为改善亚微米级球形RDX的规模化制备技术,以提升其形貌均匀性、热稳定性及安全性,采用超声辅助气动浸渍重结晶(PIR)法制备亚微米球形RDX,通过SEM、XRD对其进行表征,研究了溶剂种类及喷头浸没深度对RDX形貌与粒径的影响,并对其热分解性...为改善亚微米级球形RDX的规模化制备技术,以提升其形貌均匀性、热稳定性及安全性,采用超声辅助气动浸渍重结晶(PIR)法制备亚微米球形RDX,通过SEM、XRD对其进行表征,研究了溶剂种类及喷头浸没深度对RDX形貌与粒径的影响,并对其热分解性能和机械感度进行了测试。结果表明:以二甲基亚砜(DMSO)为溶剂、去离子水为非溶剂、浸没深度为5 mm时,制备的RDX颗粒呈球形,表面光滑,平均粒径为0.675μm,与传统喷雾重结晶法相比,其粒度更小、分布更窄、颗粒更圆润;XRD分析显示,PIR处理未改变RDX的晶型;与原料RDX相比,PIR处理所得RDX的表观活化能提高了53.35 k J·mol^(-1),热爆炸临界温度降低了28.39℃,特性落高(H50)提高了29.9 cm,爆炸概率降低了35%。PIR法能够制备出形貌均匀、热稳定性较高且机械感度较低的亚微米球形RDX。展开更多
To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The ...To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The thermal properties of pristine RDX and its modified variants(RDX@PDA-Fe,RDX@PDA-Cu,RDX@PDA-Pb)were characterized using differential scanning calorimetry(DSC)and accelerating rate calorimetry(ARC).The impact sensitivity of these materials was evaluated via the characteristic drop-height method.The results demonstrate that PDA-metal metal coatings—formed through coordination between PDA and single metal ions(Fe^(3+),Cu^(2+),or Pb^(2+))—significantly enhance RDX′s thermal stability while attenuating its mechanical sensitivity.These coatings act as energy-absorbing barriers against external stimuli,effectively mitigating RDX′s sensitivity.Furthermore,they elevate RDX′s thermal stability by increasing its decomposition onset temperature and accelerating its decomposition kinetics.The monometallic coatings also catalyze RDX′s thermal decomposition and combustion,with Cu and Pb exhibiting particularly distinct catalytic effects.展开更多
The desensitization of nitramine explosives while maintaining energetic performance is challenging.A highly efficient desensitizer is the key to solving the antinomy.This study focuses on using porous organic cages(PO...The desensitization of nitramine explosives while maintaining energetic performance is challenging.A highly efficient desensitizer is the key to solving the antinomy.This study focuses on using porous organic cages(POCs),specifically CC3 and RCC3,to desensitize RDX.By coating 0.1 wt%–5 wt%of POCs on RDX particles,a series of composite energetic materials were prepared.Characterization results show that POCs change the surface morphology of RDX,and there are interfacial interactions between them.The RDX@POCs composites exhibit enhanced stabilities in terms of heat,impact,friction,and electrostatic spark.For the RDX@RCC3-5%composite,the impact sensitivity(E_(IS)),friction sensitivity(E_(FS)),and electrostatic sensitivity(EES)were significantly reduced by 66.7%,68.8%,and 56.5%,respectively,while the detonation velocity decreased by merely 3.1%.These findings indicate that POCs,especially RCC3,are promising desensitizers for nitramine explosives,and their desensitization mechanisms likely involve barrier and buffering effects.The distinct desensitization behavior of RDX@RCC3 highlights the effectiveness of POCs in reducing the sensitivity of RDX without significantly compromising its energetic properties.展开更多
This study prepared a class of RDX-based composite microspheres(RAF)containing ADN and FKM2602.The reaction kinetics of RAF composite microspheres were effectively improved by maintaining the system's high energy ...This study prepared a class of RDX-based composite microspheres(RAF)containing ADN and FKM2602.The reaction kinetics of RAF composite microspheres were effectively improved by maintaining the system's high energy and safety performance.In the close packing state,when the heating rate is rapid,the thermal stability of RAF composite microspheres is better than that of RDX;the close packing state will reduce the degree of freedom of RDX and ADN reaction but will increase the degree of freedom of RAF composite microsphere reaction.The thermal conductivity of RAF composite microspheres is close to that of RDX.In the ignition experiment,the flame of RAF composite microspheres can be maintained without the external heat source.Regarding safety,the H50of RAF composite microspheres was 274.04%higher than that of RDX.The detonation velocity of RAF composite microspheres is slightly higher than that of raw material RDX.Overall,these findings highlight the effectiveness of ADN in enhancing the reaction kinetics of RDX-based composites.展开更多
In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal agin...In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.展开更多
RDX/Al mixtures are widely utilized in energetic materials,yet their hybrid dust generated during production and application poses potential explosion hazards.Moreover,the synergistic explosion mechanisms remain poorl...RDX/Al mixtures are widely utilized in energetic materials,yet their hybrid dust generated during production and application poses potential explosion hazards.Moreover,the synergistic explosion mechanisms remain poorly understood,particularly at varying dust concentrations.This study systematically investigates the effects of different aluminum powder mass percentages and dust concentrations(300 g/m^(3),600 g/m^(3),900 g/m^(3))on RDX dust explosion severity,flame propagation behavior,and gaseous products.The results indicate that the maximum explosion pressure peaks at 35%RDX,65%RDX,and 80%RDX at 300 g/m^(3),600 g/m^(3),and 900 g/m^(3),respectively.Concurrently,the time for the flame to propagate to the wall(t1)reaches minimum values of 34.8 ms,25.66 ms,and 23.93 ms.The maximum rate of pressure rise is observed for pure RDX at 900 g/m^(3).Aluminum powder enhances flame propagation velocity and combustion duration,as validated by the flame propagation system.Overall,the concentrations of carbon oxides(CO+CO_(2))decrease significantly with increasing aluminum mass percentage.At 20%RDX,the concentrations decreased by 51.64%,72.31%,and 79.55%compared to pure RDX at 300 g/m^(3),600 g/m^(3),and 900 g/m^(3),respectively.Notably,N_(2)O concentration only at 300 g/m^(3)showed such a trend.It rises first and then falls at 35%RDX at 600 g/m^(3)and 900 g/m^(3).These findings elucidate the synergistic explosion mechanisms and provide critical guidelines for safe production and handling.展开更多
Aluminum(Al)powder is widely applied in thermobaric explosives due to its high energy density and favorable reaction kinetics.However,the inert oxide layer(Al_(2)O_(3))on Al particles limits combustion reactivity and ...Aluminum(Al)powder is widely applied in thermobaric explosives due to its high energy density and favorable reaction kinetics.However,the inert oxide layer(Al_(2)O_(3))on Al particles limits combustion reactivity and energy efficiency.Fluoride-based surface modification has been developed as an effective approach to address this issue.Here,four classical fluoropolymers(F11,F14,PVDF,PTFE)are employed as coatings to prepare core-shell Al/Fluoropolymer.The combustion experimental results demonstrate that the core-shell Al/PTFE exhibits the highest flame propagation rate(52.88 mm·ms^(-1))and pressure output(109.02 k Pa)performance.Consequently,core-shell Al/PTFE is selected as a high-energy fuel to prepare RDX/Al/PTFE microspheres via the emulsion and solvent evaporation method,which can enhance the energy performance of RDX.The effects of the core-shell Al/PTFE ratio and RDX content on the combustion heat and pressure output are systematically investigated.The peak pressure reaches a maximum of 187.8 k Pa when the mass ratio of RDX,Al,and PTFE is 60:25:10.Additionally,RDX/Al/PTFE microspheres exhibit significantly higher laser-induced air shock velocities,detonation heat,and detonation pressure than those of pure RDX and RDX/Al.The mechanism underlying the enhanced reactivity and energetic performance is attributed to the ability of PTFE to etch the inert Al_(2)O_(3)shell on the surface of Al particles,thereby improving post-combustion reactions and significantly increasing the overall energy output of RDX explosives.This work offers a novel design strategy for high-energy structural thermobaric explosives for the practical applications.展开更多
文摘为改善亚微米级球形RDX的规模化制备技术,以提升其形貌均匀性、热稳定性及安全性,采用超声辅助气动浸渍重结晶(PIR)法制备亚微米球形RDX,通过SEM、XRD对其进行表征,研究了溶剂种类及喷头浸没深度对RDX形貌与粒径的影响,并对其热分解性能和机械感度进行了测试。结果表明:以二甲基亚砜(DMSO)为溶剂、去离子水为非溶剂、浸没深度为5 mm时,制备的RDX颗粒呈球形,表面光滑,平均粒径为0.675μm,与传统喷雾重结晶法相比,其粒度更小、分布更窄、颗粒更圆润;XRD分析显示,PIR处理未改变RDX的晶型;与原料RDX相比,PIR处理所得RDX的表观活化能提高了53.35 k J·mol^(-1),热爆炸临界温度降低了28.39℃,特性落高(H50)提高了29.9 cm,爆炸概率降低了35%。PIR法能够制备出形貌均匀、热稳定性较高且机械感度较低的亚微米球形RDX。
基金National Natural Science Foundation of China(No.22405249)Open Project of Key Laboratory of Rubber Research Institute,Chinese Academy of Tropical Agricultural Science in 2025(No.RRI-KLOF202402)。
文摘To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The thermal properties of pristine RDX and its modified variants(RDX@PDA-Fe,RDX@PDA-Cu,RDX@PDA-Pb)were characterized using differential scanning calorimetry(DSC)and accelerating rate calorimetry(ARC).The impact sensitivity of these materials was evaluated via the characteristic drop-height method.The results demonstrate that PDA-metal metal coatings—formed through coordination between PDA and single metal ions(Fe^(3+),Cu^(2+),or Pb^(2+))—significantly enhance RDX′s thermal stability while attenuating its mechanical sensitivity.These coatings act as energy-absorbing barriers against external stimuli,effectively mitigating RDX′s sensitivity.Furthermore,they elevate RDX′s thermal stability by increasing its decomposition onset temperature and accelerating its decomposition kinetics.The monometallic coatings also catalyze RDX′s thermal decomposition and combustion,with Cu and Pb exhibiting particularly distinct catalytic effects.
文摘The desensitization of nitramine explosives while maintaining energetic performance is challenging.A highly efficient desensitizer is the key to solving the antinomy.This study focuses on using porous organic cages(POCs),specifically CC3 and RCC3,to desensitize RDX.By coating 0.1 wt%–5 wt%of POCs on RDX particles,a series of composite energetic materials were prepared.Characterization results show that POCs change the surface morphology of RDX,and there are interfacial interactions between them.The RDX@POCs composites exhibit enhanced stabilities in terms of heat,impact,friction,and electrostatic spark.For the RDX@RCC3-5%composite,the impact sensitivity(E_(IS)),friction sensitivity(E_(FS)),and electrostatic sensitivity(EES)were significantly reduced by 66.7%,68.8%,and 56.5%,respectively,while the detonation velocity decreased by merely 3.1%.These findings indicate that POCs,especially RCC3,are promising desensitizers for nitramine explosives,and their desensitization mechanisms likely involve barrier and buffering effects.The distinct desensitization behavior of RDX@RCC3 highlights the effectiveness of POCs in reducing the sensitivity of RDX without significantly compromising its energetic properties.
基金supported by the Natural Science Foundation of Shanxi Province(Grant No.202203021221120)The Open Fund of MCRI-Shannxi Laboratory of Energetic Materials(Grant No.204-J-2024-2622)。
文摘This study prepared a class of RDX-based composite microspheres(RAF)containing ADN and FKM2602.The reaction kinetics of RAF composite microspheres were effectively improved by maintaining the system's high energy and safety performance.In the close packing state,when the heating rate is rapid,the thermal stability of RAF composite microspheres is better than that of RDX;the close packing state will reduce the degree of freedom of RDX and ADN reaction but will increase the degree of freedom of RAF composite microsphere reaction.The thermal conductivity of RAF composite microspheres is close to that of RDX.In the ignition experiment,the flame of RAF composite microspheres can be maintained without the external heat source.Regarding safety,the H50of RAF composite microspheres was 274.04%higher than that of RDX.The detonation velocity of RAF composite microspheres is slightly higher than that of raw material RDX.Overall,these findings highlight the effectiveness of ADN in enhancing the reaction kinetics of RDX-based composites.
基金supported by the National Key Laboratory of Energetic Materials, China (Grant No. 2023-LB-036-09).
文摘In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.
基金the financial support of the Shanxi Fire&Explosion-Proofing Safety Engineering and Technology Research Center,North University of China。
文摘RDX/Al mixtures are widely utilized in energetic materials,yet their hybrid dust generated during production and application poses potential explosion hazards.Moreover,the synergistic explosion mechanisms remain poorly understood,particularly at varying dust concentrations.This study systematically investigates the effects of different aluminum powder mass percentages and dust concentrations(300 g/m^(3),600 g/m^(3),900 g/m^(3))on RDX dust explosion severity,flame propagation behavior,and gaseous products.The results indicate that the maximum explosion pressure peaks at 35%RDX,65%RDX,and 80%RDX at 300 g/m^(3),600 g/m^(3),and 900 g/m^(3),respectively.Concurrently,the time for the flame to propagate to the wall(t1)reaches minimum values of 34.8 ms,25.66 ms,and 23.93 ms.The maximum rate of pressure rise is observed for pure RDX at 900 g/m^(3).Aluminum powder enhances flame propagation velocity and combustion duration,as validated by the flame propagation system.Overall,the concentrations of carbon oxides(CO+CO_(2))decrease significantly with increasing aluminum mass percentage.At 20%RDX,the concentrations decreased by 51.64%,72.31%,and 79.55%compared to pure RDX at 300 g/m^(3),600 g/m^(3),and 900 g/m^(3),respectively.Notably,N_(2)O concentration only at 300 g/m^(3)showed such a trend.It rises first and then falls at 35%RDX at 600 g/m^(3)and 900 g/m^(3).These findings elucidate the synergistic explosion mechanisms and provide critical guidelines for safe production and handling.
基金supported by the National Natural Science Foundation of China(Grant Nos.T2222027 and 12202416)。
文摘Aluminum(Al)powder is widely applied in thermobaric explosives due to its high energy density and favorable reaction kinetics.However,the inert oxide layer(Al_(2)O_(3))on Al particles limits combustion reactivity and energy efficiency.Fluoride-based surface modification has been developed as an effective approach to address this issue.Here,four classical fluoropolymers(F11,F14,PVDF,PTFE)are employed as coatings to prepare core-shell Al/Fluoropolymer.The combustion experimental results demonstrate that the core-shell Al/PTFE exhibits the highest flame propagation rate(52.88 mm·ms^(-1))and pressure output(109.02 k Pa)performance.Consequently,core-shell Al/PTFE is selected as a high-energy fuel to prepare RDX/Al/PTFE microspheres via the emulsion and solvent evaporation method,which can enhance the energy performance of RDX.The effects of the core-shell Al/PTFE ratio and RDX content on the combustion heat and pressure output are systematically investigated.The peak pressure reaches a maximum of 187.8 k Pa when the mass ratio of RDX,Al,and PTFE is 60:25:10.Additionally,RDX/Al/PTFE microspheres exhibit significantly higher laser-induced air shock velocities,detonation heat,and detonation pressure than those of pure RDX and RDX/Al.The mechanism underlying the enhanced reactivity and energetic performance is attributed to the ability of PTFE to etch the inert Al_(2)O_(3)shell on the surface of Al particles,thereby improving post-combustion reactions and significantly increasing the overall energy output of RDX explosives.This work offers a novel design strategy for high-energy structural thermobaric explosives for the practical applications.
