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Thermally robust bis(imino)pyridyl iron catalysts for ethylene polymerization:Synergy effects of weakπ-πinteraction,steric bulk,and electronic tuning
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作者 Heng Gao Zhaocong Cheng +5 位作者 Guangshui Tu Zonglin Qiu Xieyi Xiao Haotian Zhou Handou Zheng Haiyang Gao 《Chinese Chemical Letters》 2025年第5期336-341,共6页
A series of“half-sandwich”bis(imino)pyridyl iron complexes with a substituted 8-(p-Xphenyl)naphthylamine(X=OMe,Me,CF3)was designed and synthesized by combining weakπ-πinteraction with steric and electronic tunings... A series of“half-sandwich”bis(imino)pyridyl iron complexes with a substituted 8-(p-Xphenyl)naphthylamine(X=OMe,Me,CF3)was designed and synthesized by combining weakπ-πinteraction with steric and electronic tunings.The weak noncovalentπ-πinteraction as well as the steric and electronic effects of bis(imino)pyridyl iron complexes were identified by experimental analyses and calculations.The roles of weakπ-πinteraction,steric bulk,and electronic tuning on the ethylene polymerization performance of bis(imino)pyridyl iron catalysts were studied in detail.The combination ofπ-πinteraction with steric and electronic tunings can access to thermally stable bis(imino)pyridyl iron at 130°C. 展开更多
关键词 Bis(imino)pyridyl iron π-πinteraction Steric effect Electronic effect Ethylene polymerization
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Independent and interactive effects of N and P additions on foliar P fractions in evergreen forests of southern China 被引量:1
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作者 Qingquan Meng Zhijuan Shi +3 位作者 Zhengbing Yan Hans Lambers Yan Luo Wenxuan Han 《Forest Ecosystems》 2025年第1期66-73,共8页
Fertilization or atmospheric deposition of nitrogen(N)and phosphorus(P)to terrestrial ecosystems can alter soil N(P)availability and the nature of nutrient limitation for plant growth.Changing the allocation of leaf P... Fertilization or atmospheric deposition of nitrogen(N)and phosphorus(P)to terrestrial ecosystems can alter soil N(P)availability and the nature of nutrient limitation for plant growth.Changing the allocation of leaf P fractions is potentially an adaptive strategy for plants to cope with soil N(P)availability and nutrient-limiting conditions.However,the impact of the interactions between imbalanced anthropogenic N and P inputs on the concentrations and allocation proportions of leaf P fractions in forest woody plants remains elusive.We conducted a metaanalysis of data about the concentrations and allocation proportions of leaf P fractions,specifically associated with individual and combined additions of N and P in evergreen forests,the dominant vegetation type in southern China where the primary productivity is usually considered limited by P.This assessment allowed us to quantitatively evaluate the effects of N and P additions alone and interactively on leaf P allocation and use strategies.Nitrogen addition(exacerbating P limitation)reduced the concentrations of leaf total P and different leaf P fractions.Nitrogen addition reduced the allocation to leaf metabolic P but increased the allocation to other fractions,while P addition showed opposite trends.The simultaneous additions of N and P showed an antagonistic(mutual suppression)effect on the concentrations of leaf P fractions,but an additive(summary)effect on the allocation proportions of leaf P fractions.These results highlight the importance of strategies of leaf P fraction allocation in forest plants under changes in environmental nutrient availability.Importantly,our study identified critical interactions associated with combined N and P inputs that affect leaf P fractions,thus aiding in predicting plant acclimation strategies in the context of intensifying and imbalanced anthropogenic nutrient inputs. 展开更多
关键词 Anthropogenic nutrient inputs Individual and combined effects interactive effects Leaf phosphorus fractions Nitrogen and phosphorus additions Nutrient-utilization strategies Woody plants
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Mapping QTLs with epistatic effects and QTL×environment interactions for plant height using a doubled haploid population in cultivated wheat 被引量:39
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作者 Kunpu Zhang Jichun Tian Liang Zhao Shanshan Wang 《Journal of Genetics and Genomics》 SCIE CAS CSCD 北大核心 2008年第2期119-127,共9页
Quantitative trait loci (QTLs) for plant height in wheat (Triticum aestivum L.) were studied using a set of 168 doubled haploid (DH) lines, which were derived from the cross Huapei 3/Yumai 57. A genetic linkage ... Quantitative trait loci (QTLs) for plant height in wheat (Triticum aestivum L.) were studied using a set of 168 doubled haploid (DH) lines, which were derived from the cross Huapei 3/Yumai 57. A genetic linkage map was constructed using 283 SSR and 22 EST-SSR markers. The DH population and the parents were evaluated for wheat plant height in 2005 and 2006 in Tai'an and 2006 in Suzhou. QTL analyses were performed using the software of QTLNetwork version 2.0 based on the mixed linear model. Four additive QTLs and five pairs of epistatic effects were detected, which were distributed on chromosomes 3A, 4B, 4D, 5A, 6A, 7B, and 7D. Among them, three additive QTLs and three pairs of epistatic QTLs showed QTL×environment interactions (QEs). Two major QTLs, Qph4B and Qph4D, which accounted for 14.51% and 20.22% of the phenotypic variation, were located similar to the reported locations of the dwarfing genes Rhtl and Rht2, respectively. The Qph3A-2 with additive effect was not reported in previous linkage mapping studies. The total QTL effects detected for the plant height explained 85.04% of the phenotypic variation, with additive effects 46.07%, epistatic effects 19.89%, and QEs 19.09%. The results showed that both additive effects and epistatic effects were important genetic bases of wheat plant height, which were subjected to environmental modifications, and caused dramatic changes in phenotypic effects. The information obtained in this study will be useful for manipulating the QTLs for wheat plant height by molecular marker-assisted selection (MAS). 展开更多
关键词 doubled haploid population epistatic effects plant height quantitative trait loci QTL×environment interactions wheat (Triticum aestivum L.)
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Anomalous Hall effect in Bernal tetralayer graphene enhanced by spin-orbit interaction
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作者 Zhuangzhuang Qu Zhihao Chen +9 位作者 Xiangyan Han Zhiyu Wang Zhuoxian Li Qianling Liu Wenjun Zhao Kenji Watanabe Takashi Taniguchi Zhi-Gang Cheng Zizhao Gan Jianming Lu 《Chinese Physics B》 2025年第3期177-181,共5页
Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to inv... Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to investigate the influence of SOI on the anomalous Hall effect(AHE).In this structurally asymmetric device,by comparing the magnitude of AHE at positive and negative displacement fields,we find that AHE is strongly enhanced by bringing electrons in proximity to the WSe_(2) layer.Meanwhile,the enhanced AHE signal persists up to 80 K,providing important routes for topological device applications at high temperatures. 展开更多
关键词 anomalous Hall effect proximity effect Bernal tetralayer graphene spin-orbit interaction
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Identification of QTL-by-environment interaction by controlling polygenic background effect
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作者 Fuping Zhao Lixian Wang Shizhong Xu 《Journal of Genetics and Genomics》 2025年第7期915-926,共12页
The quantitative trait loci(QTL)-by-environment(Q × E) interaction effect is hard to detect because there are no effective ways to control the genomic background. In this study, we propose a linear mixed model th... The quantitative trait loci(QTL)-by-environment(Q × E) interaction effect is hard to detect because there are no effective ways to control the genomic background. In this study, we propose a linear mixed model that simultaneously analyzes data from multiple environments to detect Q × E interactions. This model incorporates two different kinship matrices derived from the genome-wide markers to control both main and interaction polygenic background effects. Simulation studies demonstrate that our approach is more powerful than the meta-analysis and inclusive composite interval mapping methods. We further analyze four agronomic traits of rice across four environments. A main effect QTL is identified for 1000-grain weight(KGW), while no QTL are found for tiller number. Additionally, a large QTL with a significant Q × E interaction is detected on chromosome 7 affecting grain number, yield, and KGW. This region harbors two important genes, PROG1 and Ghd7. Furthermore, we apply our mixed model to analyze lodging in barley across six environments. The six regions exhibiting Q × E interaction effects identified by our approach overlap with the SNPs previously identified using EM and MCMC-based Bayesian methods, further validating the robustness of our approach. Both simulation studies and empirical data analyses show that our method outperforms all other methods compared. 展开更多
关键词 Q×E interaction Main effect META-ANALYSIS Mixed model Polygenic background
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Effect of vehicle-bridge interaction on nonlinear seismic performance of bridge under strong earthquakes
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作者 Ke Chen Zhibin Jin Haoyuan Yang 《High-Speed Railway》 2025年第3期215-228,共14页
Railway bridges are continuously loaded by railway trains;therefore, it is important to understand the nonlinear seismic response of the Vehicle-Bridge Interaction (VBI) system under strong earthquakes. For this purpo... Railway bridges are continuously loaded by railway trains;therefore, it is important to understand the nonlinear seismic response of the Vehicle-Bridge Interaction (VBI) system under strong earthquakes. For this purpose, the nonlinear behavior of the pier was introduced into the in-house VBI solvers. The nonlinear the seismic response of the VBI system was comprehensively evaluated using this model, and the effect of the vehicle dynamics on seismic performance of the bridge was identified. It was found that the seismic responses of most simply-supported bridges were reduced in the presence of railway trains due to the out-of-phase motion of the vehicle-bridge system. Meanwhile, the nonlinear behavior of the pier can reduce the vehicle’s seismic responses. Therefore, ignoring the nonlinear behavior of the pier during strong earthquakes can significantly overestimate the seismic response of the vehicle. 展开更多
关键词 Bridge nonlinear behavior Vehicle dynamics effect Seismnic safety Vehicle-bridge interaction Pier height
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Peer effect of corporate ESG performance:A strategic interaction perspective
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作者 ZHANG Chen-feng 《Ecological Economy》 2025年第1期66-80,共15页
As the goal of"low carbon"sustainable development becomes more salient,the corporations'environmental,social,and governance(ESG)practices are under higher visibility.How to promote the ESG performance of... As the goal of"low carbon"sustainable development becomes more salient,the corporations'environmental,social,and governance(ESG)practices are under higher visibility.How to promote the ESG performance of corporations has become a big challenge that needs to be solved.Spatial econometrics methods based on panel data on listed corporations in the period from 2018 to 2023 are used in the paper to empirically analyze the peer effect of a corporation from the view of strategic interaction.The results found relatively positive industry peer effects as well as regional peer effects.However,the latter is much weaker.Industry-wise results indicate that most sectors demonstrate positive peer competition on ESG issues,with only a few,like the special equipment manufacturing industry,not showing significant peer effects.The empirical results in this paper support the mode of cooperative interaction among firms,help broaden the scope of understanding factors that encourage ESG practices,and suggest relevant policies for boosting corporate social responsibilities and sustainable development through encouraging factors. 展开更多
关键词 ESG performance peer effects strategic interactions among corporations spatial econometric methodology
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Rarefaction effect on non-equilibrium characteristics of laminar shock wave/boundary layer interaction
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作者 Jiahui SONG Long MIAO +4 位作者 Aiguo XU Yanbiao GAN Feng CHEN Yugan LIAO Xiao HOU 《Chinese Journal of Aeronautics》 2025年第10期311-326,共16页
A Discrete Boltzmann Method(DBM)with a Maxwell-type boundary condition is constructed to investigate the influence of rarefaction on laminar Shock Wave/Boundary Layer Interaction(SWBLI).Due to the complexity of compre... A Discrete Boltzmann Method(DBM)with a Maxwell-type boundary condition is constructed to investigate the influence of rarefaction on laminar Shock Wave/Boundary Layer Interaction(SWBLI).Due to the complexity of compressible flow,a Knudsen number vector Kn,whose components include the local Knudsen numbers such as Kn_(ρ)and Kn_(U),is introduced to characterize the local structures,where Kn_(ρ)and Kn_(U)are Knudsen numbers defined in terms of the density and velocity interfaces,respectively.Since first focusing on the steady state of SWBLI,the DBM considers up to the second-order Kn_(ρ)(rarefaction/non-equilibrium)effects.The model is validated using Mach number 2 SWBLI and the necessity of using DBM with sufficient physical accuracy is confirmed by the shock collision problem.Key findings include the following:the leading-edge shock wave increases the local density Knudsen number Kn_(ρ)and eventually leads to the failure of linear constitutive relations in the Navier-Stokes(N-S)model and surely also in the lower-order DBM;the non-equilibrium effect differences in regions behind the leading-edge shock wave are primarily correlated with Kn_(ρ),while in the separation region are primarily correlated with Kn_(U);the non-equilibrium quantities D_(2)and D_(4,2),as well as the viscous entropy production rate S_(NOMF)can be used to identify the separation zone.The findings clarify various effects and main mechanisms in different regions associated with SWBLI,which are concealed in N-S model. 展开更多
关键词 Rarefaction effects Discrete Boltzmann method Shock wave/boundary layer interaction Thermodynamic non-equilibrium Kinetic theory
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Genetic and Genotype × Environment Interaction Effects for Appearance Quality of Rice 被引量:4
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作者 Sharifi Peyman Dehghani Hamid +1 位作者 Mumeni Ali Moghaddam Mohammad 《Agricultural Sciences in China》 CAS CSCD 2009年第8期891-901,共11页
This study was conducted to generate genetic information in rice varieties based on a complete diallel crosses over two years. The results indicated that genotype effect was significant for all traits. Genotype ×... This study was conducted to generate genetic information in rice varieties based on a complete diallel crosses over two years. The results indicated that genotype effect was significant for all traits. Genotype × environment interaction effects were significant only for cooked grain length (CGL) and cooked grain shape (CGSH). General combining ability (GCA) and specific combining ability (SCA) effects were significant for entire traits, which indicated the important roles of both additive and non-additive gene actions. GCA x environment interaction effects were significant for CGL, CGSH and grain elongation index (GEI). In the controlling of the inheritance of milled grain shape (GSH), milled grain width (MGW), GEI, milled grain length (MGL), CGSH and cooked grain width (CGW), the additive gene effects were more important than non-additive one. The average degree of dominance was within the range of partial dominance for all of the traits. The narrow-sense heritability was ranged from 0.65 (GSH) to 0.36 (CGL). GCA effects were significant for all of the parents in milled grain length and it was significant for some of the parents in other traits. The crosses of Deilmani × IRFAON-215 exhibited significant SCA for GEI. The positive mean of heterosis was observed for CGW. The highest maximum values of heterosis were revealed in GEI, flowed by GSH, MGW and CGW. GCA and MPV were significantly and positively correlated together for all traits. 展开更多
关键词 appearance quality diallel analysis genetic main effects environment interaction milling quality RICE
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Interaction effects of flotation reagents for SAG mill reject of copper sulphide ore using response surface methodology 被引量:7
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作者 Ali AHMADI Mojtaba REZAEI Seyed Mohammad SADEGHIEH 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第3期792-806,共15页
Flotation reagents have a complex behaviour in the beneficiation of base minerals in clayey ores.Interaction effects of reagents on the efficiency of copper flotation for a highly clayey low-grade sulphide ore were in... Flotation reagents have a complex behaviour in the beneficiation of base minerals in clayey ores.Interaction effects of reagents on the efficiency of copper flotation for a highly clayey low-grade sulphide ore were investigated using a central composite design.Preliminary results showed that sodium-isopropyl-xanthate(SIPX)and O-isopropyl-N-ethyl-thionocarbamate(IPETC)were found to be the most efficient collectors in the presence of lime as the pH regulator.The effects of dosage of collectors(SIPX and IPETC)and the dosage of methyl-isobutyl-carbonyl(MIBC)as frother on the separation efficiency were evaluated at different pH levels.Based on the analysis of variance(ANOVA),the interaction effects of the collector−pH and collector−frother were significant for the separation efficiency.At the low level of collector dosage,increasing pH from 9 to 11 enhanced copper separation efficiency from 81%to 86%for IPETC and from 77%to 86%for SIPX.Results of ANOVA showed that the maximum copper separation efficiency(88.7%)was obtained at the dosages of 8.6 g/t SIPX,7 g/t IPETC and 20 g/t MIBC at pH 11.Finally,it was concluded that a mixture of SIPX and IPETC collectors was more suitable to treat highly clayey sulphide ores. 展开更多
关键词 FLOTATION copper sulphide REAGENT interaction effect reject ore
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Nonlinear Analysis of Flexible and Steel Catenary Risers with Internal Flow and Seabed Interaction Effects 被引量:5
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作者 陈海飞 徐思朋 郭海燕 《Journal of Marine Science and Application》 2011年第2期156-162,共7页
Flexible risers and steel catenary risers often provide unique riser solutions for today’s deepwater field development. Accurate analysis of these slender structures, in which there are high-speed HP/HT internal flow... Flexible risers and steel catenary risers often provide unique riser solutions for today’s deepwater field development. Accurate analysis of these slender structures, in which there are high-speed HP/HT internal flows, is critical to ensure personnel and asset safety. In this study, a special global coordinate-based FEM rod model was adopted to identify and quantify the effects of internal flow and hydrostatic pressure on both flexible and deepwater steel catenary risers, with emphasis on the latter. By incorporating internal flow induced forces into the model, it was found that the internal flow contributes a new term to the effective tension expression. For flexible risers in shallow water, internal flow and hydrostatic pressure made virtually no change to effective tension by merely altering the riser wall tension. In deep water the internal pressure wielded a dominant role in governing the riser effective tension and furthering the static configuration, while the effect of inflow velocity was negligible. With respect to the riser seabed interaction, both the seabed support and friction effect were considered, with the former modeled by a nonlinear quadratic spring, allowing for a consistent derivation of the tangent stiffness matrix. The presented application examples show that the nonlinear quadratic spring is, when using the catenary solution as an initial static profile, an efficient way to model the quasi-Winkler-type elastic seabed foundation in this finite element scheme. 展开更多
关键词 flexible riser steel catenary riser (SCR) rod model internal flow effective tension seabed interaction
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Effects of the Interaction between Hydroxyapatite Nanoparticles and Hepatoma Cells 被引量:1
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作者 尹美珍 XU Weiguo +4 位作者 CUI Bingcun 戴红莲 HAN Yingchao YIN Yixia LI Shipu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第3期635-642,共8页
To gain a better understanding of the anticancer effects of hydroxyapatite (HAP) nanoparticles in vivo and in vitro, the effects of the interaction of HAP nanoparticles with hepatoma cells were explored. HAP nanopar... To gain a better understanding of the anticancer effects of hydroxyapatite (HAP) nanoparticles in vivo and in vitro, the effects of the interaction of HAP nanoparticles with hepatoma cells were explored. HAP nanoparticles were prepared by homogeneous precipitation and characterized by laser particle analysis and transmission electron microscopy (TEM). HAP nanoparticles were observed to be uniformly distributed, with rod-like shapes and diameters in the range of 42.1-87.1 nm. Overnight attached, suspended, and proliferating Bel-7402 cells were incubated with HAP nanoparticles. Inverted microscopy observation revealed that HAP nanoparticles with a cell membrane showed good adsorption. TEM demonstrated that HAP nanoparticles were present on the surface of cells, continuously taken up by cells through endocytosis, and transported in vesicles close to the nucleus. Fluorescence microscopy showed that the concentrations of intracellular Ca2+ labeled with Fluo-3 calcium fluorescent probe were significantly enhanced. In addition, inverted microscopy observation revealed that suspended cells treated with HAP nanoparticles did not adhere to the culture bottle, resulting in cell death. After the overnight attached cells were treated with HAP nanoparticles for 96 h with increasing doses of HAP nanoparticles, inverted microscopy observation revealed that cell proliferation was slowed and ceU-ceU adhesion was weakened. Feulgen staining and image analysis indicated that the nuclear DNA content of the cells was markedly reduced, and argyrophilic nucleolar organizer region (AgNOR) staining and image analysis indicated that the number of AgNORs was significantly decreased. Therefore, hepatoma cells brought about the adsorption, uptake, transport and degradation of HAP nanoparticles. In addition, HAP nanoparticles affected hepatoma cells with regard to cell-cell adhesion, cell and extracellular matrix adhesion, and DNA and protein synthesis; thus inhibiting cell proliferation. This understanding of the effects of interaction between HAP nanoparticles and hepatoma cells is useful for further study of the anticancer mechanisms of HAP nanoparticles. 展开更多
关键词 hydroxyapatite nanoparticles hepatoma cells interaction effects cell adhesion
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Interaction of genotype and environment effects on important traits of cassava(Manihot esculenta Crantz) 被引量:1
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作者 Athanase Nduwumuremyi Rob Melis +1 位作者 Paul Shanahan Asiimwe Theodore 《The Crop Journal》 SCIE CAS CSCD 2017年第5期373-386,共14页
General and specific environmental adaptation of genotypes is the main goal of breeders.However, genotype-by-environment(G x E) interaction complicates the identification of genotypes for release. This study aimed at ... General and specific environmental adaptation of genotypes is the main goal of breeders.However, genotype-by-environment(G x E) interaction complicates the identification of genotypes for release. This study aimed at analyzing the effects of G x E interaction on the expression of important cassava traits using two multivariate analyses: additive main effects and multiplicative interaction(AMMI) and genotype stability index(GSI). Total carotene content(TCC), postharvest physiological deterioration(PPD), and reaction to viral diseases were significantly affected by G x E interaction effects. The low percent(%)variation due to genotype for cassava brown streak disease(GBSD) explained the influence of environment on CBSD expression. The % variation due to genotype for TCC was higher(96%) than variation due to environment(1.7%) and G x E interaction(2.4%) indicating a low interaction effect of environment on TCC accumulation. The % variation due to genotype was higher than % variation due to environment for all traits but CBSD root necrosis and CBSD on stems, indicating the influence of environment on the severity of the viral diseases. These findings indicate that screening for disease resistance requires multi-environment trials, whereas a single-environment trial suffices to screen for total carotene content. 展开更多
关键词 Additive main effects and MULTIPLICATIVE interaction GENOTYPE adaptation GENOTYPE stability index Physiological POSTHARVEST deterioration Total CAROTENE content
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Effects of Reynolds number and Schmidt number on variable density mixing in shock bubble interaction 被引量:1
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作者 Bin Yu Linying Li +2 位作者 Hui Xu Bin Zhang Hong Liu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2022年第6期26-38,I0001,共14页
Effects of Reynolds(Re)number and Schmidt(Sc)number on the flow structures and variable density mixing are numerically investigated through the canonical shock cylindrical bubble interaction.By determining the viscosi... Effects of Reynolds(Re)number and Schmidt(Sc)number on the flow structures and variable density mixing are numerically investigated through the canonical shock cylindrical bubble interaction.By determining the viscosity and diffusivity within a wide range,the controlling parameters,total vortex circulation,and compression rate,are conservative under a broad range of Re and Sc numbers(Re≈10^(3)-10^(5)and Sc≈0.1-5)in the same shock Mach(Ma)number condition(Ma=2.4).As for the Re number effect,the circulation of secondary baroclinic vorticity(SBV),induced by the main vortex centripetal acceleration,is observed to be higher in high Re number and vice versa.Based on the vorticity transport equation decomposition,a growth-inhibition vorticity dynamics balance mechanism is revealed:the vorticity viscous term grows synchronously with baroclinic production to inhibit SBV production in low Re number.By contrast,the viscous term terminates the baroclinic term with a time lag in high Re number,leading to the SBV production.Since the SBV reflects the local stretching enhancement based on the advection-diffusion equation,mixing is influenced by the Sc number in a different behavior if different Re numbers are considered.The time-averaged variable density mixing rate emerges a scaling law with Sc number asχ^(∗)=β·Sc^(−α),where the coefficientβ∼Re−0.2 and the scaling exponentα∼Re−0.385.The understanding of Re number and Sc number effect on variable density mixing provides an opportunity for mixing enhancement from the perspective of designing the viscosity and diffusivity of the fluid mixture. 展开更多
关键词 Shock bubble interaction Variable density mixing Reynolds number effect Schmidt number effect Vortex dynamics
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Synergistic effects of CeO_(2)/Cu_(2)O on CO catalytic oxidation:Electronic interaction and oxygen defect 被引量:3
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作者 Chengyan Ge Jingfang Sun +3 位作者 Qing Tong Weixin Zou Lulu Li Lin Dong 《Journal of Rare Earths》 SCIE EI CAS CSCD 2022年第8期1211-1218,共8页
For CO catalytic oxidation,Cu and Ce species are of great importance,between which the synergistic effect is worth investigating.In this work,CeO_(2)/Cu_(2)O with Cu_(2)O{111}and{100}planes were comparatively explored... For CO catalytic oxidation,Cu and Ce species are of great importance,between which the synergistic effect is worth investigating.In this work,CeO_(2)/Cu_(2)O with Cu_(2)O{111}and{100}planes were comparatively explored on CO catalytic oxidation to reveal the effects of interfacial electronic interactions and oxygen defects.The activity result demonstrates that CeO_(2)/o-Cu_(2)O{111}has superior performance compared with CeO_(2)/c-Cu_(2)O{100}.Credit to the coordination unsaturated copper atoms(Cu_(CUS))on oCu_(2)O{111}surface,the interfacial electronic interactions on CeO_(2)/o-Cu_(2)O{111}are more obvious than those on CeO_(2)/c-Cu_(2)O{100},leading to richer oxygen defect generation,better redox and activation abilities of CO and O_(2)reactants.Furthermore,the reaction mechanism of CeO_(2)/o-Cu_(2)O{111}on CO oxidation is revealed,i.e.,CO and O_(2)are adsorbed on the Cucus on Cu_(2)O{111}and oxygen defect of CeO_(2),respectively,and then synergistically promote the CO oxidation to CO_(2).The work sheds light on the designing optimized ceria and copper-based catalysts and the mechanism of CO oxidation. 展开更多
关键词 CeO_(2)/Cu_(2)O{111}{100} Synergistic effect Interfacial electronic interaction Oxygen defect CO oxidation Rare earths
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Effects of Au nanoparticle size and metal-support interaction on plasmon-induced photocatalytic water oxidation 被引量:1
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作者 Shengyang Wang Bin Zeng Can Li 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第7期1219-1227,共9页
Plasmonic photocatalysis with tunable light absorption has aroused significant attention in so-lar-to-chemical energy conversion.However,the energy conversion efficiency of plasmonic photo-catalysts is impeded by inef... Plasmonic photocatalysis with tunable light absorption has aroused significant attention in so-lar-to-chemical energy conversion.However,the energy conversion efficiency of plasmonic photo-catalysts is impeded by ineffective charge separation and the lack of highly active sites for redox reactions.In this work,the Au nanoparticle size and Au-TiO2 interaction of the Au/TiO2 plasmonic photocatalyst were adjusted simultaneously using a post-calcination treatment.The visi-ble-ight-induced water oxidation activity exhibited a volcano-like relationship with the calcination temperature;the treated photocatalyst at 600°C manifested the highest activity.Characterization with UV-visible spectra,XRD,SEM,and XPS revealed that the effect of the Au nanoparticle size and Au-TiO2 interaction were both responsible for the increase in plasmon-induced water oxidation activity. 展开更多
关键词 AU/TIO2 Water oxidation Plasmonic photocatalysis Size effect Metal-semiconductor interaction
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Discrimination geochemical interaction effects on mineralization at the polymetallic Glojeh deposit,NW Iran by interative backward quadratic modeling 被引量:1
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作者 Farshad Darabi-Golestan Ardeshir Hezarkhani 《Acta Geochimica》 EI CAS CSCD 2020年第2期236-254,共19页
The physico-chemical exchanges between hydrothermal fluids and the host rock are usually controlled by elemental interaction effects.A criterion-based backward elimination approach applies the iterative regression ana... The physico-chemical exchanges between hydrothermal fluids and the host rock are usually controlled by elemental interaction effects.A criterion-based backward elimination approach applies the iterative regression analysis and analysis of variance to investigate the geochemical features of the polymetallic Glojeh(Au-Ag-CuPb-Zn)deposit in NW Iran.A statistical definition of the elemental interaction effects(X(i-j)^2,Xi×Xj)could elucidate the relationship between variables and the performance of a full quadratic polynomial model(QPM).The model optimization procedure was carried out by the removal of insignificant predictors(P value 95%CL)based on R^2(pred.)criterion.In order to straighten the convergent trend with R^2 and R^2(adj.),R^2(pred.)gradually increased from 0%to 77.8%by 15-steps optimization.The miniature-scale geochemical changes indicate double ordinal Au(Ag,Pb)and Au(Ag,Zn)interactions within the vein and host rock,in QPM.Results show that the Au(Pb-Zn)commonly presents ordinal effect at the vein and disordinal interaction at the host rock.This ordinal-disordinal interaction revealed that elements Pb and Zn have similar geochemical features during mineralization.In addition,Akima's polynomial contour map confirms the results from Pb-Zn interaction effects by dependency tracing between Au-Pb-Zn at different populations.However,it is noteworthy that Pb and Zn occur together in the second phase of Pb-Zn-Cu±(Ag±Cd)sulfide mineralization at Glojeh,which implies intergrowth and interaction of Pb-Zn on Au concentration.Pb and Zn demonstrate relatively high mobility and are generally concentrated in the near surface zones.Nb is an immobile element during alteration and high content Hg zone is mainly restricted to narrow stripes above ore vein and veinlets. 展开更多
关键词 BACKWARD Elimination Quadratic POLYNOMIAL model Miniature-scale changes Ordinal–disordinal interaction effect Akima's POLYNOMIAL contour map Immobile element
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Analysis on Interaction Effects Between Variety and Site of Silage Maize Regional Test in Guizhou Province 被引量:1
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作者 SHU Zhong-bing GOU Xiao-song +2 位作者 CHEN Lang WANG Chun-mei REN Hong 《Agricultural Science & Technology》 CAS 2022年第1期11-16,共6页
Taking the yield in the second group of Guizhou silage maize regional test in 2019 as data information, 8 experimental sites and 12 silage maize varieties as experimental objects, the interaction effect between gene a... Taking the yield in the second group of Guizhou silage maize regional test in 2019 as data information, 8 experimental sites and 12 silage maize varieties as experimental objects, the interaction effect between gene and environment was analyzed by using AMMI model. The results showed that the average fresh weight yield of each variety was 3 199.5~3 976.6 kg/667m^(2), among them, 5 varieties had an increase in the yield. Variety variation accounted for 10.51% of the total variation;experimental site variation accounted for 63.22% of the total variation;interaction effect variation between gene and environment accounted for 26.28% of the total variation;IPCA1 and IPCA2 variation accounted for 50.7% and 31.2% of the interaction variation, respectively;IPCA3 variation accounted for 7.25% of the interaction variation. g_4, g_8, g_9, g_10, g_11 and g_12 had better adaptability to e_1, e_2, e_6 and e_7;while g_1, g_2, g_3, g_5, g_6 and g_7 had better adaptability to e_3, e_4, e_5 and e_8. In consideration of yield, g_1(Huinongqing 2) and g_9(Xinyu 666) were silage maize varieties with high and stable yield;g_3(Hemuyu 905), g_8(Wuhuayu 3) and g_11(Liangdu 191) had general stability, and their yield was higher than that of the control;g_12(Jinduyu 999) had the worst stability and low yield. 展开更多
关键词 Silage maize AMMI model GENE ENVIRONMENT interaction effect
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Comparison and Analysis of QTLs, Epistatic Effects and QTLx Environment Interactions for Yield Traits Using DH and RILs Populations in Rice
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作者 ZHAO Xin-hua QIN Yang +5 位作者 JIA Bao-yan Suk-Man Kim Hyun-Suk Lee Moo-Young Eun Kyung-Min Kim Jae-Keun Sohn 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2013年第2期198-208,共11页
Two genetic linkage maps, constructed by DH and RILs populations derived from the same parents, were carried out for the identification and comparison of QTLs controlling yield traits across different years in rice (... Two genetic linkage maps, constructed by DH and RILs populations derived from the same parents, were carried out for the identification and comparison of QTLs controlling yield traits across different years in rice (Oryza sativa L.). A total of 194 SSR and STS markers were used in two maps, of which 114 markers were same. The distribution of Samgang allele was higher in RILs population than it in DH population. Comparing with DH population, RILs population has more lines with higher yield and wider phenotypic transgressive segression for yield traits. Although most of QTLs for the same trait were different in two populations across different years, 8 QTLs (including gwp 11.1, spp5.1, spp 10.1, spp 11.2, ssrl. 1, ssrl 1.1, tgw9.1 and tgwl 1.1) were detected over 2 yr. It is important to note that pppl0.1, sppl0.1 and tgw9.1 were identified in two populations, while sppl 0.1 and tgw9.1 were simultaneity observed across different years. Epistatic effects were more important than additive effects for PPP, SPP, yield in DH population and TGW, yield in R/Ls population. Epistatic effects of DH and RILs populations were different on the same genetic background in the present study, which illuminated the QE interaction played an important role on epistatic effect. Identification and comparison of QTLs for yield traits in DH and RILs populations should provide various and more precise information. The QTLs identified in present study would be valuable in marker-assisted selection program for improving rice yield. 展开更多
关键词 RILs epistics effect QE interaction YIELD
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Effects of Hydrogen-bonding Interaction and Polarity on Emission Spectrum of Naphthalene-Triethylamine in Mixed Solvent
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作者 Yoshimi Sueishi Shunzo Yamamoto 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第5期606-611,共6页
The effects of the protic and aprotic polar solvents on the emission spectrum of the naphthalene-triethyl-amine system in THF were studied under conditions of steady-state illumination. The fluorescence spectrum of th... The effects of the protic and aprotic polar solvents on the emission spectrum of the naphthalene-triethyl-amine system in THF were studied under conditions of steady-state illumination. The fluorescence spectrum of the naphthalene-triethylamine system consists of two emission bands, the fluorescence band of naphthalene(band A, 329 nm) and the emission band of the exciplex(band B, 468 nm). The intensities of both the emission bands decrease with increasing the solvent polarity. The intensity of band B also decreases due to the hydrogen-bonding interaction between triethylamine and protic solvent, while that of band A increases. It is thus suggested that the quenching of naphthalene fluorescence by triethylamine in THF occurs through the charge transfer and electron transfer reactions. The spectral changes upon the increase of solvent polarity can be explained by the dependences of the equilibrium constant between exciplex and ion-pair and the rate constant for the electron transfer reaction from triethylamine to the excited naphthalene on the relative permittivity of solvent. It is shown that the formation of intermolecular hydrogen-bonding between triethylamine and protic solvent suppresses the quenching reaction by the decrease in free amine. Acetonitrile has only a polar effect and trichloroacetic acid only a hydrogen-bonding(or protonation) effect, while alcohols have both the effects. The effects of alcohols could be separated into the effects of solvent polarity and intermolecular hydrogen-bonding interaction quantitatively. 展开更多
关键词 Naphthalene-triethylamine Fluorescence spectrum Solvent effect Solvent polarity Hydrogen-bonding interaction.
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