In this paper the physical influences on the mechanical behavior of a Polyamide 6 (PA 6)/Mont- morillonit (MMT)-nanocomposite are examined by a selected structure modification in a numerical parameter study. Experimen...In this paper the physical influences on the mechanical behavior of a Polyamide 6 (PA 6)/Mont- morillonit (MMT)-nanocomposite are examined by a selected structure modification in a numerical parameter study. Experimental data of tensile tests of three different volume fractions at ambient temperature are used as reference. These were compared to homogenized stress-strain curves calculated with 3D representative volume elements (RVE) under periodic boundary conditions, in which the curve areas are considered until the tensile yield strength is reached. Besides the influence of filler orientation, exfoliation and its volume fraction, both adhesive interface behavior between the filler and matrix, and local partially crystalline interphases around the MMT-plates were also taken into account. A good approximation of the numerical representation of the experimental curves was achieved only after the introduction of the 30 - 40 nm thick partially crystalline interphases with higher stiffness and strength around the MMT-plates. The use of an exclusively isotropic matrix led to an underestimation of the mechanical values. The local modifications of the morphology were assumed to be transversely isotropic both in the elastic and in the plastic region. The transverse plane is defined by the lateral particle surface. Compared with the experimentally determined values of the corresponding Young’s Modulus, an excellent correlation was achieved. The yield strength for the largest volume fraction shows the best agreement with experimental values.展开更多
In this study, a numerical representative volume element (RVE) model was used to predict the mechanical properties of a Rice Husk Particulate (RHP)-Epoxy composite for use as an alternative material in non-critical ap...In this study, a numerical representative volume element (RVE) model was used to predict the mechanical properties of a Rice Husk Particulate (RHP)-Epoxy composite for use as an alternative material in non-critical applications. Seven different analytical models Counto, Ishai-Cohen, Halpin-Tsai, Nielsen, Nicolais, Modified Nicolais and Pukanszky were used as comparison tools for the numerical model. RHP-Epoxy biocomposite samples were fabricated with 0%, 10% and 30% RHP volume percentage and the experimental results benchmarked against the numerical and analytical projections. The mechanical properties estimated for 0%, 10% and 30% RHP-Epoxy composites using the numerical and analytical models were in general agreement. Using the analytical models, it was calculated that an increase in volume percentage of RHP to 30% led to continual reduction in elastic Young’s modulus and ultimate tensile strength of the composite. The numerical RVE models also predicted a similar trend between filler volume percentage and material properties. These projections were consistent with the experimental results whereby a 10% increase in RHP content led to 15% and 20% decrease in yield stress and tensile strength, but had no effect on the composite’s elastic property. Further increase in RHP volume percentage to 30% resulted in 8%, 21% and 28% reduction in Young’s modulus, yield stress and tensile strength, respectively. Overall, the results of this study suggest that RHP can be used to reduce the composite raw material costs by replacing the more expensive polymer content with agricultural waste products with limited compromise to the composite’s mechanical properties.展开更多
The addition of nanoparticles serves as an effective reinforcement strategy for polymeric coatings,utilizing their unique characteristics as well as extraordinary mechanical,thermal,and electrical properties.The excep...The addition of nanoparticles serves as an effective reinforcement strategy for polymeric coatings,utilizing their unique characteristics as well as extraordinary mechanical,thermal,and electrical properties.The exceptionally high surface-to-volume ratio of nanoparticles imparts remarkable reinforcing potentials,yet it simultaneously gives rise to a prevalent tendency for nanoparticles to agglomerate into clusters within nanocomposites.The agglomeration behavior of the nanoparticles is predominantly influenced by their distinct microstructures and varied weight concentrations.This study investigated the synergistic effects of nanoparticle geometric shape and weight concentration on the dispersion characteristics of nanoparticles and the physical-mechanical performances of nano-reinforced epoxy coatings.Three carbon-based nanoparticles,nanodiamonds(NDs),carbon nanotubes(CNTs),and graphenes(GNPs),were incorporated into epoxy coatings at three weight concentrations(0.5%,1.0%,and 2.0%).The experimental findings reveal that epoxy coatings reinforced with NDs demonstrated the most homogenous dispersion characteristics,lowest viscosity,and reduced porosity among all the nanoparticles,which could be attributed to the spherical geometry shape.Due to the superior physical properties,ND-reinforced nanocomposites displayed the highest abrasion resistance and tensile properties.Specifically,the 1.0wt%ND-reinforced nanocomposites exhibited 60%,52%,and 97%improvements in mass lost,tensile strength,and failure strain,respectively,compared to pure epoxy.Furthermore,the representative volume element(RVE)modeling was employed to validate the experimental results,while highlighting the critical role of nanoparticle agglomeration,orientation,and the presence of voids on the mechanical properties of the nanocomposites.Nano-reinforced epoxy coatings with enhanced mechanical properties are well-suited for application in protective coatings for pipelines,industrial equipment,and automotive parts,where high wear resistance is essential.展开更多
文摘In this paper the physical influences on the mechanical behavior of a Polyamide 6 (PA 6)/Mont- morillonit (MMT)-nanocomposite are examined by a selected structure modification in a numerical parameter study. Experimental data of tensile tests of three different volume fractions at ambient temperature are used as reference. These were compared to homogenized stress-strain curves calculated with 3D representative volume elements (RVE) under periodic boundary conditions, in which the curve areas are considered until the tensile yield strength is reached. Besides the influence of filler orientation, exfoliation and its volume fraction, both adhesive interface behavior between the filler and matrix, and local partially crystalline interphases around the MMT-plates were also taken into account. A good approximation of the numerical representation of the experimental curves was achieved only after the introduction of the 30 - 40 nm thick partially crystalline interphases with higher stiffness and strength around the MMT-plates. The use of an exclusively isotropic matrix led to an underestimation of the mechanical values. The local modifications of the morphology were assumed to be transversely isotropic both in the elastic and in the plastic region. The transverse plane is defined by the lateral particle surface. Compared with the experimentally determined values of the corresponding Young’s Modulus, an excellent correlation was achieved. The yield strength for the largest volume fraction shows the best agreement with experimental values.
文摘In this study, a numerical representative volume element (RVE) model was used to predict the mechanical properties of a Rice Husk Particulate (RHP)-Epoxy composite for use as an alternative material in non-critical applications. Seven different analytical models Counto, Ishai-Cohen, Halpin-Tsai, Nielsen, Nicolais, Modified Nicolais and Pukanszky were used as comparison tools for the numerical model. RHP-Epoxy biocomposite samples were fabricated with 0%, 10% and 30% RHP volume percentage and the experimental results benchmarked against the numerical and analytical projections. The mechanical properties estimated for 0%, 10% and 30% RHP-Epoxy composites using the numerical and analytical models were in general agreement. Using the analytical models, it was calculated that an increase in volume percentage of RHP to 30% led to continual reduction in elastic Young’s modulus and ultimate tensile strength of the composite. The numerical RVE models also predicted a similar trend between filler volume percentage and material properties. These projections were consistent with the experimental results whereby a 10% increase in RHP content led to 15% and 20% decrease in yield stress and tensile strength, but had no effect on the composite’s elastic property. Further increase in RHP volume percentage to 30% resulted in 8%, 21% and 28% reduction in Young’s modulus, yield stress and tensile strength, respectively. Overall, the results of this study suggest that RHP can be used to reduce the composite raw material costs by replacing the more expensive polymer content with agricultural waste products with limited compromise to the composite’s mechanical properties.
基金supported by the National Science Foundation(NSF)(No.CMMI-1750316)Pipeline and Hazardous Materials Safety Administration(PHMSA)of U.S.Department of Transportation(No.693JK31950008CAAP).
文摘The addition of nanoparticles serves as an effective reinforcement strategy for polymeric coatings,utilizing their unique characteristics as well as extraordinary mechanical,thermal,and electrical properties.The exceptionally high surface-to-volume ratio of nanoparticles imparts remarkable reinforcing potentials,yet it simultaneously gives rise to a prevalent tendency for nanoparticles to agglomerate into clusters within nanocomposites.The agglomeration behavior of the nanoparticles is predominantly influenced by their distinct microstructures and varied weight concentrations.This study investigated the synergistic effects of nanoparticle geometric shape and weight concentration on the dispersion characteristics of nanoparticles and the physical-mechanical performances of nano-reinforced epoxy coatings.Three carbon-based nanoparticles,nanodiamonds(NDs),carbon nanotubes(CNTs),and graphenes(GNPs),were incorporated into epoxy coatings at three weight concentrations(0.5%,1.0%,and 2.0%).The experimental findings reveal that epoxy coatings reinforced with NDs demonstrated the most homogenous dispersion characteristics,lowest viscosity,and reduced porosity among all the nanoparticles,which could be attributed to the spherical geometry shape.Due to the superior physical properties,ND-reinforced nanocomposites displayed the highest abrasion resistance and tensile properties.Specifically,the 1.0wt%ND-reinforced nanocomposites exhibited 60%,52%,and 97%improvements in mass lost,tensile strength,and failure strain,respectively,compared to pure epoxy.Furthermore,the representative volume element(RVE)modeling was employed to validate the experimental results,while highlighting the critical role of nanoparticle agglomeration,orientation,and the presence of voids on the mechanical properties of the nanocomposites.Nano-reinforced epoxy coatings with enhanced mechanical properties are well-suited for application in protective coatings for pipelines,industrial equipment,and automotive parts,where high wear resistance is essential.
