Reactive dyes with different reactive groups exhibit different hydrolysis and dyeing behaviors.This is particularly evident in the combination dyeing process,where the competion between hydrolysis and dyeing reactions...Reactive dyes with different reactive groups exhibit different hydrolysis and dyeing behaviors.This is particularly evident in the combination dyeing process,where the competion between hydrolysis and dyeing reactions increases the complexity.Therefore,developing an effective method to monitor the changes in reactive dyes during the dyeing process is important.This study aims to develop a capillary electrophoresis(CE)technique combined with an ultraviolet(UV)detector(CE-UV)for detecting three reactive dyes and their six derivatives(a total of nine analytes).The optimized CE conditions are 20.0 mmol/L sodium tetraborate(Na_(2)B_(4)O_(7)·10H_(2)O),acetonitrile(ACN)with a volume fraction of 15.0%,20.0 mmol/L α-cyclodextrin(α-CD),and at a pH value of 9.0(adjusted with 0.5 mol/L H_(3)BO_(3)).The limit of detection(LOD)(a signal-to-noise ratio of 3)for the nine analytes ranges from 1.38 to 5.06 mg/L.The relative standard deviations(RSDs)for peak areas and migration time are 2.19%-4.96%and 0.29%-2.75%,respectively.The method is capable of accurately identifying three reactive dyes and their six derivatives and monitoring alterations in composition and dyeing behavior during single and combination dyeing processes.展开更多
To achieve effective decolorization of reactive dyes,laccase immobilization was investigated.Laccase 0.2%(m/V)(Denilite IIS) was trapped in beads of alginate/gelatin blent with polyethylene glycol(PEG),and then the su...To achieve effective decolorization of reactive dyes,laccase immobilization was investigated.Laccase 0.2%(m/V)(Denilite IIS) was trapped in beads of alginate/gelatin blent with polyethylene glycol(PEG),and then the supporters were activated by cross-linking with glutaraldehyde.The results of repeated batch decolorization showed that gelatin and appropriate concentration of glutaraldehyde accelerated the decolorization of Reactive Red B-3BF(RRB);PEG had a positive effect on enzyme stability and led to an inc...展开更多
Four materials, sodium carboxymethylcellulose （Na-CMC）, sodium alginate （SA）, polyvinyl alcohol （PVA）, and chitosan （CTS）, were prepared as supports for entrapping fungus Aspergillusfumigatus. The adsorption o...Four materials, sodium carboxymethylcellulose （Na-CMC）, sodium alginate （SA）, polyvinyl alcohol （PVA）, and chitosan （CTS）, were prepared as supports for entrapping fungus Aspergillusfumigatus. The adsorption of synthetic dyes, Reactive Brilliant Blue KN- R, and Reactive Brilliant Red K-2BP, by these immobilized gel beads and plain gel beads was evaluated. The adsorption efficiencies of Reactive Brilliant Red K-2BP and Reactive Brilliant Blue KN-R by CTS immobilized beads were 89.1% and 93.5% in 12 h, respectively. The adsorption efficiency by Na-CMC immobilized beads was slightly lower than that of mycelial pellets. But the dye culture mediums were almost completely decolorized in 48 h using the above-mentioned two immobilized beads （exceeding 95%）. The adsorption efficiency by SA immobilized beads exceeded 92% in 48 h. PVA-SA immobilized beads showed the lowest adsorption efficiency, which was 79.8% for Reactive Brilliant Red K-2BP and 92.5% for Reactive Brilliant Blue KN-R in 48 h. Comparing the adsorption efficiency by plain gel beads, Na-CMC plain gel beads ranked next to CTS ones. SA and PVA-SA plain gel beads hardly had the ability of adsorbing dyes. Subsequently, the growth of mycelia in Na-CMC and SA immobilized beads were evaluated. The biomass increased continuously in 72 h. The adsorption capacity of Reactive Brilliant Red K-2BP and Reactive Brilliant Blue KN-R by Na-CMC immobilized beads was 78.0 and 86.7 mg/g, respectively. The SEM micrographs show that the surface structure of Na-CMC immobilized bead is loose and finely porous, which facilitates diffusion of the dyes.展开更多
The sludge, which was collected from a biological coke wastewater treatment plant, was used as a low-cost adsorbent in the removal of reactive dyes （Methylene Blue （MB） and Reactive Red 4 （RR4）） from aqueous sol...The sludge, which was collected from a biological coke wastewater treatment plant, was used as a low-cost adsorbent in the removal of reactive dyes （Methylene Blue （MB） and Reactive Red 4 （RR4）） from aqueous solution. The pH of dye solution played an important role on the dye uptake. With the solution pH increase, the MB uptake increased; whereas the RR4 uptake decreased. The maximum uptake of RR4 by protonated sludge was 73.7 mg/g at pH 1, and the maximum uptake of MB by sludge was 235.3 mg/g at pH 9. Three functional groups, including carboxyl, phosphonate, and amine group, were identified by potentiometric titration, fourier transform infrared （FT-IR） spectrometry, and X-ray photoelectron spectroscopy （XPS）. The anionic functional groups, phosphonate and carboxyl group, were identified as the binding sites for the cationic MB. Amine groups were identified to bind RR4. The main mechanism of the reactive dyestuffs adsorption is electrostatic interaction.展开更多
The development of pollution-free dyeing technology, including anhydrous dyeing and non-aqueous dyeing technologies, has always been an important way and research hot in energy conservation and emission reduction. Des...The development of pollution-free dyeing technology, including anhydrous dyeing and non-aqueous dyeing technologies, has always been an important way and research hot in energy conservation and emission reduction. Designing new structural dye molecules is the key to water-saving dyeing processes.Herein, three reactive dyes were designed and synthesized, which contained large planar multiconjugated systems and multi-reactive groups. The designed reactive dyes are expected to have high affinity and high fixations in non-aqueous or small bath dyeing processes. The reactive dyes were applied in the decamethylcyclopentasiloxane(DMCS) reverse micelle dyeing for cotton fabric. High exhaustion rate of 99.35%, 98.10% and 98.80%, and fixation rate of 95.15%, 96.34% and 94.40% for three dyes, R1,R2 and R3, could be respectively obtained. The dyes can be fully utilized and had excellent dyeing performance, fastness and levelling properties under the revere micelle dyeing. The cotton fabric is like an oil-water separator in the dyeing process, where the dye micelles rapidly absorb and permeate into the cotton fibers. DMCS circulates around the fabric to transfer mass and energy. After dyeing, the solvent can be separated quickly and reused. The new reactive dyes containing large planar and multi-conjugated systems have potential application in green and sustainable dyeing technology with less wastewater and higher utilization.展开更多
The photocatalytic degradation of reactive dyes with solar-irradiated TiO2 was investigated in these experiments which showed that: (1)the decolourization efficiency are determined by pH value, catalyst amount and lig...The photocatalytic degradation of reactive dyes with solar-irradiated TiO2 was investigated in these experiments which showed that: (1)the decolourization efficiency are determined by pH value, catalyst amount and light intensity; (2) the reactive dyes decolourized rapidly (cleavageld be biologically degradated more easily, the toxicity decreased considerably after photodegradation.The results demonstrated that the photocatalytic process would become an efficient and safe method for colour wastewater treatment and would be very useful for explaining the reaction mechanism and decolourising structure-reactivity relationship. of the azo linkage), but the intermediates needed more time to transform to further degradation products, and finally to produce CO2; (3) the main products were identified to be alkanes and alkyl amines which cou展开更多
In order to investigate the optimal foam dyeing process and the compatibility of trichromatic reactive dyes in foam dyeing,varying proportions of ternary mixtures of Remazol Red RGB,Remazol Yellow RGB and Remazol Navy...In order to investigate the optimal foam dyeing process and the compatibility of trichromatic reactive dyes in foam dyeing,varying proportions of ternary mixtures of Remazol Red RGB,Remazol Yellow RGB and Remazol Navy RGB have been used to dye bleached cotton fabric.The results showed that,the optimal dyeing condition in foam dyeing was alkaline agent 15 g/L,stabilizers 0.7g/L,blow ratio 8,and steaming time 1.5 min,respectively.Compared with conventional pad-dyeing,color strength and fixation rate of dyed fabric were higher than those of conventional paddyeing,the dyed fabric had the same washing and rubbing fastness as conventional pad-dyeing and the color shade of dyed fabric was different from that of conventional pad-dyeing.The color triangle,which consisted of 66 dyed fabric samples dyed with trichromatic reactive dyes in different proportions,could provide foundation for computer colorant formulation of the color matching system.展开更多
The photo-reactions between metabolic products of human sweat and dyestuffs on garments may produce many toxic substances which could directly contact skin and threaten human health. In order to investigate the impact...The photo-reactions between metabolic products of human sweat and dyestuffs on garments may produce many toxic substances which could directly contact skin and threaten human health. In order to investigate the impact of the perspiration on photo-fading of reactive dyes on cellulose, nine commercial reactive dyes belonging to three types of chromophores (azo, Cu-complex azo and anthraquinone) respectively were chosen and their perspiration-light stability on cotton fabric was studied following ATTS test standard. It is found that the impact of the artificial perspiration on dyes varies with different chromophores: anthraquinone reactive dyes always show the best photo-stability, whereas Cu-complex azo reactive dyes appear to be the most sensitive under exposure to light and perspiration. The pH value of perspiration also greatly influences the fading of dyes with different reactive groups: the fading rate of most chlorotriazinyl reactive dyes in acidic perspiration (pH=3.5) is higher than in alkaline perspiration (pH=8.0), while the reverse is true for most vinylsulphonyl dyes. Furthermore, the study of the contribution of individual component of the artificial perspiration discloses that L-Histidine monohydrochloride monohydrate, DL-Aspartic acid and lactic acid play the major roles on the photo-fading of those selected dyestuffs and inorganic salts including disodium hydrogen phosphate and sodium chloride usually decelerate photo-fading.展开更多
Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-se...Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.展开更多
Reactive dyes are the main dyes in printing and dyeing of cellulosic fibers.Reactive dyes fixation rate is a vital indicator to measure the degree of the covalent bond between cellulose and reactive dyes.However,the d...Reactive dyes are the main dyes in printing and dyeing of cellulosic fibers.Reactive dyes fixation rate is a vital indicator to measure the degree of the covalent bond between cellulose and reactive dyes.However,the determination of the fixation rate is tedious and time-consumptive.Based on the theory of reactive dyes dyeing and application of modern computer color matching technology,the relationship between K/S value and the fixation rate with the reactive dyes on cotton fabric was studied.The feasibility of K/S value instead of the traditional washing method for the determination of reactive dyes fixation rate was proved.In this study,the K/S value of the fabric has an excellent linear relationship to the reactive dyes fixation rate obtained by the washing method.The reactive dyes fixation rate can be obtained through the K/S correction value.展开更多
Nine kinds of reactive dye solutions: Reactive K -2RL, H-E2R, X-6B1Y, HE-4G, X-3B, K-2R, H - E7B, X -4RN and S - F3B were treated by using Fenton reagent. While the concentration of dye is 400 mg/L, the FeSO4 dosage 1...Nine kinds of reactive dye solutions: Reactive K -2RL, H-E2R, X-6B1Y, HE-4G, X-3B, K-2R, H - E7B, X -4RN and S - F3B were treated by using Fenton reagent. While the concentration of dye is 400 mg/L, the FeSO4 dosage 100 -180 mg/L, H2O2 240 -540 mg/L, that is the stoichiometric numbers of Fe2+ and H2O2 are between 1: 9 - 1:12, pH = 3, reaction tune In, temperature 25℃, the colority removal efficiency reach more than 95%, the COD removal efficiency 65% -85%, and the TOC removal efficiency 70.2%. By comparing UV-VIS absorption spectrum before and after treatment, it further shows that decomposition effect of Fenton reagent on these nine kinds of reactive dyes is satisfactory.展开更多
The effect of alkali concentrations has been studied on the color strength （K/S） and color fastness properties of single jersey cotton knitted fabrics dyed with 1% Novacron Red S-B reactive dye. Same bath scouring a...The effect of alkali concentrations has been studied on the color strength （K/S） and color fastness properties of single jersey cotton knitted fabrics dyed with 1% Novacron Red S-B reactive dye. Same bath scouring and bleaching are performed and conventional exhaust dyeing method employed by IR laboratory sample dyeing machine. Various alkali concentrations such as 6, 7, 8, 9 and 10 g/L are employed and other parameters are kept fixed. The color strength （K/S） and color fastness to wash and rubbing are examined and evaluated. It is revealed that with the increase in alkali concentration from 6 g/L to 8 g/L the value of K/S increases and then up to 10 g/L the value decreases. The overall color fastness properties to washing and rubbing for the dyed samples range from good to excellent.展开更多
Aiming to solve the problem of large discharge and severe pollution of reactive dyeing wastewater for wool fabrics,peroxodisulfate(SPS)was used for the degradation and recycling of dyeing wastewater containing reactiv...Aiming to solve the problem of large discharge and severe pollution of reactive dyeing wastewater for wool fabrics,peroxodisulfate(SPS)was used for the degradation and recycling of dyeing wastewater containing reactive dye Lanasol Red CE.The process of degrading the reactive dye was determined by using the dye residual rate as the evaluation index.The feasibility of reactive dyeing of wool fabrics using recycled dyeing wastewater was confirmed by measuring the dye uptake,exhaustion and fixation rates,as well as color parameters and fastness of the dyed fabrics.The results showed that the appropriate conditions for degrading Lanasol Red CE were 0.2 g/L SPS,an initial pH value of 3 and 100℃for 30 min.Under these conditions,the dye degradation rate was as high as 93.14%.When the recycled dyeing wastewater was used for dyeing of wool fabrics,the exhaustion rate of Lanasol Red CE exceeded 99%,and the fixation rate was higher than that achieved by the conventional dyeing process.Under the same dyeing conditions,the recycled-dyed fabrics appeared darker.When the number of cycles was fewer than five,the effect on color fastness was not obvious.Although the color fastness to rubbing and washing of the fabrics dyed in the 10th cycle decreased by half a grade and 1 grade,respectively,compared to that of the fabrics dyed with the conventional dyeing process,they still met the production requirements.展开更多
Dyeing wastewater poses a serious threat to environmental protection and industrial development.The piezoelectric effect can be used to optimize the band structure of semiconductors and improve the photon efficiency o...Dyeing wastewater poses a serious threat to environmental protection and industrial development.The piezoelectric effect can be used to optimize the band structure of semiconductors and improve the photon efficiency of photocatalysts.Bi_(2)Fe_(4)O_(9),a narrow gap semiconductor with piezoelectric effect,was prepared by a hydrothermal synthesis method for the degradation of reactive dye KN-R.The results show that the degradation efficiency of KN-R can be significantly improved by piezo-photocatalysis,and the degradation rate constant of piezo-photocatalysis k_(pi-ph)is about 3.4 times as large as the degradation rate constant of piezoelectric catalysis k_(pi)and about 2.6 times as large as the degradation rate constant of photocatalysis k_(ph).At a pH value of 3 and a lower KN-R mass concentration(60 mg/L),a higher degradation efficiency(98.5%)is achieved.CO_(3)^(2-)and cationic surfactant(CTAB)inhibit the degradation of KN-R.It is proved that the contributions of different active species to the degradation of KN-R follow the order:·OH,·O_(2)^(-),h^(+),and^(1)O_(2).The possible mechanism of piezo-photocatalytic degradation of KN-R was discussed.The photoexcitation generates a large amount of free charges,and the piezoelectric effect modulates the energy band structure of Bi_(2)Fe_(4)O_(9)and promotes the separation of photogenerated electron-hole pairs.The synergistic effect of the two factors significantly improves the degradation efficiency of KN-R.展开更多
The kinetics of hydrolysis of cationic reactive disperse dyes containing quaternary group and chemical shift（13CNMR） of the adjacent carbon atoms with pyridine-acetylamino were discussed. The results show pyridine-a...The kinetics of hydrolysis of cationic reactive disperse dyes containing quaternary group and chemical shift（13CNMR） of the adjacent carbon atoms with pyridine-acetylamino were discussed. The results show pyridine-acetylamino reactive group had higher reactivity than chloroacetylamino and chemical shift（13 CNMR） of the adjacent carbon atoms with pyridine-acetylamino moved 18.77 ppm.展开更多
Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride ...Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses.展开更多
Reactive dyes are the main species for cotton dyeing due to their wide range of hue, satisfactory color fastness and facile application method. Aiming at increasing fixation on cotton fibers, benzimidazolone yellow re...Reactive dyes are the main species for cotton dyeing due to their wide range of hue, satisfactory color fastness and facile application method. Aiming at increasing fixation on cotton fibers, benzimidazolone yellow reactive dyes, sulfonamide red reactive dyes and anthraquinone azo blue reactive dyes are designed. The preparation, characterization and application properties of these dyes with high fixation are introduced in detail. In order to achieve dye fixation to near 100%, macromolecular crosslinking reactive dyes are designed, their dyeing and fixing mechanism are discussed. These novel reactive dyes show promising application prospect in dyeing and printing of cotton fibers.展开更多
A new instant-fixation dyeing process was presented and applied for the dyeing of cotton fabric with bi-functional reactive dyes, in which electrolyte and alkali were added in the dye bath first, and then the pre-prep...A new instant-fixation dyeing process was presented and applied for the dyeing of cotton fabric with bi-functional reactive dyes, in which electrolyte and alkali were added in the dye bath first, and then the pre-prepared dye solution was dropped continuously. The color depth of dyed fabric with this process was much higher than that with conventional process and the dosage of the dyes could be reduced as much as 35% when the dark shades are dyed. Moreover, the dye fixation could be increased by 10% with the similar color depth. This novel dyeing method can be applied to both woven and knitted cotton fabric.展开更多
To understand the reaction behaviour of the reactive dye with amino groups on protein fibres,the reaction kinetics of competitive hydrolysis and ammonolysis of a monochlorotriazina reactive dye were studied at 50-80℃...To understand the reaction behaviour of the reactive dye with amino groups on protein fibres,the reaction kinetics of competitive hydrolysis and ammonolysis of a monochlorotriazina reactive dye were studied at 50-80℃ and pH=8-10 by high performance liquid chromatography(HPLC).The results showed the pseudo-first-order phenomenon for the general reaction of concurrent hydrolysis and ammonolysis of the dyes.The ammonolysis reaction was always faster than the hydrolysis reaction in the range of temperature and pH employed,but the preference for ammonolysis to hydrolysis reaction decreased with the increase of temperature and pH value.The ratios of ammonolysis/hydrolysis rate constant reduced from 17.6 to 5.4 when the temperature increased from 50 to 80℃ in pH=10,and from 7.2 to 5.4 when the pH value increased from 8 to 10 at 80℃.展开更多
A coagulation/flocculation process using the composite flocculant polyaluminum chloride-epichlorohydrin dimethylamine （PAC- EPI-DMA） was employed for the treatment of an anionic azo dye （Reactive Brilliant Red K-2B...A coagulation/flocculation process using the composite flocculant polyaluminum chloride-epichlorohydrin dimethylamine （PAC- EPI-DMA） was employed for the treatment of an anionic azo dye （Reactive Brilliant Red K-2BP dye）. The effect of viscosity 01）, basicity （B = [OH]/[Al]） and organic content （Wp） on the flocculation performance as well as the mechanism of PAC-EPI-DMA flocculant were investigated. The η was the key factor affecting the dye removal efficiency of PAC-EPI-DMA. PAC-EPI-DMA with an intermediate η （2400 mPa.sec） gave higher decolorization efficiency by adsorption bridging and charge neutralization due to the co-effect of PAC and EPI-DMA polymers. The Wp of the composite flocculant was a minor important factor for the flocculation. The adsorption bridging of PAC-EPI-DMA with η of 300 or 4300 mPa.sec played an important role with the increase of Wp, whereas the charge neutralization of them was weaker with the increase of Wp. There was interaction between Wp and B on the removal of reactive dye. The composite flocculant with intermediate viscosity and organic content was effective for the treatment of reactive dyeing wastewater, which could achieve high reactive dye removal efficiency with low organic dosage.展开更多
基金Research Foundation from National Innovation Center of Advanced Dyeing&Finishing Technology,China(No.2022GCJJ15)。
文摘Reactive dyes with different reactive groups exhibit different hydrolysis and dyeing behaviors.This is particularly evident in the combination dyeing process,where the competion between hydrolysis and dyeing reactions increases the complexity.Therefore,developing an effective method to monitor the changes in reactive dyes during the dyeing process is important.This study aims to develop a capillary electrophoresis(CE)technique combined with an ultraviolet(UV)detector(CE-UV)for detecting three reactive dyes and their six derivatives(a total of nine analytes).The optimized CE conditions are 20.0 mmol/L sodium tetraborate(Na_(2)B_(4)O_(7)·10H_(2)O),acetonitrile(ACN)with a volume fraction of 15.0%,20.0 mmol/L α-cyclodextrin(α-CD),and at a pH value of 9.0(adjusted with 0.5 mol/L H_(3)BO_(3)).The limit of detection(LOD)(a signal-to-noise ratio of 3)for the nine analytes ranges from 1.38 to 5.06 mg/L.The relative standard deviations(RSDs)for peak areas and migration time are 2.19%-4.96%and 0.29%-2.75%,respectively.The method is capable of accurately identifying three reactive dyes and their six derivatives and monitoring alterations in composition and dyeing behavior during single and combination dyeing processes.
基金supported by the National Hi-Tech Research and Development Program(863)of China(No.2007AA02Z218)the Open Project Program of Key Lab-oratory of Eco-Textiles,Jiangnan University,Ministry of Education,China(No.KLET0625) the Youth Fundof Jiangnan University(No.2006LQN002).
文摘To achieve effective decolorization of reactive dyes,laccase immobilization was investigated.Laccase 0.2%(m/V)(Denilite IIS) was trapped in beads of alginate/gelatin blent with polyethylene glycol(PEG),and then the supporters were activated by cross-linking with glutaraldehyde.The results of repeated batch decolorization showed that gelatin and appropriate concentration of glutaraldehyde accelerated the decolorization of Reactive Red B-3BF(RRB);PEG had a positive effect on enzyme stability and led to an inc...
基金Project supported by the Science and Technology Foundation of Guangzhou Municipal Environment Protection Bureau (No. 006).
文摘Four materials, sodium carboxymethylcellulose （Na-CMC）, sodium alginate （SA）, polyvinyl alcohol （PVA）, and chitosan （CTS）, were prepared as supports for entrapping fungus Aspergillusfumigatus. The adsorption of synthetic dyes, Reactive Brilliant Blue KN- R, and Reactive Brilliant Red K-2BP, by these immobilized gel beads and plain gel beads was evaluated. The adsorption efficiencies of Reactive Brilliant Red K-2BP and Reactive Brilliant Blue KN-R by CTS immobilized beads were 89.1% and 93.5% in 12 h, respectively. The adsorption efficiency by Na-CMC immobilized beads was slightly lower than that of mycelial pellets. But the dye culture mediums were almost completely decolorized in 48 h using the above-mentioned two immobilized beads （exceeding 95%）. The adsorption efficiency by SA immobilized beads exceeded 92% in 48 h. PVA-SA immobilized beads showed the lowest adsorption efficiency, which was 79.8% for Reactive Brilliant Red K-2BP and 92.5% for Reactive Brilliant Blue KN-R in 48 h. Comparing the adsorption efficiency by plain gel beads, Na-CMC plain gel beads ranked next to CTS ones. SA and PVA-SA plain gel beads hardly had the ability of adsorbing dyes. Subsequently, the growth of mycelia in Na-CMC and SA immobilized beads were evaluated. The biomass increased continuously in 72 h. The adsorption capacity of Reactive Brilliant Red K-2BP and Reactive Brilliant Blue KN-R by Na-CMC immobilized beads was 78.0 and 86.7 mg/g, respectively. The SEM micrographs show that the surface structure of Na-CMC immobilized bead is loose and finely porous, which facilitates diffusion of the dyes.
基金supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,the Ministry of Education of China
文摘The sludge, which was collected from a biological coke wastewater treatment plant, was used as a low-cost adsorbent in the removal of reactive dyes （Methylene Blue （MB） and Reactive Red 4 （RR4）） from aqueous solution. The pH of dye solution played an important role on the dye uptake. With the solution pH increase, the MB uptake increased; whereas the RR4 uptake decreased. The maximum uptake of RR4 by protonated sludge was 73.7 mg/g at pH 1, and the maximum uptake of MB by sludge was 235.3 mg/g at pH 9. Three functional groups, including carboxyl, phosphonate, and amine group, were identified by potentiometric titration, fourier transform infrared （FT-IR） spectrometry, and X-ray photoelectron spectroscopy （XPS）. The anionic functional groups, phosphonate and carboxyl group, were identified as the binding sites for the cationic MB. Amine groups were identified to bind RR4. The main mechanism of the reactive dyestuffs adsorption is electrostatic interaction.
基金supported by Natural Science Foundation of Shanghai (20ZR1400300)Textile Vision Applied Basic Research Project (J202005)National Key Research & Development Program of China (2017YFB0309600)。
文摘The development of pollution-free dyeing technology, including anhydrous dyeing and non-aqueous dyeing technologies, has always been an important way and research hot in energy conservation and emission reduction. Designing new structural dye molecules is the key to water-saving dyeing processes.Herein, three reactive dyes were designed and synthesized, which contained large planar multiconjugated systems and multi-reactive groups. The designed reactive dyes are expected to have high affinity and high fixations in non-aqueous or small bath dyeing processes. The reactive dyes were applied in the decamethylcyclopentasiloxane(DMCS) reverse micelle dyeing for cotton fabric. High exhaustion rate of 99.35%, 98.10% and 98.80%, and fixation rate of 95.15%, 96.34% and 94.40% for three dyes, R1,R2 and R3, could be respectively obtained. The dyes can be fully utilized and had excellent dyeing performance, fastness and levelling properties under the revere micelle dyeing. The cotton fabric is like an oil-water separator in the dyeing process, where the dye micelles rapidly absorb and permeate into the cotton fibers. DMCS circulates around the fabric to transfer mass and energy. After dyeing, the solvent can be separated quickly and reused. The new reactive dyes containing large planar and multi-conjugated systems have potential application in green and sustainable dyeing technology with less wastewater and higher utilization.
文摘The photocatalytic degradation of reactive dyes with solar-irradiated TiO2 was investigated in these experiments which showed that: (1)the decolourization efficiency are determined by pH value, catalyst amount and light intensity; (2) the reactive dyes decolourized rapidly (cleavageld be biologically degradated more easily, the toxicity decreased considerably after photodegradation.The results demonstrated that the photocatalytic process would become an efficient and safe method for colour wastewater treatment and would be very useful for explaining the reaction mechanism and decolourising structure-reactivity relationship. of the azo linkage), but the intermediates needed more time to transform to further degradation products, and finally to produce CO2; (3) the main products were identified to be alkanes and alkyl amines which cou
文摘In order to investigate the optimal foam dyeing process and the compatibility of trichromatic reactive dyes in foam dyeing,varying proportions of ternary mixtures of Remazol Red RGB,Remazol Yellow RGB and Remazol Navy RGB have been used to dye bleached cotton fabric.The results showed that,the optimal dyeing condition in foam dyeing was alkaline agent 15 g/L,stabilizers 0.7g/L,blow ratio 8,and steaming time 1.5 min,respectively.Compared with conventional pad-dyeing,color strength and fixation rate of dyed fabric were higher than those of conventional paddyeing,the dyed fabric had the same washing and rubbing fastness as conventional pad-dyeing and the color shade of dyed fabric was different from that of conventional pad-dyeing.The color triangle,which consisted of 66 dyed fabric samples dyed with trichromatic reactive dyes in different proportions,could provide foundation for computer colorant formulation of the color matching system.
基金Supported by Foundation of University Doctoral Programby the State Ministry of Education (No.20050255002)
文摘The photo-reactions between metabolic products of human sweat and dyestuffs on garments may produce many toxic substances which could directly contact skin and threaten human health. In order to investigate the impact of the perspiration on photo-fading of reactive dyes on cellulose, nine commercial reactive dyes belonging to three types of chromophores (azo, Cu-complex azo and anthraquinone) respectively were chosen and their perspiration-light stability on cotton fabric was studied following ATTS test standard. It is found that the impact of the artificial perspiration on dyes varies with different chromophores: anthraquinone reactive dyes always show the best photo-stability, whereas Cu-complex azo reactive dyes appear to be the most sensitive under exposure to light and perspiration. The pH value of perspiration also greatly influences the fading of dyes with different reactive groups: the fading rate of most chlorotriazinyl reactive dyes in acidic perspiration (pH=3.5) is higher than in alkaline perspiration (pH=8.0), while the reverse is true for most vinylsulphonyl dyes. Furthermore, the study of the contribution of individual component of the artificial perspiration discloses that L-Histidine monohydrochloride monohydrate, DL-Aspartic acid and lactic acid play the major roles on the photo-fading of those selected dyestuffs and inorganic salts including disodium hydrogen phosphate and sodium chloride usually decelerate photo-fading.
基金Supported by the National Science Foundation for Distinguished Young Scholar of China（20525620） the National Natural Science Foundation of China（20806013） the Program for Changjiang Scholar and Innovative Research Team in University（IRT 0711）
文摘Tertiary amine cationic polyacrylamide with high cationization degree was used as a new cationic agent to pretreat cotton with dip-pad-bake method. The obtained cationic cotton was dyed with reactive dyes in the ab-sence of electrolyte. The effects of the characteristics of the cationic agent and the pretreatment conditions on dye-ability of reactive dye were investigated. The results showed that the fixation and K/S values of the reactive dyes on the cationic cotton were improved compared with those on the untreated one in the presence of salt. Tests on fast-ness properties of the dyed cotton and fabric quality of the pretreated cotton were carried out and the results showed that wash and rub fastness of the salt-free dyeing were both satisfactory. And anti-crease property,tensile and tear strength,and handling of the cationic cotton were also good compared with that of the untreated one.
文摘Reactive dyes are the main dyes in printing and dyeing of cellulosic fibers.Reactive dyes fixation rate is a vital indicator to measure the degree of the covalent bond between cellulose and reactive dyes.However,the determination of the fixation rate is tedious and time-consumptive.Based on the theory of reactive dyes dyeing and application of modern computer color matching technology,the relationship between K/S value and the fixation rate with the reactive dyes on cotton fabric was studied.The feasibility of K/S value instead of the traditional washing method for the determination of reactive dyes fixation rate was proved.In this study,the K/S value of the fabric has an excellent linear relationship to the reactive dyes fixation rate obtained by the washing method.The reactive dyes fixation rate can be obtained through the K/S correction value.
文摘Nine kinds of reactive dye solutions: Reactive K -2RL, H-E2R, X-6B1Y, HE-4G, X-3B, K-2R, H - E7B, X -4RN and S - F3B were treated by using Fenton reagent. While the concentration of dye is 400 mg/L, the FeSO4 dosage 100 -180 mg/L, H2O2 240 -540 mg/L, that is the stoichiometric numbers of Fe2+ and H2O2 are between 1: 9 - 1:12, pH = 3, reaction tune In, temperature 25℃, the colority removal efficiency reach more than 95%, the COD removal efficiency 65% -85%, and the TOC removal efficiency 70.2%. By comparing UV-VIS absorption spectrum before and after treatment, it further shows that decomposition effect of Fenton reagent on these nine kinds of reactive dyes is satisfactory.
文摘The effect of alkali concentrations has been studied on the color strength （K/S） and color fastness properties of single jersey cotton knitted fabrics dyed with 1% Novacron Red S-B reactive dye. Same bath scouring and bleaching are performed and conventional exhaust dyeing method employed by IR laboratory sample dyeing machine. Various alkali concentrations such as 6, 7, 8, 9 and 10 g/L are employed and other parameters are kept fixed. The color strength （K/S） and color fastness to wash and rubbing are examined and evaluated. It is revealed that with the increase in alkali concentration from 6 g/L to 8 g/L the value of K/S increases and then up to 10 g/L the value decreases. The overall color fastness properties to washing and rubbing for the dyed samples range from good to excellent.
基金Youth Foundation of Hebei Province Department of Education Fund,China(No.QN2023090)Opening Project of Textile Ecological Dyeing and Finishing Key Laboratory of Sichuan Province(Chengdu Textile College),China(No.2024DF-AO2)Innovation and Entrepreneurship Training Program for College Students,China(No.202410082023)。
文摘Aiming to solve the problem of large discharge and severe pollution of reactive dyeing wastewater for wool fabrics,peroxodisulfate(SPS)was used for the degradation and recycling of dyeing wastewater containing reactive dye Lanasol Red CE.The process of degrading the reactive dye was determined by using the dye residual rate as the evaluation index.The feasibility of reactive dyeing of wool fabrics using recycled dyeing wastewater was confirmed by measuring the dye uptake,exhaustion and fixation rates,as well as color parameters and fastness of the dyed fabrics.The results showed that the appropriate conditions for degrading Lanasol Red CE were 0.2 g/L SPS,an initial pH value of 3 and 100℃for 30 min.Under these conditions,the dye degradation rate was as high as 93.14%.When the recycled dyeing wastewater was used for dyeing of wool fabrics,the exhaustion rate of Lanasol Red CE exceeded 99%,and the fixation rate was higher than that achieved by the conventional dyeing process.Under the same dyeing conditions,the recycled-dyed fabrics appeared darker.When the number of cycles was fewer than five,the effect on color fastness was not obvious.Although the color fastness to rubbing and washing of the fabrics dyed in the 10th cycle decreased by half a grade and 1 grade,respectively,compared to that of the fabrics dyed with the conventional dyeing process,they still met the production requirements.
文摘Dyeing wastewater poses a serious threat to environmental protection and industrial development.The piezoelectric effect can be used to optimize the band structure of semiconductors and improve the photon efficiency of photocatalysts.Bi_(2)Fe_(4)O_(9),a narrow gap semiconductor with piezoelectric effect,was prepared by a hydrothermal synthesis method for the degradation of reactive dye KN-R.The results show that the degradation efficiency of KN-R can be significantly improved by piezo-photocatalysis,and the degradation rate constant of piezo-photocatalysis k_(pi-ph)is about 3.4 times as large as the degradation rate constant of piezoelectric catalysis k_(pi)and about 2.6 times as large as the degradation rate constant of photocatalysis k_(ph).At a pH value of 3 and a lower KN-R mass concentration(60 mg/L),a higher degradation efficiency(98.5%)is achieved.CO_(3)^(2-)and cationic surfactant(CTAB)inhibit the degradation of KN-R.It is proved that the contributions of different active species to the degradation of KN-R follow the order:·OH,·O_(2)^(-),h^(+),and^(1)O_(2).The possible mechanism of piezo-photocatalytic degradation of KN-R was discussed.The photoexcitation generates a large amount of free charges,and the piezoelectric effect modulates the energy band structure of Bi_(2)Fe_(4)O_(9)and promotes the separation of photogenerated electron-hole pairs.The synergistic effect of the two factors significantly improves the degradation efficiency of KN-R.
文摘The kinetics of hydrolysis of cationic reactive disperse dyes containing quaternary group and chemical shift（13CNMR） of the adjacent carbon atoms with pyridine-acetylamino were discussed. The results show pyridine-acetylamino reactive group had higher reactivity than chloroacetylamino and chemical shift（13 CNMR） of the adjacent carbon atoms with pyridine-acetylamino moved 18.77 ppm.
基金Supported by the National Natural Science Foundation of China(2137604221421005)+2 种基金the National Key Technology R&D Program(2013BAF08B06)Innovative Research Team of Ministry of Education of the People's Republic of China(IRT-13R06)Dalian University of Technology(DUT2013TB07)
文摘Novel cationic cotton fabrics were prepared by an efficient and simple one-step pad–dry–bake pretreatment process with betaine as cationic reagent. Ester bonds formed between cotton fibers and betaine hydrochloride were proved by Fourier transformed infrared attenuated total reflection(FTIR-ATR) spectra. Moreover, the properties of the cationic fabrics, including X-ray Diffraction(XRD), tensile strength and whiteness and yellowness index,were investigated in comparison with that of the untreated ones. The cationic fabrics were applied in salt-free dyeing of C.I. Reactive Red 195, C.I. Reactive Yellow 145 and C.I. Reactive Blue 19. Different dye fixation processes were applied and compared for untreated and cationic cotton. Dye fixation and color fastness properties of the dyes were tested, and the results presented that dye fixation on the cationic fabrics in the absence of salt was improved with satisfactory light fastness property and applicable wash and rub fastnesses.
基金supported by the National Key Research & Development Plan (2017YFB0307401)the Liaoning Revitalization Talent Program (CLXC1801006)the Fundamental Research Funds for the Central Universities (DUT19TD28)。
文摘Reactive dyes are the main species for cotton dyeing due to their wide range of hue, satisfactory color fastness and facile application method. Aiming at increasing fixation on cotton fibers, benzimidazolone yellow reactive dyes, sulfonamide red reactive dyes and anthraquinone azo blue reactive dyes are designed. The preparation, characterization and application properties of these dyes with high fixation are introduced in detail. In order to achieve dye fixation to near 100%, macromolecular crosslinking reactive dyes are designed, their dyeing and fixing mechanism are discussed. These novel reactive dyes show promising application prospect in dyeing and printing of cotton fibers.
文摘A new instant-fixation dyeing process was presented and applied for the dyeing of cotton fabric with bi-functional reactive dyes, in which electrolyte and alkali were added in the dye bath first, and then the pre-prepared dye solution was dropped continuously. The color depth of dyed fabric with this process was much higher than that with conventional process and the dosage of the dyes could be reduced as much as 35% when the dark shades are dyed. Moreover, the dye fixation could be increased by 10% with the similar color depth. This novel dyeing method can be applied to both woven and knitted cotton fabric.
文摘To understand the reaction behaviour of the reactive dye with amino groups on protein fibres,the reaction kinetics of competitive hydrolysis and ammonolysis of a monochlorotriazina reactive dye were studied at 50-80℃ and pH=8-10 by high performance liquid chromatography(HPLC).The results showed the pseudo-first-order phenomenon for the general reaction of concurrent hydrolysis and ammonolysis of the dyes.The ammonolysis reaction was always faster than the hydrolysis reaction in the range of temperature and pH employed,but the preference for ammonolysis to hydrolysis reaction decreased with the increase of temperature and pH value.The ratios of ammonolysis/hydrolysis rate constant reduced from 17.6 to 5.4 when the temperature increased from 50 to 80℃ in pH=10,and from 7.2 to 5.4 when the pH value increased from 8 to 10 at 80℃.
基金supported by the National Natural Science Foundation of China (No. 50578089,21077066)the Key Projects in the National Science & Technology Pillar Program in the Eleventh Five-year Plan Period (No. 2006BAJ08B05-2)+2 种基金the Scientific Technology Research and Development Program of Shandong of China (No. 2009GG10006003 2010GZX20605)the Natural Science Foundation of Shandong Province of China (No. ZR2010BM014)
文摘A coagulation/flocculation process using the composite flocculant polyaluminum chloride-epichlorohydrin dimethylamine （PAC- EPI-DMA） was employed for the treatment of an anionic azo dye （Reactive Brilliant Red K-2BP dye）. The effect of viscosity 01）, basicity （B = [OH]/[Al]） and organic content （Wp） on the flocculation performance as well as the mechanism of PAC-EPI-DMA flocculant were investigated. The η was the key factor affecting the dye removal efficiency of PAC-EPI-DMA. PAC-EPI-DMA with an intermediate η （2400 mPa.sec） gave higher decolorization efficiency by adsorption bridging and charge neutralization due to the co-effect of PAC and EPI-DMA polymers. The Wp of the composite flocculant was a minor important factor for the flocculation. The adsorption bridging of PAC-EPI-DMA with η of 300 or 4300 mPa.sec played an important role with the increase of Wp, whereas the charge neutralization of them was weaker with the increase of Wp. There was interaction between Wp and B on the removal of reactive dye. The composite flocculant with intermediate viscosity and organic content was effective for the treatment of reactive dyeing wastewater, which could achieve high reactive dye removal efficiency with low organic dosage.
