A series of efficient ruthenium chloride (RuCl_3)-anchored MOF catalysts,such as RuCl_3@MIL-101 (Cr)-Sal,and RuCl_3@MIL-101 (Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM)of the term...A series of efficient ruthenium chloride (RuCl_3)-anchored MOF catalysts,such as RuCl_3@MIL-101 (Cr)-Sal,and RuCl_3@MIL-101 (Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM)of the terminal amino of MIL-101(Cr)-NH_2 with salicylaldehyde, 2-diphenylphosphinobenzaldehyde (DPPBde) and anchoring of Ru (Ⅲ) ions. The stronger coordination electron donor interaction between Ru (Ⅲ) ions and chelating groups in the RuCl_3@MIL-101 (Cr)-DPPB enhances its catalytic performance for CO_2 hydrogenation to formic acid. The turnover number (TON) of formic acid was up to 831 in reaction time of 2 h with dimethyl sulfoxide (DMSO) and water (H_2O) as mixed solvent, trimethylamine (Et_3N) as organic base, and PPh_3 as electronic additive.展开更多
We study various particle–hole excitations and possible superconducting pairings mediated by these fluctuations in doped α-RuCl_3 by using multi-band Hubbard model with all t_(2g) orbitals. By performing a random-ph...We study various particle–hole excitations and possible superconducting pairings mediated by these fluctuations in doped α-RuCl_3 by using multi-band Hubbard model with all t_(2g) orbitals. By performing a random-phase-approximation(RPA) analysis, we find that among all particle–hole excitations, the j_(eff)= 1/2 pseudospin fluctuations are dominant, suggesting the robustness of j_(eff)= 1/2 picture even in the doped systems. We also find that the most favorable superconducting state has a d-wave pairing symmetry.展开更多
基金Financial support from the National Natural Science Foundation of China(NSFC, Nos. 21776211, 21325626)the Program for New Century Excellent Talents in University(No. NCET-13-0411)the Program of Introducing Talents of Discipline to Universities(No. B06006)
文摘A series of efficient ruthenium chloride (RuCl_3)-anchored MOF catalysts,such as RuCl_3@MIL-101 (Cr)-Sal,and RuCl_3@MIL-101 (Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM)of the terminal amino of MIL-101(Cr)-NH_2 with salicylaldehyde, 2-diphenylphosphinobenzaldehyde (DPPBde) and anchoring of Ru (Ⅲ) ions. The stronger coordination electron donor interaction between Ru (Ⅲ) ions and chelating groups in the RuCl_3@MIL-101 (Cr)-DPPB enhances its catalytic performance for CO_2 hydrogenation to formic acid. The turnover number (TON) of formic acid was up to 831 in reaction time of 2 h with dimethyl sulfoxide (DMSO) and water (H_2O) as mixed solvent, trimethylamine (Et_3N) as organic base, and PPh_3 as electronic additive.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11674158 and 11774152)the National Key Projects for Research and Development of China(Grant No.2016YFA0300401)
文摘We study various particle–hole excitations and possible superconducting pairings mediated by these fluctuations in doped α-RuCl_3 by using multi-band Hubbard model with all t_(2g) orbitals. By performing a random-phase-approximation(RPA) analysis, we find that among all particle–hole excitations, the j_(eff)= 1/2 pseudospin fluctuations are dominant, suggesting the robustness of j_(eff)= 1/2 picture even in the doped systems. We also find that the most favorable superconducting state has a d-wave pairing symmetry.
