Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incor...Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incorporation within the plough soil layer.As an innovative soil amelioration approach,the efficiency and patterns of SOC accumulation remain unclear.Two field experiments were conducted in infertile subtropical upland and paddy soils with 0,30,60,and 90 Mg ha^(-1)granulated straw incorporation.After one year,SOC accumulation efficiency from straw input remained stable in upland(30.8–37.5%)with increasing amounts of straw incorporation,while declined from 60.0 to 38.3%in paddy.In both croplands,the contributions of lignin phenols to SOC increased with increasing straw incorporation,while the contributions from amino sugars remained constant at higher straw input levels.Subsequently,the ratios of lignin phenols to amino sugars increased with increasing straw incorporation,indicating faster plant residue accumulation compared to microbial necromass,as the granulation approach limited microbial involvement in straw transformation.Thus,single-time incorporation of substantial granulated straw presents an effective agricultural strategy for rapid amelioration of infertile croplands.展开更多
With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on...With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on the synthesis of porous Fe_(3)O_(4)/C composites that incorporate dielectric and magnetic loss mechanisms via the carbothermal reduction method and optimization of waste ratio to enhance EWA performance.The Fe_(3)O_(4)/C composites with 10wt%soybean residues(Fe_(3)O_(4)/C-10),demonstrated the best EWA performance,achieving the minimum reflection loss of−56.4 dB and a bandwidth of 2.14 GHz at a thickness of 2.23 mm.This enhanced EWA performance is primarily attributable to improved impedance matching and the synergistic effect between dielectric and magnetic losses.Furthermore,radar cross-sectional simulations confirmed the practical feasibility of the porous Fe_(3)O_(4)/C composites.This study proposes a viable strategy for utilizing soybean residue and electrolytic manganese residue,highlighting their potential applications in EWA.展开更多
Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications.Coal tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilizati...Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications.Coal tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable world.In this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances assessment.Based on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were obtained.Furthermore,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of CTRCs.Results indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”mechanism.This work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.展开更多
An efficient process based on oxidizing roasting−direct reduction−smelting−electrorefining was developed to separate and recover Zn,In,Ga and Fe from a typical hazardous jarosite residue.Phase transformation and eleme...An efficient process based on oxidizing roasting−direct reduction−smelting−electrorefining was developed to separate and recover Zn,In,Ga and Fe from a typical hazardous jarosite residue.Phase transformation and element migration during each separating process were evaluated by X-ray diffraction analysis(XRD),thermo-gravimetric−differential scanning calorimetry(TG−DSC),and scanning electron microscopy−energy dispersive spectrometry(SEM−EDS).The results show that the jarosite residue decomposed into hematite and zinc ferrite when oxidizing roasted at 1250℃ for 20 min.Then,Zn and In were volatilized and enriched into flue dust through the reductive roasting of oxidized pellets at 1200℃ for 60 min.Finally,Fe and Ga were separated by smelting−electrorefining of the reduced pellets to obtain high purity iron powder with 99.5%Fe and anode slime with 456 g/t Ga.Through the process,a total recovery of 97.42%Zn,87.86%In,90.70%Fe and 84.78%Ga can be achieved.展开更多
Cyclosporin A fermentation residue(CFR)is a type of organic waste generated during the production of cyclosporin A,which are abundant in nutrients including organic matter,phosphorus,nitrogen and potassium.Inappropria...Cyclosporin A fermentation residue(CFR)is a type of organic waste generated during the production of cyclosporin A,which are abundant in nutrients including organic matter,phosphorus,nitrogen and potassium.Inappropriate handling of CFR not only waste valuable bioresources,but may also lead to the cyclosporin A and associated resistance genes into the natural environment,posing a significant threat to ecological system and human health.Land application was an effective way to resource recovery of CFR after aerobic composting(CAC).This study investigated the impact of CAC on soil fertility and environmental safety.The results indicated that CAC could improve soil nutrient contents and enhance enzyme activities.CAC altered the diversity and community composition of soil bacteria,resulting in an increase in the abundance of relevant bacteria beneficial for organic matter decomposition and cyclosporin A degradation.The introduced cyclosporin A(71.69μg/kg)completely degraded within 20 days due to soil biodegradation.The significantly increased abundance of intIl,mdr3,pgp,TSR and pmra in the soil cultivation early stage were restored to the soil background level within 90 days,indicating a reduced risk of antimicrobial resistance.The results demonstrated that reasonable land application of CAC could improve soil fertility without antimicrobial resistance risk,which is helpful for evaluating the resource utilization value and environmental risks of antibiotic fermentation residue after aerobic composting.展开更多
A new manufactured soil product (Turba) was produced using acidified bauxite residue into which 10% green waste compost had been incorporated. A laboratory/greenhouse experiment was carried out to determine if sand co...A new manufactured soil product (Turba) was produced using acidified bauxite residue into which 10% green waste compost had been incorporated. A laboratory/greenhouse experiment was carried out to determine if sand could be used as an ingredient or an amendment for Turba. Sand was added at rates of 0%, 5%, 10%, 25, 50% and 75% (w/w) in two different ways 1) by incorporating it into the Turba during its manufacture (IN) or 2) by mixing it with Turba aggregates after their manufacture (OUT). Incorporation of sand into Turba aggregates (IN) decreased the percentage of sample present as large aggregates (2 - 4 mm dia.) after crushing and sieving (<4 mm) and also reduced the stability of 2 - 4 mm dia. formed aggregates (to dry/wet sieving) and are therefore not recommended. In a 16-week greenhouse study, ryegrass shoot yields were greater in Turba than in sand [and decreased with increasing sand additions (OUT)] while root dry matter showed the opposite trend. The greater grass growth in Turba than sand was attributed to incipit water stress in plants grown in sand and this may have promoted greater allocation of assimilates to roots resulting in a greater root-to-top mass ratio. The much lower macroporosity in Turba coupled with the solid cemented nature of Turba aggregates resulted in production of thinner roots and therefore greater root length than in sand. Turba (manufactured from bauxite residue and compost added at 10% w/w) is a suitable medium for plant growth and there is no advantage in incorporating sand into, or with, the Turba aggregates.展开更多
The residual biomass composed of pseudo trunks and banana leaves is very important and poorly valued. There is very little quantified data on the deposits of residual biomass from banana plantations in Senegal and in ...The residual biomass composed of pseudo trunks and banana leaves is very important and poorly valued. There is very little quantified data on the deposits of residual biomass from banana plantations in Senegal and in particular in the Tambacounda region. In this work, we seek to evaluate the methanogenic potential and to valorize this biomass in biogas and biofertilizer. The laboratory experiment lasted approximately 35 days. During this time, the methanogenic microorganisms degrade the organic residue provided, which results in the production of biogas. At the end of the reactions, the rate of biogas production drops, indicating the end of the biodegradation of organic matter. Biogas production is measured over time and the composition of the biogas produced is analyzed by gas chromatography (GC) or by an infrared analyzer. The methane potential of each sample is determined from the cumulative quantity of methane produced in each flask representing a digestion system. The measurement can be expressed in m3 of CH4 per tonne of dry matter or per tonne of raw material. The first challenge of this study therefore lies in the acquisition of reliable and usable data to quantify the methanizable biomass. This study will allow us not only to evaluate the quantities of pseudo trunks and banana leaves available in a plot after harvest but also to test the biogas and methane production potential (BMP test) of this substrate and therefore determine the expected biogas production of this biomass.展开更多
In the context of Industry 5.0,more emphasis is placed on human-centric smart manufacturing patterns.Product design is a vital phase of smart manufacturing,involving user engagement is an essential factor in enhancing...In the context of Industry 5.0,more emphasis is placed on human-centric smart manufacturing patterns.Product design is a vital phase of smart manufacturing,involving user engagement is an essential factor in enhancing design quality and fostering innovation.With user involvement in-depth,dynamically changing user requirements and feedback bring new problems to the design process,and the traditional linear solving process cannot perceive such variations timely,which causes hysteresis in the solution.The design solution's hysteresis affects the consensus achievement process between the designer and user,further prolonging the iteration cycle.To address this issue,a human-centric product conceptual design model is proposed for the timely translation of such variations into design solutions.In this model,design problems are formed by centering on user requirements,designer and user collaboratively solve the problems to form design solutions.Through a cycle of problem-driven,knowledgesupported,and solution evaluation,new problems are solved promptly to achieve progressive solution convergence,which clarifies the iterative evolution process and improves iterative efficiency.To verify the effectiveness of the model,a natural gas well foaming agent automatic filling device design is presented.展开更多
Continental crust is the long-term achievements of Earth's evolution across billions of years.The continental rocks could have been modified by various types of geological processes,such as metamorphism,weathering...Continental crust is the long-term achievements of Earth's evolution across billions of years.The continental rocks could have been modified by various types of geological processes,such as metamorphism,weathering,and reworking.Therefore,physical or chemical properties of rocks through time record the composite effects of geological,biological,hydrological,and climatological processes.Temporal variations in these time series datasets could provide important clues for understanding the co-evolution of different layers on Earth.However,deciphering Earth's evolution in deep time is challenged by incompleteness,singularity,and intermittence of geological records associated with extreme geological events,hindering a rigorous assessment of the underlying coupling mechanisms.Here,we applied the recently developed local singularity analysis and wavelet analysis method to deep-time U-Pb age spectra and sedimentary abundance record across the past 3.5 Gyrs.Standard cross-correlation analysis suggests that the singularity records of marine sediment accumulations and magmatism intensity at continental margin are correlated negatively(R^(2)=0.8),with a delay of~100 Myr.Specifically,wavelet coherence analysis suggests a~500-800 Myr cycle of correlation between two records,implying a coupling between the major downward processes(subduction and recycling sediments)and upward processes(magmatic events)related to the aggregation and segregation of supercontinents.The results clearly reveal the long-term cyclic feedback mechanism between sediment accumulation and magmatism intensity through aggregation of supercontinents.展开更多
Erythromycin fermentation residue(EFR)represents a typical hazardous waste produced by the microbial pharmaceutical industry.Although electrolysis is promising for EFR disposal,its microbial threats remain unclear.Her...Erythromycin fermentation residue(EFR)represents a typical hazardous waste produced by the microbial pharmaceutical industry.Although electrolysis is promising for EFR disposal,its microbial threats remain unclear.Herein,metagenomics was coupled with the random forest technique to decipher the antibiotic resistance patterns of electrochemically treated EFR.Results showed that 95.75%of erythromycin could be removed in 2 hr.Electrolysis temporarily influenced EFRmicrobiota,where the relative abundances of Proteobacteria and Actinobacteria increased,while those of Fusobacteria,Firmicutes,and Bacteroidetes decreased.A total of 505 antibiotic resistance gene(ARG)subtypes encoding resistance to 21 antibiotic types and 150 mobile genetic elements(MGEs),mainly including plasmid(72)and transposase(52)were assembled in EFR.Significant linear regression models were identified among microbial richness,ARG subtypes,and MGE numbers(r^(2)=0.50-0.81,p<0.001).Physicochemical factors of EFR(Total nitrogen,total organic carbon,protein,and humus)regulated ARG and MGE assembly(%IncMSE value=5.14-14.85).The core ARG,MGE,and microbe sets(93.08%-99.85%)successfully explained 89.71%-92.92%of total ARG and MGE abundances.Specifically,gene aph(3 )-I,transposase tnpA,and Mycolicibacterium were the primary drivers of the resistance dissemination system.This study also proposes efficient resistance mitigation measures,and provides recommendations for future management of antibiotic fermentation residue.展开更多
This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determine...This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determined at different temperatures using the hot wire method of the “FP2C” machine, where the hot wire probe is inserted between two specimens. The values of the thermal conductivity in powdered Borassus wood range from 0.170 W/mK to 0.182 W/mK for female wood (FNTF) and from 0.169 W/mK to 0.173 W/mK for male wood. For the female and male fibers, the thermal conductivity values range from 0.137 W/mK to 0.157 W/mK for the female and from 0.138 W/mK to 0.168 W/mK for the male. The thermal effusivity of the residues and fibers of Borassus wood varies from: 509.6 Ws1/2/m2K to 543 Ws1/2/m2K for the powder of female wood and from 524.6 Ws1/2/m2K to 547 Ws1/2/m2K for the powder of male wood. For the fibers of Borassus wood, the values range from 410.6 Ws1/2/m2K to 523.6 Ws1/2/m2K for the female wood fibers and from 420.3 Ws1/2/m2K to 480.3 Ws1/2/m2K for the male wood fibers. These results are important for the applications of Borassus wood residues and fibers in construction works regarding the thermal insulation of habitats.展开更多
This paper reviewed the toxicity,maximum residue limits(MRLs)and current residue status of commonly used plant growth regulators in vegetables,including 2,4-dichlorophenoxyacetic acid(2,4-D),naphthaleneacetic acid(NAA...This paper reviewed the toxicity,maximum residue limits(MRLs)and current residue status of commonly used plant growth regulators in vegetables,including 2,4-dichlorophenoxyacetic acid(2,4-D),naphthaleneacetic acid(NAA),ethephon,gibberellin,and paclobutrazol.Methods for reducing residues of plant growth regulators in vegetables were discussed,and recommendations and strategies for their application were proposed.展开更多
Pesticide residues are related to environmental pollution,food safety and other issues,and sample processing is a key link in the whole analysis and detection process.Therefore,it is of far-reaching significance to es...Pesticide residues are related to environmental pollution,food safety and other issues,and sample processing is a key link in the whole analysis and detection process.Therefore,it is of far-reaching significance to establish a reliable and safe pretreatment technique for pesticide detection.QuEChERS(quick,easy,cheap,effective,rugged and safe),as a pretreatment method for pesticide residue analysis,is widely used in the field of testing and analysis because of its characteristics of rapidity,simplicity,low cost and high efficiency.In this paper,the effects of material selection involving extractants,analyte protectants and purification agents and their ratio optimization in QuEChERS method on the improvement of pretreatment efficiency were analyzed,hoping to provide further technical reference for expanding the pretreatment technique.展开更多
The growing population and industrialization have led to significant production in agro-industrial sectors,result-ing in large amounts of agro-industrial residues often left untreated,posing potential environmental is...The growing population and industrialization have led to significant production in agro-industrial sectors,result-ing in large amounts of agro-industrial residues often left untreated,posing potential environmental issues.There-fore,finding effective ways to utilize these bio-based residues is crucial.One promising approach is to use these low-or no-value agro-industrial wastes as raw materials for producing renewable biomaterials,including proteins and peptides.Research has extensively explored peptide extraction using plant and animal-based agro-industrial residue.Due to lower processing costs and beneficial bioactive properties,peptides derived from waste could replace synthetic peptides and those extracted from food sources.The isolation,purification,and analysis processes of these peptides are thoroughly examined to optimize their extraction and ensure their purity and efficacy.These peptides’bioactive properties and mechanisms are being analyzed for their potential applications in the biomedical field.Additionally,the applications of bioactive peptides in medical fields,such as drug delivery systems,tissue engineering,and bioprinting,are discussed.展开更多
Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the m...Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the mechanism and optimal conditions for As fixation in ACR via scorodite formation,while the waste siderite tailings were used to further demonstrate the cotreatment method.The cotreatment method starts with an introduction of sulfuric acid to the ACR for As extraction and gypsum precipitation,and is followed by the addition of H_(2)O_(2) to oxidize As(Ⅲ)in the extraction solutions and finalized by adding siderite with continuous air injection for scorodite formation.The dissolution-oxidation of siderite can slowly produce Fe(Ⅲ)to control aqueous As(V)-Fe(Ⅲ)precipitation supersaturation for continuous scorodite crystallization.Chemical analyses show that the extraction efficiency of As from the ACR reaches 94.55%,while the precipitation yield of extracted As via scorodite formation arrives at 99.63% and 99.47%,leading to fixation efficiency of 94.20% and 94.04% in terms of the total As in the ACR by using siderite reagent and tailings,respectively.The final solid products show desirable TCLP stability and long-term stability,meeting the requirement for safe storage(GB 5085.3-2007).XRD,FTIR,and TEM results reveal that such high stability is attributable to the formation of scorodite and the surface adsorption of As on the raw siderite and secondary maghemite.This innovative and economical application of siderite tailings for the treatment of hazardous ACR can be extended to the management of hydrometallurgical wastes.展开更多
Biochar,a carbon-rich material derived from the thermochemical conversion of biomass under oxygenfree conditions,has emerged as a sustainable resource for radar-absorbing technologies.This study explores the productio...Biochar,a carbon-rich material derived from the thermochemical conversion of biomass under oxygenfree conditions,has emerged as a sustainable resource for radar-absorbing technologies.This study explores the production of activated biochars from end-of-life wood panels using a scalable and sustainable physical activation method with CO_(2) at different temperatures,avoiding the extensive use of corrosive chemicals and complex procedures associated with chemical or vacuum activation.Compared to conventional chemically or vacuum-activated biochars,the physically activated biochar demonstrated competitive performance while minimizing environmental impact,operational complexity,and energy consumption.Furthermore,activation at 750℃ reduces energy consumption by 14% and 28% compared to activations at 850℃ and 950℃,respectively,emphasizing the cost-effectiveness of this method for large-scale applications.The composite with 15% of biochar embedded in silicon rubber presented good electromagnetic performance,achieving a measured reflection loss(RL)of−37.2 dB at 11.3 GHz with an 8.4 mm thickness and an effective absorption bandwidth(EAB)of 1.25 GHz.These results highlight the potential of biocharsilicone rubber composites as flexible radar-absorbing materials(RAMs)for applications in electromagnetic shielding,anechoic chambers,and Internet of Things(IoT)devices.This study also shows the importance of forestry residues as sustainable precursors for producing low-cost porous carbon materials,aligning with circular economy principles and the United Nations’2030 Agenda for Sustainable Development.This work establishes a framework for scalable,cost-effective,and sustainable biochar production,addressing critical challenges in electromagnetic interference(EMI)mitigation and advancing the global adoption of green technologies.展开更多
Butyrylcholinesterase(BChE)is a key enzyme in the metabolism of cholinergic compounds.It has been recognized as a key biomarker for many diseases,including liver diseases and Alzheimer’s disease.However,classical met...Butyrylcholinesterase(BChE)is a key enzyme in the metabolism of cholinergic compounds.It has been recognized as a key biomarker for many diseases,including liver diseases and Alzheimer’s disease.However,classical methods for detecting BChE activity suffer from low sensitivity,cumbersome pre-treatment,and poor stability.Chemiluminescence is a promising new method for detecting and imaging the activity of BChE.It has several advantages over traditional methods,including low background interference,high sensitivity,and the absence of external illumination.In this study,we developed a novel BChE-activatable chemiluminescent probe(CL-BChE).It exhibited a significant chemiluminescence enhancement at 525nm upon incubation with BChE.It had a low limit of detection(6.25×10^(−3)U/mL)and was highly selective for BChE.CL-BChE was used to image BChE activity in living cells and tumor-bearing animal models.It was also successfully applied to detect pesticide residue,even under the interference of representative phytochromes and real vegetable samples.Given its high sensitivity,selectivity,and versatility,we believe that CL-BChE will be a promising tool for investigating BChE’s activity in biomedical research as well as other BChE-related scenarios.展开更多
The effective reuse of iron phosphate residue(IPR)is the key issue in the recycling of spent LiFePO_(4)batteries.Therefore,in this study,the reduction leaching of IPR in H_(2)SO_(4)solution by adding iron powder as re...The effective reuse of iron phosphate residue(IPR)is the key issue in the recycling of spent LiFePO_(4)batteries.Therefore,in this study,the reduction leaching of IPR in H_(2)SO_(4)solution by adding iron powder as reducing agent was investigated and compared with direct leaching.The results show that the leaching rate of IPR reached 97%under the optimum reduction leaching conditions.Kinetic studies show that the activation energy for reduction leaching is 12.71 k J/mol,while that of direct leaching is 21.57 k J/mol.Moreover,the reduction leaching time is reduced by half and the acid consumption is reduced by 30% compared to direct leaching with the same leaching rate.This work provides a scientific guidance to the treatment of iron phosphate residue from the recycling of spent LiFePO_(4)batteries.展开更多
A comprehensive insight into the evolution and molecular structure of basic and neutral nitrogen compounds during the residue hydrotreating(RHT)process was gained through ESI(+)/ESI(-)FT-ICR MS analysis of the feedsto...A comprehensive insight into the evolution and molecular structure of basic and neutral nitrogen compounds during the residue hydrotreating(RHT)process was gained through ESI(+)/ESI(-)FT-ICR MS analysis of the feedstock and its hydrogenated samples,with hydrodenitrogenation(HDN)ratios of 15.9%-70.1%.This study revealed that carbazoles,characterized by a double bond equivalent(DBE)of 9-11,were the refractory neutral nitrogen compounds during the RHT process.Their recalcitrant nature was primarily due to their low aromaticity and high steric hindrance.Conversely,quinolines(DBEs 7 to 9)were the most abundant basic nitrogen compounds.Through a meticulous analysis of DBE evolution,we revealed the intricate reaction mechanisms of benzocarbazoles and dibenzocarbazoles in residual oil,highlighting the crucial role of quinolines as key intermediates in eliminating these compounds.Interestingly,nitrogen compounds with either low or high carbon numbers(for a given DBE)exhibited higher reactivity than those with medium carbon numbers,which can be attributed to the low steric hindrance resulting from short alkyl chains and more naphthenic-aromatic structures,respectively.After hydrotreatment,the molecular structures of the most refractory or abundant nitrogen compounds could consist of two main types:those with multiple naphthenic-aromatic rings and those with long side chains near the nitrogen atom.This research has revealed nitrogen compounds'evolutionary mechanisms and refractory nature,and the molecular structure of the most resistant or abundant basic and neutral nitrogen compounds,providing a deeper understanding of the HDN process and ultimately paving the way for the rational RHT catalyst design and process development.展开更多
The effects of calcination temperature and mechanical ball milling on the physicochemical properties of electrolytic manganese residue(EMR),mineral phase transition,pozzolanic activity,and pore structure were studied....The effects of calcination temperature and mechanical ball milling on the physicochemical properties of electrolytic manganese residue(EMR),mineral phase transition,pozzolanic activity,and pore structure were studied.The experimental results show that the strength activity index(SAI)of 20%EMR mixed mortar at 28 days is 90.54%,95.40%,and 90.73%,respectively,after pretreatment with EMR at 800℃calcined for 3,5,and 8 min.This is mainly attributed to the high temperature decomposition of gypsum dihydrate to form activated calcium oxide.In addition,high temperature and mechanical force destroys the Si-O chemical bond and promotes the formation of calcium silicate gel structure.Due to the existence of a large number of gypsum phases in EMR mixed mortar,a large number of ettringite,C-S-H,aluminosilicate,C-A-S-H,and AFm are formed,which strongly verifies the volcanic activity of EMR.The leaching test shows that high temperature calcination has a significant effect on the stabilization of NH_(3)-N.However,the curing effect of Mn^(2+)is significant only in the calcination at 1000℃,but both Mn^(2+)and NH_(3)-N in the calcined EMR are higher than the emission standard.The encapsulation effect of EMR composite mortar provided by hydration products,and the buffering capacity of the Si-Al system for solidification of heavy metals and strong alkalis are conducive to the stability of Mn^(2+)and NH_(3)-N.After the EMR mixed mortar is aged for 3 days,Mn and NH_(3)-N are completely lower than the emission standard.In general,the EMR mixed mortar can meet the requirements for green building use.展开更多
基金financially supported by the National Key R&D Program of China(2021YFD1901203 and 2021YFD1901204)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0440404)+2 种基金the National Natural Science Foundation of China(42377348)the Science Foundation for Distinguished Young Scholars of Hunan Province,China(2024JJ2052)the Natural Science Foundation of Guangxi,China(2025GXNSFAA069337)。
文摘Rapidly improving infertile croplands and enhancing their soil organic carbon(SOC)pool necessitate substantial organic materials incorporation.Converting loose crop straw into granulated form facilitates uniform incorporation within the plough soil layer.As an innovative soil amelioration approach,the efficiency and patterns of SOC accumulation remain unclear.Two field experiments were conducted in infertile subtropical upland and paddy soils with 0,30,60,and 90 Mg ha^(-1)granulated straw incorporation.After one year,SOC accumulation efficiency from straw input remained stable in upland(30.8–37.5%)with increasing amounts of straw incorporation,while declined from 60.0 to 38.3%in paddy.In both croplands,the contributions of lignin phenols to SOC increased with increasing straw incorporation,while the contributions from amino sugars remained constant at higher straw input levels.Subsequently,the ratios of lignin phenols to amino sugars increased with increasing straw incorporation,indicating faster plant residue accumulation compared to microbial necromass,as the granulation approach limited microbial involvement in straw transformation.Thus,single-time incorporation of substantial granulated straw presents an effective agricultural strategy for rapid amelioration of infertile croplands.
基金supported by the National Natural Science Foundation of China(No.52471221)the Natural Science Foundation of Hunan Province,China(No.2024JJ7145)the National Sustainable Development Agenda Innovation Demonstration Zone Hunan special project,China(No.2022sfq09).
文摘With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on the synthesis of porous Fe_(3)O_(4)/C composites that incorporate dielectric and magnetic loss mechanisms via the carbothermal reduction method and optimization of waste ratio to enhance EWA performance.The Fe_(3)O_(4)/C composites with 10wt%soybean residues(Fe_(3)O_(4)/C-10),demonstrated the best EWA performance,achieving the minimum reflection loss of−56.4 dB and a bandwidth of 2.14 GHz at a thickness of 2.23 mm.This enhanced EWA performance is primarily attributable to improved impedance matching and the synergistic effect between dielectric and magnetic losses.Furthermore,radar cross-sectional simulations confirmed the practical feasibility of the porous Fe_(3)O_(4)/C composites.This study proposes a viable strategy for utilizing soybean residue and electrolytic manganese residue,highlighting their potential applications in EWA.
基金financially supported by the Research Project Supported by Shanxi Scholarship Council of China(No.2022-049)the Natural Science Foundation of Shanxi Province,China(No.20210302123167)。
文摘Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications.Coal tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable world.In this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances assessment.Based on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were obtained.Furthermore,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of CTRCs.Results indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”mechanism.This work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.
基金Hunan Provincial Key Research and Development Project, China (No. 2022SK2075)National Natural Science Foundation of China (No. 52004339)。
文摘An efficient process based on oxidizing roasting−direct reduction−smelting−electrorefining was developed to separate and recover Zn,In,Ga and Fe from a typical hazardous jarosite residue.Phase transformation and element migration during each separating process were evaluated by X-ray diffraction analysis(XRD),thermo-gravimetric−differential scanning calorimetry(TG−DSC),and scanning electron microscopy−energy dispersive spectrometry(SEM−EDS).The results show that the jarosite residue decomposed into hematite and zinc ferrite when oxidizing roasted at 1250℃ for 20 min.Then,Zn and In were volatilized and enriched into flue dust through the reductive roasting of oxidized pellets at 1200℃ for 60 min.Finally,Fe and Ga were separated by smelting−electrorefining of the reduced pellets to obtain high purity iron powder with 99.5%Fe and anode slime with 456 g/t Ga.Through the process,a total recovery of 97.42%Zn,87.86%In,90.70%Fe and 84.78%Ga can be achieved.
基金supported by the National Natural Science Foundation of China(No.52170138)the National Key Research and Development Program of China(No.2023YFD1900305)+3 种基金Qingdao Agricultural University Doctoral Start-Up Fund(No.6631122003)the Project of Talent IntroductionEducation Program of Youth Innovation Teams in Universities of Shandong Province(2021–05)Shandong Provincial College Youth Innovation Team Program(No.2023KJ169).
文摘Cyclosporin A fermentation residue(CFR)is a type of organic waste generated during the production of cyclosporin A,which are abundant in nutrients including organic matter,phosphorus,nitrogen and potassium.Inappropriate handling of CFR not only waste valuable bioresources,but may also lead to the cyclosporin A and associated resistance genes into the natural environment,posing a significant threat to ecological system and human health.Land application was an effective way to resource recovery of CFR after aerobic composting(CAC).This study investigated the impact of CAC on soil fertility and environmental safety.The results indicated that CAC could improve soil nutrient contents and enhance enzyme activities.CAC altered the diversity and community composition of soil bacteria,resulting in an increase in the abundance of relevant bacteria beneficial for organic matter decomposition and cyclosporin A degradation.The introduced cyclosporin A(71.69μg/kg)completely degraded within 20 days due to soil biodegradation.The significantly increased abundance of intIl,mdr3,pgp,TSR and pmra in the soil cultivation early stage were restored to the soil background level within 90 days,indicating a reduced risk of antimicrobial resistance.The results demonstrated that reasonable land application of CAC could improve soil fertility without antimicrobial resistance risk,which is helpful for evaluating the resource utilization value and environmental risks of antibiotic fermentation residue after aerobic composting.
文摘A new manufactured soil product (Turba) was produced using acidified bauxite residue into which 10% green waste compost had been incorporated. A laboratory/greenhouse experiment was carried out to determine if sand could be used as an ingredient or an amendment for Turba. Sand was added at rates of 0%, 5%, 10%, 25, 50% and 75% (w/w) in two different ways 1) by incorporating it into the Turba during its manufacture (IN) or 2) by mixing it with Turba aggregates after their manufacture (OUT). Incorporation of sand into Turba aggregates (IN) decreased the percentage of sample present as large aggregates (2 - 4 mm dia.) after crushing and sieving (<4 mm) and also reduced the stability of 2 - 4 mm dia. formed aggregates (to dry/wet sieving) and are therefore not recommended. In a 16-week greenhouse study, ryegrass shoot yields were greater in Turba than in sand [and decreased with increasing sand additions (OUT)] while root dry matter showed the opposite trend. The greater grass growth in Turba than sand was attributed to incipit water stress in plants grown in sand and this may have promoted greater allocation of assimilates to roots resulting in a greater root-to-top mass ratio. The much lower macroporosity in Turba coupled with the solid cemented nature of Turba aggregates resulted in production of thinner roots and therefore greater root length than in sand. Turba (manufactured from bauxite residue and compost added at 10% w/w) is a suitable medium for plant growth and there is no advantage in incorporating sand into, or with, the Turba aggregates.
文摘The residual biomass composed of pseudo trunks and banana leaves is very important and poorly valued. There is very little quantified data on the deposits of residual biomass from banana plantations in Senegal and in particular in the Tambacounda region. In this work, we seek to evaluate the methanogenic potential and to valorize this biomass in biogas and biofertilizer. The laboratory experiment lasted approximately 35 days. During this time, the methanogenic microorganisms degrade the organic residue provided, which results in the production of biogas. At the end of the reactions, the rate of biogas production drops, indicating the end of the biodegradation of organic matter. Biogas production is measured over time and the composition of the biogas produced is analyzed by gas chromatography (GC) or by an infrared analyzer. The methane potential of each sample is determined from the cumulative quantity of methane produced in each flask representing a digestion system. The measurement can be expressed in m3 of CH4 per tonne of dry matter or per tonne of raw material. The first challenge of this study therefore lies in the acquisition of reliable and usable data to quantify the methanizable biomass. This study will allow us not only to evaluate the quantities of pseudo trunks and banana leaves available in a plot after harvest but also to test the biogas and methane production potential (BMP test) of this substrate and therefore determine the expected biogas production of this biomass.
基金Supported by National Natural Science Foundation of China(Grant No.52405285)the Sichuan University Young Teachers'Capacity Improvement Program in Science and Technology Innovation(Grant No.2024SCUQJTX026)Sichuan Provincial Engineering Technology Research Center of Broadband Electronics Intelligent Manufacturing(Grant No.BEIM2022A001)。
文摘In the context of Industry 5.0,more emphasis is placed on human-centric smart manufacturing patterns.Product design is a vital phase of smart manufacturing,involving user engagement is an essential factor in enhancing design quality and fostering innovation.With user involvement in-depth,dynamically changing user requirements and feedback bring new problems to the design process,and the traditional linear solving process cannot perceive such variations timely,which causes hysteresis in the solution.The design solution's hysteresis affects the consensus achievement process between the designer and user,further prolonging the iteration cycle.To address this issue,a human-centric product conceptual design model is proposed for the timely translation of such variations into design solutions.In this model,design problems are formed by centering on user requirements,designer and user collaboratively solve the problems to form design solutions.Through a cycle of problem-driven,knowledgesupported,and solution evaluation,new problems are solved promptly to achieve progressive solution convergence,which clarifies the iterative evolution process and improves iterative efficiency.To verify the effectiveness of the model,a natural gas well foaming agent automatic filling device design is presented.
基金supported by the National Natural Science Foundation of China(No.42050103)。
文摘Continental crust is the long-term achievements of Earth's evolution across billions of years.The continental rocks could have been modified by various types of geological processes,such as metamorphism,weathering,and reworking.Therefore,physical or chemical properties of rocks through time record the composite effects of geological,biological,hydrological,and climatological processes.Temporal variations in these time series datasets could provide important clues for understanding the co-evolution of different layers on Earth.However,deciphering Earth's evolution in deep time is challenged by incompleteness,singularity,and intermittence of geological records associated with extreme geological events,hindering a rigorous assessment of the underlying coupling mechanisms.Here,we applied the recently developed local singularity analysis and wavelet analysis method to deep-time U-Pb age spectra and sedimentary abundance record across the past 3.5 Gyrs.Standard cross-correlation analysis suggests that the singularity records of marine sediment accumulations and magmatism intensity at continental margin are correlated negatively(R^(2)=0.8),with a delay of~100 Myr.Specifically,wavelet coherence analysis suggests a~500-800 Myr cycle of correlation between two records,implying a coupling between the major downward processes(subduction and recycling sediments)and upward processes(magmatic events)related to the aggregation and segregation of supercontinents.The results clearly reveal the long-term cyclic feedback mechanism between sediment accumulation and magmatism intensity through aggregation of supercontinents.
基金supported by the Special Project of Basic Scientific Research Business of Central Public Welfare Scientific Research Institutes (No.2019YSKY-027).
文摘Erythromycin fermentation residue(EFR)represents a typical hazardous waste produced by the microbial pharmaceutical industry.Although electrolysis is promising for EFR disposal,its microbial threats remain unclear.Herein,metagenomics was coupled with the random forest technique to decipher the antibiotic resistance patterns of electrochemically treated EFR.Results showed that 95.75%of erythromycin could be removed in 2 hr.Electrolysis temporarily influenced EFRmicrobiota,where the relative abundances of Proteobacteria and Actinobacteria increased,while those of Fusobacteria,Firmicutes,and Bacteroidetes decreased.A total of 505 antibiotic resistance gene(ARG)subtypes encoding resistance to 21 antibiotic types and 150 mobile genetic elements(MGEs),mainly including plasmid(72)and transposase(52)were assembled in EFR.Significant linear regression models were identified among microbial richness,ARG subtypes,and MGE numbers(r^(2)=0.50-0.81,p<0.001).Physicochemical factors of EFR(Total nitrogen,total organic carbon,protein,and humus)regulated ARG and MGE assembly(%IncMSE value=5.14-14.85).The core ARG,MGE,and microbe sets(93.08%-99.85%)successfully explained 89.71%-92.92%of total ARG and MGE abundances.Specifically,gene aph(3 )-I,transposase tnpA,and Mycolicibacterium were the primary drivers of the resistance dissemination system.This study also proposes efficient resistance mitigation measures,and provides recommendations for future management of antibiotic fermentation residue.
文摘This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determined at different temperatures using the hot wire method of the “FP2C” machine, where the hot wire probe is inserted between two specimens. The values of the thermal conductivity in powdered Borassus wood range from 0.170 W/mK to 0.182 W/mK for female wood (FNTF) and from 0.169 W/mK to 0.173 W/mK for male wood. For the female and male fibers, the thermal conductivity values range from 0.137 W/mK to 0.157 W/mK for the female and from 0.138 W/mK to 0.168 W/mK for the male. The thermal effusivity of the residues and fibers of Borassus wood varies from: 509.6 Ws1/2/m2K to 543 Ws1/2/m2K for the powder of female wood and from 524.6 Ws1/2/m2K to 547 Ws1/2/m2K for the powder of male wood. For the fibers of Borassus wood, the values range from 410.6 Ws1/2/m2K to 523.6 Ws1/2/m2K for the female wood fibers and from 420.3 Ws1/2/m2K to 480.3 Ws1/2/m2K for the male wood fibers. These results are important for the applications of Borassus wood residues and fibers in construction works regarding the thermal insulation of habitats.
文摘This paper reviewed the toxicity,maximum residue limits(MRLs)and current residue status of commonly used plant growth regulators in vegetables,including 2,4-dichlorophenoxyacetic acid(2,4-D),naphthaleneacetic acid(NAA),ethephon,gibberellin,and paclobutrazol.Methods for reducing residues of plant growth regulators in vegetables were discussed,and recommendations and strategies for their application were proposed.
基金Supported by The Fourth Batch of High-end Talent Project in Hebei ProvinceThe Special Fund of the Central Government Guiding Local Science and Technology Development(226Z5504G)Tangshan Talent Funding Project(A202202005).
文摘Pesticide residues are related to environmental pollution,food safety and other issues,and sample processing is a key link in the whole analysis and detection process.Therefore,it is of far-reaching significance to establish a reliable and safe pretreatment technique for pesticide detection.QuEChERS(quick,easy,cheap,effective,rugged and safe),as a pretreatment method for pesticide residue analysis,is widely used in the field of testing and analysis because of its characteristics of rapidity,simplicity,low cost and high efficiency.In this paper,the effects of material selection involving extractants,analyte protectants and purification agents and their ratio optimization in QuEChERS method on the improvement of pretreatment efficiency were analyzed,hoping to provide further technical reference for expanding the pretreatment technique.
基金funded by the Thailand Graduate Institute of Science and Technology(TGIST)(Grant No.TG-BT-AIT-63-002D).
文摘The growing population and industrialization have led to significant production in agro-industrial sectors,result-ing in large amounts of agro-industrial residues often left untreated,posing potential environmental issues.There-fore,finding effective ways to utilize these bio-based residues is crucial.One promising approach is to use these low-or no-value agro-industrial wastes as raw materials for producing renewable biomaterials,including proteins and peptides.Research has extensively explored peptide extraction using plant and animal-based agro-industrial residue.Due to lower processing costs and beneficial bioactive properties,peptides derived from waste could replace synthetic peptides and those extracted from food sources.The isolation,purification,and analysis processes of these peptides are thoroughly examined to optimize their extraction and ensure their purity and efficacy.These peptides’bioactive properties and mechanisms are being analyzed for their potential applications in the biomedical field.Additionally,the applications of bioactive peptides in medical fields,such as drug delivery systems,tissue engineering,and bioprinting,are discussed.
基金supported by the National Natural Science Foundation of China(Nos.42207258 and 52270150)the Liaoning Provincial Natural Science Foundation Program Project(No.2022-BS-312)+1 种基金the Liaoning University of Technology Doctoral Research Start-up Fund Project(No.XB2021013)the Shenyang Youth Science and Technology Project(No.RC210166).
文摘Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the mechanism and optimal conditions for As fixation in ACR via scorodite formation,while the waste siderite tailings were used to further demonstrate the cotreatment method.The cotreatment method starts with an introduction of sulfuric acid to the ACR for As extraction and gypsum precipitation,and is followed by the addition of H_(2)O_(2) to oxidize As(Ⅲ)in the extraction solutions and finalized by adding siderite with continuous air injection for scorodite formation.The dissolution-oxidation of siderite can slowly produce Fe(Ⅲ)to control aqueous As(V)-Fe(Ⅲ)precipitation supersaturation for continuous scorodite crystallization.Chemical analyses show that the extraction efficiency of As from the ACR reaches 94.55%,while the precipitation yield of extracted As via scorodite formation arrives at 99.63% and 99.47%,leading to fixation efficiency of 94.20% and 94.04% in terms of the total As in the ACR by using siderite reagent and tailings,respectively.The final solid products show desirable TCLP stability and long-term stability,meeting the requirement for safe storage(GB 5085.3-2007).XRD,FTIR,and TEM results reveal that such high stability is attributable to the formation of scorodite and the surface adsorption of As on the raw siderite and secondary maghemite.This innovative and economical application of siderite tailings for the treatment of hazardous ACR can be extended to the management of hydrometallurgical wastes.
基金FINEP No.01.22.0305.00CAPES—Finance Code 88887.832847/2023-00 and 88887.631486/2021-00.
文摘Biochar,a carbon-rich material derived from the thermochemical conversion of biomass under oxygenfree conditions,has emerged as a sustainable resource for radar-absorbing technologies.This study explores the production of activated biochars from end-of-life wood panels using a scalable and sustainable physical activation method with CO_(2) at different temperatures,avoiding the extensive use of corrosive chemicals and complex procedures associated with chemical or vacuum activation.Compared to conventional chemically or vacuum-activated biochars,the physically activated biochar demonstrated competitive performance while minimizing environmental impact,operational complexity,and energy consumption.Furthermore,activation at 750℃ reduces energy consumption by 14% and 28% compared to activations at 850℃ and 950℃,respectively,emphasizing the cost-effectiveness of this method for large-scale applications.The composite with 15% of biochar embedded in silicon rubber presented good electromagnetic performance,achieving a measured reflection loss(RL)of−37.2 dB at 11.3 GHz with an 8.4 mm thickness and an effective absorption bandwidth(EAB)of 1.25 GHz.These results highlight the potential of biocharsilicone rubber composites as flexible radar-absorbing materials(RAMs)for applications in electromagnetic shielding,anechoic chambers,and Internet of Things(IoT)devices.This study also shows the importance of forestry residues as sustainable precursors for producing low-cost porous carbon materials,aligning with circular economy principles and the United Nations’2030 Agenda for Sustainable Development.This work establishes a framework for scalable,cost-effective,and sustainable biochar production,addressing critical challenges in electromagnetic interference(EMI)mitigation and advancing the global adoption of green technologies.
基金the financial support from the National Natural Science Foundation of China(Nos.82272067,81974386,and M-0696)Natural Science Foundation of Hunan Province(Nos.2022JJ80052 and 2022JJ40656)the Innovation Fund for Postgraduate Students of Central South University(No.2023ZZTS0609)。
文摘Butyrylcholinesterase(BChE)is a key enzyme in the metabolism of cholinergic compounds.It has been recognized as a key biomarker for many diseases,including liver diseases and Alzheimer’s disease.However,classical methods for detecting BChE activity suffer from low sensitivity,cumbersome pre-treatment,and poor stability.Chemiluminescence is a promising new method for detecting and imaging the activity of BChE.It has several advantages over traditional methods,including low background interference,high sensitivity,and the absence of external illumination.In this study,we developed a novel BChE-activatable chemiluminescent probe(CL-BChE).It exhibited a significant chemiluminescence enhancement at 525nm upon incubation with BChE.It had a low limit of detection(6.25×10^(−3)U/mL)and was highly selective for BChE.CL-BChE was used to image BChE activity in living cells and tumor-bearing animal models.It was also successfully applied to detect pesticide residue,even under the interference of representative phytochromes and real vegetable samples.Given its high sensitivity,selectivity,and versatility,we believe that CL-BChE will be a promising tool for investigating BChE’s activity in biomedical research as well as other BChE-related scenarios.
基金financial support from the Hunan Provincial Natural Science Foundation,China(No.2022JJ10074)。
文摘The effective reuse of iron phosphate residue(IPR)is the key issue in the recycling of spent LiFePO_(4)batteries.Therefore,in this study,the reduction leaching of IPR in H_(2)SO_(4)solution by adding iron powder as reducing agent was investigated and compared with direct leaching.The results show that the leaching rate of IPR reached 97%under the optimum reduction leaching conditions.Kinetic studies show that the activation energy for reduction leaching is 12.71 k J/mol,while that of direct leaching is 21.57 k J/mol.Moreover,the reduction leaching time is reduced by half and the acid consumption is reduced by 30% compared to direct leaching with the same leaching rate.This work provides a scientific guidance to the treatment of iron phosphate residue from the recycling of spent LiFePO_(4)batteries.
基金the financial support from the National Key Research and Development Program of China(2021YFA1501204)the project of SINOPEC RIPP Co.Ltd(PR20230230)。
文摘A comprehensive insight into the evolution and molecular structure of basic and neutral nitrogen compounds during the residue hydrotreating(RHT)process was gained through ESI(+)/ESI(-)FT-ICR MS analysis of the feedstock and its hydrogenated samples,with hydrodenitrogenation(HDN)ratios of 15.9%-70.1%.This study revealed that carbazoles,characterized by a double bond equivalent(DBE)of 9-11,were the refractory neutral nitrogen compounds during the RHT process.Their recalcitrant nature was primarily due to their low aromaticity and high steric hindrance.Conversely,quinolines(DBEs 7 to 9)were the most abundant basic nitrogen compounds.Through a meticulous analysis of DBE evolution,we revealed the intricate reaction mechanisms of benzocarbazoles and dibenzocarbazoles in residual oil,highlighting the crucial role of quinolines as key intermediates in eliminating these compounds.Interestingly,nitrogen compounds with either low or high carbon numbers(for a given DBE)exhibited higher reactivity than those with medium carbon numbers,which can be attributed to the low steric hindrance resulting from short alkyl chains and more naphthenic-aromatic structures,respectively.After hydrotreatment,the molecular structures of the most refractory or abundant nitrogen compounds could consist of two main types:those with multiple naphthenic-aromatic rings and those with long side chains near the nitrogen atom.This research has revealed nitrogen compounds'evolutionary mechanisms and refractory nature,and the molecular structure of the most resistant or abundant basic and neutral nitrogen compounds,providing a deeper understanding of the HDN process and ultimately paving the way for the rational RHT catalyst design and process development.
基金Funded by the National Natural Science Foundation of China(No.52178216)the Gansu Provincial Science and Technology Programme(No.23JRRA813)。
文摘The effects of calcination temperature and mechanical ball milling on the physicochemical properties of electrolytic manganese residue(EMR),mineral phase transition,pozzolanic activity,and pore structure were studied.The experimental results show that the strength activity index(SAI)of 20%EMR mixed mortar at 28 days is 90.54%,95.40%,and 90.73%,respectively,after pretreatment with EMR at 800℃calcined for 3,5,and 8 min.This is mainly attributed to the high temperature decomposition of gypsum dihydrate to form activated calcium oxide.In addition,high temperature and mechanical force destroys the Si-O chemical bond and promotes the formation of calcium silicate gel structure.Due to the existence of a large number of gypsum phases in EMR mixed mortar,a large number of ettringite,C-S-H,aluminosilicate,C-A-S-H,and AFm are formed,which strongly verifies the volcanic activity of EMR.The leaching test shows that high temperature calcination has a significant effect on the stabilization of NH_(3)-N.However,the curing effect of Mn^(2+)is significant only in the calcination at 1000℃,but both Mn^(2+)and NH_(3)-N in the calcined EMR are higher than the emission standard.The encapsulation effect of EMR composite mortar provided by hydration products,and the buffering capacity of the Si-Al system for solidification of heavy metals and strong alkalis are conducive to the stability of Mn^(2+)and NH_(3)-N.After the EMR mixed mortar is aged for 3 days,Mn and NH_(3)-N are completely lower than the emission standard.In general,the EMR mixed mortar can meet the requirements for green building use.
