Using quantum discord(QD)and geometric quantum discord(GQD),quantum correlation dynamics is investigated for two coupled qubits within a multiqubit interacting system in the zero-temperature bosonic reservoir,under bo...Using quantum discord(QD)and geometric quantum discord(GQD),quantum correlation dynamics is investigated for two coupled qubits within a multiqubit interacting system in the zero-temperature bosonic reservoir,under both weak and strong qubit-reservoir coupling regimes.The multiqubit system is connected with either a common bosonic reservoir(CBR)or multiple independent bosonic reservoirs(IBRs).In the CBR case,our findings indicate that both QD and GQD can be strengthened by increasing the number of qubits in the multiqubit system.Furthermore,we study the steady state QD and GQD in the strong coupling regime,and find that the stable value in the long-time limit is determined exclusively by the number of qubits.The evolution period of QD and GQD gets longer as the dipole–dipole interaction(DDI)strength increases,which helps prolong the correlation time and thus preserves the quantum correlation under the weak coupling regime.Further analysis reveals notable differences between the CBR and IBRs scenarios.In the IBRs case,the decay of QD and GQD becomes slower compared to the CBR case,with both measures tending to zero at a reduced rate.Moreover,GQD consistently exhibits lower values than QD in both scenarios.These findings provide valuable insights into the selection of appropriate correlation measurement techniques for quantifying quantum correlations.展开更多
In this study,six-dimensional(6D)time-dependent wave packet calcula-tions were employed to investigate the dissociation of HCl molecules on two bimetallic surfaces,Cu/Ag(111)and Cu/Au(111).These calculations were base...In this study,six-dimensional(6D)time-dependent wave packet calcula-tions were employed to investigate the dissociation of HCl molecules on two bimetallic surfaces,Cu/Ag(111)and Cu/Au(111).These calculations were based on two accurate potential energy surfaces(PESs)constructed using neu-ral network methodology.Density functional theory(DFT)calculations revealed that the static barrier heights for HCl on Cu/Ag(111)and Cu/Au(111)were 0.32 eV and 0.28 eV,respectively.These values are significantly lower than the barrier height on pure Cu(111)(0.52 eV),primarily due to surface strain effects.However,it was found that the 6D dissociation probability of HCl in(v=0,1,j=0)states on Cu/Au(111)was considerably lower,despite its barrier height being 0.04 eV lower than that for Cu/Ag(111).The underlying mechanism for this observation was attributed to the non-monotonic dependence of the minimum energy path(MEP)on the molecular orientation,which was induced by charge transfer effect for HCl+Cu/Au(111).In contrast,HCl+Cu/Ag(111)exhibited a monotonic dependence.These contrasting behaviors led to dis-tinct differences in rotational alignment and excitation effects for the two reactions.展开更多
We present a general numerical simulation method to solve non-Markovian dynamics of an open quantum system influenced by quantum Brownian motion.Based on the determined memory kernel function,this method enables the r...We present a general numerical simulation method to solve non-Markovian dynamics of an open quantum system influenced by quantum Brownian motion.Based on the determined memory kernel function,this method enables the resolution of non-Markovian dynamics for a wide range of system Hamiltonians and spectral densities.The system dynamics are described by exact integro-differential operator equations without any common approximations and they are simulated in this work by definite-number equations with stochastic initial conditions.This approach ensures the applicability of mature numerical methods and maintains computational complexity that remains largely invariant,even when dealing with more complex models.The high accuracy of our simulation is evident from a comparison with the results obtained from corresponding exact master equations,underscoring the reliability and precision of our method.展开更多
It is well known that the A-square term must be considered in both cavity and circuit quantum electrodynamics systems,because it arises in the derivation from the minimal coupling Hamiltonian at any finite coupling st...It is well known that the A-square term must be considered in both cavity and circuit quantum electrodynamics systems,because it arises in the derivation from the minimal coupling Hamiltonian at any finite coupling strength.In this paper,we study the quantum Rabi model with A-square terms using the Bogoliubov operator approach.After a unitary transformation,the A-square terms can be eliminated,resulting in a modified quantum Rabi model with renormalized parameters.A transcendental function responsible for the exact solution is then derived.The presence of the A-square terms is found to significantly alter the energy spectrum.The dynamics are also studied using the obtained exact wave function,which is sensitive to the strength of the A-square terms at strong coupling.We believe that these results could be observed in future light–matter interaction systems in the ultra-strong and deep strong coupling regimes.展开更多
Quantumdot inks(QDIs)represent an emerging functionalmaterial that integrates nanotechnology and fluid engineering,demonstrating significant application potential in flexible optoelectronics and high-color gamut displ...Quantumdot inks(QDIs)represent an emerging functionalmaterial that integrates nanotechnology and fluid engineering,demonstrating significant application potential in flexible optoelectronics and high-color gamut displays.Their wide applicability is due to a unique quantum confinement effect that enables precise spectral tunability and solution-processable properties.However,the complex fluid dynamics associated with QDIs at micro-/nano-scales severely limit the accuracy of inkjet printing and pattern deposition.This review systematically addresses recent advances in the hydrodynamics of QDIs,establishing scientific mechanisms and key technical breakthroughs from an interdisciplinary perspective.Current research has focused on three optimization directions:(1)regulating ligand structures to enhance colloidal stability,flow consistency,and anti-shear performance while mitigating nanoparticle aggregation;(2)incorporating low-viscosity or high-volatility solvents and surface tension modifiers to modify droplet dynamic characteristics and suppress the“coffee-ring”effect;(3)integrating advanced technologies such as electrohydrodynamic jetting and microfluidic targeted deposition to achieve submicron pattern resolution and high film uniformity,expanding adaptability in flexible electronics,biosensing,and anti-counterfeiting printing.A comparison of current technical routes and critical performance indicators has identified the dominant variables that influence QDI macroscopic/microscopic properties.A comprehensive analytical framework is presented which spans material structure,rheological behavior,manufacturing processes,and functional characteristics.Moreover,a proposed engineering‘structure–parameter–behavior–performance’serves to link core–shell structure,formulation parameters(e.g.,viscosity and surface tension),fluidic behavior(e.g.,shear thinning and Marangoni flow),and device performance(e.g.,resolution and photoluminescence efficiency).The findings provide theoretical support and decision-making guidance for the large-scale application and interdisciplinary expansion of QDIs.展开更多
Static disorder plays a crucial role in the electronic dynamics and spec-troscopy of complex molecular sys-tems.Traditionally,obtaining ob-servables averaged over static disor-der requires thousands of realiza-tions v...Static disorder plays a crucial role in the electronic dynamics and spec-troscopy of complex molecular sys-tems.Traditionally,obtaining ob-servables averaged over static disor-der requires thousands of realiza-tions via direct sampling of the dis-order distribution,leading to high computational costs.In this work,we extend the auxiliary degree-of-freedom based matrix product state(MPS)method to handle system-bath correlated thermal equilibrium initial states,which can capture static disorder effects using a one-shot quantum dynamical simulation.We validate the effectiveness of the extended method by computing the dipole-dipole time correlation function of the Holstein model relevant to the emission spectrum of molecular aggregates.Our results show that the one-shot method is very accu-rate with only a moderate increase in MPS bond dimension,thereby significantly reducing computational cost.Moreover,it enables the generation of a much larger number of samples than the conventional direct sampling method at negligible additional cost,thus reducing sta-tistical errors.This method provides a broadly useful tool for calculating equilibrium time cor-relation functions in system-bath coupled models with static disorder.展开更多
Driven critical dynamics in quantum phase transitions holds significant theoretical importance,and also has practical applications in fast-developing quantum devices.While scaling corrections have been shown to play i...Driven critical dynamics in quantum phase transitions holds significant theoretical importance,and also has practical applications in fast-developing quantum devices.While scaling corrections have been shown to play important roles in fully characterizing equilibrium quantum criticality,their impact on nonequilibrium critical dynamics has not been extensively explored.In this work,we investigate the driven critical dynamics in a two-dimensional quantum Heisenberg model.We find that in this model the scaling corrections arising from both finite system size and finite driving rate must be incorporated into the finite-time scaling form in order to properly describe the nonequilibrium scaling behaviors.In addition,improved scaling relations are obtained from the expansion of the full scaling form.We numerically verify these scaling forms and improved scaling relations for different starting states using the nonequilibrium quantum Monte Carlo algorithm.展开更多
The ability to accurately simulate the time evolu-tion of quantum systems stands as a cornerstone of modern molecular science.It provides the essential mechanistic bridge between a system’s microscopic structure and ...The ability to accurately simulate the time evolu-tion of quantum systems stands as a cornerstone of modern molecular science.It provides the essential mechanistic bridge between a system’s microscopic structure and its macroscopic function,a challenge first envisioned by Feynman.The central difficulty,and the unifying theme of this Special Topic,is the problem of“complexity”:a multifaceted challenge arising from the interplay of strongly coupled electronic and vibrational degrees of freedom,quantum statistics,and the non-trivial,often non-Markovian,memory effects exerted by a surrounding environment.展开更多
Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating el...Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating electron injection at the emitter to investigate the carrier dynamics time and impedance spectroscopy in GaAs/AlGaAs QWIPs. Our findings provide novel evidence that the escape time of electrons is the key limiting factor for the 3-dB bandwidth of QWIPs. Moreover, to characterize the impact of carrier dynamics time and non-equilibrium space charge region on impedance, we developed an equivalent circuit model where depletion region resistance and capacitance are employed to describe non-equilibrium space charge region. Using this model, we discovered that under illumination, both net charge accumulation caused by variations in carrier dynamics times within quantum wells and changes in width of non-equilibrium space charge region exert different dominant influences on depletion region capacitance at various doping concentrations.展开更多
We investigate dynamical quantum phase transitions(DQPTs)in Marko-vian open quantum systems using a variational quantum simulation(VQS)algorithm based on quantum state diffusion(QSD).This approach reformulates the Lin...We investigate dynamical quantum phase transitions(DQPTs)in Marko-vian open quantum systems using a variational quantum simulation(VQS)algorithm based on quantum state diffusion(QSD).This approach reformulates the Lindblad master equation as an ensemble of pure-state trajectories,enabling efficient simula-tion of dissipative quantum dynam-ics with effectively reduced quantum resources.Focusing on the one-di-mensional transverse-field Ising mod-el(TFIM),we simulate quench dynamics under both local and global Lindblad dissipation.The QSD-VQS algorithm accurately captures the nonanalytic cusps in the Loschmidt rate function,and reveals their modulation by dissipation strength and system size.Notably,DQPTs are gradually suppressed under strong local dissipation,while they persist under strong global dissipation due to collective environmental effects.Benchmarking against exact Lindblad solutions confirms the high accuracy and scalability of our method.展开更多
The quantum phase transition between Z_(2) plaquette valence bound solid(PVBS) and superfluid(SF) phases on the planar pyrochlore lattice(square ice) is under debate. To gain further insight, here, we focus on the dyn...The quantum phase transition between Z_(2) plaquette valence bound solid(PVBS) and superfluid(SF) phases on the planar pyrochlore lattice(square ice) is under debate. To gain further insight, here, we focus on the dynamical features of the hard-core Bose–Hubbard model on this lattice and study the excitation spectra by combining stochastic analytic continuation and quantum Monte Carlo simulation. In both PVBS and SF phases,a flat band with bow-tie structure is observed and can be explained by certain symmetries. At the transition point,the spectra turn to be continuous and gapless. A(2+1)-dimensional Abelian–Higgs model with mixed 't Hooft anomaly is proposed to describe the transition, where the anomaly matching predicts that the deconfinement can exist on the domain walls. From the snapshot of the spin configuration in real space, we found the existence of the domain wall. We also found that the spectrum along a specific path in momentum space from PVBS phase to the transition point can be well described by an XXZ spin chain, and the critical theory of XXZ spin chain matches the anomaly. The two-spinon continuum along this specific path implies additional domain walls(point defect) can emerge in the domain walls(line defect) and take the role of deconfinement at the transition point.展开更多
Multiple quantum coherences are often employed to describe quantum many-body dynamics in nuclear spin systems and recently,to characterize quantum phase transitions in trapped ions.Here we investigate the multiple-qua...Multiple quantum coherences are often employed to describe quantum many-body dynamics in nuclear spin systems and recently,to characterize quantum phase transitions in trapped ions.Here we investigate the multiple-quantum-coherence dynamics of a spin-1 Bose–Einstein condensate.By adjusting the quadratic Zeeman shift,the condensate exhibits three quantum phases.Our numerical results show that the spectrum of multiple quantum coherence does indeed catch the quantum critical points.More importantly,with only a few low-order multiple quantum coherences,the spin-1 condensate exhibits rich signals of the many-body dynamics,beyond conventional observables.The experimental implementation of such multiple quantum coherence protocol is also discussed.展开更多
In theoretical investigations of^(36)Ar published by Ge Ren et al.(Phys Lett B 138990,2024),^(36)Ar bubble nuclei,char acterized by central density depletions,were studied using the extended quantum molecular dynamics...In theoretical investigations of^(36)Ar published by Ge Ren et al.(Phys Lett B 138990,2024),^(36)Ar bubble nuclei,char acterized by central density depletions,were studied using the extended quantum molecular dynamics model.Three novel density distributions—microbubble,bubble,and cluster resonances—were identified,each showing distinc spectral signatures in the gamma-ray decay spectrum o the isoscalar monopole resonance.展开更多
Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space devel...Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space developed in J.Chem.Phys.145,204105(2016);151,024105(2019);J.Phys.Chem.Lett.12,2496(2021),non-covariant phase space functions,time-dependent weight functions,and time-dependent normalization factors to construct a novel class of phase space representations of the exact population dynamics of the two-state quantum system.The equations of motion of the trajectory on constraint phase space are isomorphic to the time-dependent Schrödinger equation.The contribution of each trajectory to the integral expression for the population dynamics is always positive semi-definite.We also prove that the triangle window function approach,albeit proposed as a heuristic empirical model in J.Chem.Phys.145,144108(2016),is related to a special case of the novel class and leads to an isomorphic representation of the exact population dynamics of the two-state quantum system.展开更多
In this paper,we consider the B?hmer–Vandersloot(BV)model of loop quantum black holes obtained from the improved dynamics approach.We adopt the Saini–Singh gauge,in which it was found analytically that the BV spacet...In this paper,we consider the B?hmer–Vandersloot(BV)model of loop quantum black holes obtained from the improved dynamics approach.We adopt the Saini–Singh gauge,in which it was found analytically that the BV spacetime is geodesically complete.We show that black/white hole horizons do not exist in this geodesically complete spacetime.Instead,there exists only an infinite number of transition surfaces,which always separate trapped regions from anti-trapped ones.Comments on the improved dynamics approach adopted in other models of loop quantum black holes are also given.展开更多
By casting evolution to the Bloch sphere, the dynamics of 2 × 2 matrix non-Hermitian systems are investigated in detail. This investigation reveals that there are four kinds of dynamical modes for such systems. T...By casting evolution to the Bloch sphere, the dynamics of 2 × 2 matrix non-Hermitian systems are investigated in detail. This investigation reveals that there are four kinds of dynamical modes for such systems. The different modes are classified by different kinds of fixed points, namely,the elliptic point, spiral point, critical node, and degenerate point. The Hermitian systems and the unbroken PT non-Hermitian cases belong to the category with elliptic points. The degenerate point just corresponds to the systems with exceptional point(EP). The topological properties of the fixed point are also discussed. It is interesting that the topological charge for the degenerate point is two, while the others are one.展开更多
Red turpentine beetle （RTB）, Dendroctongs valens LeConte, is a destructive forest invasive species in China, it mainly attacks Pings tabuliformis and P. bungeana. So far it has spread rapidly to the provinces of Sha...Red turpentine beetle （RTB）, Dendroctongs valens LeConte, is a destructive forest invasive species in China, it mainly attacks Pings tabuliformis and P. bungeana. So far it has spread rapidly to the provinces of Shanxi, Hebei, Henan, Shanxi and Beijing since its first outbreak in Shanxi Province in 1998, and has caused extensive tree mortality. Space-time dynamics of D. valens population and spatial sampling technique based on its spatial distribution pattern were ana- lyzed using geostatistical methods in the pure P. tabuliforis forests and mixedwood stands which were at different damage levels. According to the spatial distribu- tion of D. valeas population, the specific spatial sampling technique was also studied, and then was compared with traditional sampling technique. The spatial sam- piing technique combined with sampling theory and the biological characteristics of D. valens population, which not only could calcnlate the error of the sampling, but also could discuss the optimal sampling number and the optimum size of plot according to different damage levels and different stand types. This helps to explain population expansion and colonization mechanism of D. valens, and to provide a good reference for adopting snitable control measures.展开更多
The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe...The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe technique. By selectively exciting the core and shell carrier, the dynamics are studied in detail. Carrier relaxation is found faster in the conduction band of the CdS shell （about 130 fs） than that in the conduction band of the CdSe core （about 400 fs）. From the experiments it is distinctly demonstrated the existence of the defect states in the interface between the CdSe core and the CdS shell, indicating that ultrafast spectroscopy might be a suitable tool in studying interface and surface morphology properties in nanosystems.展开更多
The generalized Thirring model with impurity coupling is defined on two-dimensional noncommutativespace-time,a modified propagator and free energy are derived by means of functional integrals method.Moreover,quantum f...The generalized Thirring model with impurity coupling is defined on two-dimensional noncommutativespace-time,a modified propagator and free energy are derived by means of functional integrals method.Moreover,quantum fluctuations and excitation energies are calculated on two-dimensional black hole and soliton background.展开更多
The ultrafast carrier relaxation processes in CdTe quantum dots are investigated by femtosecond fluorescence upconversion spectroscopy.Photo-excited hole relaxing to the edge of the forbidden gap takes a maximal time ...The ultrafast carrier relaxation processes in CdTe quantum dots are investigated by femtosecond fluorescence upconversion spectroscopy.Photo-excited hole relaxing to the edge of the forbidden gap takes a maximal time of ～ 1.6 ps with exciting at 400 nm,depending on the state of the photo-excited hole.The shallow trapped states and deep trap states in the forbidden gap are confirmed for CdTe quantum dots.In addition,Auger relaxation of trapped carriers is observed to occur with a time constant of ～ 5 ps.A schematic model of photodynamics is established based on the results of the spectroscopy studies.Our work demonstrates that femtosecond fluorescence up-conversion spectroscopy is a suitable and effective tool in studying the transportation and conversion dynamics of photon energy in a nanosystem.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.11564013 and 11964010)the Natural Science Foundation of Hunan Province(Grant No.2020JJ4495)the Scientific Research Fund of Hunan Provincial Education Department,China(Grant Nos.22A0377 and 21A0333).
文摘Using quantum discord(QD)and geometric quantum discord(GQD),quantum correlation dynamics is investigated for two coupled qubits within a multiqubit interacting system in the zero-temperature bosonic reservoir,under both weak and strong qubit-reservoir coupling regimes.The multiqubit system is connected with either a common bosonic reservoir(CBR)or multiple independent bosonic reservoirs(IBRs).In the CBR case,our findings indicate that both QD and GQD can be strengthened by increasing the number of qubits in the multiqubit system.Furthermore,we study the steady state QD and GQD in the strong coupling regime,and find that the stable value in the long-time limit is determined exclusively by the number of qubits.The evolution period of QD and GQD gets longer as the dipole–dipole interaction(DDI)strength increases,which helps prolong the correlation time and thus preserves the quantum correlation under the weak coupling regime.Further analysis reveals notable differences between the CBR and IBRs scenarios.In the IBRs case,the decay of QD and GQD becomes slower compared to the CBR case,with both measures tending to zero at a reduced rate.Moreover,GQD consistently exhibits lower values than QD in both scenarios.These findings provide valuable insights into the selection of appropriate correlation measurement techniques for quantifying quantum correlations.
基金supported by the National Key R&D Program of China(No.2018YFE0203003)the National Natural Science Foundation of China(Nos.22173101,22173099,22288201,21703242)+3 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0970203)the Innovation Program for Quantum Science and Technology(No.2021ZD0303305)Dalian Talents Innovation Support Program(No.2021RD05)the Open Fund(SKLMRD-K202508)of the State Key Laboratory of Molecular Reaction Dynamics in Dalian Institute of Chemical Physics,Chinese Academy of Sciences.The computational resources are supported by SongShan Lake HPC Center(SSL-HPC)in Great Bay University.
文摘In this study,six-dimensional(6D)time-dependent wave packet calcula-tions were employed to investigate the dissociation of HCl molecules on two bimetallic surfaces,Cu/Ag(111)and Cu/Au(111).These calculations were based on two accurate potential energy surfaces(PESs)constructed using neu-ral network methodology.Density functional theory(DFT)calculations revealed that the static barrier heights for HCl on Cu/Ag(111)and Cu/Au(111)were 0.32 eV and 0.28 eV,respectively.These values are significantly lower than the barrier height on pure Cu(111)(0.52 eV),primarily due to surface strain effects.However,it was found that the 6D dissociation probability of HCl in(v=0,1,j=0)states on Cu/Au(111)was considerably lower,despite its barrier height being 0.04 eV lower than that for Cu/Ag(111).The underlying mechanism for this observation was attributed to the non-monotonic dependence of the minimum energy path(MEP)on the molecular orientation,which was induced by charge transfer effect for HCl+Cu/Au(111).In contrast,HCl+Cu/Ag(111)exhibited a monotonic dependence.These contrasting behaviors led to dis-tinct differences in rotational alignment and excitation effects for the two reactions.
基金supported by the National Natural Science Foundation of China(Grant No.12304389,12274053)the Science and Technology Research Project of Xiamen University of Technology(Grant No.YKJ19025R)the Scientific Research Foundation of NEU(Grant No.01270021920501*115)。
文摘We present a general numerical simulation method to solve non-Markovian dynamics of an open quantum system influenced by quantum Brownian motion.Based on the determined memory kernel function,this method enables the resolution of non-Markovian dynamics for a wide range of system Hamiltonians and spectral densities.The system dynamics are described by exact integro-differential operator equations without any common approximations and they are simulated in this work by definite-number equations with stochastic initial conditions.This approach ensures the applicability of mature numerical methods and maintains computational complexity that remains largely invariant,even when dealing with more complex models.The high accuracy of our simulation is evident from a comparison with the results obtained from corresponding exact master equations,underscoring the reliability and precision of our method.
基金supported by the National Science Foundation of China under Grant Nos.12305009(XYC)and 11834005(QHC)the China Postdoctoral Science Foundation under Grant No.2022M720387(XYC).
文摘It is well known that the A-square term must be considered in both cavity and circuit quantum electrodynamics systems,because it arises in the derivation from the minimal coupling Hamiltonian at any finite coupling strength.In this paper,we study the quantum Rabi model with A-square terms using the Bogoliubov operator approach.After a unitary transformation,the A-square terms can be eliminated,resulting in a modified quantum Rabi model with renormalized parameters.A transcendental function responsible for the exact solution is then derived.The presence of the A-square terms is found to significantly alter the energy spectrum.The dynamics are also studied using the obtained exact wave function,which is sensitive to the strength of the A-square terms at strong coupling.We believe that these results could be observed in future light–matter interaction systems in the ultra-strong and deep strong coupling regimes.
基金supported by the Shenzhen Polytechnic Research Fund(6023310025K)Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic(6023271017K)Horizontal Technology Development Project(6024260101K).
文摘Quantumdot inks(QDIs)represent an emerging functionalmaterial that integrates nanotechnology and fluid engineering,demonstrating significant application potential in flexible optoelectronics and high-color gamut displays.Their wide applicability is due to a unique quantum confinement effect that enables precise spectral tunability and solution-processable properties.However,the complex fluid dynamics associated with QDIs at micro-/nano-scales severely limit the accuracy of inkjet printing and pattern deposition.This review systematically addresses recent advances in the hydrodynamics of QDIs,establishing scientific mechanisms and key technical breakthroughs from an interdisciplinary perspective.Current research has focused on three optimization directions:(1)regulating ligand structures to enhance colloidal stability,flow consistency,and anti-shear performance while mitigating nanoparticle aggregation;(2)incorporating low-viscosity or high-volatility solvents and surface tension modifiers to modify droplet dynamic characteristics and suppress the“coffee-ring”effect;(3)integrating advanced technologies such as electrohydrodynamic jetting and microfluidic targeted deposition to achieve submicron pattern resolution and high film uniformity,expanding adaptability in flexible electronics,biosensing,and anti-counterfeiting printing.A comparison of current technical routes and critical performance indicators has identified the dominant variables that influence QDI macroscopic/microscopic properties.A comprehensive analytical framework is presented which spans material structure,rheological behavior,manufacturing processes,and functional characteristics.Moreover,a proposed engineering‘structure–parameter–behavior–performance’serves to link core–shell structure,formulation parameters(e.g.,viscosity and surface tension),fluidic behavior(e.g.,shear thinning and Marangoni flow),and device performance(e.g.,resolution and photoluminescence efficiency).The findings provide theoretical support and decision-making guidance for the large-scale application and interdisciplinary expansion of QDIs.
基金supported by the National Natural Science Foundation of China(No.22273005 and No.22422301)the Innovation Program for Quantum Science and Technology(No.2023ZD0300200)+1 种基金the National Security Academic Foundation(No.U2330201)the Fundamental Research Funds for the Central Universities.
文摘Static disorder plays a crucial role in the electronic dynamics and spec-troscopy of complex molecular sys-tems.Traditionally,obtaining ob-servables averaged over static disor-der requires thousands of realiza-tions via direct sampling of the dis-order distribution,leading to high computational costs.In this work,we extend the auxiliary degree-of-freedom based matrix product state(MPS)method to handle system-bath correlated thermal equilibrium initial states,which can capture static disorder effects using a one-shot quantum dynamical simulation.We validate the effectiveness of the extended method by computing the dipole-dipole time correlation function of the Holstein model relevant to the emission spectrum of molecular aggregates.Our results show that the one-shot method is very accu-rate with only a moderate increase in MPS bond dimension,thereby significantly reducing computational cost.Moreover,it enables the generation of a much larger number of samples than the conventional direct sampling method at negligible additional cost,thus reducing sta-tistical errors.This method provides a broadly useful tool for calculating equilibrium time cor-relation functions in system-bath coupled models with static disorder.
基金supported by the National Natural Science Foundation of China(Grant Nos.12104109,12222515,and 12075324)the Science and Technology Projects in Guangzhou(Grant No.2024A04J2092)the Science and Technology Projects in Guangdong Province(Grant No.211193863020).
文摘Driven critical dynamics in quantum phase transitions holds significant theoretical importance,and also has practical applications in fast-developing quantum devices.While scaling corrections have been shown to play important roles in fully characterizing equilibrium quantum criticality,their impact on nonequilibrium critical dynamics has not been extensively explored.In this work,we investigate the driven critical dynamics in a two-dimensional quantum Heisenberg model.We find that in this model the scaling corrections arising from both finite system size and finite driving rate must be incorporated into the finite-time scaling form in order to properly describe the nonequilibrium scaling behaviors.In addition,improved scaling relations are obtained from the expansion of the full scaling form.We numerically verify these scaling forms and improved scaling relations for different starting states using the nonequilibrium quantum Monte Carlo algorithm.
文摘The ability to accurately simulate the time evolu-tion of quantum systems stands as a cornerstone of modern molecular science.It provides the essential mechanistic bridge between a system’s microscopic structure and its macroscopic function,a challenge first envisioned by Feynman.The central difficulty,and the unifying theme of this Special Topic,is the problem of“complexity”:a multifaceted challenge arising from the interplay of strongly coupled electronic and vibrational degrees of freedom,quantum statistics,and the non-trivial,often non-Markovian,memory effects exerted by a surrounding environment.
基金financially supported by the National Natural Science Foundation of China (Grant No. 61991442)。
文摘Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating electron injection at the emitter to investigate the carrier dynamics time and impedance spectroscopy in GaAs/AlGaAs QWIPs. Our findings provide novel evidence that the escape time of electrons is the key limiting factor for the 3-dB bandwidth of QWIPs. Moreover, to characterize the impact of carrier dynamics time and non-equilibrium space charge region on impedance, we developed an equivalent circuit model where depletion region resistance and capacitance are employed to describe non-equilibrium space charge region. Using this model, we discovered that under illumination, both net charge accumulation caused by variations in carrier dynamics times within quantum wells and changes in width of non-equilibrium space charge region exert different dominant influences on depletion region capacitance at various doping concentrations.
基金supported by the National Natural Science Foundation of China(Nos.22273122,T2350009)the Guangdong Provincial Natural Science Foundation(No.2024A1515011504)computational resources and services provided by the national supercomputer center in Guangzhou.
文摘We investigate dynamical quantum phase transitions(DQPTs)in Marko-vian open quantum systems using a variational quantum simulation(VQS)algorithm based on quantum state diffusion(QSD).This approach reformulates the Lindblad master equation as an ensemble of pure-state trajectories,enabling efficient simula-tion of dissipative quantum dynam-ics with effectively reduced quantum resources.Focusing on the one-di-mensional transverse-field Ising mod-el(TFIM),we simulate quench dynamics under both local and global Lindblad dissipation.The QSD-VQS algorithm accurately captures the nonanalytic cusps in the Loschmidt rate function,and reveals their modulation by dissipation strength and system size.Notably,DQPTs are gradually suppressed under strong local dissipation,while they persist under strong global dissipation due to collective environmental effects.Benchmarking against exact Lindblad solutions confirms the high accuracy and scalability of our method.
基金supported by the start-up funding of CQNU (Grant No. 24XLB010)supported by the Science and Technology Research Program of Chongqing Municipal Education Commission (Grant No. KJQN202100514)+3 种基金funding from Chongqing Natural Science Foundation under Grant No. CSTB2022NSCQ-JQX0018the Fundamental Research Funds for the Central Universities Grant No. 2021CDJZYJH-003Xiaomi Foundation/Xiaomi Young Talents Programfunding from the National Science Foundation of China under Grant Nos. 12404169, 12147172, 12274046, 11874094, 12147102, and 12347101。
文摘The quantum phase transition between Z_(2) plaquette valence bound solid(PVBS) and superfluid(SF) phases on the planar pyrochlore lattice(square ice) is under debate. To gain further insight, here, we focus on the dynamical features of the hard-core Bose–Hubbard model on this lattice and study the excitation spectra by combining stochastic analytic continuation and quantum Monte Carlo simulation. In both PVBS and SF phases,a flat band with bow-tie structure is observed and can be explained by certain symmetries. At the transition point,the spectra turn to be continuous and gapless. A(2+1)-dimensional Abelian–Higgs model with mixed 't Hooft anomaly is proposed to describe the transition, where the anomaly matching predicts that the deconfinement can exist on the domain walls. From the snapshot of the spin configuration in real space, we found the existence of the domain wall. We also found that the spectrum along a specific path in momentum space from PVBS phase to the transition point can be well described by an XXZ spin chain, and the critical theory of XXZ spin chain matches the anomaly. The two-spinon continuum along this specific path implies additional domain walls(point defect) can emerge in the domain walls(line defect) and take the role of deconfinement at the transition point.
基金supported by the NSAF under Grant No.U1930201the National Natural Science Foundation of China(NSFC)under Grant Nos.12274331,91836101,12135018,12204428the Innovation Program for Quantum Science and Technology under Grant No.2021ZD0302100。
文摘Multiple quantum coherences are often employed to describe quantum many-body dynamics in nuclear spin systems and recently,to characterize quantum phase transitions in trapped ions.Here we investigate the multiple-quantum-coherence dynamics of a spin-1 Bose–Einstein condensate.By adjusting the quadratic Zeeman shift,the condensate exhibits three quantum phases.Our numerical results show that the spectrum of multiple quantum coherence does indeed catch the quantum critical points.More importantly,with only a few low-order multiple quantum coherences,the spin-1 condensate exhibits rich signals of the many-body dynamics,beyond conventional observables.The experimental implementation of such multiple quantum coherence protocol is also discussed.
文摘In theoretical investigations of^(36)Ar published by Ge Ren et al.(Phys Lett B 138990,2024),^(36)Ar bubble nuclei,char acterized by central density depletions,were studied using the extended quantum molecular dynamics model.Three novel density distributions—microbubble,bubble,and cluster resonances—were identified,each showing distinc spectral signatures in the gamma-ray decay spectrum o the isoscalar monopole resonance.
文摘Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space developed in J.Chem.Phys.145,204105(2016);151,024105(2019);J.Phys.Chem.Lett.12,2496(2021),non-covariant phase space functions,time-dependent weight functions,and time-dependent normalization factors to construct a novel class of phase space representations of the exact population dynamics of the two-state quantum system.The equations of motion of the trajectory on constraint phase space are isomorphic to the time-dependent Schrödinger equation.The contribution of each trajectory to the integral expression for the population dynamics is always positive semi-definite.We also prove that the triangle window function approach,albeit proposed as a heuristic empirical model in J.Chem.Phys.145,144108(2016),is related to a special case of the novel class and leads to an isomorphic representation of the exact population dynamics of the two-state quantum system.
基金partially supported by the National Key Research and Development Program of China under Grant No.2020YFC2201504partially supported by a NSF grant with the grant number:PHY2308845。
文摘In this paper,we consider the B?hmer–Vandersloot(BV)model of loop quantum black holes obtained from the improved dynamics approach.We adopt the Saini–Singh gauge,in which it was found analytically that the BV spacetime is geodesically complete.We show that black/white hole horizons do not exist in this geodesically complete spacetime.Instead,there exists only an infinite number of transition surfaces,which always separate trapped regions from anti-trapped ones.Comments on the improved dynamics approach adopted in other models of loop quantum black holes are also given.
基金supported by the National Natural Science Foundation of China(Grant No.12088101,and U2330401).
文摘By casting evolution to the Bloch sphere, the dynamics of 2 × 2 matrix non-Hermitian systems are investigated in detail. This investigation reveals that there are four kinds of dynamical modes for such systems. The different modes are classified by different kinds of fixed points, namely,the elliptic point, spiral point, critical node, and degenerate point. The Hermitian systems and the unbroken PT non-Hermitian cases belong to the category with elliptic points. The degenerate point just corresponds to the systems with exceptional point(EP). The topological properties of the fixed point are also discussed. It is interesting that the topological charge for the degenerate point is two, while the others are one.
基金Supported by Research Project of Jiangsu Entry-Exit Inspection and Quarantine Bureau(2015KJ49)Project of Beijing Municipal Education Commission(JD100220888)+2 种基金Project of Beijing Excellent Talents Funding(D Class)Project of Beijing Municipal Education Commission(JD100220888)Beijing Excellent Talents Funding(D Class)Project "Study on Prevention and Control Technology of Dendroctonus valens"
文摘Red turpentine beetle （RTB）, Dendroctongs valens LeConte, is a destructive forest invasive species in China, it mainly attacks Pings tabuliformis and P. bungeana. So far it has spread rapidly to the provinces of Shanxi, Hebei, Henan, Shanxi and Beijing since its first outbreak in Shanxi Province in 1998, and has caused extensive tree mortality. Space-time dynamics of D. valens population and spatial sampling technique based on its spatial distribution pattern were ana- lyzed using geostatistical methods in the pure P. tabuliforis forests and mixedwood stands which were at different damage levels. According to the spatial distribu- tion of D. valeas population, the specific spatial sampling technique was also studied, and then was compared with traditional sampling technique. The spatial sam- piing technique combined with sampling theory and the biological characteristics of D. valens population, which not only could calcnlate the error of the sampling, but also could discuss the optimal sampling number and the optimum size of plot according to different damage levels and different stand types. This helps to explain population expansion and colonization mechanism of D. valens, and to provide a good reference for adopting snitable control measures.
基金This work was supported by the National Natural Science Foundation of China （No.11074003） and the Key Program of Educational Commission of Anhui Province of China （No.KJ2010AI32）. For the help of Prof. J. L. Zhao at Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences in sample preparation is greatly appreciated.
文摘The intra- and inter-band relaxation dynamics of CdSe/CdS/ZnS core/shell/shell quantum dots are investigated with the aid of time-resolved nonlinear transmission spectra which are obtained using femtosecond pump-probe technique. By selectively exciting the core and shell carrier, the dynamics are studied in detail. Carrier relaxation is found faster in the conduction band of the CdS shell （about 130 fs） than that in the conduction band of the CdSe core （about 400 fs）. From the experiments it is distinctly demonstrated the existence of the defect states in the interface between the CdSe core and the CdS shell, indicating that ultrafast spectroscopy might be a suitable tool in studying interface and surface morphology properties in nanosystems.
基金Supported by the Natural Science Foundation of Sichuan Education Committee under Grant No.08ZA038
文摘The generalized Thirring model with impurity coupling is defined on two-dimensional noncommutativespace-time,a modified propagator and free energy are derived by means of functional integrals method.Moreover,quantum fluctuations and excitation energies are calculated on two-dimensional black hole and soliton background.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11074003 and 20973001)the Key Program of Educational Commission of Anhui Province of China (Grant No. KJ2010A132)
文摘The ultrafast carrier relaxation processes in CdTe quantum dots are investigated by femtosecond fluorescence upconversion spectroscopy.Photo-excited hole relaxing to the edge of the forbidden gap takes a maximal time of ～ 1.6 ps with exciting at 400 nm,depending on the state of the photo-excited hole.The shallow trapped states and deep trap states in the forbidden gap are confirmed for CdTe quantum dots.In addition,Auger relaxation of trapped carriers is observed to occur with a time constant of ～ 5 ps.A schematic model of photodynamics is established based on the results of the spectroscopy studies.Our work demonstrates that femtosecond fluorescence up-conversion spectroscopy is a suitable and effective tool in studying the transportation and conversion dynamics of photon energy in a nanosystem.
