The galvanic corrosion of the Q-phase/Al couple in 0.1 M NaCl solutions has been studied using the scanning vibrating electrode technique (SVET)f the scanning ion-selective electrode technique (SIET) and energy disper...The galvanic corrosion of the Q-phase/Al couple in 0.1 M NaCl solutions has been studied using the scanning vibrating electrode technique (SVET)f the scanning ion-selective electrode technique (SIET) and energy dispersive X-ray spectroscopy (EDX). The galvanic corrosion of the Q-phase/Al couple was found to be dependent on pH and immersion time. Current density maps obtained by SVET shows that the anodic oxidation processes emerge from Al in a localized manner in pH 2 and 6 solutions but is initiated in a uniform manner in pH 13 solution, whereas, the cathodic processes are more homogeneously distributed over the Q-phase at pH 2.6 and 13. It is seen that the Q-phase remains cathodic in the Q-phase/Al couple in acidic, neutral and alkaline solutions indicating that the galvanic polarity of the Q-phase is independent of pH. The effect of the galvanic corrosion was largest at pH 2 and 13 compared to pH 6. The pH map obtained by SIET indicates that the galvanic activity of the Q-phase/Al couple proceeds via heavy alkalization of the Q-phase surface with the generation of appreciable amounts of OH~ ions. The enrichment of Cu indicated by EDX is responsible for the observed cathodic activity of the Q-phase in the Q-phase/Al couple.展开更多
A ternary system comprising Ca_(20)Al_(26)Mg_(3)Si_(3)O_(68)(Q-phase),limestone,and metakaolin is proposed,and its hydration behavior,hydration product phases,microstructure,and mechanical properties are investigated ...A ternary system comprising Ca_(20)Al_(26)Mg_(3)Si_(3)O_(68)(Q-phase),limestone,and metakaolin is proposed,and its hydration behavior,hydration product phases,microstructure,and mechanical properties are investigated and compared with pure Q-phase cement.The results indicate that the ternary system exhibits exceptional and sustained compressive strength even under a 40℃environment,significantly outperforming pure Q-phase.The mechanism lies in that metakaolin effectively inhibits the transformation of metastable phase.Meanwhile,the interactions among Q-phase,limestone,and metakaolin further enhance the cementitious performance.The ternary system effectively addresses potential issues of strength loss in Q-phase cement application,and as a low-carbon cementitious material system,it holds promising potential applications.展开更多
采用磁控管做功率源的低能电子直线加速器在医疗、辐照、X射线检测等领域得到较为广泛的应用。磁控管产生的微波信号输入到加速管,对电子束进行加速,磁控管的工作频率稳定性对加速器电子束能量、能散及发射度产生直接的影响。但磁控管...采用磁控管做功率源的低能电子直线加速器在医疗、辐照、X射线检测等领域得到较为广泛的应用。磁控管产生的微波信号输入到加速管,对电子束进行加速,磁控管的工作频率稳定性对加速器电子束能量、能散及发射度产生直接的影响。但磁控管是一种振荡器,其频率受到温度、振动、负载牵引的影响会产生漂移,所以需要一套自动频率控制系统(Automatic Frequency Control,AFC)机构对磁控管进行频率控制。目前普遍采用的AFC机构主要是行波控相或双腔鉴频,对两路检波信号差分放大进而控制伺服电机进行调谐的方法实现磁控管的频率稳定。随着数字化I/Q和FPGA(Field-Programmable Gate Array)技术的不断发展,运用该技术进行磁控管的频率控制完全具备可行性。本文从理论和工程设计上阐述了数字化I/Q技术在磁控管频率控制上的应用。展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No. 51571201)
文摘The galvanic corrosion of the Q-phase/Al couple in 0.1 M NaCl solutions has been studied using the scanning vibrating electrode technique (SVET)f the scanning ion-selective electrode technique (SIET) and energy dispersive X-ray spectroscopy (EDX). The galvanic corrosion of the Q-phase/Al couple was found to be dependent on pH and immersion time. Current density maps obtained by SVET shows that the anodic oxidation processes emerge from Al in a localized manner in pH 2 and 6 solutions but is initiated in a uniform manner in pH 13 solution, whereas, the cathodic processes are more homogeneously distributed over the Q-phase at pH 2.6 and 13. It is seen that the Q-phase remains cathodic in the Q-phase/Al couple in acidic, neutral and alkaline solutions indicating that the galvanic polarity of the Q-phase is independent of pH. The effect of the galvanic corrosion was largest at pH 2 and 13 compared to pH 6. The pH map obtained by SIET indicates that the galvanic activity of the Q-phase/Al couple proceeds via heavy alkalization of the Q-phase surface with the generation of appreciable amounts of OH~ ions. The enrichment of Cu indicated by EDX is responsible for the observed cathodic activity of the Q-phase in the Q-phase/Al couple.
基金Funded by the National Natural Science Foundation of China(No.52172026)the Science and Technology Development Project of China Railway Design Corporation(Nos.2023A0226407 and 2023B03040003)。
文摘A ternary system comprising Ca_(20)Al_(26)Mg_(3)Si_(3)O_(68)(Q-phase),limestone,and metakaolin is proposed,and its hydration behavior,hydration product phases,microstructure,and mechanical properties are investigated and compared with pure Q-phase cement.The results indicate that the ternary system exhibits exceptional and sustained compressive strength even under a 40℃environment,significantly outperforming pure Q-phase.The mechanism lies in that metakaolin effectively inhibits the transformation of metastable phase.Meanwhile,the interactions among Q-phase,limestone,and metakaolin further enhance the cementitious performance.The ternary system effectively addresses potential issues of strength loss in Q-phase cement application,and as a low-carbon cementitious material system,it holds promising potential applications.
文摘采用磁控管做功率源的低能电子直线加速器在医疗、辐照、X射线检测等领域得到较为广泛的应用。磁控管产生的微波信号输入到加速管,对电子束进行加速,磁控管的工作频率稳定性对加速器电子束能量、能散及发射度产生直接的影响。但磁控管是一种振荡器,其频率受到温度、振动、负载牵引的影响会产生漂移,所以需要一套自动频率控制系统(Automatic Frequency Control,AFC)机构对磁控管进行频率控制。目前普遍采用的AFC机构主要是行波控相或双腔鉴频,对两路检波信号差分放大进而控制伺服电机进行调谐的方法实现磁控管的频率稳定。随着数字化I/Q和FPGA(Field-Programmable Gate Array)技术的不断发展,运用该技术进行磁控管的频率控制完全具备可行性。本文从理论和工程设计上阐述了数字化I/Q技术在磁控管频率控制上的应用。
