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Effects of Wax-Based Surfactant on the Quantification of Chemical Properties, Rheological, and Activation Energy of Cup Lump Rubber Modified Asphalt Binder
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作者 Zainiah Mohd Zin Mohd Rosli Mohd Hasan +3 位作者 Azura A.Rashid Muhammad Munsif Ahmad Mohd Fahmi Haikal Mohd Ghazali Hui Yao 《Journal of Polymer Materials》 2026年第1期371-391,共21页
The rapid increase in traffic loads and frequencies has rendered conventional asphalt pavement inadequate to maintain its durability under tropical climates.This challenge has necessitated the exploration of new sourc... The rapid increase in traffic loads and frequencies has rendered conventional asphalt pavement inadequate to maintain its durability under tropical climates.This challenge has necessitated the exploration of new sources of modified asphalt with enhanced stiffness and superior performance at high temperatures.Natural rubber(NR)is a renewable biopolymer that has received growing interest as a modifier for asphalt binders.Cup lump rubber(CLR),a type of NR,is used to enhance asphalt properties and improve the performance of road pavements.This study evaluates the influence of wax-based surfactants(WS)on CLR-modified asphalt binder(CMB).The assessment focuses on changes in chemical characteristics,rheological behaviour,activation energy,and morphology.Four concentrations of WS(0.1%,0.15%,0.2%,and 0.25%)were incorporated into CMB.Analysis of CMB chemical changes showed that viscosity increased due to higher sulfoxide,carbonyl,and aromatic bond indices.These chemical modifications contributed to improved resistance of the binder to heat-induced deterioration.In both unaged and aged CMB samples,the incorporation of WS reduced the sulfoxide index of the binder.Rheological analysis indicated that CMB improved rutting resistance and anti-ageing performance,while WS further enhanced fatigue resistance.Activation energy analysis suggested that the combination of CMB with 0.15%WS produced the most favourable enhancement.Micrograph results showed that WS improved binder homogeneity and interconnectivity.In conclusion,the findings indicated that incorporating 0.15%WS into CMB enhanced the performance and durability of the asphalt pavement. 展开更多
关键词 Bitumen cup lump rubber modified asphalt binder wax-based surfactant RUTTING fatigue chemical properties
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Comparative performance evaluation of asphalt binder modified with high-content pretreated crumb rubber and various additives
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作者 Abul Khair Liyang Wang +4 位作者 Hui Li Yuzhao Han Zhijie Lin Yang Sun Haopeng Zhang 《Journal of Road Engineering》 2026年第1期108-121,共14页
The addition of high-content crumb rubber(HCCR)in asphalt can effectively address waste tire pollution and provide sustainable environmental and economic advantages.However,the practical application of conventional ru... The addition of high-content crumb rubber(HCCR)in asphalt can effectively address waste tire pollution and provide sustainable environmental and economic advantages.However,the practical application of conventional rubberized binders is significantly limited by high viscosity and poor storage stability.To address these issues,researchers have pretreated crumb rubber(CR)with oil,but high-temperature performance remains insufficient.Therefore,this study aimed to optimize the viscosity,storage stability,and rheological properties of high-content crumb rubber-modified asphalt(HCCRMA)by varying the pretreatment levels of CR and incorporating various additives,including styrene-butadiene-styrene(SBS),deoiled asphalt(DA),or recycled low-density polyethylene(RLDPE).In addition,CR was pretreated with waste cooking oil(WCO)at various ratios,pre-swelling temperatures,and times.The results show that DA exhibits excellent storage stability and lower viscosity compared with other modifiers in HCCRMA,and the 4%RLDPE with pretreated HCCR has the greatest high-temperature rutting resistance.The inclusion of RLDPE increases the stiffness and elasticity of the modified asphalt,which results in greater high-temperature performance.Additionally,the fluorescence microscopy(FM)test confirms that SBS exhibits better dispersion than other modifiers and forms a more homogeneous phase separation in the HCCRMA.All in all,this research achieved an optimal balance of storage stability and rheological properties in asphalt modified with pretreated HCCR and 6%SBS,which provides a valuable reference for performance improvement of HCCR-modified binders. 展开更多
关键词 High-content crumb rubber modified asphalt Crumb rubber pretreatment Modified asphalt Storage stability Rheological properties
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Preparation Process and Performance Evaluation of Terminal Blend Composite-modified Asphalt
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作者 YUAN Yan WANG Yefei +2 位作者 CHEN Hongyu XU Song ZHENG Zhidong 《Journal of Wuhan University of Technology(Materials Science)》 2026年第1期200-209,共10页
To explore the best preparation process for terminal blend(TB)composite-modified asphalt and to filter its formulation with excellent performance,this study evaluates the performance of TB composite modified asphalt b... To explore the best preparation process for terminal blend(TB)composite-modified asphalt and to filter its formulation with excellent performance,this study evaluates the performance of TB composite modified asphalt by physical property index,microscopic morphology,rheological testing,and infrared spectroscopy on multiple scales.The results show that the best preparation process for TB-modified asphalt is stirring at 260℃ for 4 h at 400 rpm,which significantly reduces the modification time of the asphalt.From a physical property viewpoint,the TB composite-modified asphalt sample with 5% styrene-butadiene-styrene(SBS)+1% aromatics+0.1% sulfur exhibits high-comprehensive,high-and low-temperature properties.More-over,its crosslinked mesh structure comprises black rubber particles uniformly interwoven in the middle,which further enhances the performance of the asphalt and results in an excellent performance formulation.In addition,the sample with 5%SBS content has a higher G*value and smaller δ value than that with 3%SBS content,indicating that its high-temperature resistance is improved.The effect of adding 3%SBS content on the viscoelastic ratio is,to some extent,less than that caused by 20% rubber powder. 展开更多
关键词 road engineering terminal blend rubberized asphalt preparation process modification mechanism
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Microscopic and Dynamic Rheological Characteristics of Crumb Rubber Modified Asphalt 被引量:4
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作者 王岚 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第6期1022-1026,共5页
A test for crumb rubber modified asphalt containing 20% crumb rubber particles(30 mesh) was performed using a scanning electron microscope(SEM).The experimental results indicate that the crumb rubber particles are... A test for crumb rubber modified asphalt containing 20% crumb rubber particles(30 mesh) was performed using a scanning electron microscope(SEM).The experimental results indicate that the crumb rubber particles are evenly distributed in the asphalt.Shear rate sweep and shear-temperature sweep tests on the crumb rubber modified asphalt at-20-80 ℃ using a dynamic shear rheology(DSR) instrument,were carried out.The tests show that the complex modulus decreases with increasing temperature;at equivalent temperature,higher load frequencies lead to a larger complex modulus,and this value increasingly decreases as the temperature increases;the phase angle increases with temperature and decreases as the load frequency increases.It can be concluded that the rutting resistance limiting temperature of crumb rubber modified asphalt is 78 ℃,and the anti-fatigue limiting temperature is 16 ℃,which shows that the asphalt has preferable rutting resistance characteristics at high temperature,as well as anti-fatigue characteristics.In addition,the complex modulus master curve at different temperatures was plotted according to the time temperature equivalence principle,which allows the study of the dynamic state behavior of crumb rubber modified asphalt at a wide range of load frequency. 展开更多
关键词 crumb rubber modified asphalt microcosmic characteristic rheology characteristic complex modulus phase angle
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Warm asphalt rubber:A sustainable way for waste tire rubber recycling 被引量:4
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作者 YU Hua-yang DENG Guan-sen +2 位作者 WANG Duan-yi ZHANG Ze-yu OESER M 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第11期3477-3498,共22页
Recycling end-of-life tire rubber as asphalt modifier is known as a sustainable paving technology with merits including enhanced pavement durability,waste tire consumption and noise reduction.However,the criticisms on... Recycling end-of-life tire rubber as asphalt modifier is known as a sustainable paving technology with merits including enhanced pavement durability,waste tire consumption and noise reduction.However,the criticisms on the high construction emissions of asphalt rubber(AR)have limited its application.Warm mix asphalt(WMA)effectively reduces the mixing and compaction temperatures of conventional hot mix asphalt mixtures.The combination of AR and WMA,called warm asphalt rubber(WAR),is a promising paving material which achieves pavement sustainability from principles to practices.Many studies have demonstrated that WMA technologies work effectively with AR pavement in different ways,alleviating the concerns of potential higher emissions of AR by decreasing mixing and paving temperatures.A comprehensive literature review about WAR brings a better understanding of this promising paving technology.The findings of 165 publications were summarized in this review.It summarized the recent developments of WAR in various aspects,including rheological properties,mix design,mixture mechanical performance,field application,construction emission,and asphalt-rubber-WMA additive interaction.It is expected that this review is able to provide extensive information to explore further research development and application of WAR. 展开更多
关键词 asphalt rubber warm mix asphalt WORKABILITY interaction performance
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Laboratory investigation on effects of organic montmorillonite on performance of crumb rubber modified asphalt 被引量:3
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作者 TAN Zhi-hua WANG Ji-jing SHI Zhen-ning 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第12期3888-3898,共11页
In this paper,organic montmorillonite(OMMT)was added into crumb rubber modified asphalt(CRMA)to improve its high temperature performance,anti-aging performance and storage stability.The effects of different OMMT conte... In this paper,organic montmorillonite(OMMT)was added into crumb rubber modified asphalt(CRMA)to improve its high temperature performance,anti-aging performance and storage stability.The effects of different OMMT content on properties of CRMA were studied.The rutting factor obtained by dynamic shear rheological(DSR)test was adopted to evaluate the high-temperature performance.The creep stiffness and m value determined by the bending beam rheometer(BBR)test were employed to evaluate the low-temperature performance.The softening point,ductility,rutting factor before and after rolling thin film ovens test(RTFOT)and pressure aging vessel test(PAV)were compared to characterize the aging properties.Moreover,the segregation test after being reserved for 48 h and 7 d was conducted,and the softening point and rutting factor of upper and lower layers of segregation pipe were adopted to evaluate the storage stability.The results indicated that the high-temperature performance and anti-aging performance were developed with the increasing content of OMMT,while the low-temperature performance deteriorated.The storage stability was improved with the increasing content of OMMT before the content exceeded 4%,after which the storage stability declined.Taking account of all factors,it is suggested that the optimum content of OMMT is 3%−4%. 展开更多
关键词 crumb rubber modified asphalt organic montmorillonite high-temperature performance low-temperature performance storage stability.
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Creep Characteristics of Crumb Rubber Modified Asphalt Binder 被引量:2
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作者 王岚 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2011年第1期118-120,共3页
Crumb rubber modified asphalt containing 20 percent crumb rubber particles of 30 mesh has been examined by Scanning Electron Microscope (SEM) to observe the microcosmic appearance and the characteristic distribution... Crumb rubber modified asphalt containing 20 percent crumb rubber particles of 30 mesh has been examined by Scanning Electron Microscope (SEM) to observe the microcosmic appearance and the characteristic distribution of crumb rubber particles in asphalt. The SEM pictures reveal that the crumb rubber particles distribute evenly in the asphalt and they are compatible well with asphalt. The shear creep test of crumb rubber modified asphalt was carried out at -10 ℃ and 40 ℃ by Dynamic Shear Rheology (DSR). The shearing deformation at different temperature and creep stiffness modulus curve at loading stage of crumb rubber modified asphalt have been measured. The stiffness modulus of crumb rubber modified asphalt is much temperature sensitive and it decays much quick at the early stage of loading than normal asphalt. The rate of decay of stiffness modulus is slow at the subsequent stage and stiffness modulus approaches to a stable value at the final stage at a higher temperature. In addition, Burgers model is suitable to describe and simulate experimental results of viscoelastic properties of the crumb rubber modified asphalt. 展开更多
关键词 crumb rubber modified asphalt CREEP stiffness modulus rheology model model parameter
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Interaction Theory of Asphalt and Rubber 被引量:1
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作者 高英 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第5期853-855,共3页
Through scanning electron microscope (SEM), spectral analysis, and component analysis tests, the interaction theory between asphalt and rubber was discussed. It is concluded that rubber powder become soft and bond t... Through scanning electron microscope (SEM), spectral analysis, and component analysis tests, the interaction theory between asphalt and rubber was discussed. It is concluded that rubber powder become soft and bond together with each other after being mixed with asphalt. The asphalt changes from a smooth homogeneous matter to a continuous mixing system which is composed of rubber powder and asphalt. The interaction is mainly physical diffusion, but there are some chemical reactions in the process, especially at long reaction time. 展开更多
关键词 crumb rubber asphalt rubber interaction theory physical diffusion chemical reactions
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Influence of Rubber Powder Movement on Properties of Asphalt Rubber from the Mesoscopic View 被引量:2
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作者 LI Haibin HU Yihong +4 位作者 SHI Xuan ZHANG Mingming ZHAO Guijuan ZOU Xiaolong SENG Yanping 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期312-324,共13页
The research on asphalt performance mainly focused on the macro performance and micro mechanism.Mesoscopic analysis was introduced to study the effect of rubber powder movement on asphalt rubber properties.After the p... The research on asphalt performance mainly focused on the macro performance and micro mechanism.Mesoscopic analysis was introduced to study the effect of rubber powder movement on asphalt rubber properties.After the preparation parameters and the preparation process of asphalt rubber were determined,the modification mechanism and rheological properties were analyzed which revealed the compatible stability mechanism.Then,the analysis model of asphalt rubber was established to focus on simulating the effect of rubber powder and the spatial movement on its mechanical properties.The experimental results show that rubber powder can make the asphalt rubber bear more uniform stress distribution and enhance the ability to resist deformation.Meanwhile,the rotational motion and final distribution of rubber powder have an obvious impact on the mechanical properties of asphalt rubber.In the selected feature points,the average stress of rubber powder at 0°space angle is only 34.1%of that at90°space angle.When the rubber powders are all in parallel in the ideal state,it enhances the mechanical properties the most.This study supplements the“mesoscopic”scale between macro and micro research.The relationship between micro mechanism and macro properties of asphalt rubber will be established from the mesoscopic perspective.It is also an effort to realize the effective correlation from micro,mesoscopic to macro in asphalt. 展开更多
关键词 asphalt rubber rubber powder movement space angle of rubber powder mesoscopic scale numerical simulation
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Microstructure characterization and thermal properties of the waste-styrene-butadiene-rubber (WSBR)-modified petroleum-based mesophase asphalt 被引量:2
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作者 Jingbo Hu Changqing Fang +2 位作者 Shisheng Zhou Youliang Cheng Hanzhi Han 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2019年第5期852-857,共6页
In this work, waste-styrene-butadiene-rubber(WSBR)-modified petroleum-based mesophase asphalt was prepared through a co-carbonization process. The influence of contents of WSBR and carbonization temperature on the pro... In this work, waste-styrene-butadiene-rubber(WSBR)-modified petroleum-based mesophase asphalt was prepared through a co-carbonization process. The influence of contents of WSBR and carbonization temperature on the properties of mesophase asphalt was investigated. The chemical constituents,microstructure and thermal property of the samples were characterized. The results show that using WSBR as modifier can significantly promote the formation of mesophase. When the temperature is constant, the addition of WSBR results in more optically anisotropic crystal structure in the samples, and a better thermal stability. When the content of WSBR is invariable, with increasing temperature, the content of anisotropic structure in mesophase asphalt becomes higher and more uniform. The thermal stability of the samples is the best when WSBR content is 10 wt%. 展开更多
关键词 Waste-styrene-butadiene-rubber MESOPHASE asphalt Thermal properties Microstructure
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Optimization of technical measures for improving high-temperature performance of asphalt-rubber mixture 被引量:2
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作者 Chuan Xiao Tianqing Ling Yanjun Qiu 《Journal of Modern Transportation》 2013年第4期273-280,共8页
Asphalt-rubber pavements often become dam-aged in high-temperature regions and appear rutted or wavy, and experience slippage. To improve the high-temperature performance of the asphalt-rubber mixture, technical measu... Asphalt-rubber pavements often become dam-aged in high-temperature regions and appear rutted or wavy, and experience slippage. To improve the high-temperature performance of the asphalt-rubber mixture, technical measurements, such as, the optimal adjustment of gradation, technique of composite modification, and control of compaction were investigated. An optimal adjustment of aggregate gradation based on stone matrix asphalt improves the high-temperature stability of the asphaltrubber mixture significantly. Through composite modifi- cation, the effect of asphalt-rubber modification was enhanced, and the dynamic stability and relative defor- mation indices of the asphalt-rubber mixture were improved significantly. Furthermore, compaction parame- ters had a significant influence on the high-temperature stability of the asphalt-rubber mixture. The rolling times for compacting the asphalt-rubber mixture should be controlled to within 18-20 round-trips at a molding temperature at 180℃; if the rolling time is a 12 round-trip, the compaction temperature of the asphalt-rubber mixture should be controlled between 180 and 190℃. 展开更多
关键词 Road engineering test asphalt-rubber mixture performance Optimization Laboratory High-temperature
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Diffusion Kinetics of Components of Asphalt Into Waste Rubber 被引量:1
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作者 LI X CHENG J QUE G H 《武汉理工大学学报》 CAS CSCD 北大核心 2010年第17期26-29,共4页
The use of waste crumb rubber powder as a modifier for modified asphalt can recycle waste rubber to ease pressure on the environment and improve the performance of asphalt. Diffusion of components of asphalt into wast... The use of waste crumb rubber powder as a modifier for modified asphalt can recycle waste rubber to ease pressure on the environment and improve the performance of asphalt. Diffusion of components of asphalt into waste rubber is of vital importance to improve the performance of rubber modified asphalt,while the related researches are scarce. Diffusion of components of asphalt into waste rubber at different temperatures has been investigated in this work. Rectangle rubber was immersed in asphalt at certain temperature for a period of time. And the mass increment of rubber was measured to determine the diffusion rate of components of asphalt into rubber. The experimental results indicated that the diffusion rate of components of asphalt into waste rubber increases along the temperature,but the diffusion rate of components of fractions oil which is distillated from catalytic cracking slurry is much higher than that of components of asphalt. Compared with asphalt,fractions oil enjoys lower viscosity and better permeability with higher content of saturates and aromatics. All the characteristics are contributed to the efficient diffusion of components of fractions into waste rubber. 展开更多
关键词 diffusion kinetics COMPONENTS fractions oil asphalt waste rubber
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Experimental Study of Rubberized Asphalt Emulsion Modified Portland cement concrete
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作者 Li Guoqiang Wei Lianyu wand Maoxiang, and Huang Wei 《河北工业大学学报》 CAS 1997年第A01期48-57,共10页
The poor fatigue properties and high rigidity of cement asphalt emulsion treated mis(CETM) have for a long time been problems restricting its further development making it impossible for C-ETMto be used as surface lay... The poor fatigue properties and high rigidity of cement asphalt emulsion treated mis(CETM) have for a long time been problems restricting its further development making it impossible for C-ETMto be used as surface layer materials. In this paper, a new kind of cement asphalt emulsion composite-rubberized asphalt emulsion modified Portland cement concrete (RACC) was proposed, which was formed by dispersing rubberized aSPhalt emulsion coated coarse aggregates into cement mortar matrix. In order to evaluate systematically the performance of RACC, laboratory tests with nearly one thousand SPecimen were conducted for resilient modulus, fatigue properties, ultimate ban and length,abrasion, temperature contraction, and dry shrinkage. The experimental results show that the problems existed in C-ETM have to a great extends been solved by RACc. To verify the field performance and inquire into paving technology, teSt road appearsatlsfactory it is concluded that when thed ape surface laycr of semi-rigid base course, RACC is more for surface layer material than both Portland cement concrete(PCC) and asphalt concrete(AC) 展开更多
关键词 AC ETM ICPT Experimental Study of rubberized asphalt Emulsion Modified Portland cement concrete
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Experimental Survey on Dry Asphalt Rubber Concrete for Sub-ballast Layers
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作者 Gaetano Di Mino Ciro Maurizio Di Liberto 《Journal of Civil Engineering and Architecture》 2012年第12期1615-1626,共12页
This paper presents the results of an experimental survey on the potential application of DARC (dry asphalt rubber concrete) in rail superstructure, within sub-ballast layers by measuring its damping and mechanical ... This paper presents the results of an experimental survey on the potential application of DARC (dry asphalt rubber concrete) in rail superstructure, within sub-ballast layers by measuring its damping and mechanical properties. Based on the environmental friendly point of view the DARC has the significant advantage as the backfill material of sub-ballast layer because the rubber comes from the waste tires of truck and its usage can results a significant recycling of non-biodegradable wastes. After a preliminary mix-design of several DARCs, with different rubber content that confirmed by using the Marshall test, the stiffness modulus and damping ratio both of a standard bituminous mixture and of dry asphalt rubber concrete with a rubber content equal to 1.5% were determined using the four points bending device. The experimental results were compared and a numerical analysis by means of a 2D lumped mass model was developed in order to evaluate the different performance within the rail superstructure in terms both of the deflection and of the pressure on sub-grade. Both the results on the mechanical and dissipative properties of the DARC and the mechanical behavior of the correlate rail superstructure encourage the authors to continue the research on the application of such material for sub-ballast layers. 展开更多
关键词 DAMPING stiffness modulus dry asphalt rubber concrete sub-ballast layers.
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Advances in Aging and Anti-Aging Research on Rubber-Modified Asphalt and Asphalt Mixtures
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作者 Yuefeng Zhu Gang Wang +1 位作者 Minshen Tang Jiawei Zhang 《World Journal of Engineering and Technology》 2022年第3期502-510,共9页
Waste rubber-modified asphalt has good anti-aging properties and can significantly improve the service life of asphalt pavements. For domestic and foreign scholars of rubber modified asphalt thermal oxygen aging, phot... Waste rubber-modified asphalt has good anti-aging properties and can significantly improve the service life of asphalt pavements. For domestic and foreign scholars of rubber modified asphalt thermal oxygen aging, photo-oxidative aging and water aging some behavioural research, and rubber asphalt aging after the characteristics of the research progress are reviewed. Especially rubber-modified asphalt after light, water and other multi-factor agingsituations, the aging situation is more serious, for rubber-modified asphalt mixture aging, rubber asphalt anti-aging process research and analysis means are still very few, the future research must have more thinking. 展开更多
关键词 Waste rubber Modified asphalt Thermal-Oxidative Aging Aging Resistance
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Construction and Durability Verification of Upper Layer of High Content (30%) Rubber Powder Asphalt Concrete Arhm-13
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作者 LIJianwen LIGuangpan +1 位作者 CHENShuyun ZHAIJinwei 《外文科技期刊数据库(文摘版)工程技术》 2022年第3期075-080,共6页
ARHM asphalt rubber has been applied in pavement engineering research for more than 20 years in our country. It has been applied and popularized in Beijing-Qinhuangdao Expressway, Jinshi Expressway and other projects ... ARHM asphalt rubber has been applied in pavement engineering research for more than 20 years in our country. It has been applied and popularized in Beijing-Qinhuangdao Expressway, Jinshi Expressway and other projects successively, but its content is relatively low. According to the characteristics that rubber powder can greatly improve the durability of asphalt concrete, the research on the mix proportion of high content (30%) rubber powder asphalt concrete was carried out. It has been verified that it has significantly improved the dynamic stability, low-temperature bending, freeze-thaw splitting and water seepage performance, and has been put into use in the bid section ZT2 of Jingde Expressway, meeting the use requirements of "no minor repair for 15 years and no major repair for 40 years" for the permanent pavement of Jingde Expressway. 展开更多
关键词 high content rubber powder asphalt concrete mix proportion design DURABILITY CONSTRUCTION
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螯合反应型净味剂对橡塑沥青的净味效果与反应机理
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作者 徐茜 张哲 +2 位作者 刘悦 耿立涛 吕健涵 《建筑材料学报》 北大核心 2026年第3期356-362,共7页
为解决橡塑沥青传统抑烟净味技术效果不佳的问题,基于沥青技术性能测试、气味强度评价以及烟气气相色谱-质谱(GC-MS)分析,研究了螯合反应型净味剂在橡塑沥青中的净味效果与反应机理。结果表明:在0.015%~0.035%掺量范围内,净味剂对沥青... 为解决橡塑沥青传统抑烟净味技术效果不佳的问题,基于沥青技术性能测试、气味强度评价以及烟气气相色谱-质谱(GC-MS)分析,研究了螯合反应型净味剂在橡塑沥青中的净味效果与反应机理。结果表明:在0.015%~0.035%掺量范围内,净味剂对沥青技术性能无不利影响;掺加净味剂后,气味强度从4级降至0级,烟气质量减少15.4%~44.3%,烟气种类减少5~9种;随着净味剂掺量的增加,恶臭、有毒及小分子无味烟气含量下降,大分子无味烟气含量上升。该净味剂通过与烟气中含S、N、O及双键等富电子基团发生络合反应实现净味作用,反应程度取决于反应物含量及其化学活性。 展开更多
关键词 橡塑沥青 沥青烟气 螯合反应型净味剂 GC-MS分析 抑烟机理
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植物油活化废胶粉/SBS复合改性沥青的性能
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作者 冯新军 栗晓晨 梁辉 《公路交通科技》 北大核心 2026年第3期49-59,共11页
【目标】为解决废胶粉/SBS复合改性沥青(CR/SBSMA)的黏度高、施工和易性与储存稳定性较差等技术问题,促进其在道路工程中的实际应用,采用植物油活化废胶粉(OCR)和SBS制备复合改性沥青(OCR/SBSMA)。【方法】首先,通过针入度、软化点、5... 【目标】为解决废胶粉/SBS复合改性沥青(CR/SBSMA)的黏度高、施工和易性与储存稳定性较差等技术问题,促进其在道路工程中的实际应用,采用植物油活化废胶粉(OCR)和SBS制备复合改性沥青(OCR/SBSMA)。【方法】首先,通过针入度、软化点、5℃延度和离析试验以及布氏黏度、弹性恢复试验,分析OCR与SBS这2种聚合物的不同掺量组合对OCR/SBSMA性能的影响,确定最优掺配比例;然后对OCR/SBSMA的常规性能、黏温特性及流变性能进行研究;最后借助荧光显微镜试验和傅里叶变换红外光谱试验对OCR/SBSMA的改性机理进行研究。【结果】2种OCR/SBSMA的最佳掺配组合分别为32%大豆油活化废胶粉(OCR-S)复配3%SBS、28%废食用油活化废胶粉(OCR-W)复配3%SBS;OCR明显降低了CR/SBSMA的黏度与离析差值,大大改善了CR/SBSMA的施工和易性及储存稳定性;OCR明显降低了CR/SBSMA的高温抗车辙因子和低温劲度模量,提高了其低温蠕变速率,表明植物油活化处理胶粉降低了CR/SBSMA的高温抗车辙能力,但显著提高了其低温抗裂性;废胶粉经过活化处理后,在改性沥青中脱硫降解程度更高,分布均匀性显著提高,SBS颗粒和OCR颗粒相互交织形成了致密的弹性网状结构;OCR/SBSMA的改性机理以物理混合为主,并伴随着苯酚与甲醛缩合、烷烃氧化裂解、SBS与油分结合等少量化学反应。【结论】研究结果可为植物油活化废胶粉/SBS复合改性沥青在道路工程中的推广应用提供理论依据和技术指导。 展开更多
关键词 道路工程 路面材料 植物油活化废胶粉 SBS复合改性沥青 施工和易性 储存稳定性
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合成生物助剂对防水沥青的改性研究
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作者 罗伟新 王伟伟 +2 位作者 吴猛 齐桂杰 刘金景 《新型建筑材料》 2026年第2期76-80,共5页
为了减少石油类软化剂的使用,研发出一种基于生物质油的合成生物助剂,添加合成生物助剂对老化沥青再生后,沥青四组分试验中,极性组分发生迁移,沥青质含量实际值比理论值减少41.7%,而饱和分含量实际值比理论值增大37.5%。防水改性沥青涂... 为了减少石油类软化剂的使用,研发出一种基于生物质油的合成生物助剂,添加合成生物助剂对老化沥青再生后,沥青四组分试验中,极性组分发生迁移,沥青质含量实际值比理论值减少41.7%,而饱和分含量实际值比理论值增大37.5%。防水改性沥青涂盖料试验表明,按m(腰果壳油)∶m(废食用油)=5∶5合成生物助剂,与相同掺量的废机油相比,防水改性沥青的低温柔性降低1℃,热老化低温柔性衰减减少25%,接缝剥离强度提高0.2 N/mm。相同性价比下,使得软化剂的添加量减少1个百分点,进而降低防水材料的成本。合成生物助剂对橡胶粉具有活化作用,使得体系的离析大幅降低,进而提升改性沥青涂盖料的热稳定性。 展开更多
关键词 腰果壳油 废食用油 合成生物助剂 沥青再生 活化橡胶
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废胶粉改性沥青热氧老化及再生研究进展
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作者 韦万峰 张仰鹏 +4 位作者 禤炜安 李运高 郭鹏 杨帆 孔令云 《化工进展》 北大核心 2026年第1期270-287,共18页
废胶粉改性沥青是一种环境友好型的道路材料,不仅缓解了废旧轮胎对自然环境的污染,而且有效延长了沥青路面的寿命。为了进一步推广废胶粉改性沥青在道路工程的应用,实现橡胶沥青路面的可持续发展,本文系统分析了废胶粉改性沥青热氧老化... 废胶粉改性沥青是一种环境友好型的道路材料,不仅缓解了废旧轮胎对自然环境的污染,而且有效延长了沥青路面的寿命。为了进一步推广废胶粉改性沥青在道路工程的应用,实现橡胶沥青路面的可持续发展,本文系统分析了废胶粉改性沥青热氧老化机理、再生情况及状态的研究方法等相关研究。首先,分析了废胶粉改性沥青热氧老化机理及老化性能,表明废胶粉改性沥青老化过程中存在橡胶粉、沥青相的同步老化,其中废胶粉与沥青的物质交互作用、橡胶粉弹性衰退情况是研究的重点。其次,梳理了老化废胶粉改性沥青再生性能的研究情况,表明传统再生剂难以恢复废胶粉改性沥青胶体结构,且当前缺少指导废胶粉改性沥青再生的相关理论。从相分离技术、宏观状态测试、微观状态测试、仿真模拟等多角度分析了废胶粉改性沥青老化、再生状态的研究方法,并阐述了这些研究方法的特点。最后,提出了废胶粉改性沥青老化、再生及其研究方法的发展趋势与展望。 展开更多
关键词 道路工程 废胶粉改性沥青 热氧老化 再生
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