganic reactions in the process of TSR(Thermochemical Sulfate Reduction) are the main reason to make disappearance of the hydrocarbons. The work in this field has often been the subject of much research work in recent years. In this paper, the thermodynamics of CH4-CaSO4 and H2S-Fe2O3 systems is discussed to investigate the possibility of reactions. It is found that these two reactions can proceed spontaneously.Increasing temperature is favorite for CH4-CaSO4 system but disfavorite for H2S-Fe2O3 system. Thermal simulation experiments were carried out using autoclave at high temperature and high pressure. The properties of the products were characterized by microcoulometry, FT-IR and XRD methods. On the basis of the experimental data, a reaction kinetic model is developed and kinetic parameters are determined.
文摘The evaporation kinetics of SnS from SnSCu2SFeS teruary system was investigated against matte grade, tetnperature and carrier gas flow rate. It was demonstrated that the evapomtion process is controlled by gas-phase mass transport. The increases of the flow rote of carrier gas and the temperature could increase the gas-phase mass transport coefficient and the Partial pressure of SnS over the melts, respectively, and hence would appreciably promote the evaporation process. An increase of matte grade could lower the activitv coefficient of SnS in the melts, which in turn would cause the reduction of the evapomtion rate of SnS
