Efficient solar light harvesting is essential for high-performance photocatalysts.Here,Rigorous CoupledWave Analysis(RCWA)computational method is used to investigate and optimize the optical absorption of TiO_(2)-BiVO...Efficient solar light harvesting is essential for high-performance photocatalysts.Here,Rigorous CoupledWave Analysis(RCWA)computational method is used to investigate and optimize the optical absorption of TiO_(2)-BiVO_(4) inverse opal(IO)structures under varying light incidence angles and pore-filling medium(air or water).Simulations were validated against experimental reflectance data.They revealed that small-pore IOs strongly absorb in the UV-C and UV-B regions due to the slow photon effect,making them ideal for sterilization and water disinfection.Medium-and large-pore IOs benefit from additional slow photon effect at the 2nd order photonic band gap,enhancing absorption across both UV and visible regions.Medium-pore IOs are suited for indoor air treatment and water purification,while large-pore IOs with the highest photon flux enhancement enable solar-driven photocatalysis such as outdoor pollutant removal and hydrogen production.For all tested IO designs,the absorbed photon flux exceeds that of equivalent planar slabs,highlighting the advantage of photonic structuring for sustainable photocatalytic applications.展开更多
为提高长波红外偏振成像系统中偏振器件性能,本文通过分析光栅材料及结构参数对光栅偏振性能的影响,设计并优化了一种双层材料构成的亚波长光栅。该光栅为矩形形貌,光栅区由铝与硒化锌构成,两种材料的厚度分别为0.6μm和0.4μm,光栅周期...为提高长波红外偏振成像系统中偏振器件性能,本文通过分析光栅材料及结构参数对光栅偏振性能的影响,设计并优化了一种双层材料构成的亚波长光栅。该光栅为矩形形貌,光栅区由铝与硒化锌构成,两种材料的厚度分别为0.6μm和0.4μm,光栅周期1μm,占空比50%。利用严格耦合波理论分析并计算该结构光栅的衍射效率,7~15μm波段的光以0~60°入射后其0级横磁模透射率达到87.54%以上,消光比超过47 d B。该光栅在10.6μm的测试波长下,TM透射率高达90.80%且具有50 d B以上的消光比,相比槽深相同的单层铝光栅,偏振透过率明显提高。仿真结果显示,该光栅在整个宽长波红外波段具有良好的偏振性能。展开更多
基金supported by the FNRS-FRFC,the Walloon Region,and the University of Namur(Conventions No.2.5020.11,GEQ U.G006.15,1610468,RW/GEQ2016 et U.G011.22)funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska Curie grant agreement n°101034383。
文摘Efficient solar light harvesting is essential for high-performance photocatalysts.Here,Rigorous CoupledWave Analysis(RCWA)computational method is used to investigate and optimize the optical absorption of TiO_(2)-BiVO_(4) inverse opal(IO)structures under varying light incidence angles and pore-filling medium(air or water).Simulations were validated against experimental reflectance data.They revealed that small-pore IOs strongly absorb in the UV-C and UV-B regions due to the slow photon effect,making them ideal for sterilization and water disinfection.Medium-and large-pore IOs benefit from additional slow photon effect at the 2nd order photonic band gap,enhancing absorption across both UV and visible regions.Medium-pore IOs are suited for indoor air treatment and water purification,while large-pore IOs with the highest photon flux enhancement enable solar-driven photocatalysis such as outdoor pollutant removal and hydrogen production.For all tested IO designs,the absorbed photon flux exceeds that of equivalent planar slabs,highlighting the advantage of photonic structuring for sustainable photocatalytic applications.
文摘为提高长波红外偏振成像系统中偏振器件性能,本文通过分析光栅材料及结构参数对光栅偏振性能的影响,设计并优化了一种双层材料构成的亚波长光栅。该光栅为矩形形貌,光栅区由铝与硒化锌构成,两种材料的厚度分别为0.6μm和0.4μm,光栅周期1μm,占空比50%。利用严格耦合波理论分析并计算该结构光栅的衍射效率,7~15μm波段的光以0~60°入射后其0级横磁模透射率达到87.54%以上,消光比超过47 d B。该光栅在10.6μm的测试波长下,TM透射率高达90.80%且具有50 d B以上的消光比,相比槽深相同的单层铝光栅,偏振透过率明显提高。仿真结果显示,该光栅在整个宽长波红外波段具有良好的偏振性能。
