Organic room-temperature phosphorescence(RTP)materials are promising for bioimaging applications due to their tunable structures,excellent biocompatibility,and long-lived luminescence.However,the development of highly...Organic room-temperature phosphorescence(RTP)materials are promising for bioimaging applications due to their tunable structures,excellent biocompatibility,and long-lived luminescence.However,the development of highly efficient organic RTP materials for aqueous systems remains challenging,as the organic phosphorescence is prone to being quenched by the dissolved oxygen in water.Herein,heteroaromatic carboxylic acids serve as ligand vips to construct a series of host-vip composites with nontoxic,dense EDTA-M(M=Ca,Mg,and Al)coordination polymer in water.These composites exhibit ultra-long pure RTP of vip molecules with phosphorescence quantum yield up to 53%,and lifetime up to 589.7 ms,due to the synergistic effect of dual-network structure:a coordinatively cross-linked network of EDTA-M,and a non-covalent bonded network formed by ligands and water molecules.The phosphorescence intensity is more than three times that of the composite with a single coordination network.Notably,the dual-network configuration can form a rigid and dense structure and block the intrusion of external H_(2)O and O_(2) molecules to avoid phosphorescence quenching in water.As a result,the RTP of the composites remains unchanged after 1 month in water.Furthermore,the nanoparticles fabricated from composites and anionic surfactants can be successfully applied in in vivo imaging of mice for the stable RTP in water.This work provides a novel strategy for the development of high-performance RTP materials in aqueous systems.展开更多
Internal rotation of conjugated organic backbone seriously impaired room temperature phosphorescence(RTP),leading to rare realization of ultra-long afterglows with RTP lifetimes over 2 s in non-bibulous polymers.Herei...Internal rotation of conjugated organic backbone seriously impaired room temperature phosphorescence(RTP),leading to rare realization of ultra-long afterglows with RTP lifetimes over 2 s in non-bibulous polymers.Herein,N-(bromophenyl)carbazoles are cyclized to lock up phenyl-carbazol internal rotation in advance and the fused nitrogen hetero-cyclic compounds are doped into poly(methyl methacrylate)(PMMA).The results show that locking up the molecular internal rotation can achieve ultra-long RTP polymers with lifetimes over 2 s,in contrast,the unlocked molecules hardly emit RTP in PMMA.The high-lying triplet excitons can transfer the energy to low-lying organic fluorescent dyes,and the persistent multicolor afterglows including white emission can be readily modulated.This work discloses an effective and extendable dopant molecular strategy for developing high-performance ultra-long organic RTP polymers.展开更多
报道了相同实验条件下激光二极管端面抽运生长型复合Nd:YVO4晶体声光调Q和RTP电光调Q激光器。应用声光调Q和RTP电光调Q分别实现了最高重复频率200 k Hz和500 k Hz的TEM00模1 064 nm激光输出,输出平均功率分别达到12.13 W和13.56 W,脉冲...报道了相同实验条件下激光二极管端面抽运生长型复合Nd:YVO4晶体声光调Q和RTP电光调Q激光器。应用声光调Q和RTP电光调Q分别实现了最高重复频率200 k Hz和500 k Hz的TEM00模1 064 nm激光输出,输出平均功率分别达到12.13 W和13.56 W,脉冲宽度分别为16.65 ns和27.27 ns,并首次对比了两种调Q体制下的高重频激光输出特性。实验结果表明,RTP电光调Q具有更好的高重频关断能力,但由于受到高压驱动的限制,RTP电光调Q无法在更高重复频率下实现窄脉宽高峰值功率激光输出,而在更高重频下仍有较好输出性能的声光调Q将取代电光调Q成为几百千甚至上兆Hz高重频激光器的首选调Q机制。展开更多
基金supported by the Startup Funds for Introduced Talents of Wuyi University(YJ202304)the National Natural Science Foundation of China(22375044).
文摘Organic room-temperature phosphorescence(RTP)materials are promising for bioimaging applications due to their tunable structures,excellent biocompatibility,and long-lived luminescence.However,the development of highly efficient organic RTP materials for aqueous systems remains challenging,as the organic phosphorescence is prone to being quenched by the dissolved oxygen in water.Herein,heteroaromatic carboxylic acids serve as ligand vips to construct a series of host-vip composites with nontoxic,dense EDTA-M(M=Ca,Mg,and Al)coordination polymer in water.These composites exhibit ultra-long pure RTP of vip molecules with phosphorescence quantum yield up to 53%,and lifetime up to 589.7 ms,due to the synergistic effect of dual-network structure:a coordinatively cross-linked network of EDTA-M,and a non-covalent bonded network formed by ligands and water molecules.The phosphorescence intensity is more than three times that of the composite with a single coordination network.Notably,the dual-network configuration can form a rigid and dense structure and block the intrusion of external H_(2)O and O_(2) molecules to avoid phosphorescence quenching in water.As a result,the RTP of the composites remains unchanged after 1 month in water.Furthermore,the nanoparticles fabricated from composites and anionic surfactants can be successfully applied in in vivo imaging of mice for the stable RTP in water.This work provides a novel strategy for the development of high-performance RTP materials in aqueous systems.
文摘Internal rotation of conjugated organic backbone seriously impaired room temperature phosphorescence(RTP),leading to rare realization of ultra-long afterglows with RTP lifetimes over 2 s in non-bibulous polymers.Herein,N-(bromophenyl)carbazoles are cyclized to lock up phenyl-carbazol internal rotation in advance and the fused nitrogen hetero-cyclic compounds are doped into poly(methyl methacrylate)(PMMA).The results show that locking up the molecular internal rotation can achieve ultra-long RTP polymers with lifetimes over 2 s,in contrast,the unlocked molecules hardly emit RTP in PMMA.The high-lying triplet excitons can transfer the energy to low-lying organic fluorescent dyes,and the persistent multicolor afterglows including white emission can be readily modulated.This work discloses an effective and extendable dopant molecular strategy for developing high-performance ultra-long organic RTP polymers.
