1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of glo...1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of global energy expenditure[1,2],necessitating urgent development of sustainable cooling alter-natives.Radiative cooling emerges as a passive thermal regu-lation strategy,operating without external energy input via direct infrared emission from materials to the environment[3].展开更多
Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films t...Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films to enhance their cooling performance.In practical applications,thermal contact between the radiative cooling film and the object significantly influences the ultimate cooling performance.However,achieving optimal thermal contact has received limited attention.In this study,we propose and experimentally demonstrate a high-power,flexible,and magnetically attachable and detachable radiative cooling film.This film consists of polymer metasurface structures on a flexible magnetic layer.The monolithic design allows for convenient attachment to and detachment from steel or iron surfaces,ensuring optimal thermal contact with minimal thermal resistance and uniform temperature distribution.Our magnetic radiative cooling film exhibits superior cooling performance compared to non-magnetic alternatives.It can reduce the temperature of stainless-steel plates under sunlight by 15.2℃,which is 3.6℃ more than that achieved by non-magnetic radiative cooling films.The radiative cooling power can reach 259W·m^(-2) at a working temperature of 70℃.Unlike other commonly used attachment methods,such as thermal grease or one-off tape,our approach allows for detachment and reusability of the cooling film according to practical needs.This method offers great simplicity,flexibility,and cost-effectiveness,making it promising for broad applications,particularly on non-horizontal irregular surfaces previously considered challenging.展开更多
Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for...Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.展开更多
The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In thi...The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.展开更多
Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor...Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.展开更多
Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spec...Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spectrum and high emissivity within the atmospheric transmission window.Unlike broadbandemissive daytime radiative cooling materials,spectrally selective daytime radiative cooling(SSDRC)materials exhibit predominant mid-infrared emission in the atmospheric transmission window.This selective mid-infrared emission suppresses thermal radiation absorption beyond the atmospheric transmission window range,thereby improving the net cooling power of daytime radiative cooling.This review elucidates the fundamental characteristics of SSDRC materials,including their molecular structures,micro-and nanostructures,optical properties,and thermodynamic principles.It also provides a comprehensive overview of the design and fabrication of SSDRC materials in three typical forms,i.e.,fibrous materials,membranes,and particle coatings,highlighting their respective cooling mechanisms and performance.Furthermore,the practical applications of SSDRC in personal thermal management,outdoor building cooling,and energy harvesting are summarized.Finally,the challenges and prospects are discussed to guide researchers in advancing SSDRC materials.展开更多
Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performan...Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performance and scalable potential.However,the use of large amounts of organic solvents,the long cycle time,and the complexity of the preparation process have limited their development.Herein,we report a two-step cold-press sintering method for the preparation of a polymer radiative cooler,which is free of organic solvents.For demonstration,a polyvinylidene fluoride-hexafluoropropylene copolymer(PVDF-HFP)coating with a solar reflectance of 97.4%and an emissivity of 0.969 within the atmospheric window is prepared,which can achieve a sub-ambient cooling phenomenon with a temperature reduction of 4.8℃.Besides,the maximal radiative cooling power of 50.2 W/m^(2)is also obtained under sunlight.After the implementation of the proposed sintered PVDF-HFP coating in buildings,more than 10%of annual energy consumption can be saved in China.This work proposes a simple,environmentally friendly,and scalable processing method for the preparation of radiative cooling materials,facilitating the large-scale application of radiative cooling technology.展开更多
Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate ada...Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate adaptation,and sustainable technology development,with applications in personal thermal management,building temperature regulation,and aerospace engineering.However,radiative cooling performance is susceptible to environmental aging and special environmental conditions,limiting its applicability in extreme environments.Herein,a critical review of extreme environmental radiative cooling is presented,focusing on enhancing environmental durability and cooling efficiency.This review first introduces the design principles of heat exchange channels,which are tailored based on the thermal flow equilibrium to optimize radiative cooling capacity in various extreme environments.Subsequently,recent advancements in radiative cooling materials and micronano structures that align with these principles are systematically discussed,with a focus on their implementation in terrestrial dwelling environments,terrestrial extreme environments,aeronautical environments,and space environments.Moreover,this review evaluates the cooling effects and anti-environmental abilities of extreme radiative cooling devices.Lastly,key challenges hindering the development of radiative cooling devices for extreme environmental applications are outlined,and potential strategies to overcome these limitations are proposed,aiming to prompt their future commercialization.展开更多
Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste p...Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste paper with one side decorated by a hydrophobic polymeric cooling coating consisting of micro/nanopore/particle hierarchical structure and the other side coated with hydrophilic MXene nanosheets for heating.The cooling surface demonstrates high solar reflectivity(96.3%)and infrared emissivity(95.5%),resulting in daytime/nighttime sub-ambient radiative cooling of 6℃/8℃with the theoretical cooling power of 100.6 and 138.5Wm^(−2),respectively.The heating surface exhibits high solar absorptivity(83.7%)and low infrared emissivity(15.2%),resulting in excellent radiative heating capacity for vehicle charging pile(~6.2℃)and solar heating performance.Impressively,the mechanical strength of Janus film increased greatly by 563%compared with that of pristine waste paper,which is helpful for its practical applications in various scenarios for switchable radiative thermal management through mechanical flipping.Energy-saving simulation results reveal that significant total energy savings of up to 32.4MJm^(−2) can be achieved annually(corresponding to the 12.4%saving ratio),showing the immense importance of reducing carbon footprint and promoting carbon neutrality.展开更多
During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation...During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation,leading to a substantial reduction in the subambient daytime radiative cooling performance.Conversely,radiative coolers featuring angular asymmetry and spectral selectivity effectively resolve the problem of thermal radiation directionality,successfully evading the interference caused by the ground-generated thermal radiation.This cooler overcomes the limitations posed by the angle of incident light,making it suitable for subambient daytime radiative cooling of vertical surfaces.Furthermore,by adjusting the structure of the cooler,the angular range of thermal radiation can be modulated,enabling the application of radiative cooling technology for intelligent temperature regulation of various inclined surfaces encountered in daily life.This innovative work makes a significant contribution to the development of subambient smart thermal interaction systems and opens up new possibilities for the practical application of radiative cooling.展开更多
Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building hea...Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.展开更多
Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo...Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.展开更多
Passive daytime radiative cooling(PDRC)technology is emerging as one of the most promising solutions to the global problem of spacing cooling,but its practical application is limited due to reduced cooling effectivene...Passive daytime radiative cooling(PDRC)technology is emerging as one of the most promising solutions to the global problem of spacing cooling,but its practical application is limited due to reduced cooling effectiveness caused by daily wear and tear,as well as dirt contamination.To tackle this problem,we report a novel strategy by introducing a renewable armor structure for prolonging the anti-fouling and cooling effectiveness properties of the PDRC coatings.The armor structure is designed by decorating fluorinated hollow glass microspheres(HGM)inside rigid resin composite matrices.The HGM serve triple purposes,including providing isolated cavities for enhanced solar reflectance,reinforcing the matrices to form robust armored structures,and increasing thermal emittance.When the coatings are worn,the HGM on the surface expose their concave cavities with numerous hydrophobic fragments,generating a highly rough surface that guarantee the superhydrophobic function.The coatings show a high sunlight reflectance(0.93)and thermal emittance(0.94)in the long-wave infrared window,leading to a cooling of 5℃ below ambient temperature under high solar flux(∼900 W/m^(2)).When anti-fouling functions are reduced,they can be regenerated more than 100 cycles without compromising the PDRC function by simple wearing treatment.Furthermore,these coatings can be easily prepared using a one-pot spray method with low-cost materials,exhibit strong adhesion to a variety of substrates,and demonstrate exceptional environmental stability.Therefore,we anticipate their immediate application opportunities for spacing cooling.展开更多
Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infra...Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infrared transmission window.However,high R_(solar) is usually achieved by increasing the coating's thickness,which not only increases materials' cost but also impairs heat transfer.Additionally,the desired high R_(solar) is vulnerable to dust pollution in the outdoors.In this work,a thin paint was designed by mixing hBN plates,PFOTS,and IPA. R_(solar)=0.963 and ε_(LWIR)=0.927 was achieved at a thickness of 150 μm due to the high backscattering ability of scatters.A high through-plane thermal conductivity(~1.82 W m^(-1) K^(-1)) also can be obtained.In addition,the porous structure coupled with the binder PFOTS resulted in a contact angle of 154°,demonstrating excellent durability under dust contamination.Outdoor experiments showed that the thin paint can obtain a 2.3℃ lower temperature for sub-ambient cooling than the reference PDRC coating in the daytime.Furtherly,the above-ambient heat dissipation performance can be enhanced by spraying the thin paint on a 3D heat sink,which was 15.7℃ lower than the reference 1D structure,demonstrating excellent performance for durable and scalable PDRC applications.展开更多
Radiative cooling materials have gained prominence as a zero-energy solution for mitigating global warming.However,a comprehensive understanding of the atomic-scale optical properties and macroscopic optical performan...Radiative cooling materials have gained prominence as a zero-energy solution for mitigating global warming.However,a comprehensive understanding of the atomic-scale optical properties and macroscopic optical performance of radiative cooling materials remains elusive,limiting insight into the underlying physics of their optical response and cooling efficacy.La_(2)O_(3)and HfO_(2),which represent rare earth and third/fourth subgroup inorganic oxides,respectively,show promise for radiative cooling applications.In this study,we used multiscale simulations to investigate the optical properties of La_(2)O_(3)and HfO_(2)across a broad spectrum.First-principles calculations revealed their dielectric functions and intrinsic refractive indices,and the results indicated that the slightly smaller bandgap of La_(2)O_(3)compared to HfO_(2)induces a higher refractive index in the solar band.Additionally,three-phonon scattering was found to provide more accurate infrared optical properties than two-phonon scattering,which enhanced the emissivity in the sky window.Monte Carlo simulations were also used to determine the macroscopic optical properties of La_(2)O_(3)and HfO_(2)coatings.Based on the simulated results,we identified that the particle size and particle volume fraction play a dominant role in the optical properties.Our findings underscore the potential of La_(2)O_(3)and HfO_(2)nanocomposites for environment-friendly cooling and offer a new approach for high-throughput screening of optical materials through multiscale simulations.展开更多
Thermoelectric generators(TEGs)play a critical role in collecting renewable energy fromthe sun and deep space to generate clean electricity.With their environmentally friendly,reliable,and noise-free operation,TEGs of...Thermoelectric generators(TEGs)play a critical role in collecting renewable energy fromthe sun and deep space to generate clean electricity.With their environmentally friendly,reliable,and noise-free operation,TEGs offer diverse applications,including areas with limited power infrastructure,microelectronic devices,and wearable technology.The review thoroughly analyses TEG system configurations,performance,and applications driven by solar and/or radiative cooling,covering non-concentrating,concentrating,radiative cooling-driven,and dual-mode TEGs.Materials for solar absorbers and radiative coolers,simulation techniques,energy storage management,and thermal management strategies are explored.The integration of TEGs with combined heat and power systems is identified as a promising application.Additionally,TEGs hold potential as charging sources for electronic devices.This comprehensive review provides valuable insights into this energy collection approach,facilitating improved efficiency,reduced costs,and expanded applications.It also highlights current limitations and knowledge gaps,emphasizing the importance of further research and development in unlocking the full potential of TEGs for a sustainable and efficient energy future.展开更多
This paper demonstrates the application of a design tool called BioTRIZ. Its developers claim that it can be used to access biological strategies for solving engineering problems. Our aim is to design a roof for hot c...This paper demonstrates the application of a design tool called BioTRIZ. Its developers claim that it can be used to access biological strategies for solving engineering problems. Our aim is to design a roof for hot climates that gets free cooling through radiant coupling with the sky. The insulation in a standard roof stops the sun and convection from warming the thermal mass. But it also restricts the mass＇s longwave view of the cool sky. Different solutions to this conflict are offered by BioTRIZ. The chosen solution is to replace the standard insulation component with an open cell honeycomb. The vertical cells would allow longwave radiation to pass, while arresting convection. The solutions offered by BioTRIZ＇s technological counterpart include no such changes in structure. It is estimated that the thermal mass in the biomimetic roof would remain on average 4.5℃ cooler than in a standard roof over a year in Riyadh, Saudi Arabia.展开更多
Epidermal electronics with superb passive-cooling capabilities are of great value for both daytime outdoor dressing comfort and low-carbon economy. Herein, a multifunctional and skinattachable electronic is rationally...Epidermal electronics with superb passive-cooling capabilities are of great value for both daytime outdoor dressing comfort and low-carbon economy. Herein, a multifunctional and skinattachable electronic is rationally developed on a porous all-elastomer metafabric for efficient passive daytime radiative cooling(PDRC) and human electrophysiological monitoring. The cooling characteristics are realized through the homogeneous impregnation of polytetrafluoroethylene microparticles in the styrene–ethylene–butylene–styrene fibers, and the rational regulation of microporosity in SEBS/PTFE metafabrics, thus synergistically backscatter ultraviolet–visible–near-infrared light(maximum reflectance over 98.0%) to minimize heat absorption while efficiently emit human-body midinfrared radiation to the sky. As a result, the developed PDRC metafabric achieves approximately 17℃ cooling effects in an outdoor daytime environment and completely retains its passive cooling performance even under 50% stretching. Further, high-fidelity electrophysiological monitoring capability is also implemented in the breathable and skin-conformal metafabric through liquid metal printing, enabling the accurate acquisition of human electrocardiograph, surface electromyogram, and electroencephalograph signals for comfortable and lengthy health regulation. Hence, the fabricated superelastic PDRC metafabric opens a new avenue for the development of body-comfortable electronics and low-carbon wearing technologies.展开更多
This paper presents design and simulation of a switchable radiative cooler that exploits phase transition in vanadium di-oxide to turn on and off in response to temperature.The cooler consists of an emitter and a sola...This paper presents design and simulation of a switchable radiative cooler that exploits phase transition in vanadium di-oxide to turn on and off in response to temperature.The cooler consists of an emitter and a solar reflector separated by a spacer.The emitter and the reflector play a role of emitting energy in mid-infrared and blocking incoming solar energy in ultraviolet to near-infrared regime,respectively.Because of the phase transition of doped vanadium dioxide at room tem-perature,the emitter radiates its thermal energy only when the temperature is above the phase transition temperature.The feasibility of cooling is simulated using real outdoor conditions.We confirme that the switchable cooler can keep a desired temperature,despite change in environmental conditions.展开更多
Passive daytime radiative cooling is achieved by radiating heat into outer space through electromagnetic waves without energy consumption. A scalable double-layer coating with a mixture of TiO_(2), SiO_(2), and Si_(3)...Passive daytime radiative cooling is achieved by radiating heat into outer space through electromagnetic waves without energy consumption. A scalable double-layer coating with a mixture of TiO_(2), SiO_(2), and Si_(3)N_(4)micron particles for radiative cooling is proposed in this study. The finite-difference time-domain algorithm is used to analyze the influence of particle size and coating thickness on radiative cooling performance. The results of the simulation show that the particle size of 3 μm can give the best cooling performance, and the coating thickness should be above 25 μm for SiO_(2)coating. Meanwhile, the mixture of SiO_(2)and Si_(3)N_(4)significantly improves the overall emissivity. Through sample preparation and characterization,the mixture coating with a 1:1 ratio addition on an Al substrate exhibits high reflectivity with a value of 87.6% in the solar spectrum, and an average emissivity of 92% in the infrared region(2.5 μm–15 μm), which can be attributed to the synergy among the optical properties of the material. Both coatings can theoretically be cooled by about 8℃ during the day and about 21℃ at nighttime with hc = 4 W·m^(-2)·K^(-1). Furthermore, even considering the significant conduction and convection exchanges, the cooling effect persists. Outdoor experimental results show that the temperature of the double-layer radiative cooling coating is always lower than the ambient temperature under direct sunlight during the day, and can be cooled by about 5℃ on average, while lower than the temperature of the aluminum film by almost 12℃.展开更多
基金the financial support from the National Key R&D Program of China(No.2020YFA0711500)the National Natural Science Foundation of China(Nos.52473215 and 52273248).
文摘1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of global energy expenditure[1,2],necessitating urgent development of sustainable cooling alter-natives.Radiative cooling emerges as a passive thermal regu-lation strategy,operating without external energy input via direct infrared emission from materials to the environment[3].
基金supported by the Australia Research Council through the Discovery Project scheme(DP190103186 and DP220100603)the Industrial Transformation Training Centres scheme(IC180100005)+5 种基金the Future Fellowship scheme(FT210100806)the Future Fellowship scheme(FT220100559)the Discovery Early Career Researcher Award scheme(DE230100383)the Shenzhen Science and Technology Program(GJHZ20240218113407015)the Natural Science Foundation of Shandong Province(ZR2021ME162)the Key Research and Development Program of Shandong Province,China(2022SFGC0501).
文摘Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films to enhance their cooling performance.In practical applications,thermal contact between the radiative cooling film and the object significantly influences the ultimate cooling performance.However,achieving optimal thermal contact has received limited attention.In this study,we propose and experimentally demonstrate a high-power,flexible,and magnetically attachable and detachable radiative cooling film.This film consists of polymer metasurface structures on a flexible magnetic layer.The monolithic design allows for convenient attachment to and detachment from steel or iron surfaces,ensuring optimal thermal contact with minimal thermal resistance and uniform temperature distribution.Our magnetic radiative cooling film exhibits superior cooling performance compared to non-magnetic alternatives.It can reduce the temperature of stainless-steel plates under sunlight by 15.2℃,which is 3.6℃ more than that achieved by non-magnetic radiative cooling films.The radiative cooling power can reach 259W·m^(-2) at a working temperature of 70℃.Unlike other commonly used attachment methods,such as thermal grease or one-off tape,our approach allows for detachment and reusability of the cooling film according to practical needs.This method offers great simplicity,flexibility,and cost-effectiveness,making it promising for broad applications,particularly on non-horizontal irregular surfaces previously considered challenging.
基金support from the Contract Research(“Development of Breathable Fabrics with Nano-Electrospun Membrane”,CityU ref.:9231419“Research and application of antibacterial and healing-promoting smart nanofiber dressing for children’s burn wounds”,CityU ref:PJ9240111)+1 种基金the National Natural Science Foundation of China(“Study of Multi-Responsive Shape Memory Polyurethane Nanocomposites Inspired by Natural Fibers”,Grant No.51673162)Startup Grant of CityU(“Laboratory of Wearable Materials for Healthcare”,Grant No.9380116).
文摘Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.
基金supported by the National Natural Science Foundation of China(52372279,52103071,52203322,52473289,52303220)the Interdisciplinary Research Project for Young Teachers of USTB(Fundamental Research Funds for the Central Universities in China,FRF-IDRY-GD22-001)。
文摘The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.
基金financially supported by Heilongjiang Postdoctoral Fund(Grant No.LBH-Z24057)Outstanding Master’s and Doctoral Thesis of Longjiang in the New Era(Grant No.LJYXL2023-076).
文摘Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.
基金supported by the National Natural Science Foundation of China(22308236)the China Postdoctoral Science Foundation(2023M742530,2024T170623)+2 种基金the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(23KJA430012)the National Natural Science Foundation of Jiangsu Province,China(BK20230501)the Opening Project of the Key Laboratory of Bionic Engineering(Ministry of Education),Jilin University(KF2023002).
文摘Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spectrum and high emissivity within the atmospheric transmission window.Unlike broadbandemissive daytime radiative cooling materials,spectrally selective daytime radiative cooling(SSDRC)materials exhibit predominant mid-infrared emission in the atmospheric transmission window.This selective mid-infrared emission suppresses thermal radiation absorption beyond the atmospheric transmission window range,thereby improving the net cooling power of daytime radiative cooling.This review elucidates the fundamental characteristics of SSDRC materials,including their molecular structures,micro-and nanostructures,optical properties,and thermodynamic principles.It also provides a comprehensive overview of the design and fabrication of SSDRC materials in three typical forms,i.e.,fibrous materials,membranes,and particle coatings,highlighting their respective cooling mechanisms and performance.Furthermore,the practical applications of SSDRC in personal thermal management,outdoor building cooling,and energy harvesting are summarized.Finally,the challenges and prospects are discussed to guide researchers in advancing SSDRC materials.
基金supported by the National Natural Science Foundation of China(NSFC 52130601 and 52106276)the Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)+1 种基金the University of Science and Technology of China-Southwest University of Science and Technology Counterpart Cooperation and Development Joint Fund(24LHJJ09)the USTC Center for Micro and Nanoscale Research and Fabrication。
文摘Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performance and scalable potential.However,the use of large amounts of organic solvents,the long cycle time,and the complexity of the preparation process have limited their development.Herein,we report a two-step cold-press sintering method for the preparation of a polymer radiative cooler,which is free of organic solvents.For demonstration,a polyvinylidene fluoride-hexafluoropropylene copolymer(PVDF-HFP)coating with a solar reflectance of 97.4%and an emissivity of 0.969 within the atmospheric window is prepared,which can achieve a sub-ambient cooling phenomenon with a temperature reduction of 4.8℃.Besides,the maximal radiative cooling power of 50.2 W/m^(2)is also obtained under sunlight.After the implementation of the proposed sintered PVDF-HFP coating in buildings,more than 10%of annual energy consumption can be saved in China.This work proposes a simple,environmentally friendly,and scalable processing method for the preparation of radiative cooling materials,facilitating the large-scale application of radiative cooling technology.
基金supported by the National Natural Science Foundation of China(52172120)Shanghai Science and Technology Development Funds(No.24CL2900500).
文摘Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate adaptation,and sustainable technology development,with applications in personal thermal management,building temperature regulation,and aerospace engineering.However,radiative cooling performance is susceptible to environmental aging and special environmental conditions,limiting its applicability in extreme environments.Herein,a critical review of extreme environmental radiative cooling is presented,focusing on enhancing environmental durability and cooling efficiency.This review first introduces the design principles of heat exchange channels,which are tailored based on the thermal flow equilibrium to optimize radiative cooling capacity in various extreme environments.Subsequently,recent advancements in radiative cooling materials and micronano structures that align with these principles are systematically discussed,with a focus on their implementation in terrestrial dwelling environments,terrestrial extreme environments,aeronautical environments,and space environments.Moreover,this review evaluates the cooling effects and anti-environmental abilities of extreme radiative cooling devices.Lastly,key challenges hindering the development of radiative cooling devices for extreme environmental applications are outlined,and potential strategies to overcome these limitations are proposed,aiming to prompt their future commercialization.
基金National Natural Science Foundation of China,Grant/Award Number:52003248Henan Province Youth Health Science and Technology Innovation Talent Training Program,Grant/Award Number:YQRC2023007+1 种基金Henan Province Excellent Youth Science Fund,Grant/Award Number:242300421064Joint Fund Predominant Discipline Cultivation Project of Henan Province,Grant/Award Number:232301420036.
文摘Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste paper with one side decorated by a hydrophobic polymeric cooling coating consisting of micro/nanopore/particle hierarchical structure and the other side coated with hydrophilic MXene nanosheets for heating.The cooling surface demonstrates high solar reflectivity(96.3%)and infrared emissivity(95.5%),resulting in daytime/nighttime sub-ambient radiative cooling of 6℃/8℃with the theoretical cooling power of 100.6 and 138.5Wm^(−2),respectively.The heating surface exhibits high solar absorptivity(83.7%)and low infrared emissivity(15.2%),resulting in excellent radiative heating capacity for vehicle charging pile(~6.2℃)and solar heating performance.Impressively,the mechanical strength of Janus film increased greatly by 563%compared with that of pristine waste paper,which is helpful for its practical applications in various scenarios for switchable radiative thermal management through mechanical flipping.Energy-saving simulation results reveal that significant total energy savings of up to 32.4MJm^(−2) can be achieved annually(corresponding to the 12.4%saving ratio),showing the immense importance of reducing carbon footprint and promoting carbon neutrality.
基金supported by the National Natural Science Foundation of China(52473270 and T2422028)the China Postdoctoral Science Foundation(2024M763485)+1 种基金the National Key R&D Program of China(2022YFA1203304)the Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(start-up grant E1552102).
文摘During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation,leading to a substantial reduction in the subambient daytime radiative cooling performance.Conversely,radiative coolers featuring angular asymmetry and spectral selectivity effectively resolve the problem of thermal radiation directionality,successfully evading the interference caused by the ground-generated thermal radiation.This cooler overcomes the limitations posed by the angle of incident light,making it suitable for subambient daytime radiative cooling of vertical surfaces.Furthermore,by adjusting the structure of the cooler,the angular range of thermal radiation can be modulated,enabling the application of radiative cooling technology for intelligent temperature regulation of various inclined surfaces encountered in daily life.This innovative work makes a significant contribution to the development of subambient smart thermal interaction systems and opens up new possibilities for the practical application of radiative cooling.
基金support from the Research Grants Council of the Hong Kong Special Administrative Region,China(PolyU152052/21E)Green Tech Fund of Hong Kong(Project No.:GTF202220106)+1 种基金Innovation and Technology Fund of the Hong Kong Special Administrative Region,China(ITP/018/21TP)PolyU Endowed Young Scholars Scheme(Project No.:84CC).
文摘Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.
基金supported by the National Science Fund for Distinguished Young Scholars(22125804)the National Natural Science Foundation of China(21808110,22078155,and 21878149).
文摘Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.
基金supported by the National Natural Science Foundation of China(Nos.52003035,52203135 and 51973023)the CHN Energy Group Project(No.GJNY-21-183).
文摘Passive daytime radiative cooling(PDRC)technology is emerging as one of the most promising solutions to the global problem of spacing cooling,but its practical application is limited due to reduced cooling effectiveness caused by daily wear and tear,as well as dirt contamination.To tackle this problem,we report a novel strategy by introducing a renewable armor structure for prolonging the anti-fouling and cooling effectiveness properties of the PDRC coatings.The armor structure is designed by decorating fluorinated hollow glass microspheres(HGM)inside rigid resin composite matrices.The HGM serve triple purposes,including providing isolated cavities for enhanced solar reflectance,reinforcing the matrices to form robust armored structures,and increasing thermal emittance.When the coatings are worn,the HGM on the surface expose their concave cavities with numerous hydrophobic fragments,generating a highly rough surface that guarantee the superhydrophobic function.The coatings show a high sunlight reflectance(0.93)and thermal emittance(0.94)in the long-wave infrared window,leading to a cooling of 5℃ below ambient temperature under high solar flux(∼900 W/m^(2)).When anti-fouling functions are reduced,they can be regenerated more than 100 cycles without compromising the PDRC function by simple wearing treatment.Furthermore,these coatings can be easily prepared using a one-pot spray method with low-cost materials,exhibit strong adhesion to a variety of substrates,and demonstrate exceptional environmental stability.Therefore,we anticipate their immediate application opportunities for spacing cooling.
基金financially supported by the Natural Science Foundation of Hunan Province(Grant No.2021JJ40732)the Central South University Innovation-Driven Research Programme(Grant No.2023CXQD012)。
文摘Passive daytime radiative cooling(PDRC) is environment-friendly without energy input by enhancing the coating's solar reflectance(R_(solar)) and thermal emittance(ε_(LWIR)) in the atmosphere's long-wave infrared transmission window.However,high R_(solar) is usually achieved by increasing the coating's thickness,which not only increases materials' cost but also impairs heat transfer.Additionally,the desired high R_(solar) is vulnerable to dust pollution in the outdoors.In this work,a thin paint was designed by mixing hBN plates,PFOTS,and IPA. R_(solar)=0.963 and ε_(LWIR)=0.927 was achieved at a thickness of 150 μm due to the high backscattering ability of scatters.A high through-plane thermal conductivity(~1.82 W m^(-1) K^(-1)) also can be obtained.In addition,the porous structure coupled with the binder PFOTS resulted in a contact angle of 154°,demonstrating excellent durability under dust contamination.Outdoor experiments showed that the thin paint can obtain a 2.3℃ lower temperature for sub-ambient cooling than the reference PDRC coating in the daytime.Furtherly,the above-ambient heat dissipation performance can be enhanced by spraying the thin paint on a 3D heat sink,which was 15.7℃ lower than the reference 1D structure,demonstrating excellent performance for durable and scalable PDRC applications.
基金the National Natural Science Foundation of China(Grant Nos.U23A20565,52301194,and 52101178)the Shanghai Science and Technology Commission(Grant No.22511100400)+1 种基金the startup funding from Shanghai Jiao Tong University(Grant No.WH220405009)Innovation Program of Shanghai Municipal Education Commission(Grant No.2023ZKZD15)for providing funding support for this research。
文摘Radiative cooling materials have gained prominence as a zero-energy solution for mitigating global warming.However,a comprehensive understanding of the atomic-scale optical properties and macroscopic optical performance of radiative cooling materials remains elusive,limiting insight into the underlying physics of their optical response and cooling efficacy.La_(2)O_(3)and HfO_(2),which represent rare earth and third/fourth subgroup inorganic oxides,respectively,show promise for radiative cooling applications.In this study,we used multiscale simulations to investigate the optical properties of La_(2)O_(3)and HfO_(2)across a broad spectrum.First-principles calculations revealed their dielectric functions and intrinsic refractive indices,and the results indicated that the slightly smaller bandgap of La_(2)O_(3)compared to HfO_(2)induces a higher refractive index in the solar band.Additionally,three-phonon scattering was found to provide more accurate infrared optical properties than two-phonon scattering,which enhanced the emissivity in the sky window.Monte Carlo simulations were also used to determine the macroscopic optical properties of La_(2)O_(3)and HfO_(2)coatings.Based on the simulated results,we identified that the particle size and particle volume fraction play a dominant role in the optical properties.Our findings underscore the potential of La_(2)O_(3)and HfO_(2)nanocomposites for environment-friendly cooling and offer a new approach for high-throughput screening of optical materials through multiscale simulations.
基金supported by the Hong Kong Polytechnic University through Projects of RCRE(Project No.1-BBEG)sponsored by the Research Grants Council of HongKong and the NationalNatural Science Foundation of China(Project No.N_PolyU513/18).
文摘Thermoelectric generators(TEGs)play a critical role in collecting renewable energy fromthe sun and deep space to generate clean electricity.With their environmentally friendly,reliable,and noise-free operation,TEGs offer diverse applications,including areas with limited power infrastructure,microelectronic devices,and wearable technology.The review thoroughly analyses TEG system configurations,performance,and applications driven by solar and/or radiative cooling,covering non-concentrating,concentrating,radiative cooling-driven,and dual-mode TEGs.Materials for solar absorbers and radiative coolers,simulation techniques,energy storage management,and thermal management strategies are explored.The integration of TEGs with combined heat and power systems is identified as a promising application.Additionally,TEGs hold potential as charging sources for electronic devices.This comprehensive review provides valuable insights into this energy collection approach,facilitating improved efficiency,reduced costs,and expanded applications.It also highlights current limitations and knowledge gaps,emphasizing the importance of further research and development in unlocking the full potential of TEGs for a sustainable and efficient energy future.
文摘This paper demonstrates the application of a design tool called BioTRIZ. Its developers claim that it can be used to access biological strategies for solving engineering problems. Our aim is to design a roof for hot climates that gets free cooling through radiant coupling with the sky. The insulation in a standard roof stops the sun and convection from warming the thermal mass. But it also restricts the mass＇s longwave view of the cool sky. Different solutions to this conflict are offered by BioTRIZ. The chosen solution is to replace the standard insulation component with an open cell honeycomb. The vertical cells would allow longwave radiation to pass, while arresting convection. The solutions offered by BioTRIZ＇s technological counterpart include no such changes in structure. It is estimated that the thermal mass in the biomimetic roof would remain on average 4.5℃ cooler than in a standard roof over a year in Riyadh, Saudi Arabia.
基金financially supported by the National Natural Science Foundation of China (21875033, 52161135302)the Research Foundation Flanders (G0F2322N)+4 种基金the China Postdoctoral Science Foundation (2022M711355)the Natural Science Foundation of Jiangsu Province (BK20221540)the Shanghai Scientific and Technological Innovation Project (18JC1410600)the Program of the Shanghai Academic Research Leader (17XD1400100)the Postgraduate Research & Practice Innovation Program of Jiangsu Province (KYCX22_2317)。
文摘Epidermal electronics with superb passive-cooling capabilities are of great value for both daytime outdoor dressing comfort and low-carbon economy. Herein, a multifunctional and skinattachable electronic is rationally developed on a porous all-elastomer metafabric for efficient passive daytime radiative cooling(PDRC) and human electrophysiological monitoring. The cooling characteristics are realized through the homogeneous impregnation of polytetrafluoroethylene microparticles in the styrene–ethylene–butylene–styrene fibers, and the rational regulation of microporosity in SEBS/PTFE metafabrics, thus synergistically backscatter ultraviolet–visible–near-infrared light(maximum reflectance over 98.0%) to minimize heat absorption while efficiently emit human-body midinfrared radiation to the sky. As a result, the developed PDRC metafabric achieves approximately 17℃ cooling effects in an outdoor daytime environment and completely retains its passive cooling performance even under 50% stretching. Further, high-fidelity electrophysiological monitoring capability is also implemented in the breathable and skin-conformal metafabric through liquid metal printing, enabling the accurate acquisition of human electrocardiograph, surface electromyogram, and electroencephalograph signals for comfortable and lengthy health regulation. Hence, the fabricated superelastic PDRC metafabric opens a new avenue for the development of body-comfortable electronics and low-carbon wearing technologies.
基金financially supported by the Green Science program funded by POSCOthe National Research Foundation(NRF)grants(NRF2019R1A2C3003129,CAMM-2019M3A6B3030637,NRF-2019R1A5A8080290,and NRF-2018M3D1A1058997)funded by the Ministry of Science and ICT,Republic of Korea+2 种基金the Global Ph.D.fellowship(NRF-2017H1A2A1043204)from the Ministry of Education,Republic of Koreathe PIURI fellowship funded by POSTECHa fellowship from Hyundai Motor Chung Mong-Koo Foundation。
文摘This paper presents design and simulation of a switchable radiative cooler that exploits phase transition in vanadium di-oxide to turn on and off in response to temperature.The cooler consists of an emitter and a solar reflector separated by a spacer.The emitter and the reflector play a role of emitting energy in mid-infrared and blocking incoming solar energy in ultraviolet to near-infrared regime,respectively.Because of the phase transition of doped vanadium dioxide at room tem-perature,the emitter radiates its thermal energy only when the temperature is above the phase transition temperature.The feasibility of cooling is simulated using real outdoor conditions.We confirme that the switchable cooler can keep a desired temperature,despite change in environmental conditions.
文摘Passive daytime radiative cooling is achieved by radiating heat into outer space through electromagnetic waves without energy consumption. A scalable double-layer coating with a mixture of TiO_(2), SiO_(2), and Si_(3)N_(4)micron particles for radiative cooling is proposed in this study. The finite-difference time-domain algorithm is used to analyze the influence of particle size and coating thickness on radiative cooling performance. The results of the simulation show that the particle size of 3 μm can give the best cooling performance, and the coating thickness should be above 25 μm for SiO_(2)coating. Meanwhile, the mixture of SiO_(2)and Si_(3)N_(4)significantly improves the overall emissivity. Through sample preparation and characterization,the mixture coating with a 1:1 ratio addition on an Al substrate exhibits high reflectivity with a value of 87.6% in the solar spectrum, and an average emissivity of 92% in the infrared region(2.5 μm–15 μm), which can be attributed to the synergy among the optical properties of the material. Both coatings can theoretically be cooled by about 8℃ during the day and about 21℃ at nighttime with hc = 4 W·m^(-2)·K^(-1). Furthermore, even considering the significant conduction and convection exchanges, the cooling effect persists. Outdoor experimental results show that the temperature of the double-layer radiative cooling coating is always lower than the ambient temperature under direct sunlight during the day, and can be cooled by about 5℃ on average, while lower than the temperature of the aluminum film by almost 12℃.
