The precise excitation of molecular vibrational states is critical for ad-vancing chemical dynamics,preci-sion spectroscopy,and trace gas sensing.This objective,however,is often hindered by the weak oscilla-tor streng...The precise excitation of molecular vibrational states is critical for ad-vancing chemical dynamics,preci-sion spectroscopy,and trace gas sensing.This objective,however,is often hindered by the weak oscilla-tor strengths of ro-vibrational tran-sitions,which render conventional continuous-wave(cw)lasers ineffec-tive due to their limited power.This fundamental challenge is overcome by cavity-enhanced excitation(CEE),a technique that locks a cw laser to a high-finesse optical cavity.This configuration amplifies the intra-cavity light intensity by several orders of magnitude while preserving a narrow spectral linewidth.The resulting synergy enables highly efficient,state-selective population transfer and high-resolution spectroscopy previously considered impractical.This review elucidates the core technique of laser-cavity locking and highlights its applications,notably in the quantitative detection of trace isotopes and the investigation of highly excited vibrational states with kilo-hertz-level accuracy.展开更多
Ultracold polar RbCs molecules are produced via photoassociation in a laser-cooled mixture of ^85Rb and ^133Cs atoms. The a3∑＋ state molecules which decay from electronically excited （2）0- state RbCs molecules are...Ultracold polar RbCs molecules are produced via photoassociation in a laser-cooled mixture of ^85Rb and ^133Cs atoms. The a3∑＋ state molecules which decay from electronically excited （2）0- state RbCs molecules are detected by resonance- enhanced two-photon ionization. The new rovibrational levels （v = 189, 190） in the （2）0- state are also observed, which exist in theory and have not been observed in experiments yet. The corresponding rotational constants are measured by photoassociation spectroscopy, which are consistent with theoretical calculations using a nonrigid rotor model.展开更多
基金supported by the Chinese Acade-my of Sciences(Grant Nos.YSBR-055,XDB0970100)the National Natural Science Foundation of China(Nos.22241302,12393825).
文摘The precise excitation of molecular vibrational states is critical for ad-vancing chemical dynamics,preci-sion spectroscopy,and trace gas sensing.This objective,however,is often hindered by the weak oscilla-tor strengths of ro-vibrational tran-sitions,which render conventional continuous-wave(cw)lasers ineffec-tive due to their limited power.This fundamental challenge is overcome by cavity-enhanced excitation(CEE),a technique that locks a cw laser to a high-finesse optical cavity.This configuration amplifies the intra-cavity light intensity by several orders of magnitude while preserving a narrow spectral linewidth.The resulting synergy enables highly efficient,state-selective population transfer and high-resolution spectroscopy previously considered impractical.This review elucidates the core technique of laser-cavity locking and highlights its applications,notably in the quantitative detection of trace isotopes and the investigation of highly excited vibrational states with kilo-hertz-level accuracy.
基金supported by the National Basic Research Program of China (Grant No. 2012CB921603)the International Science & Technology Cooperation Program of China (Grant No. 2011DFA12490)+1 种基金the National Natural Science Foundation of China (Grant Nos. 61275209, 10934004, and 11004125)the National Natural Science Foundation for Excellent Research Team, China (Grant No. 61121064)
文摘Ultracold polar RbCs molecules are produced via photoassociation in a laser-cooled mixture of ^85Rb and ^133Cs atoms. The a3∑＋ state molecules which decay from electronically excited （2）0- state RbCs molecules are detected by resonance- enhanced two-photon ionization. The new rovibrational levels （v = 189, 190） in the （2）0- state are also observed, which exist in theory and have not been observed in experiments yet. The corresponding rotational constants are measured by photoassociation spectroscopy, which are consistent with theoretical calculations using a nonrigid rotor model.
