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新型非线性光学晶体RCa_4O(BO_3)_3(R=Gd,Y)的生长及性质研究
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作者 张树君 张吉果 +3 位作者 程振翔 周广勇 韩建儒 陈焕矗 《功能材料》 EI CAS CSCD 北大核心 2000年第2期194-195,共2页
本文首次报导了利用提拉方法、使用铂坩埚在大气气氛下生长出大尺寸、高质量的GdCa4O (BO3) 3(GCOB)晶体及YCa4O(BO3) 3(YCOB)晶体。通过对几种生长方向的比较 ,选择出〈0 10〉为最佳生长方向。本文对晶体的生长习性进行了研究 ,并初步... 本文首次报导了利用提拉方法、使用铂坩埚在大气气氛下生长出大尺寸、高质量的GdCa4O (BO3) 3(GCOB)晶体及YCa4O(BO3) 3(YCOB)晶体。通过对几种生长方向的比较 ,选择出〈0 10〉为最佳生长方向。本文对晶体的生长习性进行了研究 ,并初步讨论了孪晶界面处枝蔓生长的原因。通过测量晶体的透过谱 ,发现了其透过波段宽 ,在深紫外具有较高透过率。晶体具有较好的倍频性能。对 5mm长的GOCB晶体进行了倍频研究 ,得到了 2 6 .7%的倍频转换效率。GCOB晶体和YCOB晶体还可通过掺杂实现自倍频。 展开更多
关键词 rca4O(BO3)3 非线性光学晶体 提拉法生长
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RCa_2Mg_2(VO_4)_3(R=Li,K,Na)荧光粉的制备及发光性能研究 被引量:3
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作者 张文涛 田学敏 +1 位作者 王玉龙 龙剑平 《电子元件与材料》 CAS CSCD 2015年第11期31-34,43,共5页
采用高温固相法合成了RCa2Mg2(VO4)3(R=Li,K,Na)自激活系列荧光粉,并用X射线衍射仪和荧光分光光度计对合成样品的结构和发光性能进行了表征。结果表明:在750℃下煅烧得到的RCa2Mg2(VO4)3荧光粉具有较好的晶体结构。在331 nm的紫外光激发... 采用高温固相法合成了RCa2Mg2(VO4)3(R=Li,K,Na)自激活系列荧光粉,并用X射线衍射仪和荧光分光光度计对合成样品的结构和发光性能进行了表征。结果表明:在750℃下煅烧得到的RCa2Mg2(VO4)3荧光粉具有较好的晶体结构。在331 nm的紫外光激发下,RCa2Mg2(VO4)3荧光粉在491 nm处具有较强的宽峰发射,其中Na Ca2Mg2(VO4)3的发光强度最好。Li Ca2Mg2(VO4)3、KCa2Mg2(VO4)3、Na Ca2Mg2(VO4)3的色坐标分别为(0.245,0.392)、(0.265,0.425)、(0.211,0.326),位于蓝绿光区。Eu3+掺杂后,Na Ca2Mg2(VO4)3:Eu3+样品光谱图中620 nm处出现Eu3+的发射峰,有效促使Na Ca2Mg2(VO4)3色坐标从蓝绿区(0.211,0.326)移到近白光区(0.260,0.322)。 展开更多
关键词 高温固相法 RCa2Mg2(VO4)3 自激活 发光强度 色坐标 稀土掺杂
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Rainfall Variability under Present and Future Climate Scenarios Using the Rossby Center Bias-Corrected Regional Climate Model
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作者 Jane Wangui Mugo Franklin J. Opijah +2 位作者 Joshua Ngaina Faith Karanja Mary Mburu 《American Journal of Climate Change》 2020年第3期243-265,共23页
<p align="justify"> <span style="font-family:Verdana;">This study sought to determine the spatial and temporal variability of rainfall under past and future climate scenarios. The data ... <p align="justify"> <span style="font-family:Verdana;">This study sought to determine the spatial and temporal variability of rainfall under past and future climate scenarios. The data used comprised station-based monthly gridded rainfall data sourced from the Climate Research </span><span style="font-family:Verdana;">Unit (CRU) and monthly model outputs from the Fourth Edition of the Rossby Centre (RCA4) Regional Climate Model (RCM), which has scaled-down </span><span style="font-family:Verdana;">nine GCMs for Africa. Although the 9 Global Climate Models (GCMs) downscaled by the RCA4 model was not very good at simulating rainfall in Kenya, the ensemble of the 9 models performed better and could be used for further studies. The ensemble of the models was thus bias-corrected using the scaling method to reduce the error;lower values of bias and Normalized Root Mean Square Error (NRMSE) w</span></span><span style="font-family:Verdana;">ere</span><span style="font-family:'Minion Pro Capt','serif';"><span style="font-family:Verdana;"> recorded when compared to the uncorrected models. The bias-corrected ensemble was used to study the spatial and temporal behaviour of rainfall under baseline (1971 to 2000) and future RCP 4.5 and 8.5 scenarios (2021 to 2050). An insignificant trend was noted under the </span><span style="font-family:Verdana;">baseline condition during the March-May (MAM) and October-December</span> <span style="font-family:Verdana;">(OND) rainfall seasons. A positive significant trend at 5% level was noted</span><span style="font-family:Verdana;"> under RCP 4.5 and 8.5 scenarios in some stations during both MAM and OND seasons. The increase in rainfall was attributed to global warming due to increased anthropogenic emissions of greenhouse gases. Results on the spatial variability of rainfall indicate the spatial extent of rainfall will increase under both RCP 4.5 and RCP 8.5 scenario when compared to the baseline;the increase is higher under the RCP 8.5 scenario. Overall rainfall was found to be highly variable in space and time, there is a need to invest in the early dissemination of weather forecasts to help farmers adequately prepare in case of unfavorable weather. Concerning the expected increase in rainfall in the future, policymakers need to consider the results of this study while preparing mitigation strategies against the effects of changing rainfall patterns.</span></span> </p> 展开更多
关键词 CORDEX Climate Change Bias Correction ENSEMBLE RAINFALL Kenya rca4
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Assessing the Skills of Rossby Centre Regional Climate Model in Simulating Observed Rainfall over Rwanda
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作者 Janet Umuhoza Lin Chen Lucia Mumo 《Atmospheric and Climate Sciences》 2021年第3期398-418,共21页
Rainfall over Rwanda is highly variable both in space and time. This variability leads to chronic food insecurity due to the overdependence of the economy on rain-fed agriculture systems. This study aims to evaluate t... Rainfall over Rwanda is highly variable both in space and time. This variability leads to chronic food insecurity due to the overdependence of the economy on rain-fed agriculture systems. This study aims to evaluate the skills of Rossby Centre Regional Climate Model (RCA4)</span><b> </b><span style="font-family:Verdana;">simulations driven by 10 GCMs for the period 1951-2005 using the Global Precipitation Climatology Centre (GPCC v8) as a reference. Different statistical and geospatial metrics were used to deduce the model’s skills in simulating seasonal and annual rainfall. Results show that the country received bimodal rainfall pattern;March-May (MAM) and September-December (SOND). The RCA4 models are inconsistent in simulating the MAM rainy peak. However, the models are coherent in simulating SOND seasonal peak despite exhibiting wet bias. The models show reasonable skills in simulating mean annual cycle than interannual variability as depicted by insignificant correlation and different signs of rainfall trend. Conclusively, the performance of RCA4 models in simulating observed rainfall characteristics over Rwanda is relatively weak. The performance of the models differs at various time scales. Nevertheless, the models can be ranked from the best performing to the least as;CSIRO, CanESM2, CNRM, GFDL, MIROC5, ENS, EC-Earth, HadGEM2, IPSL, MPI, and NorESM1. Ranking the performance of RCA4 historical models acts as a basis for future climate model’s selection depending on the purpose of the study. The findings of this study may help in devising appropriate climate adaptation measures to respond to the ongoing global warming for sustainable economic and livelihood development. Additionally, modelers may improve the model’s parametrization schemes and lessen the inherent chronic biases for a better presentation of the future. 展开更多
关键词 CORDEX rca4 RAINFALL Rwanda Simulation Bias
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