Quantum interference effect serves as a critical strategy for addressing incorrect energy level alignment between frontier molecular orbitals and electrodes in molecular junctions. Weak-coupling structures offer an ef...Quantum interference effect serves as a critical strategy for addressing incorrect energy level alignment between frontier molecular orbitals and electrodes in molecular junctions. Weak-coupling structures offer an effective approach to suppress phonon thermal conductance. The thermoelectric properties of pure C_(3)N_(4) nanoribbon devices and C_(3)N_(4)-C_(20) molecular junctions are systematically investigated based on density functional theory(DFT) combined with nonequilibrium Green's function(NEGF) formalism. The results show that pure C_(3)N_(4) nanoribbon devices have superior charge transport capabilities and excellent Seebeck coefficients. A remarkable thermoelectric figure of merit(ZT = 0.98)is achieved near 0.09 e V. The pronounced scattering effect induced by embedding a C_(20) molecule in the center of the C_(3)N_(4) nanoribbon significantly suppresses phonon transport. A maximum ZT value of 1.68 is observed at 0.987 e V. The electron mobility of C_(3)N_(4)-C_(20)-par is effectively increased due to quantum interference effect which greatly improves the alignment between the C_(20) molecule's frontier orbital energy level and C_(3)N_(4) electrodes. The C_(3)N_(4)-C_(20)-van der Waals(vd W) molecular junction allows very few phonons to pass through the C_(20) molecule from the left electrode to the right electrode. As a result, the C_(3)N_(4)-C_(20)-vd W junction achieves an excellent ZT value of 3.82 near the Femi level.展开更多
In this article, we propose a general principle of quantum interference for quantum system, and based on this we propose a new type of computing machine, the duality computer, that may outperform in principle both cla...In this article, we propose a general principle of quantum interference for quantum system, and based on this we propose a new type of computing machine, the duality computer, that may outperform in principle both classical computer and the quantum computer. According to the general principle of quantum interference, the very essence of quantum interference is the interference of the sub-waves of the quantum system itself A quantum system considered here can be any quantum system： a single microscopic particle, a composite quantum system such as an atom or a molecule, or a loose collection of a few quantum objects such as two independent photons. In the duality computer, the wave of the duality computer is split into several sub-waves and they pass through different routes, where different computing gate operations are performed. These sub-waves are then re-combined to interfere to give the computational results. The quantum computer, however, has only used the particle nature of quantum object. In a duality computer, it may be possible to find a marked item from an unsorted database using only a single query, and all NP-complete problems may have polynomial algorithms. Two proof-of-the-principle designs of the duality computer are presented： the giant molecule scheme and the nonlinear quantum optics scheme. We also propose thought experiment to check the related fundamental issues, the measurement efficiency of a partial wave function.展开更多
In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （...In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （A ^1 Π,v = 3） with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.展开更多
Optical bistability （0t3） and optical multi-stability （OM） of a four-level A-type atomic system with two fold lower levels inside a unidirectional ring cavity is investigated. The effect of quantum interference ar...Optical bistability （0t3） and optical multi-stability （OM） of a four-level A-type atomic system with two fold lower levels inside a unidirectional ring cavity is investigated. The effect of quantum interference arising from spontaneous emission and incoherent pumping on 013 and OM is discussed. It is found that the threshold of OB and OM can be controlled by quantum interference mechanisms. In addition intensity of coupling field and the rate of an incoherent pumping field on behavior of OB and OM are then discussed.展开更多
This paper studies the narrow spectral feature appearing in a four-level system coupled by two strong coherent fields and probed by a weak laser field. The linewidth is examined as a function of the Rabi frequencies o...This paper studies the narrow spectral feature appearing in a four-level system coupled by two strong coherent fields and probed by a weak laser field. The linewidth is examined as a function of the Rabi frequencies of coupling fields, and the result is explained by using the dressed-state formalism.展开更多
To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecul...To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecules system is described. To simulate the experiment theoretically, the theoretical model on collision-induced rotational energy transfer in an atom- ^2П[case（a）]diatom system is presented based on the first order Born approximation taking into account of the long-range interaction potential. For the ^2П electronic state in the Hund＇s case（a） diatom, the degree of the interference is discussed. The interference angles of collision-induced rotational energy transfer of CN（A^2П） in Hund＇s case（a） with He, Ne, and Ar are calculated quantitatively. The key parameters in the determination of integral interference angles are obtained.展开更多
We constructed a 36-channel magnetocardiography（MCG） system based on low-Tc direct current（DC） superconducting quantum interference device（SQUID） magnetometers operated inside a magnetically shielded room（MSR）...We constructed a 36-channel magnetocardiography（MCG） system based on low-Tc direct current（DC） superconducting quantum interference device（SQUID） magnetometers operated inside a magnetically shielded room（MSR）. Weakly damped SQUID magnetometers with large Steward–Mc Cumber parameter βc（βc≈ 5）, which could directly connect to the operational amplifier without any additional feedback circuit, were used to simplify the readout electronics. With a flux-to-voltage transfer coefficient V / Φ larger than 420 μV/Φ0, the SQUID magnetometers had a white noise level of about 5.5 f T·Hz-1/2when operated in MSR. 36 sensing magnetometers and 15 reference magnetometers were employed to realize software gradiometer configurations. The coverage area of the 36 sensing magnetometers is 210×210 mm2. MCG measurements with a high signal-to-noise ratio of 40 d B were done successfully using the developed system.展开更多
Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate inf...Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate information, an experiment with a molecular beam is carried out, and thereby the relationship between the differential interference angle and the scattering angle is obtained. Based on the first-Born approximation of time-dependent perturbation theory, the theoretical model of CQI is developed in an atom-diatom system in the condition of the molecular beam, with the long-range interaction potential taken into account. The method of measuring correctly the differential interference angle is presented. The tendencies of the differential interference angle changing with the impact parameter and rel- ative velocity are discussed. The theoretical model presented here is important for understanding or performing the experiment in the molecular beam.展开更多
This paper studies the harmonic generation of the hydrogen atom subjected to a collinear bichromatic laser field by numerically solving the time-dependent Schrbdinger equation using the split-operator pseudo-spectral ...This paper studies the harmonic generation of the hydrogen atom subjected to a collinear bichromatic laser field by numerically solving the time-dependent Schrbdinger equation using the split-operator pseudo-spectral method. By adding a frequency variation to the additional field, the contributions of different pathways to particular order harmonic generation can be isolated. The quantum interference pattern between harmonic pathways, which influences the harmonic intensity, is found to be either constructive or destructive with respect to different relative phase of the two field components. Detailed description of up to the 35th-order harmonics and the harmonic pathways for a wide range of field parameters is presented.展开更多
We investigate the quantum interference of spin wave excitations of a spin-1 atomic Bose condensate confined in an optical lattice. Single-channel and dual-channel interactions are employed in our system, and their in...We investigate the quantum interference of spin wave excitations of a spin-1 atomic Bose condensate confined in an optical lattice. Single-channel and dual-channel interactions are employed in our system, and their induced excitations are compared. Also we consider the interplay of magneto-optical excitations, which leads to a constructive or destructive effect for the creation of magnons based on background excitations. The population distributions of excited magnons can be well controlled by steering the long-range dipole-dipole interactions. Such a scheme can be used to demonstrate conventional quantum-optical phenomena like dynamical Casimir effect at finite temperatures.展开更多
Quantum interference(QI)effects,which offer unique opportunities to widely manipulate the charge transport properties in the molecular junctions,will have the potential for achieving high thermopower.Here we developed...Quantum interference(QI)effects,which offer unique opportunities to widely manipulate the charge transport properties in the molecular junctions,will have the potential for achieving high thermopower.Here we developed a scanning tunneling microscope break junction technique to investigate the thermopower through single-molecule thiophene junctions.We observed that the thermopower of 2,4-TPSAc with destructive quantum interference(DQI)was nearly twice of 2,5-TP-SAc without DQI,while the conductance of the 2,4-TP-SAc was two orders of magnitude lower than that of 2,5-TP-SAc.Furthermore,we found the thermopower was almost the same by altering the anchoring group or thiophene core in the control experiments,suggesting that the QI effect is responsible for the increase of thermopower.The density functional theory(DFT)calculations are in quantitative agreement with the experimental data.Our results reveal that QI effects can provide a promising platform to enhance the thermopower of molecular junctions.展开更多
The photoelectron energy spectra （PESs） excited by monochromatic femtosecond x-ray pulses in the presence of a femtosecond laser are investigated. APES is composed of a set of separate peaks, showing interesting com...The photoelectron energy spectra （PESs） excited by monochromatic femtosecond x-ray pulses in the presence of a femtosecond laser are investigated. APES is composed of a set of separate peaks, showing interesting comb-like structures. These structures result from the quantum interferences between photoelectron wave packets generated at different times. The width and the localization of each peak as well as the number of peaks are determined by all the laser and x-ray parameters. Most of peak heights of the PES are higher than the classical predictions.展开更多
Balanced homodyne detection has been introduced as a reliable technique of reconstructing the quantum state of a single photon Fock state, which is based on coupling the single photon state and a strong coherent local...Balanced homodyne detection has been introduced as a reliable technique of reconstructing the quantum state of a single photon Fock state, which is based on coupling the single photon state and a strong coherent local oscillator in a beam splitter and detecting the field quadrature at the output ports separately. The main challenge associated with a tomographic characterization of the single photon state is mode matching between the single photon state and the local oscillator. Utilizing the heralded single photon generated by the spontaneous parametric process, the multi-mode theoretical model of quantum interference between the single photon state and the coherent state in the fiber beam splitter is established.Moreover, the analytical expressions of the temporal-mode matching coefficient and interference visibility and relationship between the two parameters are shown. In the experimental scheme, the interference visibility under various temporalmode matching coefficients is demonstrated, which is almost accordant with the theoretical value. Our work explores the principle of temporal-mode matching between the single photon state and the coherent photon state, originated from a local oscillator, and could provide guidance for designing the high-performance balanced homodyne detection system.展开更多
Understanding the impact of substituents on the quantum interference effect at single molecule scale is of great importance for the design of molecular devices.In this work,three platinum(Ⅱ)complexes with–H,–NH_(2)...Understanding the impact of substituents on the quantum interference effect at single molecule scale is of great importance for the design of molecular devices.In this work,three platinum(Ⅱ)complexes with–H,–NH_(2)and–NO_(2)groups on conductive backbones were designed and synthesized.Single-molecule conductance,which was measured using scanning tunnelling microscope break junction(STM-BJ)technique,demonstrated a conductance freeze phenomenon under the variation of substituents.Theoretical study revealed that,despite the electronic effect of the substituents shifting the energy level of molecular orbital,the quantum interference effect vanished the influence of electronic effect on the conductance and eventually leaded to the conductance freeze.展开更多
We present a method to implement the quantum partial search of the database separated into any number of blocks with qudits, D-level quantum systems. Compared with the partial search using qubits, our method needs few...We present a method to implement the quantum partial search of the database separated into any number of blocks with qudits, D-level quantum systems. Compared with the partial search using qubits, our method needs fewer iteration steps and uses the carriers of the information more economically. To illustrate how to realize the idea with concrete physical systems, we propose a scheme to carry out a twelve-dimensional partial search of the database partitioned into three blocks with superconducting quantum interference devices （SQUIDs） in cavity QED. Through the appropriate modulation of the amplitudes of the microwave pulses, the scheme can overcome the non-identity of the cavity-SQUID coupling strengths due to the parameter variations resulting from the fabrication processes. Numerical simulation under the influence of the cavity and SQUID decays shows that the scheme could be achieved efficiently within current state-of-the-art technology.展开更多
Manipulation of spontaneous emission from an atom confined in three kinds of modified reservoirs has been investigated by means of an elliptically polarized laser field. Some interesting phenomena such as the multi-pe...Manipulation of spontaneous emission from an atom confined in three kinds of modified reservoirs has been investigated by means of an elliptically polarized laser field. Some interesting phenomena such as the multi-peak structure, extreme spectral narrowing, and cancellation of spontaneous emission can be observed by adjusting controllable system parameters. Moreover, these phenomena depend on the constructive or destructive quantum interference between multiple decay channels and which can be changed appreciably by varying the phase difference between the two circularly polarized components of the probe field. These results demonstrate the importance of an elliptially polarized laser field in controlling the spontaneous emission and its potential applications in high-precision spectroscopy.展开更多
In the system with superconducting quantum interference devices （SQUID） in cavity, a scheme for constructing two-qubit quantum phase gate via a conventional geometric phase-shift is proposed by using a quantized cav...In the system with superconducting quantum interference devices （SQUID） in cavity, a scheme for constructing two-qubit quantum phase gate via a conventional geometric phase-shift is proposed by using a quantized cavity field and classical microwave pulses. In this scheme, the gate operation is realized in the subspace spanned by the two lower flux states of the SQUID system mud the population operator of the excited state has no effect on it. Thus the effect of decoherence caused from the levels of the SQUID system is possible to minimize. Under cavity decay, our strictly numerical simulation shows that it is also possible to realize the unconventional geometric phase gate. The experimental feasibility is discussed in detail.展开更多
Inspired by a recent experiment[Phys.Rev.Lett.122253201(2019)]that an unprecedented quantum interference was observed in the way of stimulated Raman adiabatic passage(STIRAP)due to the coexisting resonant-and detuned-...Inspired by a recent experiment[Phys.Rev.Lett.122253201(2019)]that an unprecedented quantum interference was observed in the way of stimulated Raman adiabatic passage(STIRAP)due to the coexisting resonant-and detuned-STIRAPs,we comprehensively study this effect.Our results uncover the scheme robustness towards any external-field fluctuations coming from laser intensity noise and imperfect resonance condition,as well as the persistence of high-contrast interference pattern even when more nearby excited levels are involved.We verify that an auxiliary dynamical phase accumulated in hold time caused by the presence of the quasi-dark state in detuned-STIRAP can sensitively manipulate the visibility and frequency of the interference pattern,representing a new hallmark to measure the hyperfine energy accurately.The robust stability of the scheme comes from the intrinsic superiority embedded in the STIRAP mechanism that preserves the coherence of population transfer,which promises a remarkable performance of quantum interference in a practical implementation.展开更多
Spectrally uncorrelated biphotons are the essential resources for achieving various quantum information processing protocols.We theoretically investigate the generation of spectrally uncorrelated biphotons emitted by ...Spectrally uncorrelated biphotons are the essential resources for achieving various quantum information processing protocols.We theoretically investigate the generation of spectrally uncorrelated biphotons emitted by spontaneous fourwave mixing from a fiber nonlinear interferometer which consists of an N-stage nonlinear gain fiber and an(N-1)-stage dispersion modulation fiber.The output biphoton states of nonlinear interference are the coherent superposition of various biphoton states born in each nonlinear fiber,and thus the interference fringe will reshape the biphoton joint spectra.As a result,resorting to Taylor expansion to first order for phase mismatching,we theoretically verify that the orientation of phase matching contours will rotate in a specific way with only varying the length of dispersion modulation fiber.The rotation in orientation of phase matching contours may result in spectrally uncorrelated biphotons and even arbitrary correlation biphotons.Further,we choose micro/nanofiber as the nonlinear gain fiber and single-mode communication fiber as dispersion modulation fiber to numerically simulate the generation of spectrally uncorrelated biphotons from spontaneous fourwave mixing.Here,due to significant frequency detuning(hundreds of THz),Raman background noise can be considerably suppressed,even at room temperature,and photons with largely tunable wavelengths can be achieved,indicating a practicability in many quantum fields.A photon mode purity of 97.2%will be theoretically attained without weakening the heralding nature of biphoton sources.We think that this fiber nonlinear interference with the flexibly engineered quantum state can be an excellent practical source for quantum information processing.展开更多
We present a scheme to realize geometric phase-shift gate for two superconducting quantum interference device （SQUID） qubits coupled to a single-mode microwave field. The geometric phase-shift gate operation is perf...We present a scheme to realize geometric phase-shift gate for two superconducting quantum interference device （SQUID） qubits coupled to a single-mode microwave field. The geometric phase-shift gate operation is performed in two lower flux states, and the excited state [2〉 would not participate in the procedure. The SQUIDs undergo no transitions during the gate operation. Thus, the docoherence due to energy spontaneous emission based on the levels of SQUIDs are suppressed. The gate is insensitive to the cavity decay throughout the operation since the cavity mode is displaced along a circle in the phase space, acquiring a phase conditional upon the two lower flux states of the SQUID qubits, and the cavity mode is still in the original vacuum state. Based on the SQUID qubits interacting with the cavity mode, our proposed approach may open promising prospects for quantum iogic in SQUID-system.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 12164046)。
文摘Quantum interference effect serves as a critical strategy for addressing incorrect energy level alignment between frontier molecular orbitals and electrodes in molecular junctions. Weak-coupling structures offer an effective approach to suppress phonon thermal conductance. The thermoelectric properties of pure C_(3)N_(4) nanoribbon devices and C_(3)N_(4)-C_(20) molecular junctions are systematically investigated based on density functional theory(DFT) combined with nonequilibrium Green's function(NEGF) formalism. The results show that pure C_(3)N_(4) nanoribbon devices have superior charge transport capabilities and excellent Seebeck coefficients. A remarkable thermoelectric figure of merit(ZT = 0.98)is achieved near 0.09 e V. The pronounced scattering effect induced by embedding a C_(20) molecule in the center of the C_(3)N_(4) nanoribbon significantly suppresses phonon transport. A maximum ZT value of 1.68 is observed at 0.987 e V. The electron mobility of C_(3)N_(4)-C_(20)-par is effectively increased due to quantum interference effect which greatly improves the alignment between the C_(20) molecule's frontier orbital energy level and C_(3)N_(4) electrodes. The C_(3)N_(4)-C_(20)-van der Waals(vd W) molecular junction allows very few phonons to pass through the C_(20) molecule from the left electrode to the right electrode. As a result, the C_(3)N_(4)-C_(20)-vd W junction achieves an excellent ZT value of 3.82 near the Femi level.
基金The project supported by the National Fundamental Research Program under Grant No. 001CB309308, National Natural Science Foundation of China under Grant Nos. 10325521 and 60433050, and the SRFDP Program of the Ministry of Education of China
文摘In this article, we propose a general principle of quantum interference for quantum system, and based on this we propose a new type of computing machine, the duality computer, that may outperform in principle both classical computer and the quantum computer. According to the general principle of quantum interference, the very essence of quantum interference is the interference of the sub-waves of the quantum system itself A quantum system considered here can be any quantum system： a single microscopic particle, a composite quantum system such as an atom or a molecule, or a loose collection of a few quantum objects such as two independent photons. In the duality computer, the wave of the duality computer is split into several sub-waves and they pass through different routes, where different computing gate operations are performed. These sub-waves are then re-combined to interfere to give the computational results. The quantum computer, however, has only used the particle nature of quantum object. In a duality computer, it may be possible to find a marked item from an unsorted database using only a single query, and all NP-complete problems may have polynomial algorithms. Two proof-of-the-principle designs of the duality computer are presented： the giant molecule scheme and the nonlinear quantum optics scheme. We also propose thought experiment to check the related fundamental issues, the measurement efficiency of a partial wave function.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 （2003） 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO （A ^1 Π,v = 3） with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.
文摘Optical bistability （0t3） and optical multi-stability （OM） of a four-level A-type atomic system with two fold lower levels inside a unidirectional ring cavity is investigated. The effect of quantum interference arising from spontaneous emission and incoherent pumping on 013 and OM is discussed. It is found that the threshold of OB and OM can be controlled by quantum interference mechanisms. In addition intensity of coupling field and the rate of an incoherent pumping field on behavior of OB and OM are then discussed.
基金Project supported by the Natural Science Foundation from Hebei Province, China (Grant No A2005000091)
文摘This paper studies the narrow spectral feature appearing in a four-level system coupled by two strong coherent fields and probed by a weak laser field. The linewidth is examined as a function of the Rabi frequencies of coupling fields, and the result is explained by using the dressed-state formalism.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.10374040） and the Fund of the Educational Department of Liaoning Province of China （No.20060347 and No.2008290）.
文摘To study theoretically the relationship between the integral interference angle and the scat- tering angle in collisional quantum interference, the integral interference angle of atom- ^2П[case（a）] diatomic molecules system is described. To simulate the experiment theoretically, the theoretical model on collision-induced rotational energy transfer in an atom- ^2П[case（a）]diatom system is presented based on the first order Born approximation taking into account of the long-range interaction potential. For the ^2П electronic state in the Hund＇s case（a） diatom, the degree of the interference is discussed. The interference angles of collision-induced rotational energy transfer of CN（A^2П） in Hund＇s case（a） with He, Ne, and Ar are calculated quantitatively. The key parameters in the determination of integral interference angles are obtained.
基金Project supported by"One Hundred Persons Project"of the Chinese Academy of Sciences and the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB04020200)
文摘We constructed a 36-channel magnetocardiography（MCG） system based on low-Tc direct current（DC） superconducting quantum interference device（SQUID） magnetometers operated inside a magnetically shielded room（MSR）. Weakly damped SQUID magnetometers with large Steward–Mc Cumber parameter βc（βc≈ 5）, which could directly connect to the operational amplifier without any additional feedback circuit, were used to simplify the readout electronics. With a flux-to-voltage transfer coefficient V / Φ larger than 420 μV/Φ0, the SQUID magnetometers had a white noise level of about 5.5 f T·Hz-1/2when operated in MSR. 36 sensing magnetometers and 15 reference magnetometers were employed to realize software gradiometer configurations. The coverage area of the 36 sensing magnetometers is 210×210 mm2. MCG measurements with a high signal-to-noise ratio of 40 d B were done successfully using the developed system.
基金Project supported by the National Natural Science Foundation of China （Grant No 10374040）,
文摘Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate information, an experiment with a molecular beam is carried out, and thereby the relationship between the differential interference angle and the scattering angle is obtained. Based on the first-Born approximation of time-dependent perturbation theory, the theoretical model of CQI is developed in an atom-diatom system in the condition of the molecular beam, with the long-range interaction potential taken into account. The method of measuring correctly the differential interference angle is presented. The tendencies of the differential interference angle changing with the impact parameter and rel- ative velocity are discussed. The theoretical model presented here is important for understanding or performing the experiment in the molecular beam.
基金Project supported by the National Natural Science Foundation of China (Grant No 10374074)
文摘This paper studies the harmonic generation of the hydrogen atom subjected to a collinear bichromatic laser field by numerically solving the time-dependent Schrbdinger equation using the split-operator pseudo-spectral method. By adding a frequency variation to the additional field, the contributions of different pathways to particular order harmonic generation can be isolated. The quantum interference pattern between harmonic pathways, which influences the harmonic intensity, is found to be either constructive or destructive with respect to different relative phase of the two field components. Detailed description of up to the 35th-order harmonics and the harmonic pathways for a wide range of field parameters is presented.
基金Supported by the National Basic Research Program of China (973 Program) under Grant No. 2011CB921604+4 种基金the National Natural Science Foundation of China under Grant Nos. 11004057, 10828408Educational Commission of Henan Province of China under Grant No. 01026631082the “Chen Guang” Project Supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation under Grant No.10CG24
文摘We investigate the quantum interference of spin wave excitations of a spin-1 atomic Bose condensate confined in an optical lattice. Single-channel and dual-channel interactions are employed in our system, and their induced excitations are compared. Also we consider the interplay of magneto-optical excitations, which leads to a constructive or destructive effect for the creation of magnons based on background excitations. The population distributions of excited magnons can be well controlled by steering the long-range dipole-dipole interactions. Such a scheme can be used to demonstrate conventional quantum-optical phenomena like dynamical Casimir effect at finite temperatures.
基金supported by the National Natural Science Foundation of China(Nos.21722305,21933012,31871877)the National Key R&D Program of China(No.2017YFA0204902)+4 种基金the Fundamental Research Funds for the Central Universities(Nos.20720200068,20720190002)the Natural Science Foundation of Shanghai(No.20ZR1471600)the Science and Technology Commission of Shanghai Municipality(No.19DZ2271100)Natural Science Foundation of Fujian Province(No.2018J06004)the Beijing National Laboratory for Molecular Sciences(No.BNLMS202005)。
文摘Quantum interference(QI)effects,which offer unique opportunities to widely manipulate the charge transport properties in the molecular junctions,will have the potential for achieving high thermopower.Here we developed a scanning tunneling microscope break junction technique to investigate the thermopower through single-molecule thiophene junctions.We observed that the thermopower of 2,4-TPSAc with destructive quantum interference(DQI)was nearly twice of 2,5-TP-SAc without DQI,while the conductance of the 2,4-TP-SAc was two orders of magnitude lower than that of 2,5-TP-SAc.Furthermore,we found the thermopower was almost the same by altering the anchoring group or thiophene core in the control experiments,suggesting that the QI effect is responsible for the increase of thermopower.The density functional theory(DFT)calculations are in quantitative agreement with the experimental data.Our results reveal that QI effects can provide a promising platform to enhance the thermopower of molecular junctions.
基金Project supported by the National Natural Science Foundation of China (Grant No 10675014)
文摘The photoelectron energy spectra （PESs） excited by monochromatic femtosecond x-ray pulses in the presence of a femtosecond laser are investigated. APES is composed of a set of separate peaks, showing interesting comb-like structures. These structures result from the quantum interferences between photoelectron wave packets generated at different times. The width and the localization of each peak as well as the number of peaks are determined by all the laser and x-ray parameters. Most of peak heights of the PES are higher than the classical predictions.
基金Project supported by the National Special Fund for Major Research Instrument Development of China(Grant No.11527808)the Young Scientists Fund of the National Natural Science Foundation of China(Grant No.11504262)+2 种基金the National Basic Research Program of China(Grant No.2014CB340103)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120032110055)the Tianjin Research Program of Application Foundation and Advanced Technology,China(Grant No.14JCQNJC02300)
文摘Balanced homodyne detection has been introduced as a reliable technique of reconstructing the quantum state of a single photon Fock state, which is based on coupling the single photon state and a strong coherent local oscillator in a beam splitter and detecting the field quadrature at the output ports separately. The main challenge associated with a tomographic characterization of the single photon state is mode matching between the single photon state and the local oscillator. Utilizing the heralded single photon generated by the spontaneous parametric process, the multi-mode theoretical model of quantum interference between the single photon state and the coherent state in the fiber beam splitter is established.Moreover, the analytical expressions of the temporal-mode matching coefficient and interference visibility and relationship between the two parameters are shown. In the experimental scheme, the interference visibility under various temporalmode matching coefficients is demonstrated, which is almost accordant with the theoretical value. Our work explores the principle of temporal-mode matching between the single photon state and the coherent photon state, originated from a local oscillator, and could provide guidance for designing the high-performance balanced homodyne detection system.
基金the National Natural Science Foundation of China(No.92061117)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZR129)。
文摘Understanding the impact of substituents on the quantum interference effect at single molecule scale is of great importance for the design of molecular devices.In this work,three platinum(Ⅱ)complexes with–H,–NH_(2)and–NO_(2)groups on conductive backbones were designed and synthesized.Single-molecule conductance,which was measured using scanning tunnelling microscope break junction(STM-BJ)technique,demonstrated a conductance freeze phenomenon under the variation of substituents.Theoretical study revealed that,despite the electronic effect of the substituents shifting the energy level of molecular orbital,the quantum interference effect vanished the influence of electronic effect on the conductance and eventually leaded to the conductance freeze.
基金Project supported by the National Natural Science Foundation of China(Grant No.10774192)
文摘We present a method to implement the quantum partial search of the database separated into any number of blocks with qudits, D-level quantum systems. Compared with the partial search using qubits, our method needs fewer iteration steps and uses the carriers of the information more economically. To illustrate how to realize the idea with concrete physical systems, we propose a scheme to carry out a twelve-dimensional partial search of the database partitioned into three blocks with superconducting quantum interference devices （SQUIDs） in cavity QED. Through the appropriate modulation of the amplitudes of the microwave pulses, the scheme can overcome the non-identity of the cavity-SQUID coupling strengths due to the parameter variations resulting from the fabrication processes. Numerical simulation under the influence of the cavity and SQUID decays shows that the scheme could be achieved efficiently within current state-of-the-art technology.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11004069 and 91021011the Doctoral Foundation of the Ministry of Education of China under Grant No.20100142120081the National Basic Research Program of China under Grant No.2012CB922103
文摘Manipulation of spontaneous emission from an atom confined in three kinds of modified reservoirs has been investigated by means of an elliptically polarized laser field. Some interesting phenomena such as the multi-peak structure, extreme spectral narrowing, and cancellation of spontaneous emission can be observed by adjusting controllable system parameters. Moreover, these phenomena depend on the constructive or destructive quantum interference between multiple decay channels and which can be changed appreciably by varying the phase difference between the two circularly polarized components of the probe field. These results demonstrate the importance of an elliptially polarized laser field in controlling the spontaneous emission and its potential applications in high-precision spectroscopy.
基金The project supported by National Fundamental Research Program of China under Grant No.2005CB724508National Natural Science Foundation of China under Grant Nos.60478029,90503010,10634060,and 10575040
文摘In the system with superconducting quantum interference devices （SQUID） in cavity, a scheme for constructing two-qubit quantum phase gate via a conventional geometric phase-shift is proposed by using a quantized cavity field and classical microwave pulses. In this scheme, the gate operation is realized in the subspace spanned by the two lower flux states of the SQUID system mud the population operator of the excited state has no effect on it. Thus the effect of decoherence caused from the levels of the SQUID system is possible to minimize. Under cavity decay, our strictly numerical simulation shows that it is also possible to realize the unconventional geometric phase gate. The experimental feasibility is discussed in detail.
基金the National Natural Science Foundation of China(Grant Nos.11474094 and 11104076)the Science and Technology Commission of Shanghai Municipality,China(Grant No.18ZR1412800).
文摘Inspired by a recent experiment[Phys.Rev.Lett.122253201(2019)]that an unprecedented quantum interference was observed in the way of stimulated Raman adiabatic passage(STIRAP)due to the coexisting resonant-and detuned-STIRAPs,we comprehensively study this effect.Our results uncover the scheme robustness towards any external-field fluctuations coming from laser intensity noise and imperfect resonance condition,as well as the persistence of high-contrast interference pattern even when more nearby excited levels are involved.We verify that an auxiliary dynamical phase accumulated in hold time caused by the presence of the quasi-dark state in detuned-STIRAP can sensitively manipulate the visibility and frequency of the interference pattern,representing a new hallmark to measure the hyperfine energy accurately.The robust stability of the scheme comes from the intrinsic superiority embedded in the STIRAP mechanism that preserves the coherence of population transfer,which promises a remarkable performance of quantum interference in a practical implementation.
基金Project supported by the Science and Technology Key Project of Henan Province,China(Grant No.182102210577)the National Natural Science Foundation of China(Grant No.61605249)。
文摘Spectrally uncorrelated biphotons are the essential resources for achieving various quantum information processing protocols.We theoretically investigate the generation of spectrally uncorrelated biphotons emitted by spontaneous fourwave mixing from a fiber nonlinear interferometer which consists of an N-stage nonlinear gain fiber and an(N-1)-stage dispersion modulation fiber.The output biphoton states of nonlinear interference are the coherent superposition of various biphoton states born in each nonlinear fiber,and thus the interference fringe will reshape the biphoton joint spectra.As a result,resorting to Taylor expansion to first order for phase mismatching,we theoretically verify that the orientation of phase matching contours will rotate in a specific way with only varying the length of dispersion modulation fiber.The rotation in orientation of phase matching contours may result in spectrally uncorrelated biphotons and even arbitrary correlation biphotons.Further,we choose micro/nanofiber as the nonlinear gain fiber and single-mode communication fiber as dispersion modulation fiber to numerically simulate the generation of spectrally uncorrelated biphotons from spontaneous fourwave mixing.Here,due to significant frequency detuning(hundreds of THz),Raman background noise can be considerably suppressed,even at room temperature,and photons with largely tunable wavelengths can be achieved,indicating a practicability in many quantum fields.A photon mode purity of 97.2%will be theoretically attained without weakening the heralding nature of biphoton sources.We think that this fiber nonlinear interference with the flexibly engineered quantum state can be an excellent practical source for quantum information processing.
基金The project supported by the National Natural Science Foundation of China under Grant No. 10574126.
文摘We present a scheme to realize geometric phase-shift gate for two superconducting quantum interference device （SQUID） qubits coupled to a single-mode microwave field. The geometric phase-shift gate operation is performed in two lower flux states, and the excited state [2〉 would not participate in the procedure. The SQUIDs undergo no transitions during the gate operation. Thus, the docoherence due to energy spontaneous emission based on the levels of SQUIDs are suppressed. The gate is insensitive to the cavity decay throughout the operation since the cavity mode is displaced along a circle in the phase space, acquiring a phase conditional upon the two lower flux states of the SQUID qubits, and the cavity mode is still in the original vacuum state. Based on the SQUID qubits interacting with the cavity mode, our proposed approach may open promising prospects for quantum iogic in SQUID-system.
