Accurate satellite data assimilation under all-sky conditions requires enhanced parameterization of scattering properties for frozen hydrometeors in clouds.This study aims to develop a nonspherical scattering look-up ...Accurate satellite data assimilation under all-sky conditions requires enhanced parameterization of scattering properties for frozen hydrometeors in clouds.This study aims to develop a nonspherical scattering look-up table that contains the optical properties of five hydrometeor types—rain,cloud water,cloud ice,graupel,and snow—for the Advanced Radiative Transfer Modeling System(ARMS)at frequencies below 220 GHz.The discrete dipole approximation(DDA)method is employed to compute the single-scattering properties of solid cloud particles,modeling these particles as aggregated roughened bullet rosettes.The bulk optical properties of the cloud layer are derived by integrating the singlescattering properties with a modified Gamma size distribution,specifically for distributions with 18 effective radii.The bulk phase function is then projected onto a series of generalized spherical functions,applying the delta-M method for truncation.The results indicate that simulations using the newly developed nonspherical scattering look-up table exhibit significant consistency with observations under deep convection conditions.In contrast,assuming spherical solid cloud particles leads to excessive scattering at mid-frequency channels and insufficient scattering at high-frequency channels.This improvement in radiative transfer simulation accuracy for cloudy conditions will better support the assimilation of allsky microwave observations into numerical weather prediction models.·Frozen cloud particles were modeled as aggregates of bullet rosettes and the optical properties at microwave range were computed by DDA.·A complete process and technical details for constructing a look-up table of ARMS are provided.·The ARMS simulations generally show agreement with observations of MWTS and MWHS under typhoon conditions using the new look-up table.展开更多
Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films t...Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films to enhance their cooling performance.In practical applications,thermal contact between the radiative cooling film and the object significantly influences the ultimate cooling performance.However,achieving optimal thermal contact has received limited attention.In this study,we propose and experimentally demonstrate a high-power,flexible,and magnetically attachable and detachable radiative cooling film.This film consists of polymer metasurface structures on a flexible magnetic layer.The monolithic design allows for convenient attachment to and detachment from steel or iron surfaces,ensuring optimal thermal contact with minimal thermal resistance and uniform temperature distribution.Our magnetic radiative cooling film exhibits superior cooling performance compared to non-magnetic alternatives.It can reduce the temperature of stainless-steel plates under sunlight by 15.2℃,which is 3.6℃ more than that achieved by non-magnetic radiative cooling films.The radiative cooling power can reach 259W·m^(-2) at a working temperature of 70℃.Unlike other commonly used attachment methods,such as thermal grease or one-off tape,our approach allows for detachment and reusability of the cooling film according to practical needs.This method offers great simplicity,flexibility,and cost-effectiveness,making it promising for broad applications,particularly on non-horizontal irregular surfaces previously considered challenging.展开更多
Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for...Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.展开更多
Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor...Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.展开更多
The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In thi...The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.展开更多
1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of glo...1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of global energy expenditure[1,2],necessitating urgent development of sustainable cooling alter-natives.Radiative cooling emerges as a passive thermal regu-lation strategy,operating without external energy input via direct infrared emission from materials to the environment[3].展开更多
Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spec...Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spectrum and high emissivity within the atmospheric transmission window.Unlike broadbandemissive daytime radiative cooling materials,spectrally selective daytime radiative cooling(SSDRC)materials exhibit predominant mid-infrared emission in the atmospheric transmission window.This selective mid-infrared emission suppresses thermal radiation absorption beyond the atmospheric transmission window range,thereby improving the net cooling power of daytime radiative cooling.This review elucidates the fundamental characteristics of SSDRC materials,including their molecular structures,micro-and nanostructures,optical properties,and thermodynamic principles.It also provides a comprehensive overview of the design and fabrication of SSDRC materials in three typical forms,i.e.,fibrous materials,membranes,and particle coatings,highlighting their respective cooling mechanisms and performance.Furthermore,the practical applications of SSDRC in personal thermal management,outdoor building cooling,and energy harvesting are summarized.Finally,the challenges and prospects are discussed to guide researchers in advancing SSDRC materials.展开更多
Radiative cooling is a sustainable cooling technology,which can show great application in energy saving buildings.Cooling coatings gained more and more interest due to their easy processability and low cost.However,de...Radiative cooling is a sustainable cooling technology,which can show great application in energy saving buildings.Cooling coatings gained more and more interest due to their easy processability and low cost.However,developing scalable,highly solar reflective,outdoor stable and various-substrate-adaptive cooling coatings is still a great challenge.Here,a refractive index mismatch strategy was proposed to develop an organic-inorganic hybrid photonic coating by using nanocellulose-induced self-assembly process in the solution process.By mixing Al2O3,Mica and MOF as well as dispersing with cellulose nanofiber,hierarchical nanostructured coating can be obtained.Due to large amount of air pores and multiple scattering interface formation,the resultant cooling coatings exhibited high and broad sunlight reflectance of 96%and high infrared emittance of 93%.Outdoor field test demonstrated organic-inorganic hybrid photonic coating(OHPC)can achieve a daytime subambient cooling of 8.5°C during direct sunlight in Nanjing.Meanwhile,it can be brushed on different kinds of substrate,such as wood,tile,plastic,ceramic,glass,etc.,highlighting its universality.Most importantly,OHPC exhibited surface hydrophobicity and ultraviolet(UV)resistance.Energy simulation indicated over 50%cooling energy can be saved if OHPC is coated on the roofs and walls of buildings in China.This work paves the way for developing scalable,environment-adaptive,and stable daytime cooling coatings for energy savings.展开更多
Metal halide perovskites have rapidly emerged as outstanding semiconductors for laser applications.Surface plasmon resonances of metals offer a platform for improving the perovskite lasing properties of metal halide p...Metal halide perovskites have rapidly emerged as outstanding semiconductors for laser applications.Surface plasmon resonances of metals offer a platform for improving the perovskite lasing properties of metal halide perovskites by accelerating radiative recombination.However,the constraint on degrees of freedom of perovskite-metal interactions in two dimensions keeps us from getting a full picture of plasmon-involved carrier dynamics and reaching the optimum perovskite lasing performance.Here we report a strategy of synthesizing quantitative coassemblies of perovskite and metal nanocrystals for studying the effect of surface plasmons on carrier dynamics in depth and exploring plasmon-enhanced perovskite lasing performance.Within the coassembly,each metal nanocrystal supports localized surface plasmon resonances capable of accelerating radiative recombination of all adjacent perovskite nanocrystals in three dimensions.The quantitative coassemblies disclose the evolution of radiative and nonradiative recombination processes in perovskite nanocrystals with the plasmon modes,identifying an optimal metal nanocrystal content for fulfilling the highest radiative efficiency in perovskite nanocrystals.By virtue of accelerated radiative recombination,the coassemblies of perovskite and metal nanocrystals allowed for the construction of microlaser arrays with enhanced performance including low thresholds and ultrafast outputs.This work fundamentally advances the perovskite-metal systems for plasmonically enhancing perovskite optoelectronic performance.展开更多
Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate ada...Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate adaptation,and sustainable technology development,with applications in personal thermal management,building temperature regulation,and aerospace engineering.However,radiative cooling performance is susceptible to environmental aging and special environmental conditions,limiting its applicability in extreme environments.Herein,a critical review of extreme environmental radiative cooling is presented,focusing on enhancing environmental durability and cooling efficiency.This review first introduces the design principles of heat exchange channels,which are tailored based on the thermal flow equilibrium to optimize radiative cooling capacity in various extreme environments.Subsequently,recent advancements in radiative cooling materials and micronano structures that align with these principles are systematically discussed,with a focus on their implementation in terrestrial dwelling environments,terrestrial extreme environments,aeronautical environments,and space environments.Moreover,this review evaluates the cooling effects and anti-environmental abilities of extreme radiative cooling devices.Lastly,key challenges hindering the development of radiative cooling devices for extreme environmental applications are outlined,and potential strategies to overcome these limitations are proposed,aiming to prompt their future commercialization.展开更多
Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performan...Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performance and scalable potential.However,the use of large amounts of organic solvents,the long cycle time,and the complexity of the preparation process have limited their development.Herein,we report a two-step cold-press sintering method for the preparation of a polymer radiative cooler,which is free of organic solvents.For demonstration,a polyvinylidene fluoride-hexafluoropropylene copolymer(PVDF-HFP)coating with a solar reflectance of 97.4%and an emissivity of 0.969 within the atmospheric window is prepared,which can achieve a sub-ambient cooling phenomenon with a temperature reduction of 4.8℃.Besides,the maximal radiative cooling power of 50.2 W/m^(2)is also obtained under sunlight.After the implementation of the proposed sintered PVDF-HFP coating in buildings,more than 10%of annual energy consumption can be saved in China.This work proposes a simple,environmentally friendly,and scalable processing method for the preparation of radiative cooling materials,facilitating the large-scale application of radiative cooling technology.展开更多
We consider the diffusion asymptotics of a coupled model arising in radiative transfer in a unit ball inℝ3 with one-speed velocity.The model consists of a steady kinetic equation satisfied by the specific intensity of...We consider the diffusion asymptotics of a coupled model arising in radiative transfer in a unit ball inℝ3 with one-speed velocity.The model consists of a steady kinetic equation satisfied by the specific intensity of radiation coupled with a nonhomogeneous elliptic equation satisfied by the material temperature.For the O(ϵ)boundary data of the intensity of the radiation and the suitable small boundary data of the temperature,we prove the existence,uniqueness and the nonequilibrium diffusion limit of solutions to the boundary value problem for the coupled model.展开更多
China is the world's largest carbon dioxide(CO_(2)) emitter and a major trading country. Both anthropogenic and natural factors play a critical role in its carbon budget. However,previous studies mostly focus on e...China is the world's largest carbon dioxide(CO_(2)) emitter and a major trading country. Both anthropogenic and natural factors play a critical role in its carbon budget. However,previous studies mostly focus on evaluating anthropogenic emissions or the natural carbon cycle separately, and few included trade-related(import and export) CO_(2) emissions and its contribution on global warming. Using the Carbon Tracker CT2019 assimilation dataset and China trade emissions from the Global Carbon Project, we found that the change trend of global CO_(2) flux had obvious spatial heterogeneity, which is mainly affected by anthropogenic CO_(2) flux. From 2000 to 2018, carbon emissions from fossil fuels in the world and in China all showed an obvious increasing trend, but the magnitude of the increase tended to slow down.In 2018, the radiative forcing(RF) caused by China's import and export trade was-0.0038 W m^(-2), and the RF caused by natural carbon budget was-0.0027 W m^(-2), offsetting 1.54% and 1.13% of the RF caused by fossil fuels that year, respectively. From 2000 to 2018, the contribution of China's carbon emission from fossil fuels to global RF was 11.32%. Considering China's import and export trade, the contribution of anthropogenic CO_(2) emission to global RF decreased to 9.50%. Furthermore, taking into account the offset of carbon sink from China's terrestrial ecosystems, the net contribution of China to global RF decreased to 7.63%. This study demonstrates that China's terrestrial ecosystem and import and export trade are all mitigating China's impact on global anthropogenic warming, and also confirms that during the research process on climate change, comprehensively considering the carbon budget from anthropogenic and natural carbon budgets is necessary to systematically understand the impacts of regional or national carbon budgets on global warming.展开更多
Near-field thermal radiation has received increased attention due to the performance of efficient energy conversion.In this study,the vacuum gap distance between two objects,separated by 1μm polystyrene particles,is ...Near-field thermal radiation has received increased attention due to the performance of efficient energy conversion.In this study,the vacuum gap distance between two objects,separated by 1μm polystyrene particles,is investigated.The entire experimental device is installed in a highly vacuumed environment to ensure that the radiative heat flux dominates the main mode of heat transfer.Compared with the measurement of near-field thermal radiation of flat glasses,it is found that coating SiC film on the hot side of optical glass can reduce heat transfer.However,through theoretical analysis,it is shown that there is an optimal thickness of SiC film of around 1μm.In addition,the experimental data and theoretical analysis results are consistent.The experiment demonstrates that the regulation of radiative heat flux can be achieved by coating.As the thickness of SiC film on the hot side increases,the radiative heat flux decreases.展开更多
In recent years,polarization remote sensing has garnered increasing attention,particularly within the realm of meteorology.To accurately simulate polarization information,the vector discrete-ordinate radiative transfe...In recent years,polarization remote sensing has garnered increasing attention,particularly within the realm of meteorology.To accurately simulate polarization information,the vector discrete-ordinate radiative transfer(VDISORT)model developed earlier by the community is further enhanced to an advanced version(referred to as A-VDISORT)through an improved ocean surface reflection.The Fresnel reflection matrix,which includes wind-generated roughness and shading effects,is served by an ocean bidirectional reflection distribution function(BRDF).The simulation from AVDISORT is compared with SCIATRAN for a Rayleigh scattering atmosphere,and the influence of water-leaving radiance is analyzed by the PSTAR(Polarized System for Transfer of Atmospheric Radiation) model.For GaoFen-5 Directional Polarimetric Camera(DPC) observations with polarization and multi-angle information,clear-sky pixel recognition over the ocean is first carried out.The DPC reflectance of clear conditions is normalized and compared with the observations.It is shown that A-VDISORT has a high simulation accuracy with a bias of –0.0053.The difference between simulation and observation exhibits a standard normal probability distribution function.展开更多
Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events a...Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events and large fluctuations in ambient temperature disrupt thermal comfort and negatively impact health,driving a growing dependence on cooling and heating energy sources.Consequently,efficient thermal management has become a central focus of energy research.Traditional thermal management systems consume substantial energy,further contributing to greenhouse gas emissions.In contrast,emergent radiant thermal management technologies that rely on renewable energy have been proposed as sustainable alternatives.However,achieving year-round thermal management without additional energy input remains a formidable challenge.Recently,dynamic radiative thermal management technologies have emerged as the most promising solution,offering the potential for energy-efficient adaptation across seasonal variations.This review systematically presents recent advancements in dynamic radiative thermal management,covering fundamental principles,switching mechanisms,primary materials,and application areas.Additionally,the key challenges hindering the broader adoption of dynamic radiative thermal management technologies are discussed.By highlighting their transformative potential,this review provides insights into the design and industrial scalability of these innovations,with the ultimate aim of promoting renewable energy integration in thermal management applications.展开更多
Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste p...Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste paper with one side decorated by a hydrophobic polymeric cooling coating consisting of micro/nanopore/particle hierarchical structure and the other side coated with hydrophilic MXene nanosheets for heating.The cooling surface demonstrates high solar reflectivity(96.3%)and infrared emissivity(95.5%),resulting in daytime/nighttime sub-ambient radiative cooling of 6℃/8℃with the theoretical cooling power of 100.6 and 138.5Wm^(−2),respectively.The heating surface exhibits high solar absorptivity(83.7%)and low infrared emissivity(15.2%),resulting in excellent radiative heating capacity for vehicle charging pile(~6.2℃)and solar heating performance.Impressively,the mechanical strength of Janus film increased greatly by 563%compared with that of pristine waste paper,which is helpful for its practical applications in various scenarios for switchable radiative thermal management through mechanical flipping.Energy-saving simulation results reveal that significant total energy savings of up to 32.4MJm^(−2) can be achieved annually(corresponding to the 12.4%saving ratio),showing the immense importance of reducing carbon footprint and promoting carbon neutrality.展开更多
During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation...During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation,leading to a substantial reduction in the subambient daytime radiative cooling performance.Conversely,radiative coolers featuring angular asymmetry and spectral selectivity effectively resolve the problem of thermal radiation directionality,successfully evading the interference caused by the ground-generated thermal radiation.This cooler overcomes the limitations posed by the angle of incident light,making it suitable for subambient daytime radiative cooling of vertical surfaces.Furthermore,by adjusting the structure of the cooler,the angular range of thermal radiation can be modulated,enabling the application of radiative cooling technology for intelligent temperature regulation of various inclined surfaces encountered in daily life.This innovative work makes a significant contribution to the development of subambient smart thermal interaction systems and opens up new possibilities for the practical application of radiative cooling.展开更多
Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building hea...Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.展开更多
Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo...Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB3900400)the National Natural Science Foundation of China(Grant Nos.U2142212 and 42361074)。
文摘Accurate satellite data assimilation under all-sky conditions requires enhanced parameterization of scattering properties for frozen hydrometeors in clouds.This study aims to develop a nonspherical scattering look-up table that contains the optical properties of five hydrometeor types—rain,cloud water,cloud ice,graupel,and snow—for the Advanced Radiative Transfer Modeling System(ARMS)at frequencies below 220 GHz.The discrete dipole approximation(DDA)method is employed to compute the single-scattering properties of solid cloud particles,modeling these particles as aggregated roughened bullet rosettes.The bulk optical properties of the cloud layer are derived by integrating the singlescattering properties with a modified Gamma size distribution,specifically for distributions with 18 effective radii.The bulk phase function is then projected onto a series of generalized spherical functions,applying the delta-M method for truncation.The results indicate that simulations using the newly developed nonspherical scattering look-up table exhibit significant consistency with observations under deep convection conditions.In contrast,assuming spherical solid cloud particles leads to excessive scattering at mid-frequency channels and insufficient scattering at high-frequency channels.This improvement in radiative transfer simulation accuracy for cloudy conditions will better support the assimilation of allsky microwave observations into numerical weather prediction models.·Frozen cloud particles were modeled as aggregates of bullet rosettes and the optical properties at microwave range were computed by DDA.·A complete process and technical details for constructing a look-up table of ARMS are provided.·The ARMS simulations generally show agreement with observations of MWTS and MWHS under typhoon conditions using the new look-up table.
基金supported by the Australia Research Council through the Discovery Project scheme(DP190103186 and DP220100603)the Industrial Transformation Training Centres scheme(IC180100005)+5 种基金the Future Fellowship scheme(FT210100806)the Future Fellowship scheme(FT220100559)the Discovery Early Career Researcher Award scheme(DE230100383)the Shenzhen Science and Technology Program(GJHZ20240218113407015)the Natural Science Foundation of Shandong Province(ZR2021ME162)the Key Research and Development Program of Shandong Province,China(2022SFGC0501).
文摘Radiative cooling is an environmentally friendly,passive cooling technology that operates without energy consumption.Current research primarily focuses on optimizing the optical properties of radiative cooling films to enhance their cooling performance.In practical applications,thermal contact between the radiative cooling film and the object significantly influences the ultimate cooling performance.However,achieving optimal thermal contact has received limited attention.In this study,we propose and experimentally demonstrate a high-power,flexible,and magnetically attachable and detachable radiative cooling film.This film consists of polymer metasurface structures on a flexible magnetic layer.The monolithic design allows for convenient attachment to and detachment from steel or iron surfaces,ensuring optimal thermal contact with minimal thermal resistance and uniform temperature distribution.Our magnetic radiative cooling film exhibits superior cooling performance compared to non-magnetic alternatives.It can reduce the temperature of stainless-steel plates under sunlight by 15.2℃,which is 3.6℃ more than that achieved by non-magnetic radiative cooling films.The radiative cooling power can reach 259W·m^(-2) at a working temperature of 70℃.Unlike other commonly used attachment methods,such as thermal grease or one-off tape,our approach allows for detachment and reusability of the cooling film according to practical needs.This method offers great simplicity,flexibility,and cost-effectiveness,making it promising for broad applications,particularly on non-horizontal irregular surfaces previously considered challenging.
基金support from the Contract Research(“Development of Breathable Fabrics with Nano-Electrospun Membrane”,CityU ref.:9231419“Research and application of antibacterial and healing-promoting smart nanofiber dressing for children’s burn wounds”,CityU ref:PJ9240111)+1 种基金the National Natural Science Foundation of China(“Study of Multi-Responsive Shape Memory Polyurethane Nanocomposites Inspired by Natural Fibers”,Grant No.51673162)Startup Grant of CityU(“Laboratory of Wearable Materials for Healthcare”,Grant No.9380116).
文摘Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.
基金financially supported by Heilongjiang Postdoctoral Fund(Grant No.LBH-Z24057)Outstanding Master’s and Doctoral Thesis of Longjiang in the New Era(Grant No.LJYXL2023-076).
文摘Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.
基金supported by the National Natural Science Foundation of China(52372279,52103071,52203322,52473289,52303220)the Interdisciplinary Research Project for Young Teachers of USTB(Fundamental Research Funds for the Central Universities in China,FRF-IDRY-GD22-001)。
文摘The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field.In this study,a Janus window is proposed and prepared based on polymer-stabilized liquid-crystal films/thermochromic materials.It can achieve switchable front long-wave infrared emissivity(ε_(Front))and solar modulation ability(ΔT_(sol))through dynamic flipping,making it suitable for different seasonal energy-saving requirements.Outdoor experiments show that under daytime illumination,the indoor temperature decreases by 8℃,and the nighttime temperature drops by 5℃.MATLAB simulation calculations indicate that the daytime cooling power is 93 W m^(-2),while the nighttime cooling power reaches 142 W m^(-2).Interestingly,by modifying the conductive layer,it can effectively shield electromagnetic radiation(within the X-band frequency range(8.2-12.4)GHz).Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal,poly(N-isopropyl acrylamide),and normal glass when applied in different climate zones.This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.
基金the financial support from the National Key R&D Program of China(No.2020YFA0711500)the National Natural Science Foundation of China(Nos.52473215 and 52273248).
文摘1|Introduction Conventional cooling systems exhibit substantial electricity consumption and environmental detriments through contin-uous greenhouse gas emissions.Thermal management accounts for approximately 50%of global energy expenditure[1,2],necessitating urgent development of sustainable cooling alter-natives.Radiative cooling emerges as a passive thermal regu-lation strategy,operating without external energy input via direct infrared emission from materials to the environment[3].
基金supported by the National Natural Science Foundation of China(22308236)the China Postdoctoral Science Foundation(2023M742530,2024T170623)+2 种基金the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(23KJA430012)the National Natural Science Foundation of Jiangsu Province,China(BK20230501)the Opening Project of the Key Laboratory of Bionic Engineering(Ministry of Education),Jilin University(KF2023002).
文摘Daytime radiative cooling is an eco-friendly and passive cooling technology that operates without external energy input.Materials designed for this purpose are engineered to possess high reflectivity in the solar spectrum and high emissivity within the atmospheric transmission window.Unlike broadbandemissive daytime radiative cooling materials,spectrally selective daytime radiative cooling(SSDRC)materials exhibit predominant mid-infrared emission in the atmospheric transmission window.This selective mid-infrared emission suppresses thermal radiation absorption beyond the atmospheric transmission window range,thereby improving the net cooling power of daytime radiative cooling.This review elucidates the fundamental characteristics of SSDRC materials,including their molecular structures,micro-and nanostructures,optical properties,and thermodynamic principles.It also provides a comprehensive overview of the design and fabrication of SSDRC materials in three typical forms,i.e.,fibrous materials,membranes,and particle coatings,highlighting their respective cooling mechanisms and performance.Furthermore,the practical applications of SSDRC in personal thermal management,outdoor building cooling,and energy harvesting are summarized.Finally,the challenges and prospects are discussed to guide researchers in advancing SSDRC materials.
基金the Nanjing Forestry University,the Natural Science Foundation of Jiangsu Province(No.BK20230404)the Advanced Analysis and Testing Center of Nanjing Forestry University.
文摘Radiative cooling is a sustainable cooling technology,which can show great application in energy saving buildings.Cooling coatings gained more and more interest due to their easy processability and low cost.However,developing scalable,highly solar reflective,outdoor stable and various-substrate-adaptive cooling coatings is still a great challenge.Here,a refractive index mismatch strategy was proposed to develop an organic-inorganic hybrid photonic coating by using nanocellulose-induced self-assembly process in the solution process.By mixing Al2O3,Mica and MOF as well as dispersing with cellulose nanofiber,hierarchical nanostructured coating can be obtained.Due to large amount of air pores and multiple scattering interface formation,the resultant cooling coatings exhibited high and broad sunlight reflectance of 96%and high infrared emittance of 93%.Outdoor field test demonstrated organic-inorganic hybrid photonic coating(OHPC)can achieve a daytime subambient cooling of 8.5°C during direct sunlight in Nanjing.Meanwhile,it can be brushed on different kinds of substrate,such as wood,tile,plastic,ceramic,glass,etc.,highlighting its universality.Most importantly,OHPC exhibited surface hydrophobicity and ultraviolet(UV)resistance.Energy simulation indicated over 50%cooling energy can be saved if OHPC is coated on the roofs and walls of buildings in China.This work paves the way for developing scalable,environment-adaptive,and stable daytime cooling coatings for energy savings.
基金supported by the National Natural Science Foundation of China(Nos.52272186,22090023 and 22375207)Beijing Institute of Technology Research Fund Program for Young Scholars(No.XSQD-6120220081)
文摘Metal halide perovskites have rapidly emerged as outstanding semiconductors for laser applications.Surface plasmon resonances of metals offer a platform for improving the perovskite lasing properties of metal halide perovskites by accelerating radiative recombination.However,the constraint on degrees of freedom of perovskite-metal interactions in two dimensions keeps us from getting a full picture of plasmon-involved carrier dynamics and reaching the optimum perovskite lasing performance.Here we report a strategy of synthesizing quantitative coassemblies of perovskite and metal nanocrystals for studying the effect of surface plasmons on carrier dynamics in depth and exploring plasmon-enhanced perovskite lasing performance.Within the coassembly,each metal nanocrystal supports localized surface plasmon resonances capable of accelerating radiative recombination of all adjacent perovskite nanocrystals in three dimensions.The quantitative coassemblies disclose the evolution of radiative and nonradiative recombination processes in perovskite nanocrystals with the plasmon modes,identifying an optimal metal nanocrystal content for fulfilling the highest radiative efficiency in perovskite nanocrystals.By virtue of accelerated radiative recombination,the coassemblies of perovskite and metal nanocrystals allowed for the construction of microlaser arrays with enhanced performance including low thresholds and ultrafast outputs.This work fundamentally advances the perovskite-metal systems for plasmonically enhancing perovskite optoelectronic performance.
基金supported by the National Natural Science Foundation of China(52172120)Shanghai Science and Technology Development Funds(No.24CL2900500).
文摘Radiative cooling is a passive thermal management strategy that leverages the natural ability of materials to dissipate heat through infrared radiation.It has significant implications for energy efficiency,climate adaptation,and sustainable technology development,with applications in personal thermal management,building temperature regulation,and aerospace engineering.However,radiative cooling performance is susceptible to environmental aging and special environmental conditions,limiting its applicability in extreme environments.Herein,a critical review of extreme environmental radiative cooling is presented,focusing on enhancing environmental durability and cooling efficiency.This review first introduces the design principles of heat exchange channels,which are tailored based on the thermal flow equilibrium to optimize radiative cooling capacity in various extreme environments.Subsequently,recent advancements in radiative cooling materials and micronano structures that align with these principles are systematically discussed,with a focus on their implementation in terrestrial dwelling environments,terrestrial extreme environments,aeronautical environments,and space environments.Moreover,this review evaluates the cooling effects and anti-environmental abilities of extreme radiative cooling devices.Lastly,key challenges hindering the development of radiative cooling devices for extreme environmental applications are outlined,and potential strategies to overcome these limitations are proposed,aiming to prompt their future commercialization.
基金supported by the National Natural Science Foundation of China(NSFC 52130601 and 52106276)the Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)+1 种基金the University of Science and Technology of China-Southwest University of Science and Technology Counterpart Cooperation and Development Joint Fund(24LHJJ09)the USTC Center for Micro and Nanoscale Research and Fabrication。
文摘Passive daytime radiative cooling has great potential for energy conservation and sustainable development.Polymer-based radiative cooling materials have received much attention due to their excellent cooling performance and scalable potential.However,the use of large amounts of organic solvents,the long cycle time,and the complexity of the preparation process have limited their development.Herein,we report a two-step cold-press sintering method for the preparation of a polymer radiative cooler,which is free of organic solvents.For demonstration,a polyvinylidene fluoride-hexafluoropropylene copolymer(PVDF-HFP)coating with a solar reflectance of 97.4%and an emissivity of 0.969 within the atmospheric window is prepared,which can achieve a sub-ambient cooling phenomenon with a temperature reduction of 4.8℃.Besides,the maximal radiative cooling power of 50.2 W/m^(2)is also obtained under sunlight.After the implementation of the proposed sintered PVDF-HFP coating in buildings,more than 10%of annual energy consumption can be saved in China.This work proposes a simple,environmentally friendly,and scalable processing method for the preparation of radiative cooling materials,facilitating the large-scale application of radiative cooling technology.
基金Zhang’s research was supported by the NSFC(12271423,12071044)the Fundamental Research Funds for the Central Universities(xzy012022005)the Shaanxi Fundamental Science Research Project for Mathematics and Physics(23JSY026).
文摘We consider the diffusion asymptotics of a coupled model arising in radiative transfer in a unit ball inℝ3 with one-speed velocity.The model consists of a steady kinetic equation satisfied by the specific intensity of radiation coupled with a nonhomogeneous elliptic equation satisfied by the material temperature.For the O(ϵ)boundary data of the intensity of the radiation and the suitable small boundary data of the temperature,we prove the existence,uniqueness and the nonequilibrium diffusion limit of solutions to the boundary value problem for the coupled model.
基金National Natural Science Foundation of China,No.42071415National Key Research and Development Program of China,No.2021YFE0106700Outstanding Youth Foundation of Henan Natural Science Foundation,No.202300410049。
文摘China is the world's largest carbon dioxide(CO_(2)) emitter and a major trading country. Both anthropogenic and natural factors play a critical role in its carbon budget. However,previous studies mostly focus on evaluating anthropogenic emissions or the natural carbon cycle separately, and few included trade-related(import and export) CO_(2) emissions and its contribution on global warming. Using the Carbon Tracker CT2019 assimilation dataset and China trade emissions from the Global Carbon Project, we found that the change trend of global CO_(2) flux had obvious spatial heterogeneity, which is mainly affected by anthropogenic CO_(2) flux. From 2000 to 2018, carbon emissions from fossil fuels in the world and in China all showed an obvious increasing trend, but the magnitude of the increase tended to slow down.In 2018, the radiative forcing(RF) caused by China's import and export trade was-0.0038 W m^(-2), and the RF caused by natural carbon budget was-0.0027 W m^(-2), offsetting 1.54% and 1.13% of the RF caused by fossil fuels that year, respectively. From 2000 to 2018, the contribution of China's carbon emission from fossil fuels to global RF was 11.32%. Considering China's import and export trade, the contribution of anthropogenic CO_(2) emission to global RF decreased to 9.50%. Furthermore, taking into account the offset of carbon sink from China's terrestrial ecosystems, the net contribution of China to global RF decreased to 7.63%. This study demonstrates that China's terrestrial ecosystem and import and export trade are all mitigating China's impact on global anthropogenic warming, and also confirms that during the research process on climate change, comprehensively considering the carbon budget from anthropogenic and natural carbon budgets is necessary to systematically understand the impacts of regional or national carbon budgets on global warming.
文摘Near-field thermal radiation has received increased attention due to the performance of efficient energy conversion.In this study,the vacuum gap distance between two objects,separated by 1μm polystyrene particles,is investigated.The entire experimental device is installed in a highly vacuumed environment to ensure that the radiative heat flux dominates the main mode of heat transfer.Compared with the measurement of near-field thermal radiation of flat glasses,it is found that coating SiC film on the hot side of optical glass can reduce heat transfer.However,through theoretical analysis,it is shown that there is an optimal thickness of SiC film of around 1μm.In addition,the experimental data and theoretical analysis results are consistent.The experiment demonstrates that the regulation of radiative heat flux can be achieved by coating.As the thickness of SiC film on the hot side increases,the radiative heat flux decreases.
基金supported by the National Natural Science Foundation of China(Grant No.U2142212)National Key R&D Program of China(Grant No.2019QZKK,Qinghai Tibet KeKao)the National Natural Science Foundation of China(Grant No.U2242211)。
文摘In recent years,polarization remote sensing has garnered increasing attention,particularly within the realm of meteorology.To accurately simulate polarization information,the vector discrete-ordinate radiative transfer(VDISORT)model developed earlier by the community is further enhanced to an advanced version(referred to as A-VDISORT)through an improved ocean surface reflection.The Fresnel reflection matrix,which includes wind-generated roughness and shading effects,is served by an ocean bidirectional reflection distribution function(BRDF).The simulation from AVDISORT is compared with SCIATRAN for a Rayleigh scattering atmosphere,and the influence of water-leaving radiance is analyzed by the PSTAR(Polarized System for Transfer of Atmospheric Radiation) model.For GaoFen-5 Directional Polarimetric Camera(DPC) observations with polarization and multi-angle information,clear-sky pixel recognition over the ocean is first carried out.The DPC reflectance of clear conditions is normalized and compared with the observations.It is shown that A-VDISORT has a high simulation accuracy with a bias of –0.0053.The difference between simulation and observation exhibits a standard normal probability distribution function.
基金the Institute of Biomass & Functional Materials of Shaanxi University of Science and Technology for funding this research workfinancially supported by the National Natural Science Foundation of China (2207081675, 22278257, 22308209)+1 种基金the Key R&D Program of Shaanxi Province (2024SF-YBXM-586)the Project of Innovation Capability Support Program in Shaanxi Province (2024ZC-KJXX-005)
文摘Rapid population growth in recent decades has intensified both the global energy crisis and the challenges posed by climate change,including global warming.Currently,the increased frequency of extreme weather events and large fluctuations in ambient temperature disrupt thermal comfort and negatively impact health,driving a growing dependence on cooling and heating energy sources.Consequently,efficient thermal management has become a central focus of energy research.Traditional thermal management systems consume substantial energy,further contributing to greenhouse gas emissions.In contrast,emergent radiant thermal management technologies that rely on renewable energy have been proposed as sustainable alternatives.However,achieving year-round thermal management without additional energy input remains a formidable challenge.Recently,dynamic radiative thermal management technologies have emerged as the most promising solution,offering the potential for energy-efficient adaptation across seasonal variations.This review systematically presents recent advancements in dynamic radiative thermal management,covering fundamental principles,switching mechanisms,primary materials,and application areas.Additionally,the key challenges hindering the broader adoption of dynamic radiative thermal management technologies are discussed.By highlighting their transformative potential,this review provides insights into the design and industrial scalability of these innovations,with the ultimate aim of promoting renewable energy integration in thermal management applications.
基金National Natural Science Foundation of China,Grant/Award Number:52003248Henan Province Youth Health Science and Technology Innovation Talent Training Program,Grant/Award Number:YQRC2023007+1 种基金Henan Province Excellent Youth Science Fund,Grant/Award Number:242300421064Joint Fund Predominant Discipline Cultivation Project of Henan Province,Grant/Award Number:232301420036.
文摘Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis.Here,we reported a cost-effective,high-strength Janus film through surface optical engineering waste paper with one side decorated by a hydrophobic polymeric cooling coating consisting of micro/nanopore/particle hierarchical structure and the other side coated with hydrophilic MXene nanosheets for heating.The cooling surface demonstrates high solar reflectivity(96.3%)and infrared emissivity(95.5%),resulting in daytime/nighttime sub-ambient radiative cooling of 6℃/8℃with the theoretical cooling power of 100.6 and 138.5Wm^(−2),respectively.The heating surface exhibits high solar absorptivity(83.7%)and low infrared emissivity(15.2%),resulting in excellent radiative heating capacity for vehicle charging pile(~6.2℃)and solar heating performance.Impressively,the mechanical strength of Janus film increased greatly by 563%compared with that of pristine waste paper,which is helpful for its practical applications in various scenarios for switchable radiative thermal management through mechanical flipping.Energy-saving simulation results reveal that significant total energy savings of up to 32.4MJm^(−2) can be achieved annually(corresponding to the 12.4%saving ratio),showing the immense importance of reducing carbon footprint and promoting carbon neutrality.
基金supported by the National Natural Science Foundation of China(52473270 and T2422028)the China Postdoctoral Science Foundation(2024M763485)+1 种基金the National Key R&D Program of China(2022YFA1203304)the Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(start-up grant E1552102).
文摘During the daytime,conventional radiative coolers disregard the directionality of thermal radiation,thereby overlooking the upward radiation from the ground.This upward radiation enhances the outward thermal radiation,leading to a substantial reduction in the subambient daytime radiative cooling performance.Conversely,radiative coolers featuring angular asymmetry and spectral selectivity effectively resolve the problem of thermal radiation directionality,successfully evading the interference caused by the ground-generated thermal radiation.This cooler overcomes the limitations posed by the angle of incident light,making it suitable for subambient daytime radiative cooling of vertical surfaces.Furthermore,by adjusting the structure of the cooler,the angular range of thermal radiation can be modulated,enabling the application of radiative cooling technology for intelligent temperature regulation of various inclined surfaces encountered in daily life.This innovative work makes a significant contribution to the development of subambient smart thermal interaction systems and opens up new possibilities for the practical application of radiative cooling.
基金support from the Research Grants Council of the Hong Kong Special Administrative Region,China(PolyU152052/21E)Green Tech Fund of Hong Kong(Project No.:GTF202220106)+1 种基金Innovation and Technology Fund of the Hong Kong Special Administrative Region,China(ITP/018/21TP)PolyU Endowed Young Scholars Scheme(Project No.:84CC).
文摘Maintaining thermal comfort within the human body is crucial for optimal health and overall well-being.By merely broadening the setpoint of indoor temperatures,we could significantly slash energy usage in building heating,ventilation,and air-conditioning systems.In recent years,there has been a surge in advancements in personal thermal management(PTM),aiming to regulate heat and moisture transfer within our immediate surroundings,clothing,and skin.The advent of PTM is driven by the rapid development in nano/micro-materials and energy science and engineering.An emerging research area in PTM is personal radiative thermal management(PRTM),which demonstrates immense potential with its high radiative heat transfer efficiency and ease of regulation.However,it is less taken into account in traditional textiles,and there currently lies a gap in our knowledge and understanding of PRTM.In this review,we aim to present a thorough analysis of advanced textile materials and technologies for PRTM.Specifically,we will introduce and discuss the underlying radiation heat transfer mechanisms,fabrication methods of textiles,and various indoor/outdoor applications in light of their different regulation functionalities,including radiative cooling,radiative heating,and dual-mode thermoregulation.Furthermore,we will shine a light on the current hurdles,propose potential strategies,and delve into future technology trends for PRTM with an emphasis on functionalities and applications.
基金supported by the National Science Fund for Distinguished Young Scholars(22125804)the National Natural Science Foundation of China(21808110,22078155,and 21878149).
文摘Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption.
