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白云鄂博碳酸岩型REE-Nb-Fe矿床——一个罕见的中元古代破火山机构成岩成矿实例 被引量:54
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作者 郝梓国 王希斌 +2 位作者 李震 肖国望 张台荣 《地质学报》 EI CAS CSCD 北大核心 2002年第4期525-540,共16页
白云鄂博碳酸岩型REE-Nb-Fe矿床是世界上最大的稀土矿床。稀土矿石产于整个白云石碳酸岩体和部分脉状碳酸岩中。对比世界上20余个火成碳酸岩地区的特征后发现,白云鄂博地区完全具备国外火成碳酸岩区的地质特征。在岩石、矿石组合上,本... 白云鄂博碳酸岩型REE-Nb-Fe矿床是世界上最大的稀土矿床。稀土矿石产于整个白云石碳酸岩体和部分脉状碳酸岩中。对比世界上20余个火成碳酸岩地区的特征后发现,白云鄂博地区完全具备国外火成碳酸岩区的地质特征。在岩石、矿石组合上,本区也发育一套碳酸岩+超基性岩+碱性基性岩(含基性熔岩)+碱性岩+稀土矿石+铁矿石组合;在矿物组合上,以白云石为主,方解石次之,伴生一套碱性闪石、长石、霓石、磷灰石、萤石、磁铁矿、稀土矿物组合;在全岩化学成分、微量元素、稀土元素和Sr、Nd、Pb、C、O同位素上,这些岩石具有一定的亲缘关系,有着共同的来源;在岩体的形态与岩石组构上,它们以岩席、岩筒和脉岩的形式出现,并发育有强烈的熔离作用与流动构造;在区域构造上,发育隐伏穹窿构造、岩筒构造和巨型断裂汇聚构造。综合分析上述特征表明:白云鄂博地区具有中元古代破火山机构的痕迹,赋矿白云石碳酸岩体则是顺层侵入的火成碳酸岩体,东矿、主矿可能是一个火山颈构造控矿,而赋矿白云石碳酸岩体西南侧的苏木图矿床则是隐伏岩筒构造控矿。 展开更多
关键词 ree-Nb-Fe矿床 破火山机构 中元古代 内蒙古 成矿作用 碳酸盐岩 稀土金属-钕-铁矿床 成岩作用
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白云鄂博巨型REE-Nb-Fe矿区矽卡岩化时代:单颗粒金云母Rb-Sr法定年 被引量:6
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作者 杨奎锋 范宏瑞 +5 位作者 胡芳芳 李向辉 柳建勇 赵永岗 刘爽 王凯怡 《岩石学报》 SCIE EI CAS CSCD 北大核心 2007年第5期1018-1022,共5页
内蒙古白云鄂博REE-Nb-Fe矿是目前世界上最大的稀土矿床。在白云鄂博东矿体的东南侧,分布有大面积的晚古生代花岗岩。花岗岩与赋矿白云岩(H_8)呈直接的侵入接触关系,接触带发育强烈的矽卡岩化和小型铁矿化。我们在东矿采坑南侧22线1598... 内蒙古白云鄂博REE-Nb-Fe矿是目前世界上最大的稀土矿床。在白云鄂博东矿体的东南侧,分布有大面积的晚古生代花岗岩。花岗岩与赋矿白云岩(H_8)呈直接的侵入接触关系,接触带发育强烈的矽卡岩化和小型铁矿化。我们在东矿采坑南侧22线1598m平台北倾探矿钻孔650~660m岩芯段,首次发现两段矽卡岩化蚀变带。对矽卡岩中的金云母进行超低本底Rb-Sr法定年,获得309±12Ma年龄。结合矽卡岩与矿体的侵入接触关系,可以认为,晚古生代花岗岩虽已深入到矿体下部,但其侵位时间应晚于矿区最后一期强烈的稀土矿化事件,它对白云鄂博矿床来说只是一次后期破矿的构造—岩浆活动。 展开更多
关键词 矽卡岩 Rb-Sr法定年 晚古生代花岗岩 ree-Nb-Fe矿床 白云鄂博
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白云鄂博REE-Nb-Fe矿床地质与航磁、航放特征及其对找矿工作的启示 被引量:7
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作者 王继春 宋崇宇 +3 位作者 王志利 周路路 张占飞 胡巧娥 《中国地质》 CAS CSCD 北大核心 2016年第2期594-606,共13页
通过对白云鄂博REE-Nb-Fe矿床的航磁及航放成果的分析,结合矿床地质特征进行综合对比研究,发现该矿床具有独特且典型的航磁、航放特征,航磁异常特征显示矿区为强度较高的近东西向条带状正负伴生磁异常特征,是具有较强磁性的矿体与弱磁... 通过对白云鄂博REE-Nb-Fe矿床的航磁及航放成果的分析,结合矿床地质特征进行综合对比研究,发现该矿床具有独特且典型的航磁、航放特征,航磁异常特征显示矿区为强度较高的近东西向条带状正负伴生磁异常特征,是具有较强磁性的矿体与弱磁性围岩反映;航磁ΔTmax为5000 n T以上,航磁ΔTmin为-2000 n T,有30余条测线上具有明显正负磁异常发育,呈现多期次异常叠加特征,属于不同期次、不同强度磁性体的反映,说明该矿床经历过多期次构造热事件的叠加、改造活动。该矿床向下延深的规模随深度的变化有逐渐缩小的趋势,当航磁ΔT等值线向上延拓3000 m时,依然表现为较明显的正磁异常特征,这说明该矿床在深部依然存在较明显的矿化现象。另外白云鄂博矿区航放特征具有醒目的总计数率、钾、铀、钍高值晕,它们总体上呈近东西向带状展布。矿区处于航放总计数率高值区,一般为3000-15381 cps,局部为团块状,高值区范围大于矿区范围;钾含量为2.0%-2.8%的偏高值,矿床及附近局部为2.8%-12%的高值;钍含量为26×10^-6-223×10^-6。钍高值晕范围较赋矿的加里东中期第二次侵入的碳酸岩出露的范围要大;铀含量一般为大于1.6×10^-6的偏高值,矿床及附近局部为2.8×10^-6-9.1×10^-6的高值。经综合分析,充分证明该区的航磁、航放特征与矿床信息对应性较强。在今后寻找类似矿床的过程中,可以将航磁正负伴生磁异常信息作为寻找铁多金属矿的有利信息,将放射性核素钾、钍、铀等高值信息做为寻找稀土矿有利信息,对找矿工作具有十分重要的指导意义。 展开更多
关键词 白云鄂博ree-Nb-Fe矿床 航磁特征 航放特征 综合对比 内蒙古
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白云鄂博Fe-REE-Nb建造地球化学特征及成因:元素及同位素新证据 被引量:12
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作者 赖小东 杨晓勇 柳建勇 《地质学报》 CAS CSCD 北大核心 2012年第5期801-818,共18页
通过野外地质观察和室内镜下研究,利用XRF和ICP-MS对白云岩及其周围的板岩的主、微量元素进行分析,同时对硫化矿化的样品开展硫同位素测试。元素测试结果显示白云鄂博Fe-REE-Nb建造白云岩既具有部分火成碳酸岩的地球化学特征,也具有部... 通过野外地质观察和室内镜下研究,利用XRF和ICP-MS对白云岩及其周围的板岩的主、微量元素进行分析,同时对硫化矿化的样品开展硫同位素测试。元素测试结果显示白云鄂博Fe-REE-Nb建造白云岩既具有部分火成碳酸岩的地球化学特征,也具有部分沉积碳酸岩的地球化学特征,表明白云鄂博Fe-REE-Nb建造赋矿白云岩不是典型的火成碳酸岩或沉积碳酸盐岩。硫同位素的测试结果表明,全岩的硫同位素组成不呈塔式模型分布,出现两个比较明显的峰值,一个在0‰左右,具有深源特征;另一个在+8‰左右,明显高于幔源硫,这个结果说明其来源可能有两个:地幔和海水。赋矿白云岩中Nb随着稀土的富集也发生富集作用,但是Ta的富集作用却十分微弱,显示了成矿热液强烈富REE和Nb及贫Ta的元素地球化学特征。据元素和硫同位素结果,我们认为白云鄂博赋矿白云岩是沉积碳酸盐受地幔碳酸岩岩浆及派生的流体交代的产物,而非直接源于火山碳酸岩喷发成因。地幔深部碳酸岩岩浆及其派生的富稀土流体沿区域性深大断裂上涌与沉积碳酸盐岩进行交代作用,形成了白云鄂博独特巨大的Fe-REE-Nb矿床及区域性的稀土矿床。 展开更多
关键词 白云岩 地球化学 硫同位素 矿床成因 白云鄂博Fe-ree-Nb建造 内蒙古
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高REE-Nb-Fe-Mn样品Mg同位素测定的化学分离方法 被引量:1
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作者 李世珍 房楠 +2 位作者 孙剑 陈岳龙 朱祥坤 《吉林大学学报(地球科学版)》 EI CAS CSCD 北大核心 2013年第1期142-148,共7页
利用多接收电感耦合等离子体质谱仪测定Mg同位素比值时,样品溶液中的基质元素可影响Mg同位素比值的准确测定。根据白云鄂博样品富含REE、Nb、Fe(REE质量分数可达10%、Nb质量分数可达0.1%)等元素的特性,本研究在评估测试溶液中Nd(REE)、M... 利用多接收电感耦合等离子体质谱仪测定Mg同位素比值时,样品溶液中的基质元素可影响Mg同位素比值的准确测定。根据白云鄂博样品富含REE、Nb、Fe(REE质量分数可达10%、Nb质量分数可达0.1%)等元素的特性,本研究在评估测试溶液中Nd(REE)、Mn元素质量比对Mg同位素比值影响的基础上,建立了适用于富含REE、Nb、Fe等元素的特殊样品中Mg同位素的化学纯化方法。研究表明,当m(Nd)/m(Mg)>0.2、m(Mn)/m(Mg)>0.2时,REE和Mn的存在明显影响Mg同位素测定值的准确性,应予以去除。所建纯化方法首先是利用AG MP-1阴离子交换树脂,以10mol/L HCl+0.001%H2O2溶液为上样介质和淋洗液,接取前2.5mL淋洗液,去除样品中Fe、Mn等杂质元素;然后利用AG50W-X12阳离子交换树脂,以2mol/L HCl为上样介质和淋洗液,去除REE、Nb等杂质元素。所建方法满足多接收器等离子体质谱进行高REE-Nb-Fe-Mn样品中Mg同位素测定的要求。 展开更多
关键词 基质效应 分离纯化 MG同位素 ree-Nb-Fe-Mn样品 同位素 白云鄂博
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白云鄂博REE-Nb-Fe稀土矿赋矿岩系建造研究评述 被引量:12
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作者 费红彩 肖荣阁 王安建 《地质学报》 EI CAS CSCD 北大核心 2012年第5期757-766,共10页
白云鄂博特大型铌、稀土、铁矿床,由于其矿物组成的多样性、地质构造的复杂性、成矿的多期性使之成为一类典型稀土矿床,成为研究稀土矿的天然实验室。尽管已有60多年的开采及研究历史,但其含铁及稀土的矿床建造机制仍具争议。本文通过... 白云鄂博特大型铌、稀土、铁矿床,由于其矿物组成的多样性、地质构造的复杂性、成矿的多期性使之成为一类典型稀土矿床,成为研究稀土矿的天然实验室。尽管已有60多年的开采及研究历史,但其含铁及稀土的矿床建造机制仍具争议。本文通过搜集、整理国内外近几年来发表的有关赋矿岩性(白云岩、富钾板岩、富钠岩石及碳酸岩脉)的研究成果,结合笔者的认识,对各种不同观点进行了对比分析和总结,最终提出了白云鄂博碱性碳酸岩-热水沉积岩系的观点,为白云鄂博稀土矿的研究提供一定的参考价值。 展开更多
关键词 容矿岩石 稀土矿 水成与火成 成因机制 白云鄂博
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The giant Bayan Obo REE-Nb-Fe deposit,China:Controversy and ore genesis 被引量:55
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作者 Hong-Rui Fan Kui-Feng Yang +2 位作者 Fang-Fang Hu Shang Liu Kai-Yi Wang 《Geoscience Frontiers》 SCIE CAS CSCD 2016年第3期335-344,共10页
Bayan Obo ore deposit is the largest rare-earth element(REE) resource,and the second largest niobium(Nb) resource in the world.Due to the complicated element/mineral compositions and involving several geological e... Bayan Obo ore deposit is the largest rare-earth element(REE) resource,and the second largest niobium(Nb) resource in the world.Due to the complicated element/mineral compositions and involving several geological events,the REE enrichment mechanism and genesis of this giant deposit still remains intense debated.The deposit is hosted in the massive dolomite,and nearly one hundred carbonatite dykes occur in the vicinity of the deposit.The carbonatite dykes can be divided into three types from early to late:dolomite,co-existing dolomite-calcite and calcite type,corresponding to different evolutionary stages of carbonatite magmatism based on the REE and trace element data.The latter always has higher REE content.The origin of the ore-hosting dolomite at Bayan Obo has been addressed in various models,ranging from a normal sedimentary carbonate rocks to volcano-sedimentary sequence,and a large carbonatitic intrusion.More geochemical evidences show that the coarse-grained dolomite represents a Mesoproterozoic carbonatite pluton and the fine-grained dolomite resulted from the extensive REE mineralization and modification of the coarse-grained variety.The ore bodies,distributed along an E-W striking belt,occur as large lenses and underwent more intense fluoritization and fenitization.The first episode mineralization is characterized by disseminated mineralization in the dolomite.The second or main-episode is banded and/or massive mineralization,cut by the third episode consisting of aegirinerich veins.Various dating methods gave different mineralization ages at Bayan Obo,resulting in long and hot debates.Compilation of available data suggests that the mineralization is rather variable with two peaks at~1400 and 440 Ma.The early mineralization peak closes in time to the intrusion of the carbonatite dykes.A significant thermal event at ca.440 Ma resulted in the formation of late-stage veins with coarse crystals of REE minerals.Fluids involving in the REE-Nb-Fe mineralization at Bayan Obo might be REE-F-C02-NaCI-H20 system.The presence of REE-carbonates as an abundant solid in the ores shows that the original ore-forming fluids are very rich in REE,and therefore,have the potential to produce economic REE ores at Bayan Obo.the Bayan Obo deposit is a product of mantle-derived carbonatitic magmatism at ca.1400 Ma,which was likely related to the breakup of Columbia.Some remobilization of REE occurred due to subduction of the Palaeo-Asian oceanic plate during the Silurian,forming weak vein-like mineralization. 展开更多
关键词 GEOCHEMISTRY GEOCHRONOLOGY CARBONATITE DOLOMITE Bayan Obo ree-Nb-Fe deposit
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Mineralogical and Petrographic Characteristics of Indium and REE-Bearing Accessory Phases in the Kymi Granite Stock, Southern Finland 被引量:1
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作者 Thair Al-Ani Timo Ahtola +1 位作者 Janne Kuusela Nadhir Al-Ansari 《Natural Resources》 2018年第2期23-41,共19页
The Wiborg rapakivi batholith (1.64 Ga) in southeastern Finland with documented occurrences of REE, indium and Zn-Cu-Pb sulphide mineralization was studied. Hydrothermal greisen and quartz vein type Fe-Sn and Zn-Cu-Pb... The Wiborg rapakivi batholith (1.64 Ga) in southeastern Finland with documented occurrences of REE, indium and Zn-Cu-Pb sulphide mineralization was studied. Hydrothermal greisen and quartz vein type Fe-Sn and Zn-Cu-Pb are found in the Kymi granite stock as intrusions. They are enriched with indium and rare earth elements, with roquesite (CuInS2) being a major indium- carrier, whereas monazite (Ce), allanite (Ce), bastn&#228;esite (Ce), xenotime-(Y) and thorite are the main REE carriers. Combination of optical and field emission scanning electron microscopy (FE-SEM) and electron probe microanalysis (EPMA) were used to study the indium and REE-bearing mineral assemblages. EPMA of roquesite found in galena had a composition of 26.16% S, 0.02% Fe, 25.06% Cu, 0.03% Zn, 1.06% As, 0.31% Sb and 47.14% In. Substitution reaction Pb2+S2-Cu+In3+S2- is the cause of the incorporation of indium in the galena structure. The majority of the LREE are carried by monazite, bastn&#228;esite and allanite, and the HREE by xenotime and zircon. There is a partial solid solution between monazite and xenotime with minor or trace amounts of LREE in xenotime grains (6.0 wt%). LREE (>95 mol% LREE) and less than 5 mol% HREE + Y reflects the enrichment of chondrite-normalized REE of the monazite grains of the Kymi granite stock. The xenotime grains (small and irregular) main composition contains 71 - 76 mol% YPO4, 16 - 27 mol% HREE, and 6 - 8 mol% LREE. It is believed that indium and REE-mineralization presence is due to the combination of magmatic and postmagmatic processes, particularly at later stages by fluid fractionation. 展开更多
关键词 INDIUM Roquesite ree-Minerals Kymi STOCK FINLAND
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不可逆分析法研究受磁偶极子影响的Ree-Eyring纳米流体流动多相催化作用
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作者 Seemab BASHIR Muhammad RAMZAN +1 位作者 Seifedine KADRY C Ahamed SALEEL 《Journal of Central South University》 SCIE EI CAS CSCD 2023年第7期2324-2339,共16页
Ree-Eyring流体是一种非牛顿流体,具有屈服应力和剪切稀化的特点,比如乳剂、浆体和聚合物溶液。根据Ree-Eyring流体的特性,通过考虑不均匀的产热/吸收效应和黏性耗散效应,以及分析传热现象来研究磁偶极子作用下表面拉伸纳米流体的流动... Ree-Eyring流体是一种非牛顿流体,具有屈服应力和剪切稀化的特点,比如乳剂、浆体和聚合物溶液。根据Ree-Eyring流体的特性,通过考虑不均匀的产热/吸收效应和黏性耗散效应,以及分析传热现象来研究磁偶极子作用下表面拉伸纳米流体的流动行为。所建立模型考虑了对流条件下边界表面的熵产生,将偏微分方程组(PDEs)充分变换转换为耦合常微分方程组(ODEs),采用MATLAB bvp4c法进行数值计算,并以图表形式显示计算结果。结果表明,随着Brinkman数的变化,不可逆性产生率激增。此外,当热泳参数最小化时,边界附近的温度降低,而在远离边界处温度上升。表面催化参数减弱了溶质的分布,模型得到了验证。 展开更多
关键词 ree-Eyring纳米流体 磁偶极子 多相催化 熵产生
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Mineral Chemistry of Scheelite as An Indicator of Multi-stage Fluid Evolution Associated with the Riviera W-REE-Mo Deposit South Africa
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作者 Abraham Rozendaal Rene Heyn 《矿物学报》 CAS CSCD 北大核心 2013年第S1期3-3,共1页
The Neoproterozoic Riviera W-REE-Mo deposit is one of the largest unmined tungsten resources in the world and is associated with pervasively altered A-type granites of the Neoproterozoic Cape Granite Suite Western Cap... The Neoproterozoic Riviera W-REE-Mo deposit is one of the largest unmined tungsten resources in the world and is associated with pervasively altered A-type granites of the Neoproterozoic Cape Granite Suite Western Cape, South Africa. The present study investigated the mineral chemistry of scheelite, the principal ore mineral with the aim to record the variation of solid solution molybdenum for geometallurgical purposes and also as an indicator of changing redox conditions of the mineralizing hydrothermal fluids. Methodology included UV-fluorescence studies and micro-analyses by LA-ICP-MS. Results have shown that at least four phases of scheelite are hosted by the endoskarn zone, potassic alteration zone and various quartz-carbonate veins. This reflects hydrothermal fluid evolution from early stage reduced to late stage, vein associated and more oxidized. The molybdenum content of the dominant early phase scheelite is low and renders the deposit amenable to low penalty mineral recovery. 展开更多
关键词 mineral chemistry MULTI-STAGE fluid evolution SCHEELITE the Riviera W-ree-Mo DEPOSIT
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New Formulas for the Mayer and Ree-Hoover Weights of Infinite Families of Graphs
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作者 Amel Kaouche 《World Journal of Engineering and Technology》 2019年第2期283-292,共10页
The virial expansion, in statistical mechanics, makes use of the sums of the Mayer weight of all 2-connected graphs on n vertices. We study the Second Mayer weight ωM(c) and the Ree-Hoover weight ωRH(c) of a 2-conne... The virial expansion, in statistical mechanics, makes use of the sums of the Mayer weight of all 2-connected graphs on n vertices. We study the Second Mayer weight ωM(c) and the Ree-Hoover weight ωRH(c) of a 2-connected graph c which arise from the hard-core continuum gas in one dimension. These weights are computed using signed volumes of convex polytopes naturally associated with the graph c. In the present work, we use the method of graph homomorphisms, to give new formulas of Mayer and Ree-Hoover weights for special infinite families of 2-connected graphs. 展开更多
关键词 MAYER WEIGHT ree-Hoover WEIGHT Graph INVARIANTS VIRIAL Expansion
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Other Formulas for the Ree-Hoover and Mayer Weights of Families of 2-Connected Graphs
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作者 Amel Kaouche 《Journal of Applied Mathematics and Physics》 2019年第8期1800-1813,共14页
We study graph weights which naturally occur in Mayer’s theory and Ree-Hoover’s theory for the virial expansion in the context of an imperfect gas. We pay particular attention to the Mayer weight and Ree-Hoover weig... We study graph weights which naturally occur in Mayer’s theory and Ree-Hoover’s theory for the virial expansion in the context of an imperfect gas. We pay particular attention to the Mayer weight and Ree-Hoover weight of a 2-connected graph in the case of the hard-core continuum gas in one dimension. These weights are calculated from signed volumes of convex polytopes associated with the graph. In the present paper, we use the method of graph homomorphisms, to develop other explicit formulas of Mayer weights and Ree-Hoover weights for infinite families of 2-connected graphs. 展开更多
关键词 Combinatorial MAYER WEIGHT Statistical Mechanics ree-Hoover WEIGHT Graph Invariants VIRIAL Expansion
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Analysis on REE geochemical characteristics of three types of REE-rich soil in Guizhou Province,China 被引量:13
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作者 陈吉艳 杨瑞东 《Journal of Rare Earths》 SCIE EI CAS CSCD 2010年第S1期517-522,共6页
The three kinds of soil formed by the weathering of the basalt in Yema village,Weining county of Guizhou province,the carbonate rock in Guiyang district and the phosphorite in the REE-bearing phosphate mining area in ... The three kinds of soil formed by the weathering of the basalt in Yema village,Weining county of Guizhou province,the carbonate rock in Guiyang district and the phosphorite in the REE-bearing phosphate mining area in Zhijin county of Guizhou province were all rich in REE.The contents of LREE in these three soil were higher than that of HREE,which was caused by the different properties of LREE and HREE complexes.Since light REE could be easily absorbed by kaolinite grains,LREE was fully enriched in the process of desorption,migration and re-absorption,which formed a typical LREE soil.The chondrite normalized distribution models of those three types of REE-enriched soil are basically similar,which belong to the right deviation type,namely,rich in light rare earth element but short of heavy rare earth element,and showing Ce negative anomalies.Eu showed intense negative anomalies in the REE in the soil formed by the weathering of the sedimentary parent rocks(such as carbonate rock and phosphorite),while no pronounced Eu anomaly was found in the REE in the soil formed by the weathering of volcanic rocks(such as basalt).It is clear that though there were intense migration and enrichment of REE during the weathering process of rocks,no obvious differentiation of REE occurred and some features of the parent rocks were retained.That is why REE is of value in analyzing the source of materials. 展开更多
关键词 SOIL REE (rare earth elements) Guizhou province
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Mineralogical, REE-geochemical and fluid inclusion studies on some uranium occurrences, Gabal Gattar, Northeastern Desert, Egypt 被引量:5
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作者 El-Feky M.G. 《Chinese Journal Of Geochemistry》 EI CAS 2011年第4期430-443,共14页
Altered granite occurrences (GII and GV) at Gabal (G.) Gattar are the most important mineralized rocks hosting U-mineralization in Egypt. This mineralized granite is affected by multi-stage hydrothermal alteration pro... Altered granite occurrences (GII and GV) at Gabal (G.) Gattar are the most important mineralized rocks hosting U-mineralization in Egypt. This mineralized granite is affected by multi-stage hydrothermal alteration proc-esses along brittle structures. This alteration comprises pre-ore alkali-metasomatism and ore-stage hydrothermal hematitization, silicification, kaolinitization, fluoritization, carbonatization and episyenitization. Autoradiographic examination indicates that primary uranium mineralization is present as massive or disseminated ores along tectonic fractures, interstitially in granular minerals, and as cements of breccias. Uraninite, pitchblende and coffinite are the main primary minerals, while uranophane and kasolite are the secondary ones. Galena, chalcopyrite, pyrrohtite and pyrite are the most abundant sulphides in association with uranium mineralizations. Hydrothermal alterations at the GII occurrence exhibit an increase in Ni, Cu, Zn, Pb, Mo, Nb, Rb beside HREEs and a decrease in Ba, Co, Sr, and V, while alterations at the GV occurrence show enrichment in Ni, Cu, Pb, Mo, Nb, Y, HREEs and depletion in Zn, Ba, Co, Rb, Sr, and V. Hydrothermal alteration during the late magmatic stage is also identified through the development of unusual REE patterns and fractionation of ratios like Zr/Hf and Y/Ho out of the CHARAC (Charge Radius Con-trolled) range. Non-chondritic Y/Ho ratio at GV is of larger value than chondritic one which may result from wa-ter-rock interaction or print from the encompassing sedimentary rocks. Fluid inclusion studies on quartz and fluorite revealed that temperatures of the mineralizing fluids range between 126 and 240℃ at pressure ≤0.5×108 Pa and give salinity values ranging between 1 wt% and 7.8 wt% NaCl equivalent. 展开更多
关键词 稀土元素地球化学 流体包裹体 铀矿化 矿物学 埃及 全球信息基础设施 东北部 沙漠
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内蒙古白云鄂博REE-Nb-Fe矿床成因问题研究
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作者 任伊苏 杨晓勇 《地质论评》 CAS CSCD 北大核心 2016年第B11期399-400,共2页
白云鄂博REE-Nb-Fe矿床是世界上已知的最大的稀土矿床,稀土储量48Mt(6wt%RE2O3),该矿床的成因和成矿年龄至今存在较大争议。本文观察白云鄂博矿床岩相学、矿物学特征,通过激光拉曼等技术鉴定重要的稀土矿物,电子探针测出白云鄂... 白云鄂博REE-Nb-Fe矿床是世界上已知的最大的稀土矿床,稀土储量48Mt(6wt%RE2O3),该矿床的成因和成矿年龄至今存在较大争议。本文观察白云鄂博矿床岩相学、矿物学特征,通过激光拉曼等技术鉴定重要的稀土矿物,电子探针测出白云鄂博矿床单矿物化学成分,结合前人同位素年代学数据,进一步探讨白云鄂博矿床的成因机制。 展开更多
关键词 稀土 白云鄂博 矿床成因 白云岩
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Carbon and Oxygen Isotopic Characteristics of REE-Fluorocarbonate Minerals and Their Genetic Implications, Bayan Obo Deposit,Inner Mongolia, China
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作者 方涛 裘愉卓 裘秀华 《Chinese Journal Of Geochemistry》 EI CAS 1996年第1期82-86,共5页
REE-fluorocarbonates as major REE minerals in the Bayan Obo deposit, the largestREE deposit in the world, were analyzed for their stable isotopic compositions. The δ13C andδ18O values of huanghoite, cebaite and bast... REE-fluorocarbonates as major REE minerals in the Bayan Obo deposit, the largestREE deposit in the world, were analyzed for their stable isotopic compositions. The δ13C andδ18O values of huanghoite, cebaite and bastnaesite from late-stage veins vary in the ranges of -7. 8 - - 4. 0‰ and 6. 7 - 9. 4‰ respectively. These data are relatively similar tO those ofbastnaesites from banded ores: δ13C - 5. 6 - - 5. 2‰ and δ18O 3. 6 - 5. 5‰ The REEfluorocarbonates from both late-stage veins and banded ores are characterized by lower δ13C andδ18O values, especially the δ18O values of bastnaesites from banded ores. Compared with them,the disseminated bastnaesits the dolomite-type ores possess rather high δ13C and δ18O values, i.e., - 2. 1 - - O. 4‰ and 8. 6 - 12. 9‰ respectively. The high values are typical of thesedimentary host dolomite rocks as well as of the dolomite-type ores. The carbon and oxygenisotopic characteristics of REE fluorocarbonate minerals provide new evidence for the hypothesison the origin of Bayan Obo deposit-epigenetic hydrothermal metasomatism. 展开更多
关键词 碳同位素 氧同位素 稀土元素 稀土矿床 铁矿床 中国内蒙古 钕矿床
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白云鄂博超大型REE-Fe-Nb矿床基底杂岩的锆石U-Pb年龄 被引量:27
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作者 王凯怡 范宏瑞 +1 位作者 谢奕汉 李惠民 《科学通报》 EI CAS CSCD 北大核心 2001年第16期1390-1394,共5页
对白云鄂博REE-Fe-Nb矿床矿区基底杂岩进行了锆石U-Pb年龄测定, 3个不同岩性样品的锆石测定数据点拟合直线与谐和线的上交点年龄为1948~1917 Ma, 表明白云鄂博矿区基底岩石为早元古代. 这些基底岩石并未构成某一特定沉积环境中的连续... 对白云鄂博REE-Fe-Nb矿床矿区基底杂岩进行了锆石U-Pb年龄测定, 3个不同岩性样品的锆石测定数据点拟合直线与谐和线的上交点年龄为1948~1917 Ma, 表明白云鄂博矿区基底岩石为早元古代. 这些基底岩石并未构成某一特定沉积环境中的连续地层剖面, 而岩性包括了英云闪长岩和正长岩以及少量副片麻岩等岩石, 建议用白云鄂博早元古代基底杂岩代替原先的“群". 展开更多
关键词 白云鄂博 基底杂岩 锆石U-PB年龄 ree-铁-镍矿床 早元古代 英云闪长岩 正长岩
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辽宁生铁岭稀土矿磁铁变粒岩年代学和地球化学特征 及其矿床成因类型初探
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作者 鞠楠 刘博 +7 位作者 马婧轩 辛后田 刘欣 伍月 施璐 樊金虎 杨高 曾维顺 《地学前缘》 北大核心 2026年第2期195-222,共28页
辽宁中部生铁岭稀土矿床产于古元古代胶辽吉构造带南辽河群内,有关其赋矿层位里尔峪组磁铁变粒岩研究程度偏低。本文对生铁岭稀土矿磁铁变粒岩开展岩相学、锆石和独居石U-Pb年代学和微量元素分析、全岩地球化学研究,以约束其岩石成因和... 辽宁中部生铁岭稀土矿床产于古元古代胶辽吉构造带南辽河群内,有关其赋矿层位里尔峪组磁铁变粒岩研究程度偏低。本文对生铁岭稀土矿磁铁变粒岩开展岩相学、锆石和独居石U-Pb年代学和微量元素分析、全岩地球化学研究,以约束其岩石成因和构造背景,并对其成因类型进行初步探讨。岩相学、背散射图像、电子探针和独居石激光剥蚀电感耦合等离子体质谱仪(laser ablation inductively coupled plasma mass spectrometry,LA-ICP-MS)原位微区微量元素研究结果显示,生铁岭稀土矿产于里尔峪组磁铁斜长变粒岩和含磁铁黑云斜长变粒岩中,主要稀土矿物为独居石、磷钇矿和磷灰石等。锆石和独居石U-Pb年代学结果表明,生铁岭磁铁变粒岩最大沉积年龄为1.95 Ga(岩浆成因碎屑锆石),变质作用发生在1.90~1.87 Ga(变质锆石和独居石)。磁铁变粒岩Th-Sc-Zr/10和Th-Co-Zr/10图解显示样品落入大陆岛弧区域,结合区域上已发表的辽河群变沉积岩资料,认为其原岩可能是俯冲作用下的岛弧相关沉积。磁铁变粒岩样品的变质作用时限(1.90~1.87 Ga)与区域上辽河群中普遍记录的区域变质作用时限一致,形成于胶辽吉构造带形成过程中的弧陆碰撞作用。综合磁铁变粒岩的稀土元素赋存特征、岩石成因和构造产出环境,推测其成因类型应为火山沉积变质型。该认识为辽宁地区寻找火山沉积变质型稀土矿提供了理论依据,产自辽河群里尔峪组的磁铁变粒岩是重要找矿标志。 展开更多
关键词 稀土矿床 变粒岩 里尔峪组 锆石和独居石U-Pb年龄 火山沉积变质型 生铁岭
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赣南石头坪重稀土矿床地质特征及稀土矿物年代学研究
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作者 张德富 王先广 +5 位作者 吕婷婷 孙观伟 龚良信 钟文 吴德海 张永文 《中国稀土学报》 北大核心 2026年第1期90-118,共29页
赣南离子吸附型稀土矿分布广泛,但如何快速圈定找矿靶区是尚未解决的难题。本文以石头坪重稀土矿床为研究对象,从母岩特征、风化壳特征及矿体特征等方面详细分析了离子吸附型稀土矿成矿地质特征。母岩ΣREE可达500×10^(-6),富含易... 赣南离子吸附型稀土矿分布广泛,但如何快速圈定找矿靶区是尚未解决的难题。本文以石头坪重稀土矿床为研究对象,从母岩特征、风化壳特征及矿体特征等方面详细分析了离子吸附型稀土矿成矿地质特征。母岩ΣREE可达500×10^(-6),富含易风化稀土矿物,风化壳以裸脚式为主,在风化壳剖面上稀土含量多成“弓背式”变化,矿体厚度山顶较厚,山脊次之,Y_(2)O_(3)含量与重稀土品位成正相关关系。总结了稀土成矿控矿因素,成矿母岩稀土含量高且含有较多的易风化稀土矿物是离子吸附型稀土矿成矿的先决条件,亚热带季风湿润气候及风化壳剥蚀速度和抬升速度相对平衡,为风化壳的形成及稀土元素在风化壳中的保存提供了良好条件。年代学发现锆石、独居石、氟碳铈矿、磷钇矿和铌铁矿年龄均为135 Ma,说明岩体形成时稀土矿物同时结晶。基于1∶20万水系沉积物地球化学数据,将La(镧)和Y(钇)作为轻稀土和重稀土特征元素,选取两种稀土元素高背景异常区域,开展“风化壳填图+快速分析+赣南钻+浅钻+实验测试”勘查技术组合,快速高效实现离子吸附型稀土矿床找矿突破。 展开更多
关键词 离子吸附型稀土矿 重稀土 U-PB定年 找矿预测 石头坪
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资源、环境和经济的协调度和不协调来源——基于CREE-EIE分析框架 被引量:37
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作者 黄建欢 杨晓光 胡毅 《中国工业经济》 CSSCI 北大核心 2014年第7期17-30,共14页
资源、环境和经济(REE)复杂系统的协调问题备受关注,但以往文献未深入其内部全面考察区域REE不协调的来源。本文提出CREE-EIE分析框架。利用绿色效率反映REE协调度,利用无效率反映不协调程度,从长期变迁视角考察了中国30个省份REE协调... 资源、环境和经济(REE)复杂系统的协调问题备受关注,但以往文献未深入其内部全面考察区域REE不协调的来源。本文提出CREE-EIE分析框架。利用绿色效率反映REE协调度,利用无效率反映不协调程度,从长期变迁视角考察了中国30个省份REE协调度并分析其不协调的来源。本文认为,各子系统具有内在的投入产出联系,从效率视角可以更深入地研究REE协调,深入到系统内部分析不协调来源才能找到薄弱环节并予以改善。实证分析表明:区域REE协调存在明显的路径依赖和两极分化等特征,经济发达并非协调的前提条件。REE不协调的首要来源是环境无效率,但资源无效率和经济无效率也不容忽视;环境无效率主要来源于烟尘和固体废物的产出无效率,两者贡献度合计超过60%,而碳排放无效率的贡献相对最低,仅约13.5%;资源无效率主要来源于耕地、人力资源和水的投入无效率,三者贡献度合计接近70%。为改善不协调,本文建议以REE协调为区域发展导向,实施绿色效率"锦标赛",进行倒逼式管理和差别化约束,重点治理烟尘等污染物的排放,优先提升土地利用率和劳动生产率。 展开更多
关键词 资源 环境和经济 协调度 绿色效率 效率-无效率分析框架
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