Due to the nonunitary time evolution and possibly complex energy eigenvalues in non-Hermitian systems,it is still under debate how to properly deal with the dynamics of time-dependent non-Hermitian Hamiltonian.Recentl...Due to the nonunitary time evolution and possibly complex energy eigenvalues in non-Hermitian systems,it is still under debate how to properly deal with the dynamics of time-dependent non-Hermitian Hamiltonian.Recently a quantum metric framework has been proposed to study the dynamics of generated defects of a non-Hermitian system under linear quench.Here,we provide an explicit expression for the endowed Hamiltonian under quantum metric for a general twolevel non-Hermitian system.Then we propose two exactly solvable models for the study of nonadiabatic dynamics of non-Hermitian systems,and analyze the defect production using the metric method.We find that,in contrast to the direct normalization method,the metric method can reproduce the symmetry of generated defects.The power-law scaling of generated defects with respect to quench time is also obtained.展开更多
High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties w...High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties was systematically characterised and analysed. The micro-structure of the as-built steel consisted of two parts. The first part comprised martensite with twins combined with ω-Fe nano-particles, and the second part consisted of lower bainite in the molten pool, as well as upper bainite, granular bainite and tempered martensite in the heat-affected zone. With the quenching temperatures varying from 800℃ to 950℃, the micro-structure gradually transformed from acicular ferrite + martensite to tempered martensite +θ-Fe3C carbides, and the grain size exhibited noticeable growth. Moreover, quenching treatments could eliminate the anisotropy and inhomogeneity of the micro-structure. The rod-shaped nanosized η-Fe2C and θ-Fe3C precipitates were clearly observed, which were converted from ω-Fe and distributed at multiple angles in the lath. The size and number of nano-precipitates, triggered by the high self-tempering degree of martensite, gradually increased. The relationships among grain size, the twins, dislocation density and nano-precipitation and the dramatically improved performance of quenched samples were analysed using strengthening mechanisms. After quenching at 850℃, the as-built 24CrNiMo steel attained ultra-high mechanical properties including hardness, Ultimate Tensile Strength (UTS), Elongation (El) and impact energy with values of 480.9 HV_(1), 1611.4 MPa, 9.8% and 42.8 J, respectively. Meanwhile, both the wear and thermal fatigue resistance increased by approximately 40%. This study demonstrated that LPBF-fabricated 24CrNiMo steel, with matching good performances, can be achieved using a subsequent one-step quenching process.展开更多
Aiming at the improvement of the cyclic stability of La-Mg-Ni system （PuNi3-type） hydrogen storage alloy, Ni in the alloy was partly substituted by Fe. The electrode alloys of La0.7Mg0.3Co0.45Ni255-xFex （x=0, 0.1, ...Aiming at the improvement of the cyclic stability of La-Mg-Ni system （PuNi3-type） hydrogen storage alloy, Ni in the alloy was partly substituted by Fe. The electrode alloys of La0.7Mg0.3Co0.45Ni255-xFex （x=0, 0.1, 0.2, 0.3, 0.4） were prepared by casting and rapid quenching. The influence of the quenching on cyclic stability as well as structure of the alloys was investigated in detail. The results of electrochemical measurement indicated that rapid quenching significantly improved cyclic stability. When the quenching rate rose from 0 （As-cast was defined as a quenching rate of 0 m/s） to 30 m/s, the cyclic life of Fe-free alloy （x=-0） increased from 81 to 105 cycles, and for alloy containing Fe（x=0.4）, it grew from 106 to 166 cycles at a current density of 600 mA/g. The results obtained by XRD, TEM and SEM revealed that the as-cast and quenched alloys had multiphase structures, including two major phases （La, Mg）Ni3 and LaNi5 as well as an imptLrity phase LaNi2. Rapid quenching helped the formation of an amorphous-like structure in Fe containing alloys.展开更多
The determination method of catechol by fluorescence quenching was developed.The assay was based on the combination of the unique property of gold nanoparticles with tyrosinase enzymatic reaction.In the presence of ty...The determination method of catechol by fluorescence quenching was developed.The assay was based on the combination of the unique property of gold nanoparticles with tyrosinase enzymatic reaction.In the presence of tyrosinase,the fluorescence of gold nanoparticles was quenched by catechol which can be employed to detect catechol.Under the optimal conditions,a linear range 5.0×10^(-7)-1.0×10^(-3) mol L^(-1) and a detection limit 1.0×10^(-7) mol L^(-1) of catechol were obtained.o-Quinone intermediate produced...展开更多
An outline of the complete design of the cryogenic system, including the detection of quench signals, the processing flow after a quench and the concrete measures of pressure release for EAST is described in this pape...An outline of the complete design of the cryogenic system, including the detection of quench signals, the processing flow after a quench and the concrete measures of pressure release for EAST is described in this paper. The hardware and software configurations on DeltaV DCS are illustrated in detail. The results of quench protection testing in cooling experiments are also analyzed.展开更多
We study the thermalization of a quenched disordered Bose–Hubbard system. By considering the eigenstate distribution fluctuation, we show that the thermal to many-body localized transition is always connected to a mi...We study the thermalization of a quenched disordered Bose–Hubbard system. By considering the eigenstate distribution fluctuation, we show that the thermal to many-body localized transition is always connected to a minimum of this distribution fluctuation. We also observe a Mott-localized regime, where the system fails to thermalize due to the strong on-site repulsion. Lastly, we show how to detect this eigenstate distribution fluctuation in a cold atom system, which is equivalent to measure the Loschmidt echo of the system. Our work suggests a way to measure the thermal-to-localized transitions in experiments, especially for a large system.展开更多
Thyristors have longer lifetimes,higher reliability,and very high voltage and current ratings and they require less maintenance than other high-power semiconductor devices.As a result,they are particularly suitable fo...Thyristors have longer lifetimes,higher reliability,and very high voltage and current ratings and they require less maintenance than other high-power semiconductor devices.As a result,they are particularly suitable for quench protection systems(QPSs),which protect the superconducting magnets in large fusion devices from damage.In this paper,we propose a design for a 100 k A/10 k V thyristor stack supported by both theoretical and simulation-based analyses as well as experimental verification.Due to the ultrahigh electrical performance requirements imposed on the QPS by the Comprehensive Research Facility for Fusion Technology(CRAFT),three main issues must be considered:the voltage-balancing problem caused by multiple thyristors in a series structure,the increased junction temperature problem caused by extremely high currents,and the reverse recovery phenomenon that arises from the thyristor’s physical structure.Hence,a series of detailed theoretical analyses,simulations,and experiments,including a thyristor junction temperature prediction method and reverse recovery process modeling,were carried out to optimize the design.Finally,the reliability and stability of the thyristor stack were verified by a series of prototype experiments.The results confirmed the correctness and accuracy of the proposed thyristor stack design method and also indicated that the proposed thyristor stack can meet the application conditions of a 100 k A QPS in the CRAFT project.展开更多
In this paper, the electroluminescence quenching mechanism in a 5,6,11,12-tetraphenylnaphthacene （Rubrene） doped host-vip system is studied by utilizing a specially designed organic light-emitting diode with an em...In this paper, the electroluminescence quenching mechanism in a 5,6,11,12-tetraphenylnaphthacene （Rubrene） doped host-vip system is studied by utilizing a specially designed organic light-emitting diode with an emission layer consisting of a few periodic host/vip structures. Tris-（8-hydroxyquinoline） aluminium （Alq3） and Rubrene are used as the host and the vip, respectively. The thickness variation of the vip layer in each period enables the study of the effect of molecule aggregation, and the thickness variation of the host layer suggests a long range quenching mechanism of dipole-dipole interaction. The long range quenching mechanism is a Forster process, and the FSrster radius of Rubrene is between 3 and 10 nm.展开更多
Considering some characteristics of large-scale standing quench furnace, such as great heat inertia, evident time lag, strong coupling influence, hard to establish exact mathematical models of plant and etc, an artifi...Considering some characteristics of large-scale standing quench furnace, such as great heat inertia, evident time lag, strong coupling influence, hard to establish exact mathematical models of plant and etc, an artificial intelligent fuzzy control algorithm is put forward in this paper. Through adjusting the on-off ratio of electric heating elements, the temperature in furnace is controlled accurately. This paper describes structure and qualities of the large-scale standing quench furnace briefly, introduces constitution of control system, and expounds principle and implementation of intelligent control algorithm. The applied results prove that the intelligent control system can completely satisfy the technological requirements. Namely, it can realize fast increasing temperature with a little overshoot, exact holding temperature, and well-distributed temperature in quench furnace. It has raised the output and quality of aluminum material, and brought the outstanding economic and social benefits.展开更多
This paper deals with the quenching behavior of positive solutions to the Newton filtration equations coupled with boundary singularities.We determine quenching rates for non-simultaneous quenching at first,and then e...This paper deals with the quenching behavior of positive solutions to the Newton filtration equations coupled with boundary singularities.We determine quenching rates for non-simultaneous quenching at first,and then establish the criteria to identify the simultaneous and non-simultaneous quenching in terms of the parameters involved.展开更多
In this paper, the initial boundary value problem of semilinear degenerate reaction-diffusion systems is studied. The regularization method and upper and lower solutions technique are employed to show the existence an...In this paper, the initial boundary value problem of semilinear degenerate reaction-diffusion systems is studied. The regularization method and upper and lower solutions technique are employed to show the existence and continuation of a positive classical solution. The location of quenching points is found. The critical length is estimated by the eigenvalue method.展开更多
The theoretic renormalization group approach is applied to the study of the critical behavior of non-interacting system with long-range correlated quenched impurities, which has a power-like correlations . To two-loop...The theoretic renormalization group approach is applied to the study of the critical behavior of non-interacting system with long-range correlated quenched impurities, which has a power-like correlations . To two-loop order, the asymptotic scaling laws and the critical exponents are studied in the frame of a double expansion with ρ of order . In , it is argued that the initial slip exponent θ = 0 together with the dynamic exponent is exact in this kind of random system.展开更多
This paper studies quenching properties of solutions of a semilinear parabolic system with localized reaction sources in a square domain. The system has the homogeneous Dirichlet boundary condition and null initial co...This paper studies quenching properties of solutions of a semilinear parabolic system with localized reaction sources in a square domain. The system has the homogeneous Dirichlet boundary condition and null initial condition. We prove that solutions quench simultaneously, and compute approximated critical values of the system using a numerical method.展开更多
A cyclic quenching treatment(CQT)succeeded in turning a 2.3 GPa maraging steel with a Charpy impact energy of 9 J into a new grade with the same strength but a Charpy impact energy of 20 J upon 4 cyclic treatments.The...A cyclic quenching treatment(CQT)succeeded in turning a 2.3 GPa maraging steel with a Charpy impact energy of 9 J into a new grade with the same strength but a Charpy impact energy of 20 J upon 4 cyclic treatments.The improvement of mechanical properties is attributed to the refinement and increased chemical heterogeneity of the martensitic substructure,rather than the refinement of prior austenite grain(PAG),as well as the Transformation-Induced Plasticity(TRIP)effect facilitated by small austenite grains.The role of local segregation of Ni during CQT in the formation of Ni-rich austenite grains,Ni-rich martensite laths and Ni-poor martensite laths,was investigated and verified by DICTRA simulations.This study highlights the important influence of Ni partitioning behavior during CQT,providing insights into microstructural evolution and mechanical properties.展开更多
In the field of Raman spectroscopy detection,the quest for a non–noble metal,recyclable,and highly sensitive detection substrate is of utmost importance.In this work,a new crystalline and noble metal–free substrate ...In the field of Raman spectroscopy detection,the quest for a non–noble metal,recyclable,and highly sensitive detection substrate is of utmost importance.In this work,a new crystalline and noble metal–free substrate of[Bi(DMF)_(8)][PMo_(12)O_(40)](Bi–PMo_(12))is designed,which is composed of[PMo_(12)O_(40)]^(3−)and solvated[Bi(DMF)_(8)]^(3+)cations.Mechanistic studies have revealed that Raman scattering quenching phenomenon arises from two main factors.Firstly,it arises from the absorption of the scattered light due to the transition of a single electron in the reduced state of MoV between 4d orbitals.Secondly,after the interaction between the substrate and hydrazine,the surface undergoes varying degrees of roughening,leading to an impact on the scattered light intensity.These two effects collectively contribute to the detection of low concentrations of N_(2)H_(4).As a result,Bi–PMo_(12)opens up a novel Raman scattering quenching mechanism to realize the detection of reduced N_(2)H_(4)small molecules.A remarkably low detection limit of 4.5×10^(−9)ppm for N_(2)H_(4)is achieved on the Bi–PMo_(12)substrate.This detection has a lower concentration than the currently known SERS detection of N_(2)H_(4).Moreover,Bi–PMo_(12)can be recovered and reused through recrystallization,achieving a recovery rate of up to ca.51%.This study reveals the underlying potential of crystalline polyoxometalate materials in the field of Raman detection,thus opening up new avenues for highly sensitive analysis using Raman techniques.展开更多
The microstructure evolution and mechanical properties of a Fe-0.12C-0.2Si-1.6Mn-0.3Cr-0.0025B(wt.%)steel with different initial microstructures,i.e.,hot rolled(HR)and cold rolled-annealed(CRA),were studied through op...The microstructure evolution and mechanical properties of a Fe-0.12C-0.2Si-1.6Mn-0.3Cr-0.0025B(wt.%)steel with different initial microstructures,i.e.,hot rolled(HR)and cold rolled-annealed(CRA),were studied through optical microscopy,scanning electron microscopy,electron channeling contrast imaging,microhardness and room temperature uniaxial tensile tests.After water quenching from 930℃ to room temperature,a fully martensitic microstructure was obtained in both as-quenched HR and CRA specimens,which shows a microhardness of 480±5 HV,and no significant difference in microstructure and microhardness was observed.Tensile test results show that the product of tensile strength and total elongation(UTS×TE)of the as-quenched HR specimen,i.e.,24.1 GPa%,is higher than that of the as-quenched CRA specimen,i.e.,18.9 GPa%.While,after being tempered at 300℃,the martensitic microstructures and mechanical properties of the two as-quenched specimens change significantly due to the synergy role of the matrix phase softening and the precipitation strengthening.Concerning the maximum UTS×TE,it is 18.9 GPa%obtained in the as-quenched CRA one,while that is 24.4 GPa%obtained in the HR specimen after tempered at 300℃ for 5 min.展开更多
The effect of hot deformation on the quench sensitivity of the 7085 alloy was studied through hardness testing and microstructure characterization.The findings indicate that hot deformation enhances the quench sensiti...The effect of hot deformation on the quench sensitivity of the 7085 alloy was studied through hardness testing and microstructure characterization.The findings indicate that hot deformation enhances the quench sensitivity of the 7085 alloy,with the hardness difference between water quenching and air cooling increasing from 5.4%(before hot deformation)to 10.4%(after hot deformation).In the undeformed samples,the Al3Zr particles within the grains exhibit better coherent with the Al matrix.During slow quenching,only theηphase is observed on Al3Zr particles and at the grain boundaries.Hot deformation leads to a mass of recrystallization and the formation of subgrains with high dislocation density.This results in an increase in the types,quantities,and sizes of heterogeneous precipitates during quenching.In the slow quenching process,high angle grain boundaries are best for the nucleation and growth of theηphase.Secondly,a substantial quantity ofηand T phases precipitate on the non-coherent Al3Zr phase within the recrystallized grains.The locations with high dislocation density subgrains(boundaries)serve as nucleation positions for theηand T phases precipitating.Additionally,the Y phase is observed to precipitate at dislocation sites within the subgrains.展开更多
Formamidinium lead bromide(FAPbBr_(3))perovskite nanocrystals(NCs)are promising for display and lighting due to their ultra-pure green emission.However,the thermal quenching will exacerbate their performance degradati...Formamidinium lead bromide(FAPbBr_(3))perovskite nanocrystals(NCs)are promising for display and lighting due to their ultra-pure green emission.However,the thermal quenching will exacerbate their performance degradation in practical applications,which is a common issue for halide perovskites.Here,we reported the heat-resistant FAPbBr_(3)NCs prepared by a ligand-engineered room-temperature synthesis strategy.An aromatic amine,specificallyβ-phenylethylamine(PEA)or 3-fluorophenylethylamine(3-F-PEA),was incoporated as the short-chain ligand to expedite the crystallization rate and control the size distribution of FAPbBr_(3)NCs.Employing this ligand engineering approach,we synthesized high quality FAPbBr_(3)NCs with uniform grain size and reduced long-chain alkyl ligands,resulting in substantially suppressed thermal quenching and enhanced carrier transportation in the perovskite NCs films.Most notably,more than 90%of the room temperature PL intensity in the 3-F-PEA modified FAPbBr_(3)NCs film was preserved at 380 K.Consequently,we fabricated ultra-pure green EL devices with a room temperature external quantum efficiency(EQE)as high as 21.9%at the luminance of above 1,000 cd m^(-2),and demonstrated less than 10%loss in EQE at 343 K.This study introduces a novel room temperature method to synthesize efficient FAPbBr_(3)NCs with exceptional thermal stability,paving the way for advanced optoelectronic device applications.展开更多
A martensitic initial microstructure before hot forming was prepared by direct quenching after hot rolling of the hot formed steel and the effect of such initial microstructure on mechanical properties of steel was an...A martensitic initial microstructure before hot forming was prepared by direct quenching after hot rolling of the hot formed steel and the effect of such initial microstructure on mechanical properties of steel was analyzed. The process of direct quenching after hot rolling which replaced the steps of coiling and cold rolling was termed as compact process. As the temperature before direct quenching falls within the non-recrystallization range, the deformed austenite grains exhibit flattened morphology along the hot rolling direction, and the high-density dislocations and significant strain energy in deformed austenite are inherited by directly quenched martensite. Moreover, due to promotion of austenite nucleation and subsequent recrystallization during the reverse transformation process in hot forming, both reversed austenite grains and martensite laths are significantly refined. Compared to the conventional process with an initial microstructure consisting of fully recrystallized ferrite and cementite, the compact process reduces average prior austenite grain sizes from 12.5 to 5.5 μm and martensite lath widths from 202 to 123 nm. Additionally, the compact process results in a higher density of dislocations in test steel, leading to maximum yield strength (1294 MPa) and ultimate tensile strength (2266 MPa). Compared to conventional process, this compact process significantly improves the mechanical properties of the hot formed steels while simplifying the production.展开更多
基金supported by the National Key Research and Development Program of the Ministry of Science and Technology of China(Grant No.2021YFA1200700)the National Natural Science Foundation of China(Grant Nos.11905054 and 12275075)the Fundamental Research Funds for the Central Universities of China.
文摘Due to the nonunitary time evolution and possibly complex energy eigenvalues in non-Hermitian systems,it is still under debate how to properly deal with the dynamics of time-dependent non-Hermitian Hamiltonian.Recently a quantum metric framework has been proposed to study the dynamics of generated defects of a non-Hermitian system under linear quench.Here,we provide an explicit expression for the endowed Hamiltonian under quantum metric for a general twolevel non-Hermitian system.Then we propose two exactly solvable models for the study of nonadiabatic dynamics of non-Hermitian systems,and analyze the defect production using the metric method.We find that,in contrast to the direct normalization method,the metric method can reproduce the symmetry of generated defects.The power-law scaling of generated defects with respect to quench time is also obtained.
基金co-supported by the National Key Research and Development Program of China (No. 2022YFB4600500)the National Natural Science Foundation of China (No. 52235006)
文摘High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties was systematically characterised and analysed. The micro-structure of the as-built steel consisted of two parts. The first part comprised martensite with twins combined with ω-Fe nano-particles, and the second part consisted of lower bainite in the molten pool, as well as upper bainite, granular bainite and tempered martensite in the heat-affected zone. With the quenching temperatures varying from 800℃ to 950℃, the micro-structure gradually transformed from acicular ferrite + martensite to tempered martensite +θ-Fe3C carbides, and the grain size exhibited noticeable growth. Moreover, quenching treatments could eliminate the anisotropy and inhomogeneity of the micro-structure. The rod-shaped nanosized η-Fe2C and θ-Fe3C precipitates were clearly observed, which were converted from ω-Fe and distributed at multiple angles in the lath. The size and number of nano-precipitates, triggered by the high self-tempering degree of martensite, gradually increased. The relationships among grain size, the twins, dislocation density and nano-precipitation and the dramatically improved performance of quenched samples were analysed using strengthening mechanisms. After quenching at 850℃, the as-built 24CrNiMo steel attained ultra-high mechanical properties including hardness, Ultimate Tensile Strength (UTS), Elongation (El) and impact energy with values of 480.9 HV_(1), 1611.4 MPa, 9.8% and 42.8 J, respectively. Meanwhile, both the wear and thermal fatigue resistance increased by approximately 40%. This study demonstrated that LPBF-fabricated 24CrNiMo steel, with matching good performances, can be achieved using a subsequent one-step quenching process.
基金863 Program (2006AA05Z132)the National Natural Science Foundation of China (50642033)+1 种基金Natural Science Founda-tion of Inner Mongolia, China (200711020703)Science and Technology Planned Project of Inner Mongolia, China (20050205)
文摘Aiming at the improvement of the cyclic stability of La-Mg-Ni system （PuNi3-type） hydrogen storage alloy, Ni in the alloy was partly substituted by Fe. The electrode alloys of La0.7Mg0.3Co0.45Ni255-xFex （x=0, 0.1, 0.2, 0.3, 0.4） were prepared by casting and rapid quenching. The influence of the quenching on cyclic stability as well as structure of the alloys was investigated in detail. The results of electrochemical measurement indicated that rapid quenching significantly improved cyclic stability. When the quenching rate rose from 0 （As-cast was defined as a quenching rate of 0 m/s） to 30 m/s, the cyclic life of Fe-free alloy （x=-0） increased from 81 to 105 cycles, and for alloy containing Fe（x=0.4）, it grew from 106 to 166 cycles at a current density of 600 mA/g. The results obtained by XRD, TEM and SEM revealed that the as-cast and quenched alloys had multiphase structures, including two major phases （La, Mg）Ni3 and LaNi5 as well as an imptLrity phase LaNi2. Rapid quenching helped the formation of an amorphous-like structure in Fe containing alloys.
基金supported by the National Natural Science Foundation of China(No.20875059)
文摘The determination method of catechol by fluorescence quenching was developed.The assay was based on the combination of the unique property of gold nanoparticles with tyrosinase enzymatic reaction.In the presence of tyrosinase,the fluorescence of gold nanoparticles was quenched by catechol which can be employed to detect catechol.Under the optimal conditions,a linear range 5.0×10^(-7)-1.0×10^(-3) mol L^(-1) and a detection limit 1.0×10^(-7) mol L^(-1) of catechol were obtained.o-Quinone intermediate produced...
基金supported by National Meg-Science Engineering Project of Chinese Government (No.10575105)
文摘An outline of the complete design of the cryogenic system, including the detection of quench signals, the processing flow after a quench and the concrete measures of pressure release for EAST is described in this paper. The hardware and software configurations on DeltaV DCS are illustrated in detail. The results of quench protection testing in cooling experiments are also analyzed.
基金Supported by the National Natural Science Foundation of China under Grant No 11504021the Fundamental Research Funds for Central Universities of China under Grant No FRF-TP-17-023A2
文摘We study the thermalization of a quenched disordered Bose–Hubbard system. By considering the eigenstate distribution fluctuation, we show that the thermal to many-body localized transition is always connected to a minimum of this distribution fluctuation. We also observe a Mott-localized regime, where the system fails to thermalize due to the strong on-site repulsion. Lastly, we show how to detect this eigenstate distribution fluctuation in a cold atom system, which is equivalent to measure the Loschmidt echo of the system. Our work suggests a way to measure the thermal-to-localized transitions in experiments, especially for a large system.
基金supported by National Key Research and Development Program of China(Nos.2017YFE0300504 and 2017YFE0300500)the Comprehensive Research Facility for the Fusion Technology Program of China(No.2018000052-73-01-001228)。
文摘Thyristors have longer lifetimes,higher reliability,and very high voltage and current ratings and they require less maintenance than other high-power semiconductor devices.As a result,they are particularly suitable for quench protection systems(QPSs),which protect the superconducting magnets in large fusion devices from damage.In this paper,we propose a design for a 100 k A/10 k V thyristor stack supported by both theoretical and simulation-based analyses as well as experimental verification.Due to the ultrahigh electrical performance requirements imposed on the QPS by the Comprehensive Research Facility for Fusion Technology(CRAFT),three main issues must be considered:the voltage-balancing problem caused by multiple thyristors in a series structure,the increased junction temperature problem caused by extremely high currents,and the reverse recovery phenomenon that arises from the thyristor’s physical structure.Hence,a series of detailed theoretical analyses,simulations,and experiments,including a thyristor junction temperature prediction method and reverse recovery process modeling,were carried out to optimize the design.Finally,the reliability and stability of the thyristor stack were verified by a series of prototype experiments.The results confirmed the correctness and accuracy of the proposed thyristor stack design method and also indicated that the proposed thyristor stack can meet the application conditions of a 100 k A QPS in the CRAFT project.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10974013,10774013,10804006 and 60825407)the Research Fund for the Doctoral Program of Higher Education,China (Grant Nos. 20070004024 and 20070004031)+2 种基金the Beijing Science and Technology New Star Program,China (Grant No. 2007A024),and the 111 Project (Grant No. B08002)the Excellent Doctor’s Science and Technology Innovation Foundation of Beijing Jiaotong University,China (Grant No. 141049522)the Research Grants from the Academy of Sciences for the Third World (TWAS)
文摘In this paper, the electroluminescence quenching mechanism in a 5,6,11,12-tetraphenylnaphthacene （Rubrene） doped host-vip system is studied by utilizing a specially designed organic light-emitting diode with an emission layer consisting of a few periodic host/vip structures. Tris-（8-hydroxyquinoline） aluminium （Alq3） and Rubrene are used as the host and the vip, respectively. The thickness variation of the vip layer in each period enables the study of the effect of molecule aggregation, and the thickness variation of the host layer suggests a long range quenching mechanism of dipole-dipole interaction. The long range quenching mechanism is a Forster process, and the FSrster radius of Rubrene is between 3 and 10 nm.
基金Supported by The National Natural Science Foundation of China (No. 59835170).
文摘Considering some characteristics of large-scale standing quench furnace, such as great heat inertia, evident time lag, strong coupling influence, hard to establish exact mathematical models of plant and etc, an artificial intelligent fuzzy control algorithm is put forward in this paper. Through adjusting the on-off ratio of electric heating elements, the temperature in furnace is controlled accurately. This paper describes structure and qualities of the large-scale standing quench furnace briefly, introduces constitution of control system, and expounds principle and implementation of intelligent control algorithm. The applied results prove that the intelligent control system can completely satisfy the technological requirements. Namely, it can realize fast increasing temperature with a little overshoot, exact holding temperature, and well-distributed temperature in quench furnace. It has raised the output and quality of aluminum material, and brought the outstanding economic and social benefits.
基金Supported by the National Natural Science Foundation of China(10771024,11101060,11171048)
文摘This paper deals with the quenching behavior of positive solutions to the Newton filtration equations coupled with boundary singularities.We determine quenching rates for non-simultaneous quenching at first,and then establish the criteria to identify the simultaneous and non-simultaneous quenching in terms of the parameters involved.
文摘In this paper, the initial boundary value problem of semilinear degenerate reaction-diffusion systems is studied. The regularization method and upper and lower solutions technique are employed to show the existence and continuation of a positive classical solution. The location of quenching points is found. The critical length is estimated by the eigenvalue method.
文摘The theoretic renormalization group approach is applied to the study of the critical behavior of non-interacting system with long-range correlated quenched impurities, which has a power-like correlations . To two-loop order, the asymptotic scaling laws and the critical exponents are studied in the frame of a double expansion with ρ of order . In , it is argued that the initial slip exponent θ = 0 together with the dynamic exponent is exact in this kind of random system.
文摘This paper studies quenching properties of solutions of a semilinear parabolic system with localized reaction sources in a square domain. The system has the homogeneous Dirichlet boundary condition and null initial condition. We prove that solutions quench simultaneously, and compute approximated critical values of the system using a numerical method.
基金sponsored by the National Natural Science Foun-dation of China(Grant Nos.52271122,52203384).
文摘A cyclic quenching treatment(CQT)succeeded in turning a 2.3 GPa maraging steel with a Charpy impact energy of 9 J into a new grade with the same strength but a Charpy impact energy of 20 J upon 4 cyclic treatments.The improvement of mechanical properties is attributed to the refinement and increased chemical heterogeneity of the martensitic substructure,rather than the refinement of prior austenite grain(PAG),as well as the Transformation-Induced Plasticity(TRIP)effect facilitated by small austenite grains.The role of local segregation of Ni during CQT in the formation of Ni-rich austenite grains,Ni-rich martensite laths and Ni-poor martensite laths,was investigated and verified by DICTRA simulations.This study highlights the important influence of Ni partitioning behavior during CQT,providing insights into microstructural evolution and mechanical properties.
基金the financial support from the National Natural Science Foundation of China(No.21971085)the Natural Science Foundation of Shandong Province(No.ZR2021MB008)。
文摘In the field of Raman spectroscopy detection,the quest for a non–noble metal,recyclable,and highly sensitive detection substrate is of utmost importance.In this work,a new crystalline and noble metal–free substrate of[Bi(DMF)_(8)][PMo_(12)O_(40)](Bi–PMo_(12))is designed,which is composed of[PMo_(12)O_(40)]^(3−)and solvated[Bi(DMF)_(8)]^(3+)cations.Mechanistic studies have revealed that Raman scattering quenching phenomenon arises from two main factors.Firstly,it arises from the absorption of the scattered light due to the transition of a single electron in the reduced state of MoV between 4d orbitals.Secondly,after the interaction between the substrate and hydrazine,the surface undergoes varying degrees of roughening,leading to an impact on the scattered light intensity.These two effects collectively contribute to the detection of low concentrations of N_(2)H_(4).As a result,Bi–PMo_(12)opens up a novel Raman scattering quenching mechanism to realize the detection of reduced N_(2)H_(4)small molecules.A remarkably low detection limit of 4.5×10^(−9)ppm for N_(2)H_(4)is achieved on the Bi–PMo_(12)substrate.This detection has a lower concentration than the currently known SERS detection of N_(2)H_(4).Moreover,Bi–PMo_(12)can be recovered and reused through recrystallization,achieving a recovery rate of up to ca.51%.This study reveals the underlying potential of crystalline polyoxometalate materials in the field of Raman detection,thus opening up new avenues for highly sensitive analysis using Raman techniques.
基金Chongqing Natural Science Foundation(No.CSTB2022NSCQ-MSX1394)Graduate Research and Innovation Foundation of Chongqing,China(Grant No.CYS22008)+2 种基金Open Project of State Key Laboratory of Advanced Special Steel,Shanghai Key Laboratory of Advanced Ferrometallurgy,Shanghai University(SKLASS 2023-10)the Science and Technology Commission of Shanghai Municipality(No.19DZ2270200)the Open Project of the Large Casting and Forging Manufacturing Technology Engineering Center of Shanghai Institute of Mechanical and Electrical Engineering,State Key Laboratory of Vanadium and Titanium Resources Open Fund(No.2022P4FZG04A).
文摘The microstructure evolution and mechanical properties of a Fe-0.12C-0.2Si-1.6Mn-0.3Cr-0.0025B(wt.%)steel with different initial microstructures,i.e.,hot rolled(HR)and cold rolled-annealed(CRA),were studied through optical microscopy,scanning electron microscopy,electron channeling contrast imaging,microhardness and room temperature uniaxial tensile tests.After water quenching from 930℃ to room temperature,a fully martensitic microstructure was obtained in both as-quenched HR and CRA specimens,which shows a microhardness of 480±5 HV,and no significant difference in microstructure and microhardness was observed.Tensile test results show that the product of tensile strength and total elongation(UTS×TE)of the as-quenched HR specimen,i.e.,24.1 GPa%,is higher than that of the as-quenched CRA specimen,i.e.,18.9 GPa%.While,after being tempered at 300℃,the martensitic microstructures and mechanical properties of the two as-quenched specimens change significantly due to the synergy role of the matrix phase softening and the precipitation strengthening.Concerning the maximum UTS×TE,it is 18.9 GPa%obtained in the as-quenched CRA one,while that is 24.4 GPa%obtained in the HR specimen after tempered at 300℃ for 5 min.
基金Project(52205421)supported by the National Natural Science Foundation of ChinaProject(AA23023028)supported by the Guangxi Science and Technology Major Project,China+2 种基金Projects(2022B0909070001,2020B010186001)supported by the Key Research and Development Projects of Guangdong Province,ChinaProject(2021B0101220006)supported by the Guangdong Key Areas Research and Development Program“Chip,Software and Computing”Major Project,ChinaProjects(2021RC2087,2022JJ30570)supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘The effect of hot deformation on the quench sensitivity of the 7085 alloy was studied through hardness testing and microstructure characterization.The findings indicate that hot deformation enhances the quench sensitivity of the 7085 alloy,with the hardness difference between water quenching and air cooling increasing from 5.4%(before hot deformation)to 10.4%(after hot deformation).In the undeformed samples,the Al3Zr particles within the grains exhibit better coherent with the Al matrix.During slow quenching,only theηphase is observed on Al3Zr particles and at the grain boundaries.Hot deformation leads to a mass of recrystallization and the formation of subgrains with high dislocation density.This results in an increase in the types,quantities,and sizes of heterogeneous precipitates during quenching.In the slow quenching process,high angle grain boundaries are best for the nucleation and growth of theηphase.Secondly,a substantial quantity ofηand T phases precipitate on the non-coherent Al3Zr phase within the recrystallized grains.The locations with high dislocation density subgrains(boundaries)serve as nucleation positions for theηand T phases precipitating.Additionally,the Y phase is observed to precipitate at dislocation sites within the subgrains.
基金support from the National Key Research and Development Program of China(2022YFE0206000)the National Natural Science Foundation of China(U2001219,51973064)+3 种基金the Guangdong Basic and Applied Basic Research Foundation(2023B1515040003,2024A1515010262)the Natural Science Foundation of Guangdong Province(2023B1212060003)the Open Project Program of Wuhan National Laboratory for Optoelectronics(NO.2021WNLOKF014)the State Key Lab of Luminescent Materials and Devices,South China University of Technology(Skllmd-2023-05).
文摘Formamidinium lead bromide(FAPbBr_(3))perovskite nanocrystals(NCs)are promising for display and lighting due to their ultra-pure green emission.However,the thermal quenching will exacerbate their performance degradation in practical applications,which is a common issue for halide perovskites.Here,we reported the heat-resistant FAPbBr_(3)NCs prepared by a ligand-engineered room-temperature synthesis strategy.An aromatic amine,specificallyβ-phenylethylamine(PEA)or 3-fluorophenylethylamine(3-F-PEA),was incoporated as the short-chain ligand to expedite the crystallization rate and control the size distribution of FAPbBr_(3)NCs.Employing this ligand engineering approach,we synthesized high quality FAPbBr_(3)NCs with uniform grain size and reduced long-chain alkyl ligands,resulting in substantially suppressed thermal quenching and enhanced carrier transportation in the perovskite NCs films.Most notably,more than 90%of the room temperature PL intensity in the 3-F-PEA modified FAPbBr_(3)NCs film was preserved at 380 K.Consequently,we fabricated ultra-pure green EL devices with a room temperature external quantum efficiency(EQE)as high as 21.9%at the luminance of above 1,000 cd m^(-2),and demonstrated less than 10%loss in EQE at 343 K.This study introduces a novel room temperature method to synthesize efficient FAPbBr_(3)NCs with exceptional thermal stability,paving the way for advanced optoelectronic device applications.
基金financial support from the National Natural Science Foundation of China(No.52274372)the National Key Research and Development Program of China(No.2021YFB3702404).
文摘A martensitic initial microstructure before hot forming was prepared by direct quenching after hot rolling of the hot formed steel and the effect of such initial microstructure on mechanical properties of steel was analyzed. The process of direct quenching after hot rolling which replaced the steps of coiling and cold rolling was termed as compact process. As the temperature before direct quenching falls within the non-recrystallization range, the deformed austenite grains exhibit flattened morphology along the hot rolling direction, and the high-density dislocations and significant strain energy in deformed austenite are inherited by directly quenched martensite. Moreover, due to promotion of austenite nucleation and subsequent recrystallization during the reverse transformation process in hot forming, both reversed austenite grains and martensite laths are significantly refined. Compared to the conventional process with an initial microstructure consisting of fully recrystallized ferrite and cementite, the compact process reduces average prior austenite grain sizes from 12.5 to 5.5 μm and martensite lath widths from 202 to 123 nm. Additionally, the compact process results in a higher density of dislocations in test steel, leading to maximum yield strength (1294 MPa) and ultimate tensile strength (2266 MPa). Compared to conventional process, this compact process significantly improves the mechanical properties of the hot formed steels while simplifying the production.
