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Flame-retardant epoxy thermosets derived from renewable resources:Research development and future perspectives 被引量:5
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作者 Yao Yuan Weiliang Lin +2 位作者 Yi Xiao Bin Yu Wei Wang 《Journal of Materials Science & Technology》 CSCD 2024年第28期29-40,共12页
Nowadays,the predominant source for approximately 90%of epoxy resin materials worldwide is the diglycidyl ether of bisphenol A(DGEBA).However,the increasing recognition of environmental concerns,such as global warming... Nowadays,the predominant source for approximately 90%of epoxy resin materials worldwide is the diglycidyl ether of bisphenol A(DGEBA).However,the increasing recognition of environmental concerns,such as global warming and the depletion of petroleum reserves,necessitates the exploration of alternative options,specifically bio-epoxy resin derived from sustainable resources.Nonetheless,the inadequate flame retardancy of bio-epoxy resin presents a notable drawback,limiting its applicability in high-risk environments.The objective of this review article is to provide a concise overview of the latest and upto-date advances in flame-retardant epoxy resins derived from sustainable sources.Firstly,the discussion encompasses inherently flame-retardant bio-based epoxy resins,considering both bio-based epoxy monomers and bio-based curing agents,focusing on their flame retardancy and mechanical properties.Furthermore,the utilization of phosphorus-containing and silicon-containing additives in bio-based epoxy is explored.Additionally,a comprehensive evaluation of partially bio-based intrinsically flame retardant epoxy resins is provided.Finally,this article offers an extensive survey of the current state-of-the-art in the field and presents future perspectives,serving as a valuable resource for researchers engaged in the study of flame-retardant epoxy resins derived from sustainable resources. 展开更多
关键词 Bio-based epoxy Inherently flame retardant renewable resources Mechanical properties
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Bio-based polymeric materials synthesized from renewable resources: A mini-review 被引量:7
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作者 Yitong Xie Shishuai Gao +2 位作者 Daihui Zhang Chunpeng Wang Fuxiang Chu 《Resources Chemicals and Materials》 2023年第3期223-230,共8页
In recent years,bio-based polymeric materials have attracted increased attention owing to their distinctive prop-erties,including richness,sustainability,environmental friendliness,and biodegradability.This article re... In recent years,bio-based polymeric materials have attracted increased attention owing to their distinctive prop-erties,including richness,sustainability,environmental friendliness,and biodegradability.This article reviews the recent developments and potential trends of research on bio-based polymers synthesized from various re-newable resources.It covers the resources and structures of bio-based monomers,the methods of synthesis and properties of bio-based thermoplastics and thermosets,the production of bio-based composites and the fabrica-tion of functional bio-based polymers.Finally,the technological and future challenges related to enabling these materials to apply in the industry have been discussed,together with the potential solutions or directions. 展开更多
关键词 Biobased polymers renewable resources MATERIALS FUNCTIONALITY
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Hybrid Ensemble-Learning Approach for Renewable Energy Resources Evaluation in Algeria 被引量:3
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作者 El-Sayed M.El-Kenawy Abdelhameed Ibrahim +4 位作者 Nadjem Bailek Kada Bouchouicha Muhammed A.Hassan Basharat Jamil Nadhir Al-Ansari 《Computers, Materials & Continua》 SCIE EI 2022年第6期5837-5854,共18页
In order to achieve a highly accurate estimation of solar energy resource potential,a novel hybrid ensemble-learning approach,hybridizing Advanced Squirrel-Search Optimization Algorithm(ASSOA)and support vector regres... In order to achieve a highly accurate estimation of solar energy resource potential,a novel hybrid ensemble-learning approach,hybridizing Advanced Squirrel-Search Optimization Algorithm(ASSOA)and support vector regression,is utilized to estimate the hourly tilted solar irradiation for selected arid regions in Algeria.Long-term measured meteorological data,including mean-air temperature,relative humidity,wind speed,alongside global horizontal irradiation and extra-terrestrial horizontal irradiance,were obtained for the two cities of Tamanrasset-and-Adrar for two years.Five computational algorithms were considered and analyzed for the suitability of estimation.Further two new algorithms,namely Average Ensemble and Ensemble using support vector regression were developed using the hybridization approach.The accuracy of the developed models was analyzed in terms of five statistical error metrics,as well as theWilcoxon rank-sum and ANOVA test.Among the previously selected algorithms,K Neighbors Regressor and support vector regression exhibited good performances.However,the newly proposed ensemble algorithms exhibited even better performance.The proposed model showed relative root mean square errors lower than 1.448%and correlation coefficients higher than 0.999.This was further verified by benchmarking the new ensemble against several popular swarm intelligence algorithms.It is concluded that the proposed algorithms are far superior to the commonly adopted ones. 展开更多
关键词 renewable energy resources hybrid modeling tilted solar irradiation arid region
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Multi-objective planning model for simultaneous reconfiguration of power distribution network and allocation of renewable energy resources and capacitors with considering uncertainties 被引量:10
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作者 Sajad Najafi Ravadanegh Mohammad Reza Jannati Oskuee Masoumeh Karimi 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第8期1837-1849,共13页
This research develops a comprehensive method to solve a combinatorial problem consisting of distribution system reconfiguration, capacitor allocation, and renewable energy resources sizing and siting simultaneously a... This research develops a comprehensive method to solve a combinatorial problem consisting of distribution system reconfiguration, capacitor allocation, and renewable energy resources sizing and siting simultaneously and to improve power system's accountability and system performance parameters. Due to finding solution which is closer to realistic characteristics, load forecasting, market price errors and the uncertainties related to the variable output power of wind based DG units are put in consideration. This work employs NSGA-II accompanied by the fuzzy set theory to solve the aforementioned multi-objective problem. The proposed scheme finally leads to a solution with a minimum voltage deviation, a maximum voltage stability, lower amount of pollutant and lower cost. The cost includes the installation costs of new equipment, reconfiguration costs, power loss cost, reliability cost, cost of energy purchased from power market, upgrade costs of lines and operation and maintenance costs of DGs. Therefore, the proposed methodology improves power quality, reliability and security in lower costs besides its preserve, with the operational indices of power distribution networks in acceptable level. To validate the proposed methodology's usefulness, it was applied on the IEEE 33-bus distribution system then the outcomes were compared with initial configuration. 展开更多
关键词 optimal reconfiguration renewable energy resources sitting and sizing capacitor allocation electric distribution system uncertainty modeling scenario based-stochastic programming multi-objective genetic algorithm
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Tapping Renewable Energy Resources -with A Combined Capacity of 1236 MW as Target for the Year 2000
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《Electricity》 1996年第2期29-31,共3页
China began the research and development of renewable energy generation since 1970s, in particular in the Eighth Five-year Plan period, the State made closer attention to the research and development of renewable ener... China began the research and development of renewable energy generation since 1970s, in particular in the Eighth Five-year Plan period, the State made closer attention to the research and development of renewable energy, therefore the technical level, application scale and economic, social benefits have seen greater progress. The combined capacity of renewable energy generation reached 100 MW at the end of 1994. And it is planned a combined capacity of 1236 MW will be targeted for the year 2000. 展开更多
关键词 Tapping renewable Energy resources with A Combined Capacity of 1236 MW as Target for the Year 2000 TARGET
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China puts more money in renewable energy resources
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《Electricity》 2011年第5期41-41,共1页
In 2010, over 300 billion yuan ($47.31 billion) are invested in renewable energy sources in China, outranking every other country. Hence, China has become one of the world’s biggest investors in renewable energy sour... In 2010, over 300 billion yuan ($47.31 billion) are invested in renewable energy sources in China, outranking every other country. Hence, China has become one of the world’s biggest investors in renewable energy sources. 展开更多
关键词 MORE China puts more money in renewable energy resources
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Status of Renewable Energy Applications in the Malaysian Energy Mix
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作者 A.H. Shamsuddin 《Journal of Energy and Power Engineering》 2010年第12期24-30,共7页
Demand for power in Malaysia is projected to double the current demand in 2030. The current fuel mix for power generation is heavily dependent on fossil fuels. This has created energy supply and environmental sustaina... Demand for power in Malaysia is projected to double the current demand in 2030. The current fuel mix for power generation is heavily dependent on fossil fuels. This has created energy supply and environmental sustainability concerns to the industry. Furthermore, at the recent United Nations Climate Change Conference 2009-15th Conference of Parties (COP15), Malaysia had given the commitment to voluntary reduction of up to 40% in terms of emissions intensity of GDP by the year 2020 compared to 2005 levels. Renewable energy (RE) provides the best alternative in addressing these issues. In 2001, RE was regarded as the fifth fuel in the new Five Fuel Strategy of the National Energy Policy. Small Renewable Energy Program (SREP) was launched with the main objective of supporting the government's strategy to intensify the development of RE as the fifth fuel resource. Biomass, the largest amongst the main RE resources available, can be used for heat and power generation. With optimum utilization, the value ofbiomass resources in Malaysia is estimated to be more than RM 500 billion (USD 156 billion) over the next 20 years. Malaysia has the capacity to use renewable energy resources to address the national energy agenda. 展开更多
关键词 COMPONENT renewable resources renewable electricity energy policy.
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Smart Grid Innovations: Increasing Resilience, Security, and Sustainability in the Era of Energy Transition 被引量:1
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作者 Yixin Yu Yanli Liu Didi Yu 《Engineering》 2025年第8期1-2,共2页
The accelerating global energy transition,driven by climate imperatives and technological advancements,demands fundamen-tal transformations in power systems.Smart grids,characterized by cyber-physical integration,dist... The accelerating global energy transition,driven by climate imperatives and technological advancements,demands fundamen-tal transformations in power systems.Smart grids,characterized by cyber-physical integration,distributed renewable resources,and data-driven intelligence,have emerged as the backbone of this evolution.This convergence,however,introduces unprecedented complexities in resilience,security,stability,and market operation.This special issue presents five pivotal studies addressing these interconnected challenges,offering novel methodologies and insights to advance the efficiency,resilience,and sustainability of modern power systems. 展开更多
关键词 SECURITY SUSTAINABILITY global energy transitiondriven smart grids RESILIENCE distributed renewable resources renewable resourcesand cyber physical integration
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Study of the development road map of China’s renewable energy 被引量:2
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作者 Huang Qili Li Junfeng Gao Hu 《Engineering Sciences》 EI 2009年第2期5-12,共8页
Renewable energy (RE) has been attached high attention around the world due to its carbon-free and indigenous production in a sustainable way. China enjoys plenty of renewable energy resources, particularly the wind, ... Renewable energy (RE) has been attached high attention around the world due to its carbon-free and indigenous production in a sustainable way. China enjoys plenty of renewable energy resources, particularly the wind, solar, hydro- and biomass energy, which could be a sound basis for a large-scale exploitation. This report examines the current status of RE technology and industry, analyzes the challenges of promoting RE in China. In order to pave the way for a long-term development of RE, this paper outlines the basic principles and priorities for individual RE technology. In line with these, the paper puts forward the RE targets and further describes the RE road map by 2020, 2030 and extend to 2050, taking consideration of China’s RE resources, industrial basis and energy demand etc. At last, this paper provides some recommendations to ensure the achievements of the RE targets. 展开更多
关键词 China renewable energy resource development target renewable energy road map RECOMMENDATION
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Intelligent Fractional-Order Controller for SMES Systems in Renewable Energy-Based Microgrid
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作者 Aadel M.Alatwi Abualkasim Bakeer +3 位作者 Sherif A.Zaid Ibrahem E.Atawi Hani Albalawi Ahmed M.Kassem 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第8期1807-1830,共24页
An autonomous microgrid that runs on renewable energy sources is presented in this article.It has a supercon-ducting magnetic energy storage(SMES)device,wind energy-producing devices,and an energy storage battery.Howe... An autonomous microgrid that runs on renewable energy sources is presented in this article.It has a supercon-ducting magnetic energy storage(SMES)device,wind energy-producing devices,and an energy storage battery.However,because such microgrids are nonlinear and the energy they create varies with time,controlling and managing the energy inside them is a difficult issue.Fractional-order proportional integral(FOPI)controller is recommended for the current research to enhance a standalone microgrid’s energy management and performance.The suggested dedicated control for the SMES comprises two loops:the outer loop,which uses the FOPI to regulate the DC-link voltage,and the inner loop,responsible for regulating the SMES current,is constructed using the intelligent FOPI(iFOPI).The FOPI+iFOPI parameters are best developed using the dandelion optimizer(DO)approach to achieve the optimum performance.The suggested FOPI+iFOPI controller’s performance is contrasted with a conventional PI controller for variations in wind speed and microgrid load.The optimal FOPI+iFOPI controller manages the voltage and frequency of the load.The behavior of the microgrid as a reaction to step changes in load and wind speed was measured using the proposed controller.MATLAB simulations were used to evaluate the recommended system’s performance.The results of the simulations showed that throughout all interruptions,the recommended microgrid provided the load with AC power with a constant amplitude and frequency.In addition,the required load demand was accurately reduced.Furthermore,the microgrid functioned incredibly well despite SMES and varying wind speeds.Results obtained under identical conditions were compared with and without the best FOPI+iFOPI controller.When utilizing the optimal FOPI+iFOPI controller with SMES,it was found that the microgrid performed better than the microgrid without SMES. 展开更多
关键词 Fractional-order proportional integral(FOPI) intelligent controller renewable energy resources superconducting magnetic energy storage OPTIMIZATION
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Study on the Possibility of Raw Seawater into Beverage—Using Ethanol as a Renewable Resource
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作者 Akira Hiratsuka Tsutomu Demizu 《Journal of Water Resource and Protection》 2022年第4期349-384,共36页
In COVID-19 pandemic in the world, alcohol (ethanol) can be listed as a sterilizing disinfectant. It absolutely played a Messianic function on the sterilization effect. And it is said that it has one more function cal... In COVID-19 pandemic in the world, alcohol (ethanol) can be listed as a sterilizing disinfectant. It absolutely played a Messianic function on the sterilization effect. And it is said that it has one more function called “salinity reduction” but that function is not widely known. The two functions (Sterilization & Salinity Reduction) mentioned above are extremely important regarding the theme of “raw seawater into beverage” in this study. It is thought that if the two functions are achieved other water quality items such as NO<sup>-</sup>2</sub> and other items can be cleared with comparative ease. To put briefly the feature of modern waterworks in a word, it can be said that “source of water is river water and its sterilization is chlorine”. In this study, we set up it with a completely new sanitization method (great reset), that is, “source of water is mixtures (seawater and rainwater) and its sterilization is ethanol”. And it can be also expected that the capture and storage of ethanol as a renewable resource is basically possible by utilizing sunlight as a natural power. Therefore, we think that this resolves itself into a question of the choice (sense of value/culture) of the users. It means that how users finally balance out with three factors, i.e., cost, risk (safety) and benefit. Based on the viewpoint mentioned above, we examined the possibility of raw seawater into beverage using ethanol as a renewable resource to create humankind’s wisdom to the settlement (breakthrough) of the water scarcity in the world including Asia and Africa. As a result, we have obtained the new findings that suggest the possibility of raw seawater into beverage using ethanol as a renewable resource. 展开更多
关键词 Raw Seawater BEVERAGE ETHANOL renewable Resource Great Reset
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Studies on the Evolutionary Laws and Maintaining Mechanism of Renewability of the Yellow River's Water Resources
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《Bulletin of the Chinese Academy of Sciences》 2002年第4期204-206,共3页
  The Yellow River has a vast catchment area and historically it is the mother river of the Chinese nation. Now it serves as one of the main theatres for the on-going national campaign to develop China's western...   The Yellow River has a vast catchment area and historically it is the mother river of the Chinese nation. Now it serves as one of the main theatres for the on-going national campaign to develop China's western hinterland.…… 展开更多
关键词 Studies on the Evolutionary Laws and Maintaining Mechanism of Renewability of the Yellow River’s Water resources LAWS
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Cup lump rubber and natural rubber latex biopolymers as promising modifi ers for asphalt binders and mixtures:A review
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作者 Ashiru Sani Tracy Leh Xin Wong +4 位作者 Mohd Rosli Mohd Hasan Abdulnaser M.Al-Sabaeei Norhidayah Abdul Hassan Xin Qu Mohd Fahmi Haikal Mohd Ghazali 《Journal of Road Engineering》 2025年第4期531-553,共23页
This paper presents a comprehensive review of previous research based on scientific papers,technical reports,and published academic theses.The review focuses on studies and investigations concerning the application of... This paper presents a comprehensive review of previous research based on scientific papers,technical reports,and published academic theses.The review focuses on studies and investigations concerning the application of rubberbased biopolymers as modifiers in asphalt binders and mixtures,alongside relevant existing literature,encompassing their influence on asphalt binders and mixtures as well as their binder-aggregate interface performance.Incorporating rubber-based biopolymers into base asphalt significantly enhances the viscosity,complex modulus,rutting parameters,and recovery percentage while reducing non-recoverable compliance and phase angle.These alterations indicate that rubber-based biopolymer-modified asphalt displays superior resistance to permanent deformation,surpassing base asphalt's linear and non-linear rheological properties.Besides,rubber-based biopolymers alter the functional groups within the base asphalt due to the interaction in the asphalt matrix,especially afterthe aging process.These biopolymers are uniformly dispersed throughoutthe asphalt matrix,facilitated by the interconnected elastic networks among the biopolymer molecules.This improves the rheological and mechanical properties of both asphalt binders and mixtures.It is recommended that further studies investigate the combined effects of rubber-based biopolymers with other materials commonly used in asphalt modifications,such as nanomaterials and biomaterials,on the non-linear rheological and microstructural properties of asphalt binders,as well asthe performance of asphalt mixtures.Advanced simulation and modeling techniques,such as molecular dynamic simulation and machine learning should be employed to understand the behavior of rubber-based biopolymermodified asphalt binders and mixtures in various aging and loading situations. 展开更多
关键词 Elastomers Asphaltic concrete renewable resources Waste recycling Rubber-based biopolymer
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An Excellent Biobased Copolymerization Monomer Module:Synthesis of Biobased Copolymers with Excellent Heat Resistance and Hydrophilic Properties
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作者 Xiao-Jun Ma Xiao-Qing Hao +3 位作者 Hong-Ji Wang Han-Yu Yao Zi-Qing Wang Yin Lv 《Chinese Journal of Polymer Science》 2025年第11期2102-2109,I0013,共9页
The use of biomass feedstocks for the manufacture of high-performance polymers can help expand their range of applications and reduce their dependence on finite fossil resources.However,improving the heat resistance a... The use of biomass feedstocks for the manufacture of high-performance polymers can help expand their range of applications and reduce their dependence on finite fossil resources.However,improving the heat resistance and hydrophilicity of bio-based polyesters remains a significant challenge.Herein,we introduce N,N'-trans-1,4-cyclohexane-bis(pyrrolidone-4-methylcarboxylate)(CBPC),a novel bio-based tricyclic dibasic ester synthesized from renewable dimethyl itaconic acid and trans-1,4-cyclohexane diamine via an aza-Michael addition reaction.As a unique comonomer,CBPC features a rigid tricyclic backbone that significantly enhances chain packing and thermal stability,whereas its pyrrolidone side groups impart tunable polarity and improved hydrophilicity.Using CBPC,diphenyl carbonate,and 1,4-butylene glycol,a series of PBCC copolymers with 10 mol%-30 mol%CBPC was synthesized via ester-exchange and melt polycondensation methods.Incorporation of CBPC raised the melting temperature(Tm)from 56.8℃to 225.8℃and the initial decomposition temperature(Td5%)from 258.0℃to 306.7℃,positioning PBCC among the most heat-resistant bio-based polyesters reported.Additionally,the pyrrolidone units enabled transformation from hydrophobic to hydrophilic.This study demonstrates that CBPC is an effective and innovative building block for the design of bio-based polymers with enhanced thermal and surface properties,offering a promising strategy for the development of high-performance sustainable materials. 展开更多
关键词 Bio-based polyesters Poly(butylene carbonates) renewable resources Heat resistance HYDROPHILICITY
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Biomass-Derived Carbon-Based Nanomaterials: Current Research, Trends, and Challenges
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作者 Robyn Lesch Evan David Visser +1 位作者 Ntalane Sello Seroka Lindiwe Khotseng 《Journal of Renewable Materials》 2025年第10期1935-1977,共43页
The review investigates the use of biomass-derived carbon as precursors for nanomaterials,acknowledging their sustainability and eco-friendliness.It examines various types of biomasses,such as agricultural residues an... The review investigates the use of biomass-derived carbon as precursors for nanomaterials,acknowledging their sustainability and eco-friendliness.It examines various types of biomasses,such as agricultural residues and food byproducts,focussing on their transformation via environmentally friendly methods such as pyrolysis and hydrothermal carbonisation.Innovations in creating porous carbon nanostructures and heteroatom surface functionalisation are identified,enhancing catalytic performance.The study also explores the integration of biomassderived carbon with nanomaterials for energy storage,catalysis,and other applications,noting the economic and environmental benefits.Despite these advantages,challenges persist in optimising synthesis methods and scaling production.The study also highlights existing research gaps,forms a basis for future studies,and underscores the role of biomass-derived nanomaterials in promoting a circular economy and sustainability. 展开更多
关键词 Carbon in biomass circular economy renewable resources green chemistry environmentally friendly
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Stronger together: perovskite/silicon tandem solar cells 被引量:1
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作者 Shenghan Wu Shengqiang Ren +1 位作者 Cong Chen Dewei Zhao 《Journal of Semiconductors》 2025年第5期5-7,共3页
Solar energy, as a renewable resource, is an effective solution to the current global energy shortage problem. To actively respond to the call for "carbon peak" and "carbon neutrality", solar cell ... Solar energy, as a renewable resource, is an effective solution to the current global energy shortage problem. To actively respond to the call for "carbon peak" and "carbon neutrality", solar cell industry has experienced unprecedented development. The full utilization of solar energy resources remains an urgent issue to be addressed. 展开更多
关键词 carbon neutrality renewable resource perovskite silicon tandem solar cells solar energy carbon peak global energy shortage problem solar cell
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How many grid-forming converters are needed?-A techno-economic perspective
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作者 Guoxuan Cui Hongyang Jia +1 位作者 Ning Zhang Fei Teng 《iEnergy》 2025年第2期79-85,共7页
Renewable generation is rapidly increasing and transforming power systems toward“new-type power systems”.The integration of renewable energy resources necessitates a shift from conventional grid-following converters... Renewable generation is rapidly increasing and transforming power systems toward“new-type power systems”.The integration of renewable energy resources necessitates a shift from conventional grid-following converters(GFLs)to advanced grid-forming controls.Although grid-forming converters(GFMs)provide grid support and enhance system stability under weak grid conditions,their deployment requires more robust hardware,complex control algorithms and system operation constraints,resulting in planning and operational trade-offs between system stability and cost efficiency.This paper studies the underexplored question of how many GFMs are needed from a techno-economic perspective.The holistic analysis integrates long-term planning,short-term operational strategies and dynamic stability considerations,thereby supporting large-scale renewable integration while ensuring system security and economic benefits. 展开更多
关键词 Grid-forming grid-following power system planning optimal GFM allocation power system operation renewable energy resources
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Covalent modification of multiwalled carbon nanotubes with a low molecular weight chitosan 被引量:2
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作者 Gang Ke Wen Chao Guan +4 位作者 Chang Yu Tang Zhen Hu Wen Jie Guan Dan Lin Zeng Feng Deng 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第3期361-364,共4页
Covalent modification of shortened multiwalled carbon nanombes (MWNTs) with a natural low molecular weight chitosan (LMCS) was accomplished by the nucleophilic substitution reaction. The LMCS modified MWNTs (MWNT... Covalent modification of shortened multiwalled carbon nanombes (MWNTs) with a natural low molecular weight chitosan (LMCS) was accomplished by the nucleophilic substitution reaction. The LMCS modified MWNTs (MWNT-LMCS) were characterized by FTIR, solid-state ^13C NMR, and XPS spectroscopies, thermogravimetric analysis, and transmission electron microscopy. The results revealed that amino and primary hydroxyl groups of the LMCS participated mainly in the formation of the MWNT-LMCS conjugates. The MWNT-LMCS consists of 58 wt.% LMCS, and about four molecular chains of the LMCS were attached to 1000 carbon atoms of the nanotube sidewalls. As a novel derivative of the MWNTs, the MWNT-LMCS not only solved in DMF, DMAc and DMSO, but also in aqueous acetic acid solution. 展开更多
关键词 Carbon nanotubes CHITOSAN renewable resources MODIFICATION
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Homogeneous modification of carbon nanotubes with cellulose acetate 被引量:1
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作者 Gang Ke 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第11期1376-1380,共5页
An efficient strategy that comprised shorten, chain extension, active groups introducing and homogeneous reaction tactics, was adopted to modify multiwalled carbon nanotubes (MWNTs) with cellulose acetate (CA). Sp... An efficient strategy that comprised shorten, chain extension, active groups introducing and homogeneous reaction tactics, was adopted to modify multiwalled carbon nanotubes (MWNTs) with cellulose acetate (CA). Specially, by utilizing 2,4,6-trichloro- 1,3,5-triazine, a reactive intermediate of the MWNTs (MWNT-triazine) was obtained. Suitable solubility of the MWNT-triazine helps make the homogeneous modification become reality. Detailed characterizations further verified that reaction between chloride atoms in the MWNT-triazine and hydroxyl groups in the CA had contributed to the formation of MWNT-CA conjugates. The novel MWNT-CA consists of carbon (76.3%), oxygen (18.4%) and nitrogen (5.3%). With a nanotube-attached CA content of 42.8 wt%, the MWNT-CA is readily soluble in DMSO, NMP, DMF and DMAc. Confirmation of the CA-based modification route might lead to studies aiming for specific sorption and isolation. 展开更多
关键词 Carbon nanotubes Cellulose acetate renewable resources MODIFICATION NANOCOMPOSITES
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Building a Highly Stable Ultrathin Nanoporous Layer Assisted by Glucose for Desalination 被引量:1
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作者 Yanqiu Zhang Fan Yang +3 位作者 Hongguang Sun Yongping Bai Songwei Li Lu Shao 《Engineering》 SCIE EI CAS 2022年第9期247-255,共9页
Although nanoporous membranes are of great interest in desalination,it is still challenging to construct highly permeable nanoporous membranes with excellent rejections for an efficient desalination process.In this wo... Although nanoporous membranes are of great interest in desalination,it is still challenging to construct highly permeable nanoporous membranes with excellent rejections for an efficient desalination process.In this work,highly permeable nanoporous membranes were built from renewable resources,assisted by the versatile functions of glucose and dopamine,with coupling reactive groups via interfacial reaction with 1,3,5-benzenetricarbonyl trichloride(TMC).The small molecules(0.66 nm)of glucose,which have high hydrophilicity,can diffuse into the membrane for an effective reaction to ensure structural integration.Our novel ultrathin(~44 nm)nanofiltration(NF)membrane exhibits ultra-high Na_(2)SO_(4)flux and excellent rejection of Na_(2)SO_(4)(66.5 L·m^(-2)·h^(-1),97.3%)and MgSO4(63.0 L·m^(-2)·h^(-1),92.1%)under a pressure of 5 bar(1 bar=10^(5)Pa)which is much superior to the performance of natural-product NF membranes.The membrane demonstrates excellent long-term stability,as well as tremendous acid-base and alkali-base stability and high anti-pollution capacity.The designed membrane materials and architecture open a new door to biopolymer-based separation membranes beyond existing membrane materials. 展开更多
关键词 Nanoporous membrane renewable resources NANOFILTRATION DESALINATION GLUCOSE
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