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Wider frequency domain for negative refraction index in a quantized composite right–left handed transmission line
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作者 Qi-Xuan Wu Shun-Cai Zhao 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第6期468-472,共5页
The refraction index of the quantized lossy composite right-left handed transmission line(CRLH-TL) is deduced in the thermal coherence state. The results show that the negative refraction index(herein the left-hand... The refraction index of the quantized lossy composite right-left handed transmission line(CRLH-TL) is deduced in the thermal coherence state. The results show that the negative refraction index(herein the left-handedness) can be implemented by the electric circuit dissipative factors(i.e., the resistances R and conductances G) in a higher frequency band(1.446 GHz≤ ω ≤ 15 GHz), and flexibly adjusted by the left-handed circuit components(Cl, Ll) and the right-handed circuit components(Cr, Lr) at a lower frequency(ω = 0.995 GHz). The flexible adjustment for left-handedness in a wider bandwidth will be significant for the microscale circuit design of the CRLH-TL and may make the theoretical preparation for its compact applications. 展开更多
关键词 quantized composite right-left handed transmission line negative refraction index frequency do- main
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Digital light processing 3D printing of ceramics for W-band gradient refractive index metalens
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作者 Wuzhao Li Siqian Wu +2 位作者 Jin Chen Rong Wang Qi Ge 《International Journal of Extreme Manufacturing》 2026年第1期601-616,共16页
Gradient refractive index(GRIN)metalenses are increasingly valued in high-frequency communication due to their exceptional radiation performance.Ceramics with high dielectric constants and low dielectric losses are id... Gradient refractive index(GRIN)metalenses are increasingly valued in high-frequency communication due to their exceptional radiation performance.Ceramics with high dielectric constants and low dielectric losses are ideal candidates for GRIN metalenses.Digital light processing(DLP)3D printing provides a feasible and efficient approach for manufacturing ceramic GRIN metalenses.However,the scattering of ultraviolet(UV)light by ceramic particles in the slurry reduces the printing accuracy of DLP technology,making it difficult to achieve the intricate structural features required for GRIN metalenses in high-frequency communication.In this work,we propose an approach to improve printing accuracy by optimizing the ceramic slurry composition and implementing a dimensional compensation design strategy.Utilizing geometric optics and the S-parameter inversion method,we design a GRIN metalens consisting of two distinct types of subwavelength unit cells(Y-shaped and circular hole geometries)with a minimum feature size of 160μm.Through a refined slurry formulation and precise design parameter compensation,high-fidelity ceramic GRIN metalenses are successfully fabricated.The fabricated metalens exhibits a maximum gain enhancement of 18.4 dBi and a deflection angle of±30°over a bandwidth of 37.84% in the W-band(75-110 GHz).The highly directional far-field beam radiation and efficient beam steering capabilities highlight the potential of ceramic GRIN metalenses for applications in satellite communications,radar systems,and other high-frequency technologies. 展开更多
关键词 3D printing CERAMICS digital light processing gradient refractive index metalens
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Highly sensitive,multi-stage,and mid-infrared refractive index sensor based on photonic spin Hall effect
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作者 Jiaye Ding Chenglong Wang +2 位作者 Shengli Liu Peng Dong Jie Cheng 《Chinese Physics B》 2026年第1期432-438,共7页
Surface polaritons,as surface electromagnetic waves propagating along the surface of a medium,have played a crucial role in enhancing photonic spin Hall effect(PSHE)and developing highly sensitive refractive index(RI)... Surface polaritons,as surface electromagnetic waves propagating along the surface of a medium,have played a crucial role in enhancing photonic spin Hall effect(PSHE)and developing highly sensitive refractive index(RI)sensors.Among them,the traditional surface plasmon polariton(SPP)based on noble metals limits its application beyond the near-infrared(IR)regime due to the large negative permittivity and optical losses.In this contribution,we theoretically proposed a highly sensitive PSHE sensor with the structure of Ge prism-SiC-Si:InAs-sensing medium,by taking advantage of the hybrid surface plasmon phonon polariton(SPPhP)in mid-IR regime.Here,heavily Si-doped InAs(Si:InAs)and SiC excite the SPP and surface phonon polariton(SPhP),and the hybrid SPPhP is realized in this system.More importantly,the designed PSHE sensor based on this SPPhP mechanism achieves the multi-stage RI measurements from 1.00025-1.00225 to 1.70025-1.70225,and the maximal intensity sensitivity and angle sensitivity can be up to 9.4×10^(4)μm/RIU and245°/RIU,respectively.These findings provide a new pathway for the enhancement of PSHE in mid-IR regime,and offer new opportunities to develop highly sensitive RI sensors in multi-scenario applications,such as harmful gas monitoring and biosensing. 展开更多
关键词 refractive index(RI)sensor photonic spin Hall effect MID-IR MULTI-STAGE
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Realization of absolute negative refraction index by a photonic crystal using anisotropic dielectric material 被引量:1
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作者 方云团 欧阳征标 《Chinese Optics Letters》 SCIE EI CAS CSCD 2008年第1期57-60,共4页
A method to realize absolute negative refraction index -1 with a two-dimensional (2D) photonic crystal is presented by introducing dielectric anisotropy in the photonic crystal material. The band structures of E-pol... A method to realize absolute negative refraction index -1 with a two-dimensional (2D) photonic crystal is presented by introducing dielectric anisotropy in the photonic crystal material. The band structures of E-polarization mode and H-polarization mode can be adjusted by changing the parameters of materials. Thus the two modes with different polarizations have the same negative refraction index -1 for the same frequency. The results are demonstrated by numerical simulation based on the finite-difference time-domain (FDTD) method. 展开更多
关键词 Realization of absolute negative refraction index by a photonic crystal using anisotropic dielectric material mode EFS
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High index of refraction via quantum interference in a three-level system of Er^3+-doped yttrium aluminium garnet crystal
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作者 何琼毅 王铁军 高锦岳 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第8期1798-1805,共8页
A simple three-level system is proposed to produce high index of refraction with zero absorption in an Er^3+-doped yttrium aluminium garnet (YAG) crystal, which is achieved for a probe field between the excited sta... A simple three-level system is proposed to produce high index of refraction with zero absorption in an Er^3+-doped yttrium aluminium garnet (YAG) crystal, which is achieved for a probe field between the excited state 4I13/2 and ground state 4I15/2 by adjusting a strong coherent driving field between the upper excited state 4I11/2 and 4I15/2. It is found that the changes of the frequency of the coherent driving field and the concentration of Er^3+ ions in the YAG crystal can maximize the index of refraction accompanied by vanishing absorption. This result could be useful for the dispersion compensation in fibre communication, laser particle acceleration, high precision magnetometry and so on. 展开更多
关键词 electromagnetically induced transparency high index of refraction with zero absorption Er^3+-doped yttrium aluminium garnet crystal
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Optofluidic refractive index sensor with microtube-coupled suspended core fiber
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作者 WAN Jing HUIYongxiang +2 位作者 GAO Lizao ZHANG Wei WAN Hongdan 《Optoelectronics Letters》 2025年第10期589-594,共6页
Based on optofluidics and whispering gallery mode(WGM)theory,here an optofluidic refractive index sensor with microtube-coupled suspended core fiber(SCF)is proposed.It solves the issues of general sensors with microca... Based on optofluidics and whispering gallery mode(WGM)theory,here an optofluidic refractive index sensor with microtube-coupled suspended core fiber(SCF)is proposed.It solves the issues of general sensors with microcavity-coupled fiber taper such as too fragile,unstable performance due to open coupling,poor portability and repeatability,while overcoming the poor performance of low refractive index sensing in general full-package fiber sensors.The sensor only needs a very small amount of liquid sample(about 1.8 nL).The proposed sensor combines the excellent performance of full package,optofluidics and WGM resonator.The resonant characteristics and sensing performance of the sensor are analyzed and discussed by the theoretical simulation.The simulation results indicate that the sensor has a wide refractive index sensing range(1.330-1.700)and good performance.The resonance wavelength shift has a good linear relationship with the liquid refractive index variation.In the low refractive index region,the sensitivity is 222.5-247.5 nm/RIU,Q-factor is 1.03×10^(3) and the detection limit is 3.64×10^(-4) RIU.In the medium and high refractive index regions,the sensitivity is 564.4-846.2 nm/RIU,Q-factor is up to 8.62×10^(4),and the detection limit can be as low as 1.29×10^(-6) RIU.The sensor exhibits a high sensitivity,a high Q-factor and a very low detection limit. 展开更多
关键词 whispering gallery mode wgm theoryhere theoretical simulation whispering gallery mode microtube coupled suspended core fiber optofluidic refractive index sensor low refractive index sensing sensing performance refractive index sensing range
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High sensitivity and low refractive index D-type photonic crystal fiber sensor based on surface plasmon resonance
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作者 GAO Jiachen MING Xianbing WEN Xiang 《Optoelectronics Letters》 2025年第9期528-534,共7页
A D-type photonic crystal fiber(PCF) sensor based on surface plasmon resonance(SPR) principle is designed.In order to excite the SPR effect,a gold film is plated on the open-loop channel of the sensor,the free electro... A D-type photonic crystal fiber(PCF) sensor based on surface plasmon resonance(SPR) principle is designed.In order to excite the SPR effect,a gold film is plated on the open-loop channel of the sensor,the free electrons in a metal are resonated with photons.The structural parameters are fine-tuned and the sensing performance of the sensor is studied.The results show that the maximum spectral sensitivity reaches 18 000 nm/RIU in the refractive index range of 1.24—1.32,and the maximum resolution is 5.56×10^(-6) RIU.The novel structure with high sensitivity and low refractive index provides a new perspective for fluid density detection. 展开更多
关键词 high sensitivity d type photonic crystal fiber surface plasmon resonance spr gold film maximum resolution refractive index low refractive index surface plasmon resonance
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Investigation of edge states variation in valley photonic crystals by modulating the refractive index of domain walls
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作者 ZHANG Run ZHONG Xingli +2 位作者 LIN Zhongxi QIU Weibin SU Hui 《Optoelectronics Letters》 2025年第3期160-166,共7页
Realizing the valley Hall effect by breaking the spatial inversion symmetry of photonic systems has become a cutting-edge field of micro-nano-optics,since the valley degree of freedom was introduced into photonic syst... Realizing the valley Hall effect by breaking the spatial inversion symmetry of photonic systems has become a cutting-edge field of micro-nano-optics,since the valley degree of freedom was introduced into photonic system.Various novel devices based on the domain walls of the valley photonic crystals have also been demonstrated.In this article,we investigate the variation of edge states by the modulation of refractive index within the domain walls,and the geometric difference between the dielectric columns of the sublattices.Straight photonic crystal waveguides with three types of domain walls(bearded,zigzag,armchair)are constructed.Simulation results show that the creation of a double-edge state in the band diagram results in two windows of stable transmission in tunable bands.Our findings might have significant implications in the field of novel optical devices. 展开更多
关键词 modulation refractive index domain walls variation edge states breaking spatial inversion symmetry valley degree freedom photonic crystals geometric difference dielectric columns photonic systems
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Super-resolving refractive index measurements with even coherent-state sources and parity detection
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作者 Qiang Wang Xiaohao Yang +1 位作者 Fu Song Lili Hao 《Chinese Physics B》 2025年第12期260-267,共8页
High-precision refractive index measurement has become a research hotspot in recent years.However,traditional refractive index measurement often adopts intensity detection,whose performance is restricted by the classi... High-precision refractive index measurement has become a research hotspot in recent years.However,traditional refractive index measurement often adopts intensity detection,whose performance is restricted by the classical detection limit and is thus hard to improve further.In order to break through this limitation,we propose a quantum-enhanced refractive index sensing scheme utilizing even-coherent-state sources in combination with parity detection.In this paper,we analyze the detection performance of the proposed system.Due to the inevitable photon loss in practical applications,the effects of photon loss on resolution and sensitivity are also investigated.Numerical results show that the resolution of the proposed strategy breaks through the Rayleigh limit and achieves super-resolving refractive index measurement.Relative to existing coherent-state schemes,our strategy leads to a twofold resolution improvement.Furthermore,the physical origins of the super-resolution are analyzed. 展开更多
关键词 refractive index measurement even coherent state parity photon counting DETECTION SUPER-RESOLUTION
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Efficient Prediction of Refractive Index and Abbe Number in Polymers Using Density Functional Theory
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作者 Lu-Kun Feng Ai-Wei Zhang +3 位作者 Guo-Hua Huang Cai-Zhen Zhu Ming-Liang Wang Jian Xu 《Chinese Journal of Polymer Science》 2025年第8期1468-1482,共15页
Polymer optical materials are becoming increasingly important in modern technologies owing to their unique properties.This study applies coupled perturbed density functional theory(DFT)to predict the refractive index(... Polymer optical materials are becoming increasingly important in modern technologies owing to their unique properties.This study applies coupled perturbed density functional theory(DFT)to predict the refractive index(RI)and Abbe number of polymers.Using the LorentzLorenz equation,the frequency-dependent polarizability and molecular volume were calculated to estimate RI.Wavelength-dependent RI values were used to derive the Abbe numbers.Our results show a strong correlation with experimental data,with Pearson coefficients of 0.912 for RI and 0.968 for Abbe number,enabling the introduction of linear correction functions to minimize discrepancies between theoretical predictions and experimental results.By categorizing polymers into classes such as poly(methyl methacrylate)(PMMA)-,polyethylene(PE)-,polycarbonate(PC)-,polyimide(PI)-,and polyurethane(PU)-based materials,this method enables precise predictions and reduces discrepancies using linear correction functions.This efficient and direct computational framework avoids the complexity of traditional models and offers a practical tool for the design and optimization of advanced optical materials. 展开更多
关键词 Optical polymers Refractive index prediction Abbe number prediction Coupled perturbed DFT Linear correction
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Excited state refraction of C_(70)/toluene studied by using 4f coherent imaging system with phase object 被引量:1
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作者 刘南春 石光 +1 位作者 杨俊义 宋瑛林 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第1期304-309,共6页
Dynamic nonlinearities of C70/toluene solution are measured and analysed by an improved picosecond timeresolved pump-probe system based on a nonlinear imaging technique with phase object. The photophysical parameters ... Dynamic nonlinearities of C70/toluene solution are measured and analysed by an improved picosecond timeresolved pump-probe system based on a nonlinear imaging technique with phase object. The photophysical parameters are determined by the five-level model, which is adopted to interpret the experimental data. The change of refraction index per unit density of the excited state obtained by a numerically simulation is a critical factor to determine the nonlinear behaviour of C70 in picosecond time regime. 展开更多
关键词 4f system excited state refraction C70/toluene solution refraction index per unit density
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Fiber-optic microstructured sensors based on abrupt field patterns: theory, fabrication, and applications
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作者 Yuxuan Yi Wanlai Zhu +4 位作者 Zao Yi Zigang Zhou Shubo Cheng Majid Niaz Akhtar Sohail Ahmad 《Opto-Electronic Science》 2026年第1期13-31,共19页
Fiber-optic sensing technology has the advantages of passivity, anti-electromagnetic interference, longdistancemeasurement, high sensitivity and high accuracy, small size, and adaptability to harsh environments such a... Fiber-optic sensing technology has the advantages of passivity, anti-electromagnetic interference, longdistancemeasurement, high sensitivity and high accuracy, small size, and adaptability to harsh environments such ashigh-vacuum, high-pressure, and strong magnetic fields compared with the traditional electrical sensing technology.However, with the increasing application requirements, how to further improve the sensitivity of fiber-optic sensors,extend the detection limit and improve the maintenance-free capability has become one of the core issues of thecurrent research. This paper reviews the principle, preparation, and application of fiber-optic microstructured sensingbased on abrupt field type. It specifically outlines the development and applications of micro-nano optical fibers,photonic crystal optical fibers, optical fiber gratings and structured optical fibers, and lists the main preparationmethods of two types of micro-nano optical fibers from the basic theory of optical fiber microstructured sensordevices. 展开更多
关键词 fiber-optic microstructure sensing sudden field-type fiber-optic microstructure devices fiber-optic refractive index sensors micro-and nanofibers Wiener fiber preparation
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Measurement of refrative index based on fiber Mach-Zehnder interference
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作者 谷瑾瑜 王冠军 +2 位作者 安永泉 刘星麟 张美芹 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2016年第2期106-109,共4页
In order to detect the refractive index of liquid with high precision,based on modular interference,Mach-Zehnder optical fiber refractive rate sensor was studied.Sensor structure is composed of ordinary single-mode fi... In order to detect the refractive index of liquid with high precision,based on modular interference,Mach-Zehnder optical fiber refractive rate sensor was studied.Sensor structure is composed of ordinary single-mode fiber and multimode fiber,according to the singlemode multimode singlemode sequence to fuse together,and the fused optical fiber is used to process the taper.As a result,the diameter of the sensing head is about 10μm.Experimental results show that,as liquid refractive index increases range from 1.33 to 1.35,the loss peak of the transmission spectrum will shift to long wave direction. 展开更多
关键词 optical fiber fusion optical fiber tapering Mach-Zehnder interference refractive index measurement optical fiber sensor
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How to realize a negative refractive index material at the atomic level in an optical frequency range? 被引量:5
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作者 沈建其 阮智超 何赛灵 《Journal of Zhejiang University Science》 EI CSCD 2004年第11期1322-1326,共5页
The theoretical mechanism for realizing a negative refractive index material in an optical frequency range with an atomic gas system of electromagnetically induced transparency (EIT) is studied. It is shown that under... The theoretical mechanism for realizing a negative refractive index material in an optical frequency range with an atomic gas system of electromagnetically induced transparency (EIT) is studied. It is shown that under certain conditions such a dense gas can exhibit simultaneously negative permittivity and negative permeability, and negligibly small loss. 展开更多
关键词 Negative refractive index Left-handed medium Electromagnetically induced transparency Atomic level Optical frequency
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High-refractive index acrylate polymers for applications in nanoimprint lithography 被引量:4
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作者 Yunhui Tang Stefano Cabrini +1 位作者 Jun Nie Carlos Pina-Hernandez 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第1期256-260,共5页
The development of polymeric optical materials with a higher refractive index,transparency in the visible spectrum region and easier processability is increasingly desirable for advanced optical applications such as m... The development of polymeric optical materials with a higher refractive index,transparency in the visible spectrum region and easier processability is increasingly desirable for advanced optical applications such as microlenses,image sensors,and organic light-emitting diodes.Most acrylates have a low refractive index(around 1.50)which does not meet the high perfo rmance requirements of advanced optical materials.In this research,three novel acrylates were synthesized via a facile one-step approach and used to fabricate optical transparent polymers.All of the polymers reveal good optical properties including high transparency(≥90%)in the visible spectrum region and high refractive index values(1.6363)at 550 nm.Moreover,nanostructures of these acrylate polymers with various feature sizes including nanogratings and photonic crystals were successfully fabricated using nanoimprint lithography.These results indicate that these acrylates can be used in a wide range of optical and optoelectronic devices where nanopatterned films with high refractive index and transparency are required. 展开更多
关键词 High refractive index ACRYLATE Facile synthesis NANOSTRUCTURE Nanoimprint lithography
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Preparation of Titanium-silphenylene-siloxane Hybrid Polymers with High Refractive Index,Transmittance,and Thermal Stability 被引量:5
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作者 Dong Zhao Shu-Xi Shan +3 位作者 Meng Zhang Xiao-A Zhang Sheng-Ling Jiang Ya-Fei Lyu 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2020年第9期973-982,I0007,共11页
Vinyl-containingtitanium-silphenylene-sioxane oligomers(O1,O2,O3,andO4)withdifferent molar ratios of titanium to silicon were successfully synthesized in high yields by nonhydrolytic sol-gel reaction,and the obtained ... Vinyl-containingtitanium-silphenylene-sioxane oligomers(O1,O2,O3,andO4)withdifferent molar ratios of titanium to silicon were successfully synthesized in high yields by nonhydrolytic sol-gel reaction,and the obtained four oligomers were further crosslinked with methylphenyl hydro-silicone oil(4)to form corresponding polymers(P1,P2,P3,and P4)by hydrosilylation reaction.Their structures were characterized with spectroscopic characterization techniques including FTIR,1H-NMR,and Raman spectroscopy.The effect of titanium element on crosslinking behavior,thermal resistance,refractive index,transparency,thermal aging stability,glass transition temperature,and surface properties of the polymers were studied.Compared with titanium-free polymer P1,the thermal resistance,refractive index,and thermal aging stability of titanium-silphenylene-siloxane polymers(P2,P3,and P4)were significantly improved.The titanium-silphenylene-siloxane polymers achieved a high refractive index(n=1.580-1.584)and thermostability(Tsd>500℃).In thermal aging,the polymers exhibited superior performances with high optical transparency(~90%at 450 nm)and exhibited high thermal stability(~84%at 450 nm after thermal aging at 150℃for 120 h).These data indicate that the polymers have potential application in optical materials such as LED encapsulants. 展开更多
关键词 Titanium-silphenylene-siloxane hybrid polymers High refractive index and transmittance Thermal stability
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Influence of Refractive Index Distribution on Brillouin Gain Spectrum in GeO_(2)-Doped Optical Fibers 被引量:4
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作者 JI Zhengyuan LU Yuangang +3 位作者 PAN Yuhang PENG Jianqin ZHANG Zelin WANG Jiming 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2021年第5期769-787,共19页
GeO_(2) is commonly used as dopant to adjust the refractive index profile(RIP)and the acoustic velocity profile(AVP)in the fiber,thereby forming different Brillouin gain spectrum(BGS)characteristics such as Brillouin ... GeO_(2) is commonly used as dopant to adjust the refractive index profile(RIP)and the acoustic velocity profile(AVP)in the fiber,thereby forming different Brillouin gain spectrum(BGS)characteristics such as Brillouin gain,acoustic mode number and peak intensity difference.When an optical fiber is used in optical fiber sensing or communication system,its BGS characteristics may play an important role in determining the performance of the system.In this paper,finite element analysis(FEA)method is used to study the influence of refractive index distribution and its corresponding AVP on the BGS in step-index,graded-index,and complex-index optical fibers.A new method has also been proposed to efficiently discriminate acoustic mode solution and obtain the new and full images of total Brillouin gain and acoustic modes number of the fiber as a function of the refractive index distribution,considering the influence of changing the refractive index difference and the geometric size simultaneously.For each type of optical fiber,the recommended parameter range is provided for optical fiber sensing and optical fiber communication.Moreover,the suitable optical fiber with close peak intensity in its multi-peak BGS is explored and achieved,which can be used in Brillouin beat spectrum detection systems to improve sensing accuracy. 展开更多
关键词 Brillouin gain spectrum optical fiber acoustic mode refractive index finite element analysis(FEA)
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Highly sensitive fiber refractive index sensor based on side-core holey structure 被引量:3
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作者 韩雅 夏历 刘德明 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期225-229,共5页
We propose a side-core holey fiber (SCHF)-based surface plasmon resonance (SPR) sensor to achieve high refractive index (RI) sensitivity. The SCHF structure can facilitate analyte filling and enhance the overlap... We propose a side-core holey fiber (SCHF)-based surface plasmon resonance (SPR) sensor to achieve high refractive index (RI) sensitivity. The SCHF structure can facilitate analyte filling and enhance the overlapping area of the core mode and surface plasmon polariton (SPP) mode. The coupling properties of the sensor are analyzed by numerical simulation. The maximum sensitivity of 5000 nm/RIU in an RI range of 1.33-1.44, and the average sensitivity of 9295 nm/RIU in an RI range from 1.44 to 1.54 can be obtained. 展开更多
关键词 holy fiber surface plasmon resonance refractive index fiber sensor
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Prediction of Density and Refractive Index of Lubricating Oils during Secondary Solvent Extraction Process by Furfural 被引量:3
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作者 Xu Xiaoling Liu Yansheng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2021年第3期127-136,共10页
To meet the requirements for high aromatic content and low polycyclic aromatic(PCA)concentration,eco-friendly aromatic-rich rubber extender oils are usually produced by two-stage solvent extraction processes with furf... To meet the requirements for high aromatic content and low polycyclic aromatic(PCA)concentration,eco-friendly aromatic-rich rubber extender oils are usually produced by two-stage solvent extraction processes with furfural.Among the different properties of rubber processing oils,density and refractive index are some of the most important properties related to their final quality.Two types of methods,including a pseudo-component approach by using mixing rules and several correlations,were used for calculation of density and refractive index at 20℃ of paraffinic furfural-extract oils and their secondary raffinates.Results indicated that similar accuracy was obtained for predicting the density and the refractive index of furfural+furfural-extract paraffinic oil systems.However,the quadratic correlation presents its advantage over the pseudo-component approach when the composition of oils is not available.Moreover,the quadratic correlation was also used for naphthenic lubricating oils during two-stage solvent extraction processes.The predictions showed much larger discrepancies with respect to experimental values than those of paraffinic lubricating oils,which indicated that the quadratic correlation was more suitable for paraffinic oils with a CN value of below 37%. 展开更多
关键词 DENSITY refractive index pseudo-components paraffinic furfural-extract oils naphthenic lubricating oils solvent extraction
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Predictive methods for density and refractive index of naphthenic lubricating oils during solvent extraction process 被引量:2
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作者 Xiao-Ling Xu Tian-Qi Wang +2 位作者 Guang-Huai Chen Jun-Wei Hou Yan-Sheng Liu 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1934-1946,共13页
Lubricating oils are usually produced by solvent extraction to separate aromatics in order to achieve the desired specifications and better quality products.Among the different properties of lubricating oils,density a... Lubricating oils are usually produced by solvent extraction to separate aromatics in order to achieve the desired specifications and better quality products.Among the different properties of lubricating oils,density and refractive index are some of the most important properties which can both be used for petroleum fluid characterization.Predictions of density and refractive index for naphthenic oils during solvent extraction by DMSO obtained by the pseudo-component approach and the quadratic correlation were both examined.The pseudo-component approach is a method to predict density and refractive index from composition while the latter merely relates density to refractive index.Results indicated that the predictions yielded by the pseudo-component method were in good agreement with experimental data for naphthenic oils.And the use of a function of refractive index(FRI_(20))as a pseudo-component property remarkably improved n_(20)predictions for the naphthenic mixtures.However,the density and refractive index predictions obtained by the quadratic correlation exhibited significantly higher de-viations for naphthenic oils than those for paraffinic oils.Thus a new modified correlation of the same functional form was proposed for naphthenic oils.The modification significantly improved predictions for naphthenic oils,which presented similar accuracy as the pseudo-component approach.And the previous correlation was still used for paraffinic oils.Additionally,effect of temperature on density and refractive index of naphthenic oils was examined.Results showed that the modified quadratic correlation was accurate for describing the relationship between density and refractive index of naphthenic oils at 20-90℃.The temperature dependence of density and refractive index for the raffinates and the extracts could be accurately described by the thermal coefficients for saturates and aromatics,respectively.Regarding the refractive index variation of the extracts with temperature,the empirical equation was proved to be a better option compared with the method using the thermal coefficient for aromatics. 展开更多
关键词 DENSITY Refractive index Pseudo-components Paraffinic lubricating oils Naphthenic lubricating oils Solvent extraction
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