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Mechanism analysis of effect of MgO on reduction swelling behaviour of iron pellets in CO/H_(2)atmosphere based on first-principles calculations
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作者 Hong-ming Long Jing-shu An +3 位作者 Xing-wang Li Ting Wu Sheng-ping He Jie Lei 《Journal of Iron and Steel Research International》 2025年第1期73-84,共12页
To explain the influence mechanism of MgO on the consolidation and reduction characteristics of roasted iron pellets,the properties and structure of pellets were investigated from multi-dimensions.It indicated that th... To explain the influence mechanism of MgO on the consolidation and reduction characteristics of roasted iron pellets,the properties and structure of pellets were investigated from multi-dimensions.It indicated that the MgO addition decreased the reduction swelling index(RSI)and reduction degree of pellets in both CO and H_(2)atmospheres.During the stepwise reduction process of Fe2O3→Fe3O4→FeO,the reduction behaviour of pellets in CO and H_(2)was similar,while the reduction rate of pellets in H_(2)atmosphere was almost twice as high as that in CO atmosphere.During the stepwise reduction process of FeO→Fe,the RSI of pellets showed a logarithmic increase in CO atmosphere and a linear decrease in H_(2)atmosphere.As investigated by first-principles calculations,C and Fe mainly formed chemical bonds,and the CO reduction process released energy,promoting the formation of iron whiskers.However,H and Fe produced weak physical adsorption,and the H_(2)reduction process was endothermic,inhibiting the generation of iron whiskers.With Mg2+doping in FexO,the nucleation region of iron whiskers expanded in CO reduction process,and the morphology of iron whiskers transformed from“slender”to“stocky,”reducing RSI of the pellets. 展开更多
关键词 MGO CO atmosphere H_(2)atmosphere reduction degree reduction swelling index First-principles calculation
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Multi-Degree Reduction of Bézier Curves with Distance and Energy Optimization 被引量:2
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作者 Xuli Han Jing Yang 《Journal of Applied Mathematics and Physics》 2016年第1期8-15,共8页
In this paper, we propose a new approach to the problem of degree reduction of Bézier curves based on the given endpoint constraints. A differential term is added for the purpose of controlling the smoothness to ... In this paper, we propose a new approach to the problem of degree reduction of Bézier curves based on the given endpoint constraints. A differential term is added for the purpose of controlling the smoothness to a certain extent. Considering the adjustment of second derivative in curve design, a modified objective function including two parts is constructed here. One part is a kind of measure of the distance between original high order Bézier curve and degree-reduced curve. The other part represents the second derivative of degree-reduced curve. We tackle two kinds of conditions which are position vector constraint and tangent vector constraint respectively. The explicit representations of unknown points are presented. Some examples are illustrated to show the influence of the differential terms to approximation and smoothness effect. 展开更多
关键词 Bézier Curve degree reduction Endpoint Constraint Differential Constraint L2-Norm
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A quadratic programming method for optimal degree reduction of Bézier curves with G^1-continuity
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作者 LU Li-zheng WANG Guo-zhao 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第10期1657-1662,共6页
This paper presents a quadratic programming method for optimal multi-degree reduction of B6zier curves with G^1-continuity. The L2 and I2 measures of distances between the two curves are used as the objective function... This paper presents a quadratic programming method for optimal multi-degree reduction of B6zier curves with G^1-continuity. The L2 and I2 measures of distances between the two curves are used as the objective functions. The two additional parameters, available from the coincidence of the oriented tangents, are constrained to be positive so as to satisfy the solvability condition. Finally, degree reduction is changed to solve a quadratic problem of two parameters with linear constraints. Applications of degree reduction of Bezier curves with their parameterizations close to arc-length parameterizations are also discussed. 展开更多
关键词 degree reduction Bezier curves Optimal approximation G^1-continuity Quadratic programming
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Constrained multi-degree reduction of triangular Bézier surfaces
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作者 ZHOU Lian WANG Guo-jin 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2009年第4期417-430,共14页
This paper proposes and applies a method to sort two-dimensional control points of triangular Bezier surfaces in a row vector. Using the property of bivariate Jacobi basis functions, it further presents two algorithms... This paper proposes and applies a method to sort two-dimensional control points of triangular Bezier surfaces in a row vector. Using the property of bivariate Jacobi basis functions, it further presents two algorithms for multi-degree reduction of triangular Bezier surfaces with constraints, providing explicit degree-reduced surfaces. The first algorithm can obtain the explicit representation of the optimal degree-reduced surfaces and the approximating error in both boundary curve constraints and corner constraints. But it has to solve the inversion of a matrix whose degree is related with the original surface. The second algorithm entails no matrix inversion to bring about computational instability, gives stable degree-reduced surfaces quickly, and presents the error bound. In the end, the paper proves the efficiency of the two algorithms through examples and error analysis. 展开更多
关键词 triangular Bezier surface EXPLICIT boundary curve constraint corner constraint degree reduction Jacobi polynomial
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APPROXIMATE COMMON DIVISORS OF POLYNOMIALS AND DEGREE REDUCTION FOR RATIONAL CURVES 被引量:1
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作者 SUN JIANZHONG,CHEN FALAI AND QU YONGMING 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 1998年第4期437-444,共8页
Abstract This paper deals with how to perturb a given set of polynomials so as to include a common linear factor. An algorithm is derived for determining such a set of perturbation polynomials which are subject to cer... Abstract This paper deals with how to perturb a given set of polynomials so as to include a common linear factor. An algorithm is derived for determining such a set of perturbation polynomials which are subject to certain constrains at the endpoints of a prescribed parametric interval and minimized in a certain sense. This result can be combined with subdivision technique to obtain a continuous piecewise approximation to a rational curve. 展开更多
关键词 Rational curve degree reduction SUBDIVISION approximate common divisor
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Reduction mechanism of Fe2O3-Cr2O3-NiO system by carbon
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作者 张延玲 郭文明 +1 位作者 刘洋 贾昕磊 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第6期1318-1325,共8页
Isothermal experiments on the reduction of Fe_2O_3-Cr_2O_3-NiO(molar ratio of Fe-to-Cr-to-Ni is 3:2:2)by graphite were carried out at 1350–1550°C,and effects of various factors on reduction degree were studied.T... Isothermal experiments on the reduction of Fe_2O_3-Cr_2O_3-NiO(molar ratio of Fe-to-Cr-to-Ni is 3:2:2)by graphite were carried out at 1350–1550°C,and effects of various factors on reduction degree were studied.The results show that the reaction rate of the Fe_2O_3-Cr_2O_3-NiO system is fast during the initial period(reduction degree,α<38%),and then the rate decreases until the end of the reduction.Factors such as temperature,carbon content,sample size have a more significant effect during the final stage(α>38%).The metallic product formed at the initial stage(a Fe-Ni alloy)greatly promotes the reduction of Cr2O3 at the final stage.Further,during the reduction of Fe_2O_3-Cr_2O_3-NiO by carbon,interfacial reaction is the rate-controlling step and g(α)=1-(1-α)0.5 is the reaction mechanism for the initial stage,whereas two-dimensional diffusion is the rate-controlling step and f(α)=α+(1-α)ln(1-α)is the reaction mechanism for the final stage.The apparent activation energies are 55.43 k J/mol and 174.54 k J/mol for the initial and the final stages,respectively. 展开更多
关键词 Fe2O3-Cr2O3-NiO system isothermal reduction reduction degree KINETICS reaction mechanism
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Softening and Melting Behavior of Mixed Burden for Oxygen Blast Furnace 被引量:6
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作者 AN Xiu-wei WANG Jing-song +2 位作者 LAN Rong-zong HAN Yi-hua XUE Qing-guo 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2013年第5期11-16,共6页
The behaviors of mixed burden in the cohesive zone of oxygen blast furnace were studied by softening and melting tests, and the influence of reducing gas and burden basicity on the softening and melting behaviors of m... The behaviors of mixed burden in the cohesive zone of oxygen blast furnace were studied by softening and melting tests, and the influence of reducing gas and burden basicity on the softening and melting behaviors of mixed burden was also investigated. The results indicated that the softening range became wide, however, the melting range narrowed sharply in the atmosphere of oxygen blast furnace. The permeability of burden in the oxygen blast furnace was obviously improved comparing with the conventional blast furnace. In addition, the content of sulphur in the dripping iron of oxygen blast furnace was much lower than that of conventional blast furnace, however, the content of carbon increased. An optimum basicity of burden, which could lead to the appearance of the narrower melting range and better permeability of burden, was obtained in the atmosphere of oxygen blast furnace. 展开更多
关键词 oxygen blast furnace SOFTENING MELTING mixed burden BASICITY reduction degree
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Mineralization characteristics of pellets prepared by ultrafine magnetite concentrate:influence on metallurgical property and improving method 被引量:2
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作者 Xiao-hui Fan Zhi-an Zhou +4 位作者 Shu Wang Min Gan Zhi-yun Ji Xu-ling Chen Zhi-yuan Tian 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2023年第3期446-455,共10页
The reducing property of pellets prepared by ultrafine magnetite concentrate(UMC)and improving method were revealed.The results show that the reduction degree of UMC pellets is only about 56%compared with that of pell... The reducing property of pellets prepared by ultrafine magnetite concentrate(UMC)and improving method were revealed.The results show that the reduction degree of UMC pellets is only about 56%compared with that of pellets prepared from ordinary iron ore concentrate with relatively coarse particle size,which is significantly lower than the general reduction degree of about 70%.When the composite binder composed of bentonite and organic binder was added,the reduction degree was significantly increased to 69.66%.The revealed mechanism shows that the reduced pellets with common bentonite have a concentric structure,the oxidation gap between the inner and outer layers is obvious,and the outer dense oxide layer hinders the oxidation and reduction of the inner layer.After adding the composite binder,the organic components significantly improved the internal porosity of the pellets and the aggregation degree of ultrafine iron ore concentrate particles in the granulation process,forming a porous structure.The non-uniform double-layer structure is eliminated,and the increased pores are conducive to the internal diffusion of CO,and finally the reduction degree of pellets is increased to the level equivalent to that of ordinary magnetite pellets. 展开更多
关键词 Ultrafine magnetite concentrate Mineralization characteristics reduction degree Improving method Function mechanism
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Approximate Degree Reduction of Bezier Curves 被引量:10
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作者 胡事民 孙家广 +1 位作者 金通光 汪国昭 《Tsinghua Science and Technology》 SCIE EI CAS 1998年第2期51-54,共4页
Degree reduction of parametric curves and surfaces is an important process in data communication between CAD systems. The degenerate condition of Bezier curves and the constrained optimization method are used to devel... Degree reduction of parametric curves and surfaces is an important process in data communication between CAD systems. The degenerate condition of Bezier curves and the constrained optimization method are used to develop a new degree reduction method for Bezier curves. An error analysis of the degree reduction is also given. The degree reduction scheme is combined with a subdivision algorithm to generate lower degree approximations which are within some preset error tolerance of the prescribed Bezier curve. Geometric continuity between adjacent curve segments is also considered in the subdivision/degree reduction process. 展开更多
关键词 Bezier curve degree reduction degenerate condition constrained optimization geometric continuity
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UNIFYING REPRESENTATION OF BZIER CURVE AND GENERALIZED BALL CURVES 被引量:16
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作者 Wu HongyiDept. ofMath. and Mech., HefeiUniv. of Technology,Hefei230009. 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2000年第1期109-121,共13页
This paper presents two new families of the generalized Ball curves which include the Be ′zier curve, the generalized Ball curves defined by Wang and Said independently and some intermediate curves. The relati... This paper presents two new families of the generalized Ball curves which include the Be ′zier curve, the generalized Ball curves defined by Wang and Said independently and some intermediate curves. The relative degree elevation and reduction schemes, recursive algorithms and the Bernstein\|Be ′zier representation are also given. 展开更多
关键词 Be'zier curve generalized Ballcurve degree elevation and reduction recursive algorithm .
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Approximate Degree Reduction of Triangular Bezier Surfaces 被引量:4
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作者 胡事民 左征 孙家广 《Tsinghua Science and Technology》 SCIE EI CAS 1998年第2期55-58,共4页
Degree reduction of parametric curves and surfaces is an important process in the exchange of product model data between various CAD systems. In this paper the degenerate conditions of triangular Bezier surface patch... Degree reduction of parametric curves and surfaces is an important process in the exchange of product model data between various CAD systems. In this paper the degenerate conditions of triangular Bezier surface patches are derived. The degenerate conditions and constrained optimization methods are used to develop a degree reduction method for triangular Bezier surface patches. The error in the degree reduction of a triangular Bezier surface is also shown to depend on some geometric invariants which decrease exponentially in the subdivision process. Therefore, the degree reduction method can be combined with a subdivision algorithm to generate lower degree approximations which are within some preset error tolerance. 展开更多
关键词 CAGD triangular Bezier surface degree reduction degenerate condition constrained optimization method
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Activation of small molecules over praseodymium-doped ceria 被引量:1
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作者 Meiling Guo Xuebin Liu Amorelli Angelo 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第11期1800-1809,共10页
Praseodymium can modify the properties of ceria(CeO_(2)),changing the electronic structure,reducibility and catalytic behavior.Oxygen vacancies in the ceria-based samples can activate C–O and C–H bonds of small mole... Praseodymium can modify the properties of ceria(CeO_(2)),changing the electronic structure,reducibility and catalytic behavior.Oxygen vacancies in the ceria-based samples can activate C–O and C–H bonds of small molecules such as CO_(2)and propane.Partially reduced Pr/CeO_(2)-x can selectively activate C–H of propane,giving a propylene selectivity of ca.75%at a propane conversion of 5%to 10%.Excess reduction of Pr/CeO_(2)-x induces coking reactions during propane dehydrogenation,resulting in fast catalyst deactivation. 展开更多
关键词 CEO2 Pr dopant Oxygen vacancy degree of reduction Propane dehydrogenation
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Optimal multi-degree reduction of C-Bezier surfaces with constraints
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作者 Lian ZHOU Xin-hui LIN +1 位作者 Hong-yan ZHAO Jin CHEN 《Frontiers of Information Technology & Electronic Engineering》 SCIE EI CSCD 2017年第12期2009-2016,共8页
We propose an optimal approach to solve the problem of multi-degree reduction of C-Brzier surfaces in the norm L2 with prescribed constraints. The control points of the degree-reduced C-Brzier surfaces can be explicit... We propose an optimal approach to solve the problem of multi-degree reduction of C-Brzier surfaces in the norm L2 with prescribed constraints. The control points of the degree-reduced C-Brzier surfaces can be explicitly obtained by using a matrix operation that is based on the transfer matrix of the C-Brzier basis. With prescribed boundary constraints, this method can be applied to piecewise continuous patches or to a single patch with the combination of surface subdivision. The resulting piecewise approximating patches are globally G1 continuous. Finally, numerical examples are presented to show the effectiveness of the method. 展开更多
关键词 C-Bezier surfaces degree reduction Boundary constraints _
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Assessment of Nanoparticle-Enriched Solvents for Oil Recovery Enhancement
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作者 Muayad M.Hasan Firas K.Al-Zuhairi +1 位作者 Anfal H.Sadeq Rana A.Azeez 《Fluid Dynamics & Materials Processing》 EI 2023年第11期2827-2835,共9页
Solvents are generally used to reduce the viscosity of heavy crude oil and ultimately enhance oil recovery.Recently,a new method has been introduced where nanoparticles(NPs)are exploited to induce enhanced oil recover... Solvents are generally used to reduce the viscosity of heavy crude oil and ultimately enhance oil recovery.Recently,a new method has been introduced where nanoparticles(NPs)are exploited to induce enhanced oil recovery owing to their ability to improve the mobility ratio,dampen the interfacial tension,and alter rock wett-ability.This study investigated the integration of nano-alumina(Al_(2)O_(3))NPs with an n-hexane solvent.In parti-cular,a Brookfield viscometer has been used to measure the crude oil viscosity and it has been found that NPs can effectively lead to a significant decrease in the overall oil viscosity(70 cp using the solvent only,45 cp when NPs are added). 展开更多
关键词 NANOTECHNOLOGY viscosity reduction organic solvents degree of viscosity reduction(DVR) enhanced oil recovery(EOR)
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Establishing a generalized model for accurate prediction of higher heating values of substances with large ash fractions
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作者 Peng Jiang Lin Li +5 位作者 Han Lin Tuo Ji Liwen Mu Yuanhui Ji Xiaohua Lu Jiahua Zhu 《Green Chemical Engineering》 2025年第3期372-379,共8页
The higher heating value(HHV)of biomass is a crucial property for design calculations and numerical simulations in bioenergy utilization.However,existing models for HHV prediction faced challenges in terms of predicti... The higher heating value(HHV)of biomass is a crucial property for design calculations and numerical simulations in bioenergy utilization.However,existing models for HHV prediction faced challenges in terms of predictive accuracy and generalization capability across various solid waste types,especially for those with high ash content.This work proposed a novel HHV prediction model based on its reduction degree(D_(R))and ash content(Cash).First,ultimate analysis of biomass was applied to establish the calculation method of D_(R);then,the correlation between D_(R),Cash,and HHV was analyzed using the Pearson Correlation Coefficient;subsequently,the HHV=f(D_(R),Cash)model was developed using regression analysis.Furthermore,the accuracy was compared to previous literature in terms of correlation coefficient(R^(2)),root mean square error(RMSE),and mean absolute error(MAE).Results revealed that this model provided attractive accuracy with R^(2)=0.854,RMSE=0.900,and MAE=0.773 within a wide range of ash content from 0 to 83.32 wt%.Even higher accuracy was achieved with this model in predicting the HHV of coal,biochar,and bio-oil,with R^(2)of 0.961,0.989,and 0.939,respectively.Conclusively,this work proposed the use of D_(R)for HHV estimation,which was not only a simple and accurate approach but also widely applicable to various fuels. 展开更多
关键词 BIOMASS Higher heating value reduction degree Predicting model Ash content
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An orthogonal basis for the hyperbolic hybrid polynomial space 被引量:4
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作者 HUANG Yu WANG GuoZhao 《Science in China(Series F)》 2007年第1期21-28,共8页
Motivated by the wlde usage of the Tchebyshev basis and Legendre basis in the algebra polynomial space, we construct an orthogonal basis with the properties of the H-Bézier basis In the hyperbolic hybrid polynomi... Motivated by the wlde usage of the Tchebyshev basis and Legendre basis in the algebra polynomial space, we construct an orthogonal basis with the properties of the H-Bézier basis In the hyperbolic hybrid polynomial space, which is similar to the Legendre basis and holds remarkable properties. Moreover, we derive the transformation matrices that map the H-Bézler basis and the orthogonal basis forms into each other. An example for approximating the degree reduction of the H- Bézier curves Is sketched to Illustrate the utility of the orthogonal basis. 展开更多
关键词 H-Bézier basis orthogonal basis basis transformations degree reduction
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