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Getters Reactants. I. Thermo-Sedimentational Activation
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作者 Konstantin Chuntonov 《Journal of Materials Science and Chemical Engineering》 2024年第10期1-12,共12页
A new method for chemical pumping of gases has been developed using reactive alloys of Li with IIA metals in the liquid state. It is an answer to the need for ultra-high and extremely high vacuum without loose solid p... A new method for chemical pumping of gases has been developed using reactive alloys of Li with IIA metals in the liquid state. It is an answer to the need for ultra-high and extremely high vacuum without loose solid particles. Another application of this development is the production of high- and ultra-pure noble gases in a one-step process. Both of these solutions are unprecedented;they are based on a new gas/melt sorption interface that raises the overall bar of technical advances in the field to a higher level, simplifying sorption equipment and leading to cost savings. 展开更多
关键词 Interface Gas/Melt Vacuum Pump Gas Sorption Getters reactants SEDIMENTATION Noble Gases
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Retinol-binding protein, acute phase reactants and Helicobacter pylori infection in patients with gastric adenocarcinoma 被引量:7
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作者 Nicolas Tsavaris Christos Kosmas +8 位作者 Petros Kopterides Dimitrios Tsikalakis Hlias Skopelitis Fotini Sakelaridi Nikitas Papadoniou Michalis Tzivras Vasilios Balatsos Christos Koufos Athanasios Archimandritis 《World Journal of Gastroenterology》 SCIE CAS CSCD 2005年第45期7174-7178,共5页
AIM: To determine the serum levels of c-reactive protein (CRP), transferrin (TRF), a2-macroglobulin (A2M), ceruloplasmin (CER), al-acid glycoprotein (AAG), prealbumin (P-ALB) and retinol-binding protein ... AIM: To determine the serum levels of c-reactive protein (CRP), transferrin (TRF), a2-macroglobulin (A2M), ceruloplasmin (CER), al-acid glycoprotein (AAG), prealbumin (P-ALB) and retinol-binding protein (RBP) in gastric carcinoma patients and to explore their possible correlation with underlying Helicobacter pylori (H pylon) infection. METHODS: We measured the serum levels of CRP, TRF, A2M, CER, AAG, P-ALB, and RBP in 153 preoperative patients (93 males; mean age: 63.1±11.3 years) with non-cardia gastric adenocarcinoma and 19 healthy subjects. RESULTS: The levels of CRP, CER, RBP, and AAG in cancer patients were significantly higher than those in healthy controls (P〈0.0001), while no difference was found regarding the TRF, P-ALB, and A2M levels. Cancer patients with H py/ori infection had significantly lower RBP values compared to non-infected ones (P〈0.0001) and also higher values of CRP and AAG (P = 0.09 andP = 0.08, respectively). CONCLUSION: High serum levels of CRP, CER and AAG in cancer patients do not seem to be related to H pylori infection. Retinol-binding protein seems to discriminate between infected and non-infected patients with gastric carcinoma. Further studies are needed to explore if it is directly involved in the pathogenesis of the disease or is merely an epiphenomenon. 展开更多
关键词 Gastric cancer Helicobacter pylori Acutephase reactants Al-acid glycoprotein TRANSFERRIN A2-macroglobulin CERULOPLASMIN Retinol-binding protein Pre-albumin c-reactive protein
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Unveiling the importance of reactant mass transfer in environmental catalysis:Taking catalytic chlorobenzene oxidation as an example 被引量:5
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作者 Kexin Cao Xiaoxia Dai +1 位作者 Zhongbiao Wu Xiaole Weng 《Chinese Chemical Letters》 SCIE CAS CSCD 2021年第3期1206-1209,共4页
To date,investigations onto the regulation of reactants mass transfer has been paid much less attention in environmental catalysis.Herein,we demonstrated that by rationally designing the adsorption sites of multi-reac... To date,investigations onto the regulation of reactants mass transfer has been paid much less attention in environmental catalysis.Herein,we demonstrated that by rationally designing the adsorption sites of multi-reactants,the pollutant destruction efficiency,product selectivity,reaction stability and secondary pollution have been all affected in the catalytic chlorobenzene oxidation(CBCO).Experimental results revealed that the co-adsorption of chlo robenzene(CB)and gaseous O_(2)at the oxygen vacancies of CeO_(2)led to remarkably high CO_(2)generation,owning to their short mass transfer distance on the catalyst surface,while their separated adsorptions at Bronsted HZSM-5 and CeO_(2)vacancies resulted in a much lower CO_(2)generation,and produced significant polychlorinated byproducts in the off-gas.Howeve r,this separated adsorption model yielded superior long-term stability for the CeO_(2)/HZSM-5 catalyst,owning to the protection of CeO_(2)oxygen vacancies from Cl poisoning by the preferential adsorption of CB on the Bronsted acidic sites.This work unveils that design of environmental catalysts needs to consider both of the catalyst intrinsic property and reactant mass transfer;investigations of the latter could pave a new way for the development of highly efficient catalysts towards environmental pollution control. 展开更多
关键词 VOCs oxidation Chlorinated organics reactant mass transfer Secondary pollution Catalyst design Environmental catalysis
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EFFECT OF BACKGROUND REACTANT GRADIENT ON TRACER DISPERSION:A CASE STUDY OF IMPULSE INJECTION OF REACTANT INTO AN OPEN REACTOR
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作者 毛在砂 陈家镛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1995年第3期24-33,共10页
The paradox is well known that the residence time distribution(RTD)is not valid forthe estimation of the conversion of a first order reaction in an open tubular reactor.A casc ofδ injection of reactive species into a... The paradox is well known that the residence time distribution(RTD)is not valid forthe estimation of the conversion of a first order reaction in an open tubular reactor.A casc ofδ injection of reactive species into an open flow system is investigated theoretically in this paper.The analytical solution with the Laplace transform demonstrated that the conversion of a first orderreaction is identical to that in a closed reactor under steady state.The effect of the backgroundreactant concentration gradient addressed by the authors in a previous paper was employed to thiscase.and the numerical solution of the tracer dispersion based on this novel argument gave rise to asimilar value of conversion.suggesting the validity of the concept and the significance of the subtledifference between RTDs determined with or without the presence of a background reactant in anopen flow system. 展开更多
关键词 axial DISPERSION model OPEN REACTOR RESIDENCE time distribution EFFECT of BACKGROUND reactant
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RESIDENCE TIME DISTRIBUTION IN AN OPEN REACTOR:EFFECT OF BACKGROUND REACTANT ON TRACER DISPERSION
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作者 毛在砂 陈家镛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1993年第2期33-43,共11页
A new approach is presented for deriving the residence time distribution(RTD)in open-type reactors with exclusion of residence in the fore section.Inasmuch as failure to predict the con-version of chemical reactions h... A new approach is presented for deriving the residence time distribution(RTD)in open-type reactors with exclusion of residence in the fore section.Inasmuch as failure to predict the con-version of chemical reactions has been evidenced in many occasions,numerical solution of tracerdispersion in the presence of background concentration gradient of reactant is given to demonstratethe strong effect of background reactant on the true RTD a reactant molecule experiences.Withinthe error of computation,the conversion of a first-order chemical reaction under steady state is shownto be equal in both closed and open reactors,despite difference in relevant 展开更多
关键词 axial DISPERSION model OPEN REACTOR RESIDENCE time distribution EFFECT of BACKGROUND reactant
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Electro-oxidation of mixed reactants of ethanol and formate on Pd/C in alkaline fuel cells
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作者 Myounghoon Choun Jaeyoung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第4期683-690,共8页
Direct ethanol fuel cells have attracted attention as an alternative energy technology due to several advantages such as high theoretical energy density and abundant supply of ethanol.In spite of the advantages,commer... Direct ethanol fuel cells have attracted attention as an alternative energy technology due to several advantages such as high theoretical energy density and abundant supply of ethanol.In spite of the advantages,commercialization of direct ethanol fuel cells is hampered by the relatively low performance caused by its slow oxidation kinetics and difficulty of complete oxidation.In this study,formate,which has relatively faster oxidation kinetics,was mixed with ethanol to compensate the latter’s sluggish kinetics.Effects of p H,concentration,scan rate,and temperature on the mixed reactants oxidation on Pd were investigated by electrochemical experiments such as potential sweep and potentiostatic methods.Furthermore,the potential of the mixed reactants as fuel was evaluated by single cell experiments.As a result,we demonstrate that mixing formate with ethanol results in enhanced power performance in a single cell system. 展开更多
关键词 ETHANOL FORMATE Mixed reactants Alkaline media PALLADIUM Electro-oxidation
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KINETIC EQUATIONS WITH VARIATION OF LIQUID REACTANT CONCENTRATION
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作者 YIN Qunsheng ZHAO Tiancong ZHONG Tingke LIN Ruoya Central South University of Technology,Changsha,China YIN Qunsheng Lecturer Dept.of Metallurgy,Central South University of Technology Changsha 410083,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1990年第10期258-264,共7页
For two common types of liquid-solid heterogeneous reactions,the kinetic equations have been established which involved both the variation of liquid reactant concentration and the va- riation of solid reactant geornet... For two common types of liquid-solid heterogeneous reactions,the kinetic equations have been established which involved both the variation of liquid reactant concentration and the va- riation of solid reactant geornetry with the reaction time.The experimental results show that the kinetic equations are more accurate and reasonable than those appeared in previous litera- tures.Moreover,they are also suitable for gas-solid heterogeneous reactions in principle. 展开更多
关键词 kinetic equation heterogeneous reaction reactant concentration
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Differences in Acute Phase Reactants between Gout and Pseudogout
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作者 Clement E. Tagoe Yasmin Raza 《International Journal of Clinical Medicine》 2013年第12期13-19,共7页
Objectives: To define clinical differences in the acute phase response and serum acute phase reactants between gout, pseudogout and crystal-induced arthritis in the presence of non-articular infections (CAI). Patients... Objectives: To define clinical differences in the acute phase response and serum acute phase reactants between gout, pseudogout and crystal-induced arthritis in the presence of non-articular infections (CAI). Patients and Methods: Eleven patients with definite gout, 12 patients with pseudogout and 5 patients with CIA were included in the study. Results: The erythrocyte sedimentation rate (ESR) was significantly different between gout (68.2 ± 49.9 mm/Hr) and CIA (113.8 ± 37.2 mm/Hr) but not between gout and pseudogout (83.9 ± 45.6 mm/Hr) or between pseudogout and CIA. The C-reactive protein (CRP) was significantly increased between gout (10.1 ± 7.9 mg/dL) and pseudogout (18.9 ± 9.8 mg/dL), gout and CIA (36.5 ± 12.4 mg/dL) as well as between pseudogout and CIA. The peripheral white cell count was significantly different between gout (9.27 ± 3.7 k/μL) and CIA (16.5 ± 6.8 k/μL), and between pseudogout (8.9 ± 3.2 k/μL) and CIA. Conclusions: Measurement of ESR and CRP are helpful in crystal-induced arthritis. The CRP has more discriminating utility than the ESR in distinguishing between gout, pseudogout and CIA. Peripheral wbc is most useful for differentiating crystal-induced arthritis from CIA. 展开更多
关键词 GOUT PSEUDOGOUT Crystal-Induced Arthritis Acute Phase reactantS C-Reactive Protein Calcium PYROPHOSPHATE DIHYDRATE Deposition Disease
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Distinct microstructure and property evolution of 0.76(Bi_(0.5)Na_(0.5))TiO_(3)-0.24SrTiO_(3) ferroelectric ceramics synthesized with different TiO_(2) reactants
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作者 Jian Guo Ji Zhang +1 位作者 Jing Wang Shan-Tao Zhang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第20期73-79,共7页
Single phase 0.76(Bi_(0.5)Na_(0.5))TiO_(3)–0.24SrTiO_(3) ferroelectric ceramics have been synthesized with homogenous anatase and hierarchical rutile TiO_(2) raw reactants(BNST-A and BNST-R).Either calcined powder pe... Single phase 0.76(Bi_(0.5)Na_(0.5))TiO_(3)–0.24SrTiO_(3) ferroelectric ceramics have been synthesized with homogenous anatase and hierarchical rutile TiO_(2) raw reactants(BNST-A and BNST-R).Either calcined powder persists the microstructure characteristics of raw reactants.As the result,when the sintering temperature increases from 1000 to 1200℃,the average grain size and density of BNST-A increase from 0.49 to 1.48μm and 5.02 to 5.61 g/cm^(3),while those of BNST-R from 0.86 to 1.44μm and 5.37 to 5.61 g/cm^(3).BNST-A illustrates a predominant ergodic relaxor state,and BNST-R prefers a non-ergodic relaxor state,as evidenced by the distinct polarization-electric field loops and current-electric field curves.Especially,such a distinct ferroelectric state is independent of sintering temperature.It is believed that the special hierarchical microstructure of rutile TiO_(2) reactant is beneficial to form denser ceramics with larger grains,and thus suppresses the contributions of polar nanoregions and defect-induced built-in field to ferroelectric property,leading to non-ergodic relaxor state.This work clearly demonstrates the nonnegligible effects of TiO_(2) reactants on the microstructure and properties of BNST ferroelectric ceramics. 展开更多
关键词 BNST ferroelectric ceramics TiO_(2)raw reactants Microstructure and property evolution
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太阳能热化学储能技术关键材料研究现状 被引量:3
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作者 胡若兰 邓巍 +2 位作者 赵勇 谢小军 张恩享 《热力发电》 北大核心 2025年第1期1-11,共11页
回顾了近年来太阳能驱动的固-气、气-气和液-气热化学储能体系应用的反应物和催化剂等关键材料的研究进展;综述了碳酸盐、氢氧化物、金属氢化物、金属氧化物、有机物和氨等材料的热化学储能特性以及反应物材料改性、新材料开发和催化剂... 回顾了近年来太阳能驱动的固-气、气-气和液-气热化学储能体系应用的反应物和催化剂等关键材料的研究进展;综述了碳酸盐、氢氧化物、金属氢化物、金属氧化物、有机物和氨等材料的热化学储能特性以及反应物材料改性、新材料开发和催化剂改良等的研究现状。目前,适用于太阳能热化学储能的反应物材料在循环稳定性、反应活性、转化率、储能密度、成本或安全性等方面或多或少存在不足,限制了太阳能热化学储能技术的商业化应用。未来,仍需在已知热化学反应体系的基础上研制兼顾储能密度和循环反应稳定性、无腐蚀性和无毒性且具有成本效益的先进复合材料,同时开发新型高效催化剂以提高反应速率,扩展示范应用场景和规模,进一步提升太阳能热化学储能技术的成熟度。 展开更多
关键词 太阳能利用 热化学储能 储能材料 反应物 催化剂
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Recent advances of CO_(2)hydrogenation to methanol
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作者 Feng Hong Yanan Qi +5 位作者 Zuodong Yang Lijun Yu Xiaoguang Guan Jiangyong Diao Bo Sun Hongyang Liu 《DeCarbon》 2025年第2期84-101,共18页
The increasingly serious climate issue compels urgent greenhouse gas mitigation strategies.As a budget,plentiful,renewable feedstock and major contributor to global warming,the large-scale catalytic transformation of ... The increasingly serious climate issue compels urgent greenhouse gas mitigation strategies.As a budget,plentiful,renewable feedstock and major contributor to global warming,the large-scale catalytic transformation of CO_(2)has attracted widespread attention from society due to its potential as a solution to the environment and energy crises.At present,catalytic hydrogenation of carbon dioxide to organic chemicals is the primary approach in its industrial applications.In recent decades,various materials containing Cu-,precious metal-,In-,Zn-,and Ga-based catalysts have been designed for CO_(2)hydrogenation to methanol.Likewise,great advances have been made in CO_(2)-to-chemicals,such as olefins,aromatics,and gasoline by combining CO_(2)-to-CH3OH with methanol transformation or tandem reaction of reverse water-gas shift and Fischer-Tropsch(FT)synthesis.This review exhibits the recent advances in the hydrogenation of CO_(2)-to-CH3OH including the catalyst system,CO_(2)activation,nature of active sites,intermediate species(formate or carboxyl),structure-activity relationship,and reaction mechanism.Finally,challenges and outlooks in CO_(2)hydrogenation to methanol are summarized. 展开更多
关键词 CO_(2)hydrogenation METHANOL reactants activation Structure-activity relationship Reaction mechanism
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Electrochemiluminescence from tris(2,2′-bipyridyl) ruthenium (Ⅱ) in the presence of aminocarboxylic acid co-reactants 被引量:2
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作者 YIN XueBo, SHA BeiBei & HE XiWen Research Centre for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China 《Science China Chemistry》 SCIE EI CAS 2009年第9期1394-1401,共8页
Due to the highly sensitive electrochemiluminescence (ECL), tris(2,2′-bipyridyl) ruthenium(II) (Ru(bpy)32+) is often used in the field of bioarrays with the help of co-reactants. However, the generally used co-reacta... Due to the highly sensitive electrochemiluminescence (ECL), tris(2,2′-bipyridyl) ruthenium(II) (Ru(bpy)32+) is often used in the field of bioarrays with the help of co-reactants. However, the generally used co-reactant, tripropylamine (TPA), is toxic, corrosive and volatile. Therefore, the search for safe, sensitive and economical co-reactants is critical. Herein, three aminocarboxylic acids, ethylenediamine-tetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and 2-hydroxyethylethylene diaminetriacetic acid (HEDTA), have been investigated as potential co-reactants for promoting Ru(bpy)32+ ECL behaviour. A possible ECL mechanism is also presented. The experimental results suggested that the co-reactants have a different ECL behaviour compared to TPA, such as different pH- and surfactant-responses. The detection limits of Ru(bpy)32+ using NTA, EDTA and HEDTA as co-reactants are 1, 60 and 680 fmol·L-1, respectively. The results indicate that NTA has a much higher efficiency than TPA to excite Ru(bpy)3 2+ ECL under their own optimal conditions. NTA could be widely used in many fields because it is less toxic, corrosive and volatile than TPA. Moreover, using Ru(bpy)3 2+ ECL, a sensitive method for the detection of aminocarboxylic acids is also developed. An improvement of four orders of magnitude in detection limits is obtained for EDTA compared to the known Ru(bpy) 3 2+ chemiluminescent methods. 展开更多
关键词 Ru(bpy)32+ ELECTROCHEMILUMINESCENCE co-reactants aminocarboxylic ACIDS
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质子交换膜燃料电池在线活化工艺综述
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作者 贾秋红 贾刘含 +3 位作者 陈义 王谷城 高祖昌 韩明 《电源技术》 北大核心 2025年第3期497-505,共9页
活化是质子交换膜燃料电池投入使用和达到最佳性能的必要过程之一,各种活化工艺中在线活化工艺是提升电堆性能的关键步骤之一。从膜润湿、传输通道建立和微观电极重构等方面对质子交换膜燃料电池的活化机理阐述说明。主要从电压&电... 活化是质子交换膜燃料电池投入使用和达到最佳性能的必要过程之一,各种活化工艺中在线活化工艺是提升电堆性能的关键步骤之一。从膜润湿、传输通道建立和微观电极重构等方面对质子交换膜燃料电池的活化机理阐述说明。主要从电压&电流、操作参数、反应物和综合控制等4个方面对国内外学者关于质子交换膜燃料电池在线活化工艺的研究成果进行了总结分析。随着在线活化方法的不断改进,电堆输出性能提高,活化时长缩短实现了快速活化。对四种在线活化工艺各自的特点和优缺点进行了对比分析并给出了建议,得出在线综合控制活化工艺具有活化效果更好,时间更短等优点,是今后在线活化的热点方向之一。 展开更多
关键词 燃料电池活化工艺 电流&电压 操作参数 反应物
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脊得舒丸联合三伏贴治疗肾虚督寒型强直性脊柱炎临床研究
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作者 陈蕾 周子朋 杨帅 《新中医》 2025年第12期80-86,共7页
目的:观察脊得舒丸联合三伏贴治疗肾虚督寒型强直性脊柱炎(AS)的临床疗效,以及对骨代谢和炎症因子的影响。方法:选取2021年6月—2023年6月在河南省中医院治疗的108例肾虚督寒型AS患者,使用随机数字表法分为研究组与对照组各54例。2组均... 目的:观察脊得舒丸联合三伏贴治疗肾虚督寒型强直性脊柱炎(AS)的临床疗效,以及对骨代谢和炎症因子的影响。方法:选取2021年6月—2023年6月在河南省中医院治疗的108例肾虚督寒型AS患者,使用随机数字表法分为研究组与对照组各54例。2组均给予常规西药治疗,对照组在常规西药基础上给予脊得舒丸治疗,研究组在常规西药基础上给予脊得舒丸联合三伏贴治疗。比较2组临床疗效、骨代谢指标、炎症因子、急性期反应标志物、中医证候积分、巴氏AS疾病活动指数(BASDAI)评分、腰骶疼痛视觉模拟评分法(VAS)评分及不良反发生率。结果:治疗后,研究组总有效率96.23%(51/53),高于对照组82.35%(42/51)(P<0.05)。2组血清骨特异性碱性磷酸酶(BALP)、骨钙素(OC)、Ⅰ型前胶原羧基末端肽(PⅠCP)、Ⅰ型前胶原氨基末端肽(PⅠNP)水平均较治疗前升高(P<0.05),研究组上述4项指标水平均高于对照组(P<0.05);2组血清25-羟维生素D[25(OH) D]、甲状旁腺激素(PTH)水平比较,差异均无统计学意义(P>0.05)。2组血清白细胞介素-6(IL-6)、白细胞介素-17(IL-17)、白细胞介素-23(IL-23)、肿瘤坏死因子-α(TNF-α)、C-反应蛋白(CRP)及血沉(ESR)水平均较治疗前降低(P<0.05),研究组上述6项指标水平均低于对照组(P<0.05)。2组腰胯疼痛、腰部活动受限、腰膝酸软、喜暖畏寒、神疲乏力积分及中医证候总分均较治疗前降低(P<0.05),研究组上述5项中医证候积分及总分均低于对照组(P<0.05)。2组BASDAI、VAS评分均较治疗前降低(P<0.05),研究组BASDAI、VAS评分均低于对照组(P<0.05)。研究组不良反应率13.21%(7/53),与对照组11.76%(6/51),差异无统计学意义(P>0.05)。结论:脊得舒丸联合三伏贴治疗肾虚督寒型AS,可有效改善骨代谢,减轻炎症反应,缓解症状,临床疗效良好。 展开更多
关键词 强直性脊柱炎 肾虚督寒型 脊得舒丸 三伏贴 疼痛 骨代谢 炎症因子 急性期反应标志物
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How does supergravity affect combustion?
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作者 Wenjun Kong Zheng Chen 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2024年第6期39-40,共2页
It is well known that gravity may have a profound impact on the combustion process under certain conditions[1].The densities of the gaseous combustion products are typically 5-12 times lower than those of reactants.Un... It is well known that gravity may have a profound impact on the combustion process under certain conditions[1].The densities of the gaseous combustion products are typically 5-12 times lower than those of reactants.Under normal gravity conditions,the density difference generates buoyant forces that drive the flow,which affects the combustion process through flow-transport-chemistry interaction.For example,the buoyant convection in normal gravity causes the candle flame to be shaped like a teardrop while spherical candle flame is observed in microgravity.Recently,microgravity combustion has drawn great attention.A series of combustion experiments have been and will be conducted in the International Space Station and Chinese Space Station.In fact,significant progress has been made in microgravity combustion.For example,the discovery of steadily burning cool flames[2]in microgravity experiments was regarded as one of the"20 Breakthroughs from 20 Years of Science aboard the International Space Station". 展开更多
关键词 interaction. reactant typically
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电解水制氢耦合有机物氧化研究进展 被引量:3
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作者 夏天 栗振华 +1 位作者 邵明飞 段雪 《石油炼制与化工》 CAS CSCD 北大核心 2024年第1期42-51,共10页
利用可再生能源(太阳能、风能)驱动的电解水制氢技术是获取“绿氢”的必经之路,是实现碳中和的重要战略措施。然而,目前电解水制氢技术仍面临电解效率低和能耗高等问题。其原因之一在于阳极析氧反应(OER)动力学过程缓慢,制约了阴极产氢... 利用可再生能源(太阳能、风能)驱动的电解水制氢技术是获取“绿氢”的必经之路,是实现碳中和的重要战略措施。然而,目前电解水制氢技术仍面临电解效率低和能耗高等问题。其原因之一在于阳极析氧反应(OER)动力学过程缓慢,制约了阴极产氢,并且阳极产物氧气的附加值较低。利用电解水过程中阳极产生的“活性氧”物种催化有机物选择性氧化(替代OER),被证明是能够降低电解水反应电压、提高产氢效率的有效策略,并且利用阳极得到高附加值化学品可以进一步分摊并降低制氢成本,最近受到科研界和产业界的广泛关注。基于此,总结了近年来电解水制氢耦合有机物氧化方面的研究进展,包括:阳极表面水活化产生活性氧的种类及其催化有机氧化反应机理、反应物吸附过程强化提升反应速率相关策略、电解水制氢耦合氧化反应器设计和产物分离等技术。最后,对该领域的未来发展前景和面临的挑战进行了总结和展望。 展开更多
关键词 电解水制氢 活性氧 耦合反应 有机氧化 反应物富集
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漂移管工作温度对离子迁移率谱的影响 被引量:11
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作者 贾建 郭会勇 +2 位作者 高晓光 何秀丽 李建平 《分析化学》 SCIE EI CAS CSCD 北大核心 2006年第12期1783-1786,共4页
离子迁移率、反应物离子的种类和产量与漂移管工作温度有很大的关系。本研究在不同温度下进行了离子迁移率实验,结果表明,离子迁移率随温度的升高而增大,而提高工作温度可以减少水分子对产物离子的影响,有利于改善系统检测的分辨率;选... 离子迁移率、反应物离子的种类和产量与漂移管工作温度有很大的关系。本研究在不同温度下进行了离子迁移率实验,结果表明,离子迁移率随温度的升高而增大,而提高工作温度可以减少水分子对产物离子的影响,有利于改善系统检测的分辨率;选择合适漂移管工作温度,能有效地增加反应物离子的产量,从而提高系统检测的灵敏度和选择性。 展开更多
关键词 离子迁移率谱 离子迁移 漂移管 反应物离子 产物离子
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长期施肥土壤中酶活性的剖面分布及其动力学特征研究 被引量:22
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作者 邱莉萍 刘军 +1 位作者 王益权 张兴昌 《植物营养与肥料学报》 CAS CSCD 北大核心 2005年第6期737-741,749,共6页
对连续25年的长期培肥试验地中土壤剖面酶活性的分布及土壤酶的催化反应特性进行了研究,结果发现,土壤脲酶、碱性磷酸酶和蔗糖酶活性在土壤剖面中的分布从表层到深层,酶活性依次减小;而多酚氧化酶呈“波浪”型分布。土壤中脲酶、碱性磷... 对连续25年的长期培肥试验地中土壤剖面酶活性的分布及土壤酶的催化反应特性进行了研究,结果发现,土壤脲酶、碱性磷酸酶和蔗糖酶活性在土壤剖面中的分布从表层到深层,酶活性依次减小;而多酚氧化酶呈“波浪”型分布。土壤中脲酶、碱性磷酸酶、蔗糖酶活性与相应土层的有机质含量呈极显著正相关;多酚氧化酶无此相关性。土壤脲酶和碱性磷酸酶活性均随时间的延长而逐渐趋于一个稳定值,且各个时段酶活性均为施肥处理高于不施肥处理,说明施肥能显著提高土壤酶活性。土壤脲酶和碱性磷酸酶酶促反应初速度(V0)均随温度和底物浓度的增加而增加,至一定温度和底物浓度时,V0不再增加;不同培肥措施下V0为:厩肥>秸秆>化肥>对照。 展开更多
关键词 长期施肥 酶活性 剖面分布 底物浓度 酶促反应初速度
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反应物浓度对NaYF_4∶Yb^(3+),Tm^(3+)晶相的影响 被引量:11
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作者 陈喆 刘真育 +1 位作者 赵丹 秦伟平 《发光学报》 EI CAS CSCD 北大核心 2011年第9期853-857,共5页
利用水热法,制备了具有不同形貌的NaYF4∶20%Yb3+,1%Tm3+上转换发光粒子。利用扫描电子显微镜、X射线衍射分析、发光光谱测量等手段对样品进行了形貌、晶相和发光性质的表征。结果表明,通过调控反应物的浓度,可以实现NaYF4基质从立方相... 利用水热法,制备了具有不同形貌的NaYF4∶20%Yb3+,1%Tm3+上转换发光粒子。利用扫描电子显微镜、X射线衍射分析、发光光谱测量等手段对样品进行了形貌、晶相和发光性质的表征。结果表明,通过调控反应物的浓度,可以实现NaYF4基质从立方相到六角相的晶相转变。在980 nm红外光的激发下,六角相的NaYF4∶20%Yb3+,1%Tm3+上转换发光粒子发出蓝紫色可见光。通过分析反应物浓度对产物晶相的影响,为制备晶相可控的上转换发光材料提供了新的实验依据。 展开更多
关键词 NAYF4 稀土 反应物浓度 晶相 上转换发光
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基于量纲分析的爆炸冲击波效应靶模型分析与实验研究 被引量:12
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作者 李丽萍 孔德仁 +2 位作者 王芳 商飞 贾云飞 《振动与冲击》 EI CSCD 北大核心 2016年第6期100-103,168,共5页
针对传统的冲击波压力电测法易受爆炸场寄生效应干扰问题,提出基于效应靶塑性变形的爆炸冲击波压力评定方法。由于效应靶理论模型复杂、参数较多,利用量纲分析方法简化模型获得爆炸冲击波压力作用的效应靶最大挠度与炸药TNT当量、炸高... 针对传统的冲击波压力电测法易受爆炸场寄生效应干扰问题,提出基于效应靶塑性变形的爆炸冲击波压力评定方法。由于效应靶理论模型复杂、参数较多,利用量纲分析方法简化模型获得爆炸冲击波压力作用的效应靶最大挠度与炸药TNT当量、炸高及炸距之关系,并建立冲击波压力作用的效应靶最大挠度计算模型;设计100 kg、60 kg、20 kg三种标准TNT爆炸的立靶、平靶实验,用回归分析法获得二者经验模型系数。结果表明,立靶与平靶两种结构效应靶最大挠度实验结果与经验模型计算结果误差分别优于3.59%及3.33%。该研究可指导战斗部冲击波压力评估,进而减少爆炸实验量。 展开更多
关键词 爆炸力学 效应靶 塑性大变形 量纲分析 冲击波压力评定
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