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Degradation of natural red mudstone subjected to long-term relative humidity cycles
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作者 Kang Chen Rui Zhang +2 位作者 Shengyang Yuan Jie Ma Huan Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5800-5815,共16页
This paper presents a multi-scale experimental investigation of the weathering degradation of red mudstone.Natural rocks were extracted from the surface ground to 120 m,inwhich three sets of samples were selected to c... This paper presents a multi-scale experimental investigation of the weathering degradation of red mudstone.Natural rocks were extracted from the surface ground to 120 m,inwhich three sets of samples were selected to consider the different initial rock fabrics.The long-term relative humidity(RH)cycles under two amplitudes were imposed on red mudstone to simulate the weathering process.After RH cycles,a series of uniaxial compression tests,Brazilian splitting tests and bender-extender element tests were carried out to examine the reduction in strength and stiffness.The objective of this study is to develop an extended stress-volume framework characterizing the degradation of natural red mudstone both at microscale and macroscale.Accompanied by the irreversible swelling of the rock specimen is the progressive degradation of strength,stiffness and Poisson's ratio.A unified exponential degradation model in terms of the irreversible volumetric strain was thus proposed to capture such a degradation pattern.The effect of the initial rock fabric was evident.The highest degradation rate and potential were identified in slightly weathered specimens.Significant slaking of aggregates and crack propagation were confirmed by scanning electron microscope(SEM)micrographs,which were considered as the main consequence of structure damage leading to degradation of mechanical properties.The structure damage during RH cycles denoted the hysteresis nature in the response to the cycling hydraulic reaction,in turn causing the increase in volumetric strain.Thus,the stress-volume relation rather than the suction relation was found in more reasonable agreement with the experimental results. 展开更多
关键词 Red mudstone Weathering degradation relative humidity cycles Unified degradation model Microstructure tests
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Test and Evaluation of Relative Humidity Forecast in Each Competition Area of the "14 th National Winter Games" by Intelligent Forecasting Methods
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作者 Sitong LIU Xuefeng YANG 《Meteorological and Environmental Research》 2025年第1期37-40,共4页
Based on ground observation data of relative humidity,the prediction performance of STNF and MIFS in each competition area during February 13-26,2024 was tested and evaluated by using two intelligent forecasting metho... Based on ground observation data of relative humidity,the prediction performance of STNF and MIFS in each competition area during February 13-26,2024 was tested and evaluated by using two intelligent forecasting methods(STNF and MIFS).The results show that STNF had better performance in forecasting relative humidity in high-altitude areas,and was suitable for fine forecasting under complex terrain.MIFS improved the short-term forecast of some low-altitude stations,but the long-term reliability was insufficient.STNF method performed better than MIFS during 0-24 h.As the prediction time extended to 24-72 h,the errors of both methods showed a systematic increase trend.STNF had higher precision,lower root mean square error and smaller mean error in most regions under the background of most weather systems,showing its superiority as a forecasting method of relative humidity.However,the precision of MIFS was slightly higher than that of STNF in Liangcheng without system background,revealing that MIFS may also be an effective option in some specific conditions. 展开更多
关键词 Intelligent forecast relative humidity Model test
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Effect of relative humidity on the desulfurization performance of calcium-based desulfurizer 被引量:1
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作者 Juan Lǖ Yu Fu +3 位作者 Haiyan Yu HuanWang Zhe Wang Haiyan Chen 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第4期179-188,共10页
Low desulfurization efficiency impedes the wide application of dry desulfurization technology,which is a low-cost and simple process,and one significant solution is the development and manufacture of high-performance ... Low desulfurization efficiency impedes the wide application of dry desulfurization technology,which is a low-cost and simple process,and one significant solution is the development and manufacture of high-performance desulfurizers.In this study,firstly,a steam jet mill was used to digest quicklime;then,we utilized numerical simulation to study the flow field distribution and analyze the driving factors of quicklime digestion;and lastly,the desulfurization performance of the desulfurizer was evaluated under different relative humidities.The results show that the desulfurizer prepared via the steam jet mill had better apparent activity than traditional desulfurizers.Also,the entire jet flow field of the steam jet mill is in a supersonic and highly turbulent flow state,with high crushing intensity and good particle acceleration performance.Sufficient contact with the nascent surface maximizes the formation of slaked lime.The experiments demonstrated that the operating time with 100%desulfurization efficiency and the“break-through”time for the desulfurizer prepared via the steam jet mill is longer than that of traditional desulfurizers,and has significant advantages,especially at low flue gas relative humidity.Compared with traditional desulfurizers,the desulfurizer prepared via steam jet mill expands the range of acceptable flue gas temperature,and the failure temperature is 1.625 times that of traditional desulfurizers.This work breaks through the technical bottleneck of low dry desulfurization efficiency,which is an important step in pushing forward the application of dry desulfurization. 展开更多
关键词 Dry desulfurization relative humidity Desulfurization efficiency High-efficiency desulfurizer Quicklime digestion
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Prediction of Low Heating Value of Sugar Cane Bagasse as a Fuel for Industrial Boilers in the High Relative Humidity Region: Case of Cameroon
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作者 Pierre Kana-Donfack Maxell Tientcheu-Nsiewe +1 位作者 Denis Tcheukam-Toko César Kapseu 《Open Journal of Applied Sciences》 2024年第6期1604-1624,共21页
Many attempts have been made to estimate calorific value of bagasse using mathematical equations, which were created based on data from proximate, ultimate, physical and chemical analysis. Questions have been raised o... Many attempts have been made to estimate calorific value of bagasse using mathematical equations, which were created based on data from proximate, ultimate, physical and chemical analysis. Questions have been raised on the applicability of these equations in different parts of the globe. This study was initiated to tackle these problems and also check the most suited mathematical models for the Law Heating Value of Cameroonian bagasse. Data and bagasse samples were collected at the Cameroonian sugarcane factory. The effects of cane variety, age of harvesting, source, moisture content, and sucrose on the LHV of Cameroon bagasse have been tested. It was shown that humidity does not change within a variety, but changes from the dry season to the rainy season;the sugar in the rainy season is significantly different from that collected in the dry season. Samples of the same variety have identical LHV. LHV in the dry season is significantly different from LHV in the rainy season. According to the fact that this study was done for cane with different ages of harvesting, the maturity of Cameroonian sugarcane does not affect LHV of bagasse. Tree selected models are much superior tool for the prediction of the LHV for bagasse in Cameroon compared to others. The standard deviation of these validated models is around 200 kJ/kg compared to the experimental. Thus, the models determined in foreign countries, are not necessarily applicable in predicting the LHV of bagasse in other countries with the same accuracy as that in their native country. There was linear relationship between humidity, ash and sugar content in the bagasse. It is possible to build models based on data from physical composition of bagasse using regression analysis. 展开更多
关键词 Sugarcane Bagasse relative humidity ASH Low Heating Value
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Analysis on the Climate Characteristics of Relative Humidity in Recent 40 Years in Urumqi City 被引量:2
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作者 李瑞 柳芳 +1 位作者 冉桂平 杨霞 《Meteorological and Environmental Research》 CAS 2010年第8期21-23,26,共4页
By using the daily average relative humidity data in Urumqi during 1961-2000,the basic climate characteristics and the variation trend of relative humidity in Urumqi in recent 40 years were analyzed.The results showed... By using the daily average relative humidity data in Urumqi during 1961-2000,the basic climate characteristics and the variation trend of relative humidity in Urumqi in recent 40 years were analyzed.The results showed that the yearly average relative humidity in Urumqi was 57.5%.The relative humidity in winter was 77.5% which was the biggest all the year round,and the relative humidity in summer was 41.2% which was the smallest.The relative humidity in spring,summer,autumn,winter and the yearly relative humidity all displayed the increase trend.The yearly mean relative humidity had the periods of mainly 2,3-4 and quasi-7 years.The periodic oscillation of quasi-7 years was the strongest. 展开更多
关键词 relative humidity Climate variation Wavelet analysis Urumqi City China
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Factors affecting relative humidity during wood vacuum drying 被引量:1
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作者 肖辉 蔡英春 《Journal of Forestry Research》 SCIE CAS CSCD 2009年第2期165-167,I0004,共4页
Effects of pressure and temperature in the chamber during vacuum drying on the relative humidity and evaporation of wood surface were investigated by using the vacuum chamber. The setting temperature during vacuum dry... Effects of pressure and temperature in the chamber during vacuum drying on the relative humidity and evaporation of wood surface were investigated by using the vacuum chamber. The setting temperature during vacuum drying included dry-bulb temperature ta, the wet-bulb temperature tw and the temperature difference between the air in the vacuum chamber and the cooling water in the condenser. Results indicated that relative humidity during vacuum drying was affected by the dry-bulb temperature td, the wet-bulb temperature tw and the temperature difference between the air in the vacuum chamber and the water in the condenser. Relative humidity of wood decreased with the increase in temperature at the given temperature of the water in the condenser. The relative humidity was affected slightly by pressure in the vacuum chamber pA, and it decreased from 70% to 65% with pA increased from 50 kPa to 101 kPa. Moreover, there was nearly no evaporation under the vacuum without external heating. 展开更多
关键词 influencing factors radio frequency relative humidity wood vacuum drying
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Effects of relative humidity and PM2.5 chemical compositions on visibility impairment in Chengdu, China 被引量:25
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作者 Fan Liu Qinwen Tan +2 位作者 Xia Jiang Fumo Yang Wenju Jiang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2019年第12期15-23,共9页
To better understand the potential causes of visibility impairment in autumn and winter in Chengdu,relative humidity(RH),visibility,the concentrations of PM2.5 and its chemical components were on-line measured continu... To better understand the potential causes of visibility impairment in autumn and winter in Chengdu,relative humidity(RH),visibility,the concentrations of PM2.5 and its chemical components were on-line measured continuously in Chengdu from Nov.2016 to Jan.2017.Six obvious haze episodes occurred in Chengdu,with the total time of haze episodes accounted for more than 90%of the total observation period,and higher NO2 concentrations and RH were related to the high particle concentrations in haze episodes.The visibility decreased in a non-linear tendency under different RH conditions with the increase of PM2.5 concentrations,which was more sensitive to RH under lower PM2.5 concentrations.The threshold concentration of PM2.5 got more smaller with the increase of RH.During the entire observation period,organic matter(OM)was the largest contributor(31.12%to extinction coefficient(bext)),followed by NH4NO3 and(NH4)2SO4 with 28.03%and 23.01%,respectively.However,with the visibility impairment from Type I(visibility>10 km)to Type IV(visibility≤2 km),the contribution of OM to bextdecreased from 38.12%to 26.77%,while the contribution of NH4NO3 and(NH4)2SO4 to bextincreased from 19.09%and 20.20%to 34.29%and 24.35%,respectively,and NH4NO3 became the largest contributor to bextat Type IV.The results showed that OM and NH4NO3 were the key components of PM2.5 for visibility impairment in Chengdu,indicating that the control of precursors emissions of carbonaceous species and NH4NO3 could effectively improve the visibility in Chengdu. 展开更多
关键词 Visibility impairment PM2.5 chemical composition relative humidity Light extinction coefficient Secondary formation
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Effects of relative humidity on animal health and welfare 被引量:14
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作者 XIONG Yan MENG Qing-shi +2 位作者 GAO Jie TANG Xiang-fang ZHANG Hong-fu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2017年第8期1653-1658,共6页
Farm animals are sources of meat, milk and eggs for the humans, and animal health ensures the quality and security of these agricultural and sideline products. The animal raising conditions in livestock stations and p... Farm animals are sources of meat, milk and eggs for the humans, and animal health ensures the quality and security of these agricultural and sideline products. The animal raising conditions in livestock stations and poultry houses play vital roles in both animal health and production. One of the major factors affecting raising conditions, relative humidity, has not received much attention even though it is important for animal husbandry. In this review, we summarize the impacts of relative humidity on animal health and welfare to draw attention for its importance in the improvement of animal raising conditions in the future. 展开更多
关键词 relative humidity ANIMAL HEALTH WELFARE
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Observations of nitrous acid and its relative humidity dependence in Shanghai 被引量:10
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作者 HAO Nan ZHOU Bin CHEN Dan CHEN Li-min 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第5期910-915,共6页
Nitrous acid, HNO2, is an important precursor of OH radicals in the troposphere. Measurements of HNO2 and NO2, using differential optical absorption spectroscopy (DOAS), were performed in Shanghai, China for a perio... Nitrous acid, HNO2, is an important precursor of OH radicals in the troposphere. Measurements of HNO2 and NO2, using differential optical absorption spectroscopy (DOAS), were performed in Shanghai, China for a period from October 22, 2004 to January 4, 2005. The mean (and median) hourly concentrations of HNO2 and NO2 during this period were 1.1 (0.7) ppb and 24 (21.4) ppb respectively. A correlation between HNO2/NO2 and PM10 mass concentrations was obtained. This correlation suggests that significant heterogeneous chemical production of HNO2 may occur through NO2 reactions on aerosol surfaces. This hypothesis was further supported by detailed analysis of selected pollution episodes in this study. At the same time, the water dependence of HNO2 formation was studied by analysis of relative humidity (RH). It showed that the maximum HNO2/NO2 ratio was increased along with RH below 70% and inhibited at RH〉70%. 展开更多
关键词 DOAS heterogeneous formation nitrous acid PM o aerosol relative humidity
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High-resolution Surface Relative Humidity Computation Using MODIS Image in Peninsular Malaysia 被引量:9
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作者 PENG Guangxiong LI Jing +2 位作者 CHEN Yunhao Abdul Patah NORIZAN Liphong TAY 《Chinese Geographical Science》 SCIE CSCD 2006年第3期260-264,共5页
Forest fire is a serious disaster all over the world. The Fire Weather Index (FWI) System can be used in ap- plied forestry as a tool to investigate and manage all types of fire. Relative humidity (RH) is a very impor... Forest fire is a serious disaster all over the world. The Fire Weather Index (FWI) System can be used in ap- plied forestry as a tool to investigate and manage all types of fire. Relative humidity (RH) is a very important parameter to calculate FWI. However, RH interpolated from meteorological data may not be able to provide precise and confident values for areas between far separated stations. The principal objective of this study is to provide high-resolution RH for FWI using MODIS data. The precipitable water vapor (PW) can be retrieved from MODIS using split window tech- niques. Four-year-time-series (2000-2003) of 8-day mean PW and specific humidity (Q) of Peninsular Malaysia were analyzed and the statistic expression between PW and Q was developed. The root-mean-square-error (RMSE) of Q es- timated by PW is generally less than 0.0004 and the correlation coefficient is 0.90. Based on the experiential formula between PW and Q, surface RH can be computed with combination of auxiliary data such as DEM and air temperature (Ta). The mean absolute errors of the estimated RH in Peninsular Malaysia are less than 5% compared to the measured RH and the correlation coefficient is 0.8219. It is proven to be a simple and feasible model to compute high-resolution RH using remote sensing data. 展开更多
关键词 relative humidity precipitable water vapor specific humidity MODIS
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Seasonal Variation in Air Temperature and Relative Humidity on Building Areas and in Green Spaces in Beijing, China 被引量:10
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作者 KUANG Wenhui 《Chinese Geographical Science》 SCIE CSCD 2020年第1期75-88,共14页
The cooling and humidifying effects of urban parks are an essential component of city ecosystems in terms of regulating microclimates or mitigating urban heat islands(UHIs).Air temperature and relative humidity are tw... The cooling and humidifying effects of urban parks are an essential component of city ecosystems in terms of regulating microclimates or mitigating urban heat islands(UHIs).Air temperature and relative humidity are two main factors of thermal environmental comfort and have a critical impact on the urban environmental quality of human settlements.We measured the 2-m height air temperature and relative humidity at the Beijing Olympic Park and a nearby building roof for more than 1 year to elucidate seasonal variations in air temperature and relative humidity,as well as to investigate the outdoor thermal comfort.The results showed that the lawn of the park could,on average,reduce the air temperature by(0.80±0.19)℃,and increase the relative humidity by(5.24±2.91)% relative to the values measured at the building roof during daytime.During the nighttime,the lawn of the park reduced the air temperature by(2.64±0.64)℃ and increased the relative humidity by(10.77±5.20)%.The park was cooler and more humid than surrounding building area,especially in night period(more pronounced cooling with 1.84℃).Additionally,the lawn of the park could improve outdoor thermal comfort through its cooling and humidifying effects.The level of thermal comfort in the park was higher than that around the building roof for a total of 11 days annually in which it was above one or more thermal comfort levels(average reduced human comfort index of 0.92)except during the winter. 展开更多
关键词 air temperature relative humidity outdoor thermal comfort urban park planning
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Effects of relative humidity on the characterization of a photochemical smog chamber 被引量:7
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作者 Gaoshuo Hu Yongfu Xu Long Jia 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2011年第12期2013-2018,共6页
Water vapor plays an important role in many atmospheric chemical reactions. A self-made indoor environmental smog chamber was used to investigate the effects of relative humidity (RH) on its characterization, which ... Water vapor plays an important role in many atmospheric chemical reactions. A self-made indoor environmental smog chamber was used to investigate the effects of relative humidity (RH) on its characterization, which included the wall effects of reactive species such as O3 and NOx, and the determination of chamber-dependent OH radicals in terms of CO-NOx irradiation experiments. Results showed that the rate constant of O3 wall losses increased with increasing RH, and that their relationship was linearly significant. Although RH aflected the rate constant of NOx wall losses, their relationship was not statistically significant. Background air generated a small amount of ozone at both high and low RH. When RH varied from 5% to 79%, the apparent rate constant kNO2→HONO for the conversion of NO2 into gas phase HONO was estimated in the range of 0.70×10-3–2.5×10-3 min-1. A linear relationship between kNO2→HONO and RH was obtained as kNO2→HONO (10-3 min-1) = –0.0255RH + 2.64, with R2 and P value being 0.978 and 0.01. To our knowledge, this is the first report on their relationship. The generation mechanism for HONO and OH was also discussed in this work. 展开更多
关键词 chamber characterization relative humidity wall effects OH radicals
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Evaluation of Surface Relative Humidity in China from the CRA-40 and Current Reanalyses 被引量:8
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作者 Jingpeng ZHANG Tianbao ZHAO +6 位作者 Zhi LI Chunxiang LI Zhen LI Kairan YING Chunxiang SHI Lipeng JIANG Wenyu ZHANG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2021年第11期1958-1976,共19页
Recently,the China Meteorological Administration(CMA)released a new Global Atmospheric Reanalysis(CRA-40)dataset for the period 1979−2018.In this study,surface relative humidity(RH)from CRA-40 and other current reanal... Recently,the China Meteorological Administration(CMA)released a new Global Atmospheric Reanalysis(CRA-40)dataset for the period 1979−2018.In this study,surface relative humidity(RH)from CRA-40 and other current reanalyses(e.g.,CFSR,ERA5,ERA-Interim,JRA-55,and MERRA-2)is comprehensively evaluated against homogenized observations over China.The results suggest that most reanalyses overestimate the observations by 15%−30%(absolute difference)over the Tibetan Plateau but underestimate the observations by 5%−10%over most of northern China.The CRA-40 performs relatively well in describing the long-term change and variance seen in the observed surface RH over China.Most of the reanalyses reproduce the observed surface RH climatology and interannual variations well,while few reanalyses can capture the observed long-term RH trends over China.Among these reanalyses,the CFSR does poorly in describing the interannual changes in the observed RH,especially in Southwest China.An empirical orthogonal function(EOF)analysis also suggests that the CRA-40 performs better than other reanalyses to capture the first two leading EOF modes revealed by the observations.The results of this study are expected to improve understanding of the strengths and weaknesses of the current reanalysis products and thus facilitate their application. 展开更多
关键词 surface relative humidity CRA-40 reanalysis current reanalysis EVALUATION
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The Impact of Relative Humidity and Atmospheric Pressure on Mortality in Guangzhou, China 被引量:7
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作者 OU Chun Quan YANG Jun +5 位作者 OU Qiao Qun LIU Hua Zhang LIN Guo Zhen CHEN Ping Yan QIAN Jun GUO Yu Ming 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2014年第12期917-925,共9页
Objective Although many studies have examined the effects of ambient temperatures on mortality, little evidence is on health impacts of atmospheric pressure and relative humidity. This study aimed to assess the impact... Objective Although many studies have examined the effects of ambient temperatures on mortality, little evidence is on health impacts of atmospheric pressure and relative humidity. This study aimed to assess the impacts of atmospheric pressure and relative humidity on mortality in Guangzhou, China. Methods This study included 213,737 registered deaths during 2003-2011 in Guangzhou, China. A quasi-Poisson regression with a distributed lag non-linear model was used to assess the effects of atmospheric pressure/relative humidity. Results We found significant effect of low atmospheric pressure/relative humidity on mortality. There was a 1.79% (95% confidence interval: 0.38%-3.22%) increase in non-accidental mortality and a 2.27% (0.07%-4.51%) increase in cardiovascular mortality comparing the 5th and 25th percentile of atmospheric pressure. A 3.97% (0.67%-7.39%) increase in cardiovascular mortality was also observed comparing the 5th and 25th percentile of relative humidity. Women were more vulnerable to decrease in atmospheric pressure and relative humidity than men. Age and education attainment were also potential effect modifiers. Furthermore, low atmospheric pressure and relative humidity increased temperature-related mortality. Conclusion Both low atmospheric pressure and relative humidity are important risk factors of mortality. Our findings would be helpful to develop health risk assessment and climate policy interventions that would better protect vulnerable subgroups of the population. 展开更多
关键词 relative humidity Atmospheric pressure TEMPERATURE MORTALITY
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Effect of Relative Humidity on Catalytic Combustion of Toluene over Copper Based Catalysts with Different Supports 被引量:5
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作者 方健才 陈晓 +2 位作者 夏启斌 奚红霞 李忠 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第5期767-772,共6页
The copper based catalysts, CuO/T-Al2O3, CuO/y-Al2O3-cordierite (Cord) and CuO/Cord, were prepared by impregnation method. The catalytic activity of the catalysts was tested in absence and presence of water vapor,an... The copper based catalysts, CuO/T-Al2O3, CuO/y-Al2O3-cordierite (Cord) and CuO/Cord, were prepared by impregnation method. The catalytic activity of the catalysts was tested in absence and presence of water vapor,and the catalysts were characterized. Temperature program desorption (TPD) experiments or toluene and water on the catalysts were carried out. The influence of water vapor on the activity of the catalysts was discussed. Results showed that addition of the water vapor has a significant negative effect on the catalytic activity of the catalysts.The higher the concentration of the Water vapor in feed steam was, the lower the catalytic activity of the copper based catalysts became, which could be mainly ascribed to the competition of water molecules with toluene molecules for adsorption on the catalyst surfaces. TPD experiments showed that the strength of the interaction between water molecules and three catalysts followed the order: CuO/γ-Al2O3〉CuO/γ-Al2O3-Cord〉CuO/Cord. As a consequence of that, the degree of degradation in the catalytic activity of these three catalysts by the water vapor followed the order: CuO/γ-Al2O3〉CuO/y-Al2O3-Cord〉CuO/Cord. However, the negative effect of the water vapor was reversible. 展开更多
关键词 copper based catalysts relative humidity TOLUENE catalytic combustion water inhibition
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Relationship Between Autogenous Deformation and Internal Relative Humidity of High-strength Expansive Concrete 被引量:5
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作者 胡曙光 吴静 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第3期504-508,共5页
The relationship between autogenous deformation and internal relative humidity(IRH) of high-strength concrete and high-strength expansive concrete were investigated.The experimental results indicate that,there exist... The relationship between autogenous deformation and internal relative humidity(IRH) of high-strength concrete and high-strength expansive concrete were investigated.The experimental results indicate that,there exists a good linear relationship between autogenous shrinkage and IRH of high-strength concrete but a nonlinear relationship between autogenous deformation and IRH of high-strength expansive concrete with expansive agent.The new autogenous deformation curve can be obtained by transforming the autogenous deformation data of high-strength expansive concrete,and there exists linear relationship between the autogenous deformation and IRH.The concept of "critical internal relative humidity" was proposed,which is defined as the value of IRH when autogenous deformation is zero,to effectively reflect the autogenous deformation characteristic of expansive concrete. 展开更多
关键词 expansive concrete autogenous deformation internal relative humidity RELATIONSHIP
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Heterogeneous uptake of NO_2 on soils under variable temperature and relative humidity conditions 被引量:3
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作者 Lei Wang Weigang Wang Maofa Ge 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2012年第10期1759-1766,共8页
Heterogeneous reactions of nitrogen dioxide (NO2) on soils collected from Dalian (S 1) and Changsha (S2) were investigated over the relative humidity (RH) range of 5%-80% and temperature range of 278-328 K usi... Heterogeneous reactions of nitrogen dioxide (NO2) on soils collected from Dalian (S 1) and Changsha (S2) were investigated over the relative humidity (RH) range of 5%-80% and temperature range of 278-328 K using a horizontal coated-wall flow tube. The initial uptake coefficients of NO2 on S2 exhibited a decreasing trend from (10 ± 1.3) × 10-8 to (3.1 ± 0.5) x 10-8 with the relative humidity increasing from 5% to 80%. In the temperature effect studies, the initial uptake coefficients of S1 and S2 decreased from (10± 1.2) × 10-8 to (3.8 ± 0.5) × 10-8 and from (16± 2.2) × 10-8 to (3.8 ±0.4) × 10-8 when temperature increased from 278 to 288 K for S1 and from 278 to 308 K for S2, respectively. As the temperature continued to increase, the initial uptake coefficients of S1 and S2 returned to (7.9 ± 1.1)× 10-8 and (20 ± 3.1) × 10-8 at 313 and 328 K, respectively. This study shows that relative humidity could influence the uptake kinetics of NO2 on soil and temperature would impact the heterogeneous chemistry of NO2. 展开更多
关键词 heterogeneous reactions soil particles uptake coefficients temperature dependence relative humidity effect
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Decomposition of Polycyclic Aromatic Hydrocarbon (PAHs) on Mineral Surface under Controlled Relative Humidity 被引量:3
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作者 Shuji TAMAMURA Tsutomu SATO +2 位作者 Yukie OTA Ning TANG Kazuichi HAYAKAWA 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2006年第2期185-191,共7页
The fate of Polycyclic Aromatic Hydrocarbons (PAHs) residing in the atmosphere has received enormous attention in recent years due to their mutagenic and carcinogenic risks on human health. In this context, the stab... The fate of Polycyclic Aromatic Hydrocarbons (PAHs) residing in the atmosphere has received enormous attention in recent years due to their mutagenic and carcinogenic risks on human health. In this context, the stability of pyrene (as a representative PAHs) on quartz, alumina, montmorillonite, kaolinite, humic acid and quartz coated with sorbed humic acid was investigated at controlled relative humidity (RH: i.e. 5% and 30%) without light irradiation in order to detect the presence of catalytic effect of mineral surface on PAHs decomposition. The stability of pyrene was found to depend strongly on the physicochemical properties of the substrates. Quartz showed a strong catalytic effect for the decomposition of pyrene even though it was coated with sorbed humic acid. Pyrene sorbed on montmorillonite and humic acid remained stable during the experimental period (i.e. 3 days). Moisture in the experimental cell also affected the stability of pyrene in particular minerals. Especially, pyrene sorbed on alumina was rapidly decomposed at higher RH. However, there were almost no effect in the case of quartz, kaolinite and humic acid. Depending on the physicochemical properties of aerosols and RH, PAHs associated with minerals in the atmosphere would be decomposed and/or stably reside in the atmosphere. 展开更多
关键词 MINERAL PAHS relative humidity DECOMPOSITION
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Changes in visibility with PM_(2.5) composition and relative humidity at a background site in the Pearl River Delta region 被引量:19
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作者 Xiaoxin Fu Xinming Wang +9 位作者 Qihou Hu Guanghui Li Xiang Ding Yanli Zhang Quanfu He Tengyu Liu Zhou Zhang Qingqing Yu Ruqing Shen Xinhui Bi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2016年第2期10-19,共10页
In fall–winter, 2007–2013, visibility and light scattering coefficients(b sp) were measured along with PM_(2.5)mass concentrations and chemical compositions at a background site in the Pearl River Delta(PRD) r... In fall–winter, 2007–2013, visibility and light scattering coefficients(b sp) were measured along with PM_(2.5)mass concentrations and chemical compositions at a background site in the Pearl River Delta(PRD) region. The daily average visibility increased significantly(p 〈 0.01) at a rate of 1.1 km/year, yet its median stabilized at ~13 km. No haze days occurred when the 24-hr mean PM_(2.5)mass concentration was below 75 μg/m^3. By multiple linear regression on the chemical budget of particle scattering coefficient(b sp), we obtained site-specific mass scattering efficiency(MSE) values of 6.5 ± 0.2, 2.6 ± 0.3, 2.4 ± 0.7 and 7.3 ± 1.2 m2/g,respectively, for organic matter(OM), ammonium sulfate(AS), ammonium nitrate(AN) and sea salt(SS). The reconstructed light extinction coefficient(b ext) based on the Interagency Monitoring of Protected Visual Environments(IMPROVE) algorithm with our site-specific MSE revealed that OM, AS, AN, SS and light-absorbing carbon(LAC) on average contributed 45.9% ± 1.6%,25.6% ± 1.2%, 12.0% ± 0.7%, 11.2% ± 0.9% and 5.4% ± 0.3% to light extinction, respectively.Averaged b ext displayed a significant reduction rate of 14.1/Mm·year(p 〈 0.05); this rate would be 82% higher if it were not counteracted by increasing relative humidity(RH) and hygroscopic growth factor(f(RH)) at rates of 2.5% and 0.16/year-1(p 〈 0.01), respectively, during the fall–winter, 2007–2013. This growth of RH and f(RH) partly offsets the positive effects of lowered AS in improving visibility, and aggravated the negative effects of increasing AN to impair visibility. 展开更多
关键词 PM_(2.5) Visibility Mass scattering efficiency Light extinction coefficient relative humidity
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Validation of ERA5-Land temperature and relative humidity on four Peruvian glaciers using on-glacier observations 被引量:2
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作者 BONSHOMS Martí UBEDA Jose +3 位作者 LIGUORI Giovanni KORNER Philipp NAVARRO Alvaro CRUZ Rolando 《Journal of Mountain Science》 SCIE CSCD 2022年第7期1849-1873,共25页
Weather and climate conditions drive the evolution of tropical glaciers which play an important role as water reservoirs for Peruvian inhabitants in the arid coast and semi-arid Andean region.The scarcity of long-term... Weather and climate conditions drive the evolution of tropical glaciers which play an important role as water reservoirs for Peruvian inhabitants in the arid coast and semi-arid Andean region.The scarcity of long-term high-quality observations over Peruvian glaciers has motivated the extensive use of reanalysis data to describe the climatic evolution of these glaciers.However,the representativeness and uncertainties of these reanalysis products over these glaciers are still poorly constrained.This study evaluates the ability of the ERA-Land reanalysis(ERAL)to reproduce hourly and monthly 2 m air temperature and relative humidity(T2m and Rh2m,respectively)over several Peruvian glaciers.We compared the ERAL with data from four on-glacier automatic weather stations(AWS),whose hourly time series were completed with nearby stations,for the period January 2017 to December 2019.Results indicates a better performance of the reanalysis for T2m(r>0.80)than for Rh2m(~0.4<r<~0.6)in all four glaciers.Concerning the observations,both parameters show a daily cycle influenced by the presence of the glacier.This influence is more prominent during the dry months when the so-called glacier damping and cooling effects are stronger.On a monthly time scale,the ERAL validation for both parameters are better in wet outer tropical sites(RMSE between±0.2℃ for T2m and between 3%-7% for Rh2m)rather than in dry outer tropical sites(RMSE between±0.2℃ for T2m and between 3%-7% for Rh2m).Among all sites considered in the study,the Rh2m bias is the highest in the Cavalca glacier(correlation of 0.81;RMSE 13%,MAE 11% and bias 8.3%)and the lowest in Artesonraju glacier(correlation of 0.96;RMSE 3%;MAE 2.3% and bias-0.8%).Based on certain considerations outlined in this paper,it is appropriate to use ERAL to characterize T2m and Rh2m conditions on Peruvian glaciers,particularly in the wet outer tropics. 展开更多
关键词 ERA5 Land Tropical glaciers TEMPERATURE relative humidity Peru VALIDATION
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