[Objective] Liquid special fertilizer for drip irrigation of sugarcane was de- veloped and the fertilizer patterns were explored in the production to provide techni- cal support for fertigation production of modern ag...[Objective] Liquid special fertilizer for drip irrigation of sugarcane was de- veloped and the fertilizer patterns were explored in the production to provide techni- cal support for fertigation production of modern agriculture. [Method] ROC22 was selected as experimental material, two formulas of liquid special fertilizer for sugar- cane developed by the cooperation between Guangxi Academy of Agricultural Sci- ences and New Orientation （Guangxi） Chemical Industry Co.,Ltd. were selected, namely, balanced 21-21-21 ~ TE of Xinfangxiang and hyperkalemic 13-6-39-TE of Xinfangxiang. Taking conventional fertilization as the control （CK）, two modes of ap- plying base fertilizer at the earlier stage ＋ fertigation in the tillering stage and ferti- gation in the whole growth period were set. [Result] The two modes of fertilization had not significant effects on the emergence of sugarcane, but applying base fertil- izer at the earlier stage ＋ timely applying water soluble fertilizer in the tillering stage was conducive to the tillering of sugarcane. Harvest results showed that the effects of different treatments on plant height and yield were significant, in which the yield of sugarcane under the treatment of hyperkalemic water-soluble fertilizer increased by 13.04% compared with conventional treatment, and the income increased by 4 500 yuan/hm2, [Conclusion] Liquid special fertilizer for drip irrigation of sugarcane signifi- cantly promoted the growth of sugarcane, moreover, under the same condition, the effect of hyperkalemic water-soluble fertilizer was better.展开更多
A rapid, sensitive and specific ultra-high-performance liquid chromatography tandem mass spectrometry （UPLC-MS） method was developed for the analysis of tetracycline antibiotics, including tetracycline （TC）, oxyte...A rapid, sensitive and specific ultra-high-performance liquid chromatography tandem mass spectrometry （UPLC-MS） method was developed for the analysis of tetracycline antibiotics, including tetracycline （TC）, oxytetracycline （OTC）, chlortetracycline （CTC） and their 4-epimers （4-epiTCs） in agricultural soil fertilized with swine manure. Soil samples were extracted and cleaned-up with 10 mL EDTA-McIlvaine buffer solution （pH 4.0）, then cleaned-up and pre-concentrated using the Oasis MAX cartridge and then eluted with 1 mL solution by mixing formic acid, methanol and water at a ratio of 2：15：83 （v/v/v）. The purified samples were separated by an ACQUITY UPLC BEH C18 column using acetonitrile and water containing 0.1% formic acid mobile phase and detected by a single quadrupole MS. The limits of detection for the soil extraction method （LODsoil） ranged from 0.6-2.5 lag kg-~ with recoveries from 23.3-159.2%. Finally, the method was applied to an agricultural field in an area with intensive pig-fattening farming. Tetracyclines were detected in soil from 2.8 to 42.4 μg kg-1 soil. These results demonstrate that soil from swine farms can become severely contaminated with tetracycline antibiotics and their metabolites.展开更多
The enantiomer residues of metalaxyl, napropamide, triticonazole and metconazole were detected in soil by Qu EChERS-ultra performance liquid chromatography-tandem mass spectrometry（UPLC-MS/MS）. The soil sample was e...The enantiomer residues of metalaxyl, napropamide, triticonazole and metconazole were detected in soil by Qu EChERS-ultra performance liquid chromatography-tandem mass spectrometry（UPLC-MS/MS）. The soil sample was extracted with acetonitrile containing 1% acetic acid and purified using Qu ECh ERS method. Quantitative analysis for the enantiomers of these four chiral pesticides was performed in MS in multi-response monitoring（MRM） mode by external standard method. All enantiomers showed good linearity in the range of 0.5 to 50 μg/L. The average recoveries of enantiomers in soil were 81.74% to 105.79% with relative standard deviations（RSDs） from 3.69% to 7.86%. The method quantitative limit（MQL） was 5.3-30.3 ng/kg. The method can be used for rapid screening and determination of chiral pesticides in soil.展开更多
The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization ...The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization of three single-component NAPLs in a sandy soil, constant initial lumped mass transfer coefficient (λgN,0) canbe obtained if the relative saturation (ξ) between NAPL phase and gas phase is higher than a critical value (ξc), andthe lumped mass transfer coefficient decreases with ξ when ξ＜ξc. It is also shown that the lumped mass transfercoefficient can be increased by blending porous micro-particles into the sandy soil because of the increasing of theinterfacial area.展开更多
Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loos...Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loosely coupled liquid-gas-solid three-phase model, linking two numerical codes,TOUGH2/EOS3, which is used for water-air two-phase flow analysis, and FLAC^(3D), which is used for mechanical analysis, was established. The model was validated through a documented water drainage experiment over a sandy column and a comparison of the results with measured data and simulated results from other researchers. The proposed model was used to investigate the features of water-air two-phase flow and stress fields in an unsaturated soil slope during rainfall infiltration. The slope stability analysis was then performed based on the simulated water-air two-phase seepage and stress fields on a given slip surface. The results show that the safety factor for the given slip surface decreases first, then increases, and later decreases until the rainfall stops. Subsequently, a sudden rise occurs. After that, the safety factor decreases continually and reaches its lowest value, and then increases slowly to a steady value. The lowest value does not occur when the rainfall stops, indicating a delayed effect of the safety factor. The variations of the safety factor for the given slip surface are therefore caused by a combination of pore-air pressure, matric suction, normal stress, and net normal stress.展开更多
The study investigated using rice husk biochar(RHB)to immobilize TNT and RDX explosives in soil at demining sites in Amuru District,Uganda.RHB produced via pyrolysis at 550℃was applied at a rate of 5%w/w to soil samp...The study investigated using rice husk biochar(RHB)to immobilize TNT and RDX explosives in soil at demining sites in Amuru District,Uganda.RHB produced via pyrolysis at 550℃was applied at a rate of 5%w/w to soil samples spiked at 50μg·g^(−1)RDX or TNT.The Liquid chromatography-tandem mass spectrometer(LC-MS/MS)analysis showed that the RHB immobilized 56%-67%of RDX and 55%-69%of TNT.The biochar’s porous structure and surface functional groups facilitated the explosive adsorption,reducing bioavailability.This demonstrates RHB’s effectiveness as an environmentally friendly and cost-effective remediation strategy.展开更多
This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial...This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial neural network modeling techniques,the Authors interrogated a large database assembled from the existing research literature to assess the performance of twelve equation rules in predicting the undrained shear strength(s_(u))mobilized for remolded fine-grained soils at different values of liquidity index(I_(L))and water content ratio.Based on their analyses,the Authors proposed a simple and reportedly reliable correlation(i.e.,Eq.9 in their paper)for predicting s_(u) over the I_(L) range of 0.15 to 3.00.This article describes various shortcomings in the Authors’assembled database(including potentially anomalous data and covering an excessively wide I_(L) range in relation to routine geotechnical and transportation engineering applications)and their proposed s_(u)=f(I_(L))correlation.Contrary to the Authors’assertions,their proposed correlation is not reliable for fine-grained soils with consistencies in the general firm to stiff range(i.e.,for 0.15<I_(L)<0.40),increasingly overestimating s_(u) for reducing I_(L),and eventually predicting s_(u)→+∞for I_(L)→0.15+(while producing mathematically undefined s_(u) for I_(L)<0.15),thus rendering their correlation unconservative and potentially leading to unsafe geotechnical designs.Exponential or regular-power type s_(u)=f(I_(L))models are more s_(u)itable when developing correlations that are applicable over the full plastic range(of 0<I_(L)<1),thereby providing reasonably conservative s_(u) predictions for use in the preliminary design for routine geotechnical engineering applications.展开更多
The increasing use of petroleum-derived fuels over the last few decades has subsequently augmented the risk of spills in the environment. Soil pollution with petroleum hydrocarbons(principally caused by leaks in pipel...The increasing use of petroleum-derived fuels over the last few decades has subsequently augmented the risk of spills in the environment. Soil pollution with petroleum hydrocarbons(principally caused by leaks in pipelines and underground storage tanks) is one of the major sources of soil degradation. Once in soil, fuel hydrocarbons suffer from a wide variety of multiphase processes including transport(advection, diffusion, and dispersion) among and within phases(aqueous and non-aqueous liquid, gas, and soil solids), mass transfer among phases(volatilization, sorption, and solution), and other natural attenuation processes, such as biodegradation and plant uptake and metabolism. This review identifies and describes the major processes occurring in soil that have a significant influence on the environmental fate of petroleum hydrocarbons. The definition of the processes involved in pollutant migration and distribution in soil and the formulation of adequate equations using accurate parameters(e.g., diffusion coefficients, velocity of advective flows, and mass transfer coefficients) will allow prediction of the final fate of soil pollutants. In addition to transport and mass transfer processes,which are more widely studied, the incorporation of attenuation mechanisms driven by microorganisms and plants is essential to predict the final concentration of the pollutants in the whole multiphase scenario. This work underlines the importance of the determination of accurate parameters through the performance of laboratory and/or field-scale experiments to develop precise pollutant migration models.展开更多
Canopy effect refers to the phenomenon in which moisture accumulates underneath an impervious cover.A canopy effect can lead to full saturation of the soil underneath the impervious cover.A recent theoretical study se...Canopy effect refers to the phenomenon in which moisture accumulates underneath an impervious cover.A canopy effect can lead to full saturation of the soil underneath the impervious cover.A recent theoretical study separates the canopy effect into two types.The first one is caused by evaporation-condensation in unsaturated soils,while the second one is induced by freezing-enhanced vapour transfer in unsaturated soils.To validate experimentally these two types of canopy effect and to reveal their mechanisms,moisture-migration experiments were carried out,using a newly developed laboratory apparatus for unsaturated frozen soils.Six conditions were applied to the calcareous sand,with different initial water contents and boundary temperatures.The results show that water content in the upper portion of the sample increased under an upward temperature gradient,and the increment of water content was greater if the soil was subjected to freezing.For the freezing cases,the depth of the peak water content was in line with the freezing front.And the greater the initial water content,the more the water content accumulated at the freezing front.However,a lower cooling rate seemed to facilitate vapour migration.For the unfrozen cases,the water content in the upper portion of the sample also increased;and the increases became more apparent with a higher initial moisture content.The temperature gradient can also inhibit the vapour migration.A less steep temperature gradient always resulted in a more notable inhibition effect.Test results seem to verify the theory of the canopy effect.展开更多
High liquid limit soil generally adopted in expressway embankment construction of southern mountains, which often expresses some characteristics including high moisture content, high porosity ratio, low permeability, ...High liquid limit soil generally adopted in expressway embankment construction of southern mountains, which often expresses some characteristics including high moisture content, high porosity ratio, low permeability, high compressibility, certain disintegration, and so on. Spring soil phenomenon and inhomogeneous compaction have effects on the quality of embankment construction, just because the water in soil is difficult to evaporate. Based on the study of reinforcement mechanism for high liquid limit soil, in situ tests for dynamic compaction treatment in Yizhang-Fengtouling expressway embankment were developed. The reliable and economical dynamic compaction treatment methods and the construction technology for large range high liquid limit soil embankment in southern mountains expressway were discussed. In the process, convenient measurement methods were adopted to evaluate the treatment effects. The test results show that the dynamic compaction method has good treatment effects on the local red clay embankment. The embankment compaction degree is improved with compactness coming to 90% around tamping pits and compactness over 95% in tamping pits interior after tamping. The bearing capacity, the physical mechanic-property and the shear strength for soil are obviously improved, which are enhanced with cohesive strength increasing over 10 kPa and compression modulus increasing over 3 MPa.展开更多
Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)an...Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)and soil moisture(SM)conditions on a land surface energy and water simulation in the permafrost region in the Tibetan Plateau(TP)using the Community Land Model version 5.0(CLM5.0).The results indicate that the default initial schemes for ST and SM in CLM5.0 were simplistic,and inaccurately represented the soil characteristics of permafrost in the TP which led to underestimating ST during the freezing period while overestimating ST and underestimating SLW during the thawing period at the XDT site.Applying the long-term spin-up method to obtain initial soil conditions has only led to limited improvement in simulating soil hydrothermal and surface energy fluxes.The modified initial soil schemes proposed in this study comprehensively incorporate the characteristics of permafrost,which coexists with soil liquid water(SLW),and soil ice(SI)when the ST is below freezing temperature,effectively enhancing the accuracy of the simulated soil hydrothermal and surface energy fluxes.Consequently,the modified initial soil schemes greatly improved upon the results achieved through the long-term spin-up method.Three modified initial soil schemes experiments resulted in a 64%,88%,and 77%reduction in the average mean bias error(MBE)of ST,and a 13%,21%,and 19%reduction in the average root-mean-square error(RMSE)of SLW compared to the default simulation results.Also,the average MBE of net radiation was reduced by 7%,22%,and 21%.展开更多
The present study is inscribed within the framework of the geotechnical characterization of the soils of the Santchou plain, their classification for employment as pavement subgrade, various identification tests were ...The present study is inscribed within the framework of the geotechnical characterization of the soils of the Santchou plain, their classification for employment as pavement subgrade, various identification tests were carried out on the samples. The results obtained showed that with a wide range of different grain sizes, the studied soils showed low content in clay grains and dominance of either sand grains or silt grains, this can be explaining how most of these soil are poorly graded. According to the USDA textural classification, the grain size distribution of these soils makes them to be classified as Silty Loam types to Sandy Loam types. Despite of their organic matter content which is less than 10%, according to their respective methylene blue values, the soils studied along the section should be mainly loamy soil of medium plasticity to clayed soil, therefore showing a sensibility of its behavior to variation of water content. That last one is confirmed by the consistency parameters of these soils which show intermediate plasticity to highly plastic. Also, the bearing capacity proposed by these soils at their respective optimum dry densities is relatively small, although most of these experimental CBR values of the studied soils are more important than the ones prescribed by the AASHTO Classification system for A5, A6, and A7 types, and the French Highway Earthworks Manual Classifications system (GTR) for the corresponding A2 and A3 types.展开更多
The investigation of the long-term performance of solidified/stabilized （S/S） contaminated soils was carried out in a trial site in southeast UK. The soils were exposed to the maximum natural weathering for four yea...The investigation of the long-term performance of solidified/stabilized （S/S） contaminated soils was carried out in a trial site in southeast UK. The soils were exposed to the maximum natural weathering for four years and sampled at various depths in a controlled manner. The chemical properties （e.g., degree of carbonation （DOC）, pH, electrical conductivity （EC）） and physical properties （e.g., moisture content （MC）, liquid limit CLL）, plastic limit （PL）, plasticity index （PI）） of the samples untreated and treated with the traditional and accelerated carbonated S/S processes were analyzed. Their variations on the depths of the soils were also studied. The result showed that the broad geotechnical properties of the soils, manifested in their PIs, were related to the concentration of the water soluble ions and in particular the free calcium ions. The samples treated with the accelerated carbonation technology （ACT）, and the untreated samples contained limited number of free calcium ions in solutions and consequently interacted with waters in a similar way. Compared with the traditional cement-based S/S technology, e.g., treatment with ordinary portland cement （OPC） or EnvirOceM, ACT caused the increase of the PI of the treated soil and made it more stable during long-term weathering. The PI values for the four soils ascended according to the order： the EnvirOceM soil, the OPC soil, the ACT soil, and the untreated soil while their pH and EC values descended according to the same order.展开更多
Organochlorine pesticides and polychlorinated biphenyls are toxic, carcinogenic, and have a high potential for bioaccumulation. Due to their stability, they are still considered an environmental problem even though th...Organochlorine pesticides and polychlorinated biphenyls are toxic, carcinogenic, and have a high potential for bioaccumulation. Due to their stability, they are still considered an environmental problem even though the use of most of them has been phased out several decades ago. Soil is a matrix which can retain these contaminants to a great extent. This ability is often associated with the total organic carbon content (TOC). In order to judge the pollution status of soil and to make monitoring data more easily comparable a simple, yet robust extraction method is needed. Agitation solid-liquid-extraction is well suited for this purpose. However, the influence of TOC on the analyte recovery has to be known. For the presented study, 12 organochlorine pesticides and 7 polychlorinated biphenyls were spiked into four model soils with organic carbon contents between 1.6% - 13.3%. The matrices were extracted using solid-liquid extraction between 45 minutes and 16 hours. For comparison, all soils were also extracted using pressurised liquid extraction and Soxhlet extraction. After clean-up the extracts were measured using a gas chromatography-mass spectrometry (GC-MS) system. Statistical analysis of the results implied that the TOC content of the soils did not have significant influence on the extraction efficiency. A longer solid-liquid extraction time did not necessarily increase analyte recovery: Extraction for one hour resulted in 88% recovery while 16 hour extraction led to 89%. Thus, the efficiency of all the methods was comparable for all model soils. Additional investigations regarding GC liner performance highlighted the need for isotopically labelled standards during the analysis of thermolabile pesticides.展开更多
Determination of physical property of the soil helps in identification and classification of soil which includes analysis of particle size distribution, Atterberg limits, water content, specific gravity, phase determi...Determination of physical property of the soil helps in identification and classification of soil which includes analysis of particle size distribution, Atterberg limits, water content, specific gravity, phase determination and direct shear test. Water plays an important role in triggering landslides and slope failures. Increase of water content reduces the stability of slope. When the moisture content exceeds plastic limits, the slope begins to deform. Three soil samples are collected from the study area and the average bulk density, moisture content and specific gravity are 1.577, 37.032 and 2.434 respectively. Atterberg limit is the most distinctive properties of fine grained sediments and may be used to distinguish silts from clays. Plastic limits (WP), liquid limit (WL), shrinkage limit (WS) values of Nungbi Khunou are 26.236%, 48% and 9.4% respectively. Plasticity index (IP), consistency index (IC) and liquidity index (IL) value is 21.764%, 0.379%, and 60.623% respectively. From index properties value, the soil is highly plastic, stiff and semi-solid in nature. The soil sample falls under CI group in plasticity chart which indicates organic silt and clay soil with medium compressibility and plasticity. Phase determination and particle size distribution result in very high porosity and highly saturated soils which are well graded in nature. Slope and aspect map are prepared from DEM using ArcGIS. Slope is an important contributory factor to landslide, and slope reported from the sampling area indicates gentle slope. Aspect refers to the direction of the terrain faces which is influenced by component like vegetation, settlement, agriculture, precipitation, wind etc. Factor of safety (Fs) calculated from shear stress data is less than 1 indicating unstable slope. From the above finding, the study area may result in sudden and unpredictable failure due to volumetric changes in soil.展开更多
In a greenhouse experiment,the effects of soil microorganisms and extracts of Achnatherum inebrians on the seed germination and seedling growth of Elymus nutans were studied.The results showed that both the extracts f...In a greenhouse experiment,the effects of soil microorganisms and extracts of Achnatherum inebrians on the seed germination and seedling growth of Elymus nutans were studied.The results showed that both the extracts from aboveground and belowground parts of A.inebrians significantly inhibited the germination rate,germination potential,germination index,vigor index,seedling height,root length,and fresh weight of E.nutans,but increased malondialdehyde content,catalase,peroxidase and superoxide dismutase activity of E.nutans seedlings(p<0.05).The allelopathy of aqueous extracts of the aboveground parts of A.inebrians was stronger than that of the pre-cipitates.Aqueous extracts of the aboveground parts of A.inebrians decreased seed germination rate,germination potential,germination index,vigor index,seedling length,root length,and seedling fresh weight by 10.45%-74.63%,24.18%-32.50%,19.03%-73.36%,37.83%-88.41%,21.42%-53.14%,2.65%-40.21%,and 20.45%-61.36%,respectively,and malondialdehyde content,peroxidase,catalase,and superoxide dismutase activity increased by 8.09%-62.24%,27.83%-86.47%,22.90%-93.17%,and 11.15%-75.91%,respectively.The above indexes were higher in live soil than in sterilized soil.Soil microorganisms increased the allelopathy of A.inebrians.The seed germination rate,germination potential,germination index,vigor index,seedling length,and seedling fresh weight of E.nutans planted in live soil decreased by 8.22%-48.48%,10.00%-51.85%,8.19%-53.26%,16.43%-60.03%,12.91%-28.81%,and 9.09%-22.86%compared with sterilized soil,respectively.Malondialdehyde content,peroxidase,catalase,and superoxide dismutase activity of E.nutans planted in live soil increased by 53.91%-81.06%,15.71%-57.34%,33.33%-86.31%,and 9.78%-52.51%compared with sterilized soil,respectively.The existence of soil microorganisms enhanced the allelopathy of the secondary metabolites of A.inebrians.A combination of microorganisms and aqueous extracts from the aboveground parts of A.inebrians had the strongest allelopathic effect on E.nutans.展开更多
The AD 79 eruption of Somma-Vesuvius completely buried the ancient landscape around Pompeii (Italy) to some extent conserving the pre-AD 79 Roman paleosols of the Sarno River plain. To estimate potential post-burial s...The AD 79 eruption of Somma-Vesuvius completely buried the ancient landscape around Pompeii (Italy) to some extent conserving the pre-AD 79 Roman paleosols of the Sarno River plain. To estimate potential post-burial soil developments of these paleosols detailed soil liquid and solid phase analysis were carried out. Firstly, an in-situ soil hydrological monitoring was conducted within a pre-AD 79 paleosol in natural undisturbed stratification. The results show that soil water flow and nutrient transport from the overlying volcanic deposits into the pre-AD 79 paleosol take place. Secondly, to estimate their influence on the paleosol’s mineral soil properties, the solid phase of four pre-AD 79 paleosols and associated modern unburied soils were analysed and compared. By combining the data from the soil liquid and solid phase analysis, potential post-burial changes in the paleosols were estimated. Finally, a rise of the mean groundwater table was determined since AD 79. This distinguishes the Sarno River plain into two different zones of post-burial soil developments: 1) lower altitudes where formerly terrestrial paleosols are now influenced by groundwater dynamics and 2) higher altitudes where the paleosols are still part of the vadose zone and rather influenced by infiltration water or interflow. Thus, the mechanism of potential post-burial soil development being active in the pre-AD 79 paleosols is not uniform for the entire Sarno River plain but strongly depends on the paleotopographic situation.展开更多
基金Supported by the Special Fund of Modern Agricultural Technology System Construction(CARS-20-3-5)the Project of Youth Fund of Guangxi Academy of Agricultural Sciences(Gui Nong Ke 2014YQ33)the Special Scientific Research Project of Guangxi Academy of Agricultural Sciences-Key Project Fund(Gui Nong Ke 2013YZ12)~~
文摘[Objective] Liquid special fertilizer for drip irrigation of sugarcane was de- veloped and the fertilizer patterns were explored in the production to provide techni- cal support for fertigation production of modern agriculture. [Method] ROC22 was selected as experimental material, two formulas of liquid special fertilizer for sugar- cane developed by the cooperation between Guangxi Academy of Agricultural Sci- ences and New Orientation （Guangxi） Chemical Industry Co.,Ltd. were selected, namely, balanced 21-21-21 ~ TE of Xinfangxiang and hyperkalemic 13-6-39-TE of Xinfangxiang. Taking conventional fertilization as the control （CK）, two modes of ap- plying base fertilizer at the earlier stage ＋ fertigation in the tillering stage and ferti- gation in the whole growth period were set. [Result] The two modes of fertilization had not significant effects on the emergence of sugarcane, but applying base fertil- izer at the earlier stage ＋ timely applying water soluble fertilizer in the tillering stage was conducive to the tillering of sugarcane. Harvest results showed that the effects of different treatments on plant height and yield were significant, in which the yield of sugarcane under the treatment of hyperkalemic water-soluble fertilizer increased by 13.04% compared with conventional treatment, and the income increased by 4 500 yuan/hm2, [Conclusion] Liquid special fertilizer for drip irrigation of sugarcane signifi- cantly promoted the growth of sugarcane, moreover, under the same condition, the effect of hyperkalemic water-soluble fertilizer was better.
文摘A rapid, sensitive and specific ultra-high-performance liquid chromatography tandem mass spectrometry （UPLC-MS） method was developed for the analysis of tetracycline antibiotics, including tetracycline （TC）, oxytetracycline （OTC）, chlortetracycline （CTC） and their 4-epimers （4-epiTCs） in agricultural soil fertilized with swine manure. Soil samples were extracted and cleaned-up with 10 mL EDTA-McIlvaine buffer solution （pH 4.0）, then cleaned-up and pre-concentrated using the Oasis MAX cartridge and then eluted with 1 mL solution by mixing formic acid, methanol and water at a ratio of 2：15：83 （v/v/v）. The purified samples were separated by an ACQUITY UPLC BEH C18 column using acetonitrile and water containing 0.1% formic acid mobile phase and detected by a single quadrupole MS. The limits of detection for the soil extraction method （LODsoil） ranged from 0.6-2.5 lag kg-~ with recoveries from 23.3-159.2%. Finally, the method was applied to an agricultural field in an area with intensive pig-fattening farming. Tetracyclines were detected in soil from 2.8 to 42.4 μg kg-1 soil. These results demonstrate that soil from swine farms can become severely contaminated with tetracycline antibiotics and their metabolites.
基金Supported by the Special Fund for Basic Scientific Research of Central Colleges,South-Central University for Nationalities(CZW15088)
文摘The enantiomer residues of metalaxyl, napropamide, triticonazole and metconazole were detected in soil by Qu EChERS-ultra performance liquid chromatography-tandem mass spectrometry（UPLC-MS/MS）. The soil sample was extracted with acetonitrile containing 1% acetic acid and purified using Qu ECh ERS method. Quantitative analysis for the enantiomers of these four chiral pesticides was performed in MS in multi-response monitoring（MRM） mode by external standard method. All enantiomers showed good linearity in the range of 0.5 to 50 μg/L. The average recoveries of enantiomers in soil were 81.74% to 105.79% with relative standard deviations（RSDs） from 3.69% to 7.86%. The method quantitative limit（MQL） was 5.3-30.3 ng/kg. The method can be used for rapid screening and determination of chiral pesticides in soil.
基金Supported by the National Natural Science Foundation of China (No. 20276048).
文摘The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization of three single-component NAPLs in a sandy soil, constant initial lumped mass transfer coefficient (λgN,0) canbe obtained if the relative saturation (ξ) between NAPL phase and gas phase is higher than a critical value (ξc), andthe lumped mass transfer coefficient decreases with ξ when ξ＜ξc. It is also shown that the lumped mass transfercoefficient can be increased by blending porous micro-particles into the sandy soil because of the increasing of theinterfacial area.
基金supported by the National Natural Science Foundation of China(Grants No.51579170 and 51179118)the Science Fund for Creative Research Groups of the National Natural Science Foundation of China(Grant No.51321065)
文摘Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loosely coupled liquid-gas-solid three-phase model, linking two numerical codes,TOUGH2/EOS3, which is used for water-air two-phase flow analysis, and FLAC^(3D), which is used for mechanical analysis, was established. The model was validated through a documented water drainage experiment over a sandy column and a comparison of the results with measured data and simulated results from other researchers. The proposed model was used to investigate the features of water-air two-phase flow and stress fields in an unsaturated soil slope during rainfall infiltration. The slope stability analysis was then performed based on the simulated water-air two-phase seepage and stress fields on a given slip surface. The results show that the safety factor for the given slip surface decreases first, then increases, and later decreases until the rainfall stops. Subsequently, a sudden rise occurs. After that, the safety factor decreases continually and reaches its lowest value, and then increases slowly to a steady value. The lowest value does not occur when the rainfall stops, indicating a delayed effect of the safety factor. The variations of the safety factor for the given slip surface are therefore caused by a combination of pore-air pressure, matric suction, normal stress, and net normal stress.
文摘The study investigated using rice husk biochar(RHB)to immobilize TNT and RDX explosives in soil at demining sites in Amuru District,Uganda.RHB produced via pyrolysis at 550℃was applied at a rate of 5%w/w to soil samples spiked at 50μg·g^(−1)RDX or TNT.The Liquid chromatography-tandem mass spectrometer(LC-MS/MS)analysis showed that the RHB immobilized 56%-67%of RDX and 55%-69%of TNT.The biochar’s porous structure and surface functional groups facilitated the explosive adsorption,reducing bioavailability.This demonstrates RHB’s effectiveness as an environmentally friendly and cost-effective remediation strategy.
文摘This opinion article discusses the original research work of Yünkül et al.(the Authors)published in the Journal of Mountain Science 21(9):3108–3122.Employing non-linear regression,fuzzy logic and artificial neural network modeling techniques,the Authors interrogated a large database assembled from the existing research literature to assess the performance of twelve equation rules in predicting the undrained shear strength(s_(u))mobilized for remolded fine-grained soils at different values of liquidity index(I_(L))and water content ratio.Based on their analyses,the Authors proposed a simple and reportedly reliable correlation(i.e.,Eq.9 in their paper)for predicting s_(u) over the I_(L) range of 0.15 to 3.00.This article describes various shortcomings in the Authors’assembled database(including potentially anomalous data and covering an excessively wide I_(L) range in relation to routine geotechnical and transportation engineering applications)and their proposed s_(u)=f(I_(L))correlation.Contrary to the Authors’assertions,their proposed correlation is not reliable for fine-grained soils with consistencies in the general firm to stiff range(i.e.,for 0.15<I_(L)<0.40),increasingly overestimating s_(u) for reducing I_(L),and eventually predicting s_(u)→+∞for I_(L)→0.15+(while producing mathematically undefined s_(u) for I_(L)<0.15),thus rendering their correlation unconservative and potentially leading to unsafe geotechnical designs.Exponential or regular-power type s_(u)=f(I_(L))models are more s_(u)itable when developing correlations that are applicable over the full plastic range(of 0<I_(L)<1),thereby providing reasonably conservative s_(u) predictions for use in the preliminary design for routine geotechnical engineering applications.
基金supported by the European Regional Development Fund (ERDF) Interreg Sudoe Program (No. PhytoSUDOE401-SOE1/P5/E0189)the Galician government (Agrupación Estratéxica CRETUS+1 种基金 No. 402 AGRU2015/02)a postdoctoral fellowship (No. ED481B 2017/073) granted to Dr. Balseiro-Romero by the Consellería de Cultura, Educacióne Ordenación Universitaria (Xunta de Galicia, Spain)
文摘The increasing use of petroleum-derived fuels over the last few decades has subsequently augmented the risk of spills in the environment. Soil pollution with petroleum hydrocarbons(principally caused by leaks in pipelines and underground storage tanks) is one of the major sources of soil degradation. Once in soil, fuel hydrocarbons suffer from a wide variety of multiphase processes including transport(advection, diffusion, and dispersion) among and within phases(aqueous and non-aqueous liquid, gas, and soil solids), mass transfer among phases(volatilization, sorption, and solution), and other natural attenuation processes, such as biodegradation and plant uptake and metabolism. This review identifies and describes the major processes occurring in soil that have a significant influence on the environmental fate of petroleum hydrocarbons. The definition of the processes involved in pollutant migration and distribution in soil and the formulation of adequate equations using accurate parameters(e.g., diffusion coefficients, velocity of advective flows, and mass transfer coefficients) will allow prediction of the final fate of soil pollutants. In addition to transport and mass transfer processes,which are more widely studied, the incorporation of attenuation mechanisms driven by microorganisms and plants is essential to predict the final concentration of the pollutants in the whole multiphase scenario. This work underlines the importance of the determination of accurate parameters through the performance of laboratory and/or field-scale experiments to develop precise pollutant migration models.
基金supported by National Basic Research Program of China (No. 2014CB047001)National Natural Science Foundation of China (No. 51508578)
文摘Canopy effect refers to the phenomenon in which moisture accumulates underneath an impervious cover.A canopy effect can lead to full saturation of the soil underneath the impervious cover.A recent theoretical study separates the canopy effect into two types.The first one is caused by evaporation-condensation in unsaturated soils,while the second one is induced by freezing-enhanced vapour transfer in unsaturated soils.To validate experimentally these two types of canopy effect and to reveal their mechanisms,moisture-migration experiments were carried out,using a newly developed laboratory apparatus for unsaturated frozen soils.Six conditions were applied to the calcareous sand,with different initial water contents and boundary temperatures.The results show that water content in the upper portion of the sample increased under an upward temperature gradient,and the increment of water content was greater if the soil was subjected to freezing.For the freezing cases,the depth of the peak water content was in line with the freezing front.And the greater the initial water content,the more the water content accumulated at the freezing front.However,a lower cooling rate seemed to facilitate vapour migration.For the unfrozen cases,the water content in the upper portion of the sample also increased;and the increases became more apparent with a higher initial moisture content.The temperature gradient can also inhibit the vapour migration.A less steep temperature gradient always resulted in a more notable inhibition effect.Test results seem to verify the theory of the canopy effect.
基金Project(50708033) supported by the National Natural Science Foundation of China
文摘High liquid limit soil generally adopted in expressway embankment construction of southern mountains, which often expresses some characteristics including high moisture content, high porosity ratio, low permeability, high compressibility, certain disintegration, and so on. Spring soil phenomenon and inhomogeneous compaction have effects on the quality of embankment construction, just because the water in soil is difficult to evaporate. Based on the study of reinforcement mechanism for high liquid limit soil, in situ tests for dynamic compaction treatment in Yizhang-Fengtouling expressway embankment were developed. The reliable and economical dynamic compaction treatment methods and the construction technology for large range high liquid limit soil embankment in southern mountains expressway were discussed. In the process, convenient measurement methods were adopted to evaluate the treatment effects. The test results show that the dynamic compaction method has good treatment effects on the local red clay embankment. The embankment compaction degree is improved with compactness coming to 90% around tamping pits and compactness over 95% in tamping pits interior after tamping. The bearing capacity, the physical mechanic-property and the shear strength for soil are obviously improved, which are enhanced with cohesive strength increasing over 10 kPa and compression modulus increasing over 3 MPa.
基金the National Natural Science Foundation of China(Grant No.U20A2081)West Light Foundation of the Chinese Academy of Sciences(Grant No.xbzg-zdsys-202102)the Second Tibetan Plateau Scientific Expedition and Research(STEP)Project(Grant No.2019QZKK0105).
文摘Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)and soil moisture(SM)conditions on a land surface energy and water simulation in the permafrost region in the Tibetan Plateau(TP)using the Community Land Model version 5.0(CLM5.0).The results indicate that the default initial schemes for ST and SM in CLM5.0 were simplistic,and inaccurately represented the soil characteristics of permafrost in the TP which led to underestimating ST during the freezing period while overestimating ST and underestimating SLW during the thawing period at the XDT site.Applying the long-term spin-up method to obtain initial soil conditions has only led to limited improvement in simulating soil hydrothermal and surface energy fluxes.The modified initial soil schemes proposed in this study comprehensively incorporate the characteristics of permafrost,which coexists with soil liquid water(SLW),and soil ice(SI)when the ST is below freezing temperature,effectively enhancing the accuracy of the simulated soil hydrothermal and surface energy fluxes.Consequently,the modified initial soil schemes greatly improved upon the results achieved through the long-term spin-up method.Three modified initial soil schemes experiments resulted in a 64%,88%,and 77%reduction in the average mean bias error(MBE)of ST,and a 13%,21%,and 19%reduction in the average root-mean-square error(RMSE)of SLW compared to the default simulation results.Also,the average MBE of net radiation was reduced by 7%,22%,and 21%.
文摘The present study is inscribed within the framework of the geotechnical characterization of the soils of the Santchou plain, their classification for employment as pavement subgrade, various identification tests were carried out on the samples. The results obtained showed that with a wide range of different grain sizes, the studied soils showed low content in clay grains and dominance of either sand grains or silt grains, this can be explaining how most of these soil are poorly graded. According to the USDA textural classification, the grain size distribution of these soils makes them to be classified as Silty Loam types to Sandy Loam types. Despite of their organic matter content which is less than 10%, according to their respective methylene blue values, the soils studied along the section should be mainly loamy soil of medium plasticity to clayed soil, therefore showing a sensibility of its behavior to variation of water content. That last one is confirmed by the consistency parameters of these soils which show intermediate plasticity to highly plastic. Also, the bearing capacity proposed by these soils at their respective optimum dry densities is relatively small, although most of these experimental CBR values of the studied soils are more important than the ones prescribed by the AASHTO Classification system for A5, A6, and A7 types, and the French Highway Earthworks Manual Classifications system (GTR) for the corresponding A2 and A3 types.
文摘The investigation of the long-term performance of solidified/stabilized （S/S） contaminated soils was carried out in a trial site in southeast UK. The soils were exposed to the maximum natural weathering for four years and sampled at various depths in a controlled manner. The chemical properties （e.g., degree of carbonation （DOC）, pH, electrical conductivity （EC）） and physical properties （e.g., moisture content （MC）, liquid limit CLL）, plastic limit （PL）, plasticity index （PI）） of the samples untreated and treated with the traditional and accelerated carbonated S/S processes were analyzed. Their variations on the depths of the soils were also studied. The result showed that the broad geotechnical properties of the soils, manifested in their PIs, were related to the concentration of the water soluble ions and in particular the free calcium ions. The samples treated with the accelerated carbonation technology （ACT）, and the untreated samples contained limited number of free calcium ions in solutions and consequently interacted with waters in a similar way. Compared with the traditional cement-based S/S technology, e.g., treatment with ordinary portland cement （OPC） or EnvirOceM, ACT caused the increase of the PI of the treated soil and made it more stable during long-term weathering. The PI values for the four soils ascended according to the order： the EnvirOceM soil, the OPC soil, the ACT soil, and the untreated soil while their pH and EC values descended according to the same order.
文摘Organochlorine pesticides and polychlorinated biphenyls are toxic, carcinogenic, and have a high potential for bioaccumulation. Due to their stability, they are still considered an environmental problem even though the use of most of them has been phased out several decades ago. Soil is a matrix which can retain these contaminants to a great extent. This ability is often associated with the total organic carbon content (TOC). In order to judge the pollution status of soil and to make monitoring data more easily comparable a simple, yet robust extraction method is needed. Agitation solid-liquid-extraction is well suited for this purpose. However, the influence of TOC on the analyte recovery has to be known. For the presented study, 12 organochlorine pesticides and 7 polychlorinated biphenyls were spiked into four model soils with organic carbon contents between 1.6% - 13.3%. The matrices were extracted using solid-liquid extraction between 45 minutes and 16 hours. For comparison, all soils were also extracted using pressurised liquid extraction and Soxhlet extraction. After clean-up the extracts were measured using a gas chromatography-mass spectrometry (GC-MS) system. Statistical analysis of the results implied that the TOC content of the soils did not have significant influence on the extraction efficiency. A longer solid-liquid extraction time did not necessarily increase analyte recovery: Extraction for one hour resulted in 88% recovery while 16 hour extraction led to 89%. Thus, the efficiency of all the methods was comparable for all model soils. Additional investigations regarding GC liner performance highlighted the need for isotopically labelled standards during the analysis of thermolabile pesticides.
文摘Determination of physical property of the soil helps in identification and classification of soil which includes analysis of particle size distribution, Atterberg limits, water content, specific gravity, phase determination and direct shear test. Water plays an important role in triggering landslides and slope failures. Increase of water content reduces the stability of slope. When the moisture content exceeds plastic limits, the slope begins to deform. Three soil samples are collected from the study area and the average bulk density, moisture content and specific gravity are 1.577, 37.032 and 2.434 respectively. Atterberg limit is the most distinctive properties of fine grained sediments and may be used to distinguish silts from clays. Plastic limits (WP), liquid limit (WL), shrinkage limit (WS) values of Nungbi Khunou are 26.236%, 48% and 9.4% respectively. Plasticity index (IP), consistency index (IC) and liquidity index (IL) value is 21.764%, 0.379%, and 60.623% respectively. From index properties value, the soil is highly plastic, stiff and semi-solid in nature. The soil sample falls under CI group in plasticity chart which indicates organic silt and clay soil with medium compressibility and plasticity. Phase determination and particle size distribution result in very high porosity and highly saturated soils which are well graded in nature. Slope and aspect map are prepared from DEM using ArcGIS. Slope is an important contributory factor to landslide, and slope reported from the sampling area indicates gentle slope. Aspect refers to the direction of the terrain faces which is influenced by component like vegetation, settlement, agriculture, precipitation, wind etc. Factor of safety (Fs) calculated from shear stress data is less than 1 indicating unstable slope. From the above finding, the study area may result in sudden and unpredictable failure due to volumetric changes in soil.
基金This work was supported by the Budgetary Project the Chinese Academy of Sciences Leads the Sub-Project of Class A Project(XDA26020202)the National“973”Program Project Topics(2014CB138702)+2 种基金the Basic Scientific Research Business Expenses of Central Universities(Lzujbky-2022-kb10)the 111 Wisdom Base(B12002)the Fundamental Research Funds for the Central Public Welfare Research Institutes(Chinese Academy of Forestry)(CAFYBB2021ZD001).
文摘In a greenhouse experiment,the effects of soil microorganisms and extracts of Achnatherum inebrians on the seed germination and seedling growth of Elymus nutans were studied.The results showed that both the extracts from aboveground and belowground parts of A.inebrians significantly inhibited the germination rate,germination potential,germination index,vigor index,seedling height,root length,and fresh weight of E.nutans,but increased malondialdehyde content,catalase,peroxidase and superoxide dismutase activity of E.nutans seedlings(p<0.05).The allelopathy of aqueous extracts of the aboveground parts of A.inebrians was stronger than that of the pre-cipitates.Aqueous extracts of the aboveground parts of A.inebrians decreased seed germination rate,germination potential,germination index,vigor index,seedling length,root length,and seedling fresh weight by 10.45%-74.63%,24.18%-32.50%,19.03%-73.36%,37.83%-88.41%,21.42%-53.14%,2.65%-40.21%,and 20.45%-61.36%,respectively,and malondialdehyde content,peroxidase,catalase,and superoxide dismutase activity increased by 8.09%-62.24%,27.83%-86.47%,22.90%-93.17%,and 11.15%-75.91%,respectively.The above indexes were higher in live soil than in sterilized soil.Soil microorganisms increased the allelopathy of A.inebrians.The seed germination rate,germination potential,germination index,vigor index,seedling length,and seedling fresh weight of E.nutans planted in live soil decreased by 8.22%-48.48%,10.00%-51.85%,8.19%-53.26%,16.43%-60.03%,12.91%-28.81%,and 9.09%-22.86%compared with sterilized soil,respectively.Malondialdehyde content,peroxidase,catalase,and superoxide dismutase activity of E.nutans planted in live soil increased by 53.91%-81.06%,15.71%-57.34%,33.33%-86.31%,and 9.78%-52.51%compared with sterilized soil,respectively.The existence of soil microorganisms enhanced the allelopathy of the secondary metabolites of A.inebrians.A combination of microorganisms and aqueous extracts from the aboveground parts of A.inebrians had the strongest allelopathic effect on E.nutans.
基金part of the interdisciplinary SALVE-research project undertaken by the German Archaeological Institute(DAI)in cooperation with the Heidelberg Academy of Sciences and Humanities(HAW)and the University of Tübingen(www.salve-research.org)Project directors are Florian Seiler(DAI)and Michael Märker(HAW)and it was funded by the Deutsche Forschungsgemeinschaft(German Research Foundation).
文摘The AD 79 eruption of Somma-Vesuvius completely buried the ancient landscape around Pompeii (Italy) to some extent conserving the pre-AD 79 Roman paleosols of the Sarno River plain. To estimate potential post-burial soil developments of these paleosols detailed soil liquid and solid phase analysis were carried out. Firstly, an in-situ soil hydrological monitoring was conducted within a pre-AD 79 paleosol in natural undisturbed stratification. The results show that soil water flow and nutrient transport from the overlying volcanic deposits into the pre-AD 79 paleosol take place. Secondly, to estimate their influence on the paleosol’s mineral soil properties, the solid phase of four pre-AD 79 paleosols and associated modern unburied soils were analysed and compared. By combining the data from the soil liquid and solid phase analysis, potential post-burial changes in the paleosols were estimated. Finally, a rise of the mean groundwater table was determined since AD 79. This distinguishes the Sarno River plain into two different zones of post-burial soil developments: 1) lower altitudes where formerly terrestrial paleosols are now influenced by groundwater dynamics and 2) higher altitudes where the paleosols are still part of the vadose zone and rather influenced by infiltration water or interflow. Thus, the mechanism of potential post-burial soil development being active in the pre-AD 79 paleosols is not uniform for the entire Sarno River plain but strongly depends on the paleotopographic situation.
