Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,...Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.展开更多
Traditional heat treatment methods require a significant amount of time and energy to affect atomic diffusion and enhance the spheroidization process of carbides in bearing steel,while pulsed current can accelerate at...Traditional heat treatment methods require a significant amount of time and energy to affect atomic diffusion and enhance the spheroidization process of carbides in bearing steel,while pulsed current can accelerate atomic diffusion to achieve ultra-fast spheroidization of carbides.However,the understanding of the mechanism by which different pulse current parameters regulate the dissolution behavior of carbides requires a large amount of experimental data to support,which limits the application of pulse current technology in the field of heat treatment.Based on this,quantify the obtained pulse current processing data to create an important dataset that could be applied to machine learning.Through machine learning,the mechanism of mutual influence between carbide regulation and various factors was elucidated,and the optimal spheroidization process parameters were determined.Compared to the 20 h required for traditional heat treatment,the application of pulsed electric current technology achieved ultra-fast spheroidization of GCr15 bearing steel within 90 min.展开更多
The chain-like prior particle boundaries(PPBs)as a kind of stubborn harmful precipitate will hinder atomic diffusion and particle connection.They can only be broken into nanoscale through thermal deformation(1160–120...The chain-like prior particle boundaries(PPBs)as a kind of stubborn harmful precipitate will hinder atomic diffusion and particle connection.They can only be broken into nanoscale through thermal deformation(1160–1200℃).Here,treated by the pulsed electric current at 800℃,PPBs were dissolved quickly as a result of the interaction between the pulsed electric current and the chain-like structure.According to the electromigration theory and the calculation results,the high current density regions will be mainly produced at the gaps due to the conductivity difference between the precipitates and the matrix.The atomic diffusion flux caused by the pulsed electric current is proportional to the current density.Therefore,the existence of a large number of gaps in the chain-like PPBs will make the high current density regions play a more positive role in fast-dissolution.展开更多
Gain refinement in metal alloy can be achieved by applying an electric current pulse(ECP)in solidification process.Forced flow inside the melt has been proved to be a key role in grain refinement.In this paper,the flu...Gain refinement in metal alloy can be achieved by applying an electric current pulse(ECP)in solidification process.Forced flow inside the melt has been proved to be a key role in grain refinement.In this paper,the fluid flow inside Ga 20 wt%-In 12 wt%-Sn alloy induced by a damping sinusoidal ECP flowing through two parallel electrodes into the cylindrical melt was investigated by both experimental measurements and numerical simulations.Experimental results showed that a strong descending jet was induced beneath the bottom of electrodes under the application of ECP.Besides,it was found that flow intensity increases with the increase of amplitude,frequency,and pulse width,respectively.In order to unlock the formation mechanism of flow pattern and the relevance of flow intensity varied with electrical parameters,a three-dimensional numerical model under the application of ECP was established.Meanwhile,a comparative study was conducted by numerical simulations to reveal the distributions of electromagnetic fields and forced flow.Numerical results showed that the downward Lorentz force induced by ECP was concentrated beneath the bottom of electrodes.This downward Lorentz force induces a descending jet and provokes a global forced flow.According to numerical simulations,the evolution of flow intensity with electrical parameters under the application of ECP can be understood by the time averaged impulse of Lorentz force.展开更多
The fracture of pipelines caused by corrosion cracks and the resulting oil and gas leakage can lead to great environmentalpollution and economic losses. These negative effects are due to serious corrosion of the plain...The fracture of pipelines caused by corrosion cracks and the resulting oil and gas leakage can lead to great environmentalpollution and economic losses. These negative effects are due to serious corrosion of the plain carbon steels used for armorof flexible pipe in oil and gas transmission medium. However, corrosion resistance of carbon steel armors has yet to beimproved. In this study, the relationship between corrosion resistance and pearlite fraction in the plain carbon steels hasbeen investigated through the application of pulsed electric current. Based on immersion test and electrochemical mea-surement, pulsed electric current increases the corrosion resistance of the plain carbon steels by reducing the fraction ofpearlite phase. Pitting corrosion, which tends to initiate by galvanic corrosion of ferrite and cementite, is therefore inhibiteddue to the decrease in pearlite fraction （mixture of ferrite and cementite） under electropulsing.展开更多
The impurity iron in silicon material will seriously affect the photoelectric conversion efficiency of silicon solar cells.However,the traditional silicon purification method has the disadvantages of long cycle,high e...The impurity iron in silicon material will seriously affect the photoelectric conversion efficiency of silicon solar cells.However,the traditional silicon purification method has the disadvantages of long cycle,high energy consumption and serious pollution.In this study,an efficient and green pulsed electric current purification technology is proposed.The electromigration effect of iron elements,the current density gradient driving of iron phase,and the gravity of iron phase all affect the migration behavior of iron phase in silicon melt under pulsed electric current.Regardless of the depth of electrode insertion into the silicon melt,the solubility of iron in silicon decreases under the pulsed electric current,which helps to form the iron phase.At the same time,the iron phase tends to sink toward the bottom under the influence of gravity.When the electrode is shallowly inserted,a non-uniform electric field is formed in the silicon melt,and the iron phase is mainly driven by the current density gradient to accelerate sink toward the bottom.When the electrode is fully inserted,an approximately uniform electric field is formed in the silicon melt,and iron elements are preferentially migrated to the cathode by electromigration,forming iron phase sinking at the cathode.The study of impurity iron migration behavior in silicon melt under pulsed electric current provides a new approach for the purification of polycrystalline silicon.展开更多
Residual stress in high-carbon steel affects the dimensional accuracy, structural stability, and integrity of components. Although the evolution of residual stress under an electric field has received extensive attent...Residual stress in high-carbon steel affects the dimensional accuracy, structural stability, and integrity of components. Although the evolution of residual stress under an electric field has received extensive attention, its elimination mechanism has not been fully clarified. In this study, it was found that the residual stress of high-carbon steel could be effectively relieved within a few minutes through the application of a low density pulse current. The difference between the current pulse treatment and traditional heat treatment in reducing residual stress is that the electric pulse provides additional Gibbs free energy for the system, which promotes dislocation annihilation and carbon atom diffusion to form carbides, thus reducing the free energy of the system. The electroplastic and thermal effects of the pulse current promoted the movement of dislocations under the electric field, thus eliminating the internal stress caused by dislocation entanglement. The precipitation of carbides reduced the carbon content of the steel matrix and lattice shrinkage, thereby reducing the residual tensile stress. Considering that a pulsed current has the advantages of small size, small power requirement, continuous output, and continuously controllable parameters, it has broad application prospects for eliminating residual stress.展开更多
As the most important irradiation-induced defects,dislocation loop and copper-rich nanocluster are the major contributors to the embrittlement of the neutron-irradiated reactor pressure vessel steels.In this study,suc...As the most important irradiation-induced defects,dislocation loop and copper-rich nanocluster are the major contributors to the embrittlement of the neutron-irradiated reactor pressure vessel steels.In this study,such nano-defects were introduced into the material by 3 MeV Fe ions up to the dose of 1 dpa at high temperature(290℃)to simulate neutron irradiation.It was found that pulsed electric current can effectively reduce 95%of irradiation-induced hardening.Correspondingly,the characterization results showed that almost all the dislocation loops disappeared and the quantity of copper-rich nanoclusters also reduced greatly at relatively low temperature(450℃),and the process took only 20 min.Mean-while,it was qualitatively proved by positron annihilation spectroscopy that the number of irradiation-induced vacancy-type defects and solute-enriched clusters was significantly decreased after electropuls-ing.Furthermore,under the pulsed electric field,the rapid annihilation of the dislocation loops due to their accelerated collision with vacancies can remove the nucleation sites of the copper-rich nanoclusters and make them become dispersed,further promoting the nanoclusters that lack nucleation sites dissolv-ing faster.Therefore,this electropulsing treatment provides a practical“in-situ”performance repair tech-nology to extend the service life of reactor pressure vessel steels by regulating the interaction between vacancies,interstitial atoms and irradiation-induced defects.展开更多
The application of electric current pulse（ECP） to a solidification process refers to the immersion of electrodes into the liquid metal and the employment of thermal insulators on the upper surface of metal.In order ...The application of electric current pulse（ECP） to a solidification process refers to the immersion of electrodes into the liquid metal and the employment of thermal insulators on the upper surface of metal.In order to ascertain the effects of these two factors on the structure refinement by the ECP technique,three groups of experiments were performed with different types of electrodes or various thermal insulators.By the comparison between solidification structures under different conditions,it is followed that the electrode and the thermal insulator have an obvious influence on the grain refinement under an applied ECP,and further analysis demonstrates that the thermal conditions of the liquid surface play a vital role in the modification of solidification structure.Also,the results support the viewpoint that most of the equiaxed grains originate from the liquid surface subjected to an ECP.展开更多
A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards a...A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.展开更多
The reactor pressure vessel(RPV)is susceptible to brittle fracture due to the influence of ion irradiation and high temperature,which presents a significant risk to the safe operation of nuclear reactors.It has been d...The reactor pressure vessel(RPV)is susceptible to brittle fracture due to the influence of ion irradiation and high temperature,which presents a significant risk to the safe operation of nuclear reactors.It has been demonstrated that pulsed electric current can effectively address the issue of embrittlement in RPV steel.However,the relationship between pulse parameters(duty ratio,frequency,current,and time)and the effectiveness of pulse current processing has not been systematically studied.The application of machine learning methods enables autonomous exploration and learning of the relationship between data.Consequently,this study proposes a machine learning method based on the random forest model to establish the relationship between the parameters of electrical pulses and the repair effect of RPV steel.A generative adversarial network is employed to enhance data diversity and scalability,while a particle swarm optimization algorithm is utilized to optimize the initialization weights and biases of the random forest model,aiming to improve the model’s fitting ability and training performance.The results indicate that the coefficient of determination R-square(R^(2)),root mean squared error and mean absolute error values are 0.934,0.045,and 0.036,respectively,suggesting that the model has the potential to predict the performance recovery of RPV steel after pulsed electric field treatment.The prediction of the impact of pulse current parameters on the repair effect will help to enhance and optimize the repair process,thereby providing a scientific basis for pulse current repair processing.展开更多
Three kinds of AI-Si piston alloys were prepared and subjected to pulse electric current treatment （PECT） at different pouring temperatures. Some aspects of the solidification microstructures were examined including...Three kinds of AI-Si piston alloys were prepared and subjected to pulse electric current treatment （PECT） at different pouring temperatures. Some aspects of the solidification microstructures were examined including the morphology and the distribution of the matrix and the secondary phases by using of optical microscopy （OM）, SEM and EDS methods. Results indicate that PECT can refine the grains of α-AI in the alloys as effectively as chemical modification by sodium salt. The processing parameters of PECT on the multi-component AI-Si alloys were then optimized through the testing of tensile strength, elongation and microhardness of the prepared alloys. A new theory was put forward to explain the mechanism of PECT.展开更多
A new approach to applying the electric current pulse （ECP） with parallel electrodes to the promotion of the transition from columnar crystal to equiaxed crystal and the improvement of macrosegregation was introduce...A new approach to applying the electric current pulse （ECP） with parallel electrodes to the promotion of the transition from columnar crystal to equiaxed crystal and the improvement of macrosegregation was introduced. The ECP was applied to different stages of the solidification. The results showed that the application of the ECP in both the initial stage （the thickness of solidified shell reached 2 mm approximately） and the late stage （the thickness of solidified shell reached 14 mm approximately） of solidification can promote the columnar to equiaxed transition （CET）. The analysis showed that during solidification, a large number of nuclei around the upper surface fell off due to ECP, which subsequently showered on the melt and impinged the growth front of the columnar crystal. Therefore, the CEToccurred. In addition, this method was also employed to influence the solidification process of bearing steel, and the results showed that the structure was changed from columnar crystal to equiaxed crystal, indicating that ECP can enhance the homogeneity of structure and composition of bearing steel.展开更多
In this work, low-density electric current pulse （ECP） has been applied to submerged entry nozzle （SEN） and its effect on the morphology of the inclusion buildup and the distribution of the inclusions in slab has ...In this work, low-density electric current pulse （ECP） has been applied to submerged entry nozzle （SEN） and its effect on the morphology of the inclusion buildup and the distribution of the inclusions in slab has been explored. The results reveal that under the unique effects of ECP, part of small inclusions less than 10 μm is expelled through the boundary layer along the current direction to form dense inclusion buildup. This method is of great potential to prolong the service life of SEN and improve the quality of the steel product.展开更多
Microstructure of reaction sintering of ZnAl2O4 at 1500℃ by hot-pressing(HP) and pulse electric current was investigated. The results indicated that the existed cracks in sintered body were caused by structure mismat...Microstructure of reaction sintering of ZnAl2O4 at 1500℃ by hot-pressing(HP) and pulse electric current was investigated. The results indicated that the existed cracks in sintered body were caused by structure mismatch. It is the evidence that periodical temperature field existed during pulse electric current sintering of nonconductive materials. The distance between high temperature areas was related to die diameter.展开更多
Continuous solidification experiments are carried out with Pb–Al alloys under the influence of the electric current pulses（ECPs）. The results demonstrate that the ECPs mainly affect the microstructure formation thr...Continuous solidification experiments are carried out with Pb–Al alloys under the influence of the electric current pulses（ECPs）. The results demonstrate that the ECPs mainly affect the microstructure formation through changing the energy barrier for the nucleation of the minority phase droplets（MPDs） and minority phase particles（MPPs） during cooling Pb–Al alloys in the liquid–liquid and liquid–solid phase transformation temperature ranges in advance of the solidification of the matrix liquid. For Pb–Al alloys with Al-rich droplets/particles as the minority phase, the ECPs lower the energy barriers for the nucleation of the MPDs/MPPs and cause a significant increase in the nucleation rate of the MPDs/MPPs and, thus,promote the formation of Pb–Al alloys with a well-dispersed or even nanoparticles dispersed microstructure. The ECPs parameters show an important influence on the microstructure formation of Pb–Al alloys. The refinement extent of the MPDs/MPPs increases with the increase in the peak current density. For a given peak current density, the refinement extent of the MPDs/MPPs increases with the increases in the pulse frequency and pulse width first, and then level off and become asymptotic.展开更多
The sintering resistance for conductive TiB2 and non-conductive A12O3 as well as empty die during pulse current sintering were investigated in this paper. Equivalent resistances were measured by current and valtage du...The sintering resistance for conductive TiB2 and non-conductive A12O3 as well as empty die during pulse current sintering were investigated in this paper. Equivalent resistances were measured by current and valtage during sintering the conductive and non-conductive materials in the same conditions. It is found that the current paths for conductive are different from those for non-conductive materials. For non-conductive materials, sintering resistances are influenced by powder sizes and heating rates, which indicates that pulse current has some interaction with non-conductive powders. For conductive TiB2 , sintering resistances are influenced by heating rates and ball-milling time, which indicates the effect of powders activated by spark.展开更多
Nano-scale phases can enhance or reduce the mechanical properties of materials,so it is very important to control the size of the phases.Copper-rich nanoclusters as matrix defects will significantly reduce the perform...Nano-scale phases can enhance or reduce the mechanical properties of materials,so it is very important to control the size of the phases.Copper-rich nanoclusters as matrix defects will significantly reduce the performance of materials for key nuclear power components,while traditional heat treatment method has a technical bottleneck for the dissolution of nanoclusters.A new method of using the inherent electrical property discrepancies between the matrix material and the nanoclusters to effectively dissolve the nanoclusters through pulsed electric current to realize the recovery of material aging degradation performance is proposed.The performance evolution of simulated steel in the aging-external field repair cycle was studied,and it was found the dislocations as the preferred nucleation sites of nanoclusters were regulated in virtue of the non-thermal effect of current,resulting in a decrease in dislocation density and entanglement release.In the subsequent thermal aging process,the embrittlement rate of the aged and tempered material trained by the electric pulse was slower than that of the untreated sample.When moving dislocations are pinned by nanoclusters under high stress,nano-scale dislocations can be induced into the clusters.The dislocations near the nanoclusters and the newly formed nano-scale dislocations in the nanoclusters act as fast diffusion channels,which can further accelerate the dissolution of the nanoclusters.展开更多
Laser Wakefield plasma acceleration of electrons to energies above 10 GeV, may be possible in the new high power Laser beam facilities. The design of an Electron Spectrometer with an electro-magnet with adjustable mag...Laser Wakefield plasma acceleration of electrons to energies above 10 GeV, may be possible in the new high power Laser beam facilities. The design of an Electron Spectrometer with an electro-magnet with adjustable magnetic field is proposed for the characterization of electron energy spectrum with a precision better than 10% for the entire energy range from 0.5 GeV to 38 GeV. The expected precision in the measurement of the electron energy is calculated as a function of the magnetic field, of the electron energy and of the magnet length. To outline the advantages offered by a pulsed electromagnet with high magnetic fields, the mass and the electric power lost in the coils of a 4 m long electromagnet with continuous current and Iron yoke are calculated.展开更多
We study electric currents in a piezoelectric semiconductor fiber under a constant voltage and time-dependent axial stresses applied locally.From a nonlinear numerical analysis based on a one-dimensional phenomenologi...We study electric currents in a piezoelectric semiconductor fiber under a constant voltage and time-dependent axial stresses applied locally.From a nonlinear numerical analysis based on a one-dimensional phenomenological model using the commercial software COMSOL,it is found that pulse electric currents can be produced by periodic or time-harmonic stresses.The pulse currents can be tuned by the amplitude and frequency of the applied stress.The result obtained provides a new approach for the mechanical control of electric currents in piezoelectric semiconductor fibers and has potential applications in piezotronics.展开更多
基金supported by the Fundamental Research Funds for the Central Universities(No.FRF-BD-23-01).
文摘Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.
基金supported by the National Key R&D Program of China(2020YFA0714900,2023YFB3709903)the National Natural Science Foundation of China(U21B2082,52474410)+6 种基金the Key R&D Program of Shandong Province,China(2023CXGC010406)the Scientific Research Special Project for First-Class Disciplines in Inner Mongolia Autonomous Region(YLXKZX-NKD-001)the International Science and Technology Cooperation Project of Higher Education Institutions in Inner Mongolia Autonomous Region(GHXM-002)the Natural Science Foundation of Inner Mongolia Autonomous Region of China(2024ZD06)the Technology Support Project for the Construction of Major Innovation Platforms in Inner Mongolia Autonomous Region(XM2024XTGXQ16)the Beijing Municipal Natural Science Foundation(2222065)the Fundamental Research Funds for the Central Universities(FRF-TP-22-02C2).
文摘Traditional heat treatment methods require a significant amount of time and energy to affect atomic diffusion and enhance the spheroidization process of carbides in bearing steel,while pulsed current can accelerate atomic diffusion to achieve ultra-fast spheroidization of carbides.However,the understanding of the mechanism by which different pulse current parameters regulate the dissolution behavior of carbides requires a large amount of experimental data to support,which limits the application of pulse current technology in the field of heat treatment.Based on this,quantify the obtained pulse current processing data to create an important dataset that could be applied to machine learning.Through machine learning,the mechanism of mutual influence between carbide regulation and various factors was elucidated,and the optimal spheroidization process parameters were determined.Compared to the 20 h required for traditional heat treatment,the application of pulsed electric current technology achieved ultra-fast spheroidization of GCr15 bearing steel within 90 min.
基金financially supported by the National Natural Science Foundation of China(Nos.51874023 and U1860206)the Fundamental Research Funds for the Central Universities(FRF-TP20-02B)the Recruitment Program of Global Experts。
文摘The chain-like prior particle boundaries(PPBs)as a kind of stubborn harmful precipitate will hinder atomic diffusion and particle connection.They can only be broken into nanoscale through thermal deformation(1160–1200℃).Here,treated by the pulsed electric current at 800℃,PPBs were dissolved quickly as a result of the interaction between the pulsed electric current and the chain-like structure.According to the electromigration theory and the calculation results,the high current density regions will be mainly produced at the gaps due to the conductivity difference between the precipitates and the matrix.The atomic diffusion flux caused by the pulsed electric current is proportional to the current density.Therefore,the existence of a large number of gaps in the chain-like PPBs will make the high current density regions play a more positive role in fast-dissolution.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.U1760204,51974183,52071194,and 52074180).
文摘Gain refinement in metal alloy can be achieved by applying an electric current pulse(ECP)in solidification process.Forced flow inside the melt has been proved to be a key role in grain refinement.In this paper,the fluid flow inside Ga 20 wt%-In 12 wt%-Sn alloy induced by a damping sinusoidal ECP flowing through two parallel electrodes into the cylindrical melt was investigated by both experimental measurements and numerical simulations.Experimental results showed that a strong descending jet was induced beneath the bottom of electrodes under the application of ECP.Besides,it was found that flow intensity increases with the increase of amplitude,frequency,and pulse width,respectively.In order to unlock the formation mechanism of flow pattern and the relevance of flow intensity varied with electrical parameters,a three-dimensional numerical model under the application of ECP was established.Meanwhile,a comparative study was conducted by numerical simulations to reveal the distributions of electromagnetic fields and forced flow.Numerical results showed that the downward Lorentz force induced by ECP was concentrated beneath the bottom of electrodes.This downward Lorentz force induces a descending jet and provokes a global forced flow.According to numerical simulations,the evolution of flow intensity with electrical parameters under the application of ECP can be understood by the time averaged impulse of Lorentz force.
基金financially supported by the National Natural Science Foundation of China(No.51601011)the Fundamental Research Funds for the Central Universities+2 种基金the Recruitment Program of Global Expertsthe State Grid Scientific and Technological Research Program of China(No.5211DS17001X)the Zhejiang Electric Power Corporation Scientific and Technological Research Program of China(No.5211DS5002 M).
文摘The fracture of pipelines caused by corrosion cracks and the resulting oil and gas leakage can lead to great environmentalpollution and economic losses. These negative effects are due to serious corrosion of the plain carbon steels used for armorof flexible pipe in oil and gas transmission medium. However, corrosion resistance of carbon steel armors has yet to beimproved. In this study, the relationship between corrosion resistance and pearlite fraction in the plain carbon steels hasbeen investigated through the application of pulsed electric current. Based on immersion test and electrochemical mea-surement, pulsed electric current increases the corrosion resistance of the plain carbon steels by reducing the fraction ofpearlite phase. Pitting corrosion, which tends to initiate by galvanic corrosion of ferrite and cementite, is therefore inhibiteddue to the decrease in pearlite fraction （mixture of ferrite and cementite） under electropulsing.
基金financially supported by the National Natural Science Foundation of China(No.U21B2082)Natural Science Foundation of Beijing Municipality(No.2222065)and Fundamental Research Funds for the Central Universities(No.FRF-TP-22-02C2).
文摘The impurity iron in silicon material will seriously affect the photoelectric conversion efficiency of silicon solar cells.However,the traditional silicon purification method has the disadvantages of long cycle,high energy consumption and serious pollution.In this study,an efficient and green pulsed electric current purification technology is proposed.The electromigration effect of iron elements,the current density gradient driving of iron phase,and the gravity of iron phase all affect the migration behavior of iron phase in silicon melt under pulsed electric current.Regardless of the depth of electrode insertion into the silicon melt,the solubility of iron in silicon decreases under the pulsed electric current,which helps to form the iron phase.At the same time,the iron phase tends to sink toward the bottom under the influence of gravity.When the electrode is shallowly inserted,a non-uniform electric field is formed in the silicon melt,and the iron phase is mainly driven by the current density gradient to accelerate sink toward the bottom.When the electrode is fully inserted,an approximately uniform electric field is formed in the silicon melt,and iron elements are preferentially migrated to the cathode by electromigration,forming iron phase sinking at the cathode.The study of impurity iron migration behavior in silicon melt under pulsed electric current provides a new approach for the purification of polycrystalline silicon.
基金The work was financially supported by the Natural Science Foundation of Beijing Municipality(2222065)the National Natural Science Foundation of China(U21B2082)Fundamental Research Funds for the Central Universities(FRF-TP-22-02C2).
文摘Residual stress in high-carbon steel affects the dimensional accuracy, structural stability, and integrity of components. Although the evolution of residual stress under an electric field has received extensive attention, its elimination mechanism has not been fully clarified. In this study, it was found that the residual stress of high-carbon steel could be effectively relieved within a few minutes through the application of a low density pulse current. The difference between the current pulse treatment and traditional heat treatment in reducing residual stress is that the electric pulse provides additional Gibbs free energy for the system, which promotes dislocation annihilation and carbon atom diffusion to form carbides, thus reducing the free energy of the system. The electroplastic and thermal effects of the pulse current promoted the movement of dislocations under the electric field, thus eliminating the internal stress caused by dislocation entanglement. The precipitation of carbides reduced the carbon content of the steel matrix and lattice shrinkage, thereby reducing the residual tensile stress. Considering that a pulsed current has the advantages of small size, small power requirement, continuous output, and continuously controllable parameters, it has broad application prospects for eliminating residual stress.
基金supported by the National Natural Science Foundation of China(No.U21B2082)the Beijing Municipal Natural Science Foundation(No.2222065)the Fundamental Research Funds for the Central Universities(No.FRF-TP-22-02C2).
文摘As the most important irradiation-induced defects,dislocation loop and copper-rich nanocluster are the major contributors to the embrittlement of the neutron-irradiated reactor pressure vessel steels.In this study,such nano-defects were introduced into the material by 3 MeV Fe ions up to the dose of 1 dpa at high temperature(290℃)to simulate neutron irradiation.It was found that pulsed electric current can effectively reduce 95%of irradiation-induced hardening.Correspondingly,the characterization results showed that almost all the dislocation loops disappeared and the quantity of copper-rich nanoclusters also reduced greatly at relatively low temperature(450℃),and the process took only 20 min.Mean-while,it was qualitatively proved by positron annihilation spectroscopy that the number of irradiation-induced vacancy-type defects and solute-enriched clusters was significantly decreased after electropuls-ing.Furthermore,under the pulsed electric field,the rapid annihilation of the dislocation loops due to their accelerated collision with vacancies can remove the nucleation sites of the copper-rich nanoclusters and make them become dispersed,further promoting the nanoclusters that lack nucleation sites dissolv-ing faster.Therefore,this electropulsing treatment provides a practical“in-situ”performance repair tech-nology to extend the service life of reactor pressure vessel steels by regulating the interaction between vacancies,interstitial atoms and irradiation-induced defects.
基金Project(2009AA03Z110) supported by the National High Technology Research and Development Program of ChinaProject (2011CB012902) supported by the National Basic Research Program of China
文摘The application of electric current pulse（ECP） to a solidification process refers to the immersion of electrodes into the liquid metal and the employment of thermal insulators on the upper surface of metal.In order to ascertain the effects of these two factors on the structure refinement by the ECP technique,three groups of experiments were performed with different types of electrodes or various thermal insulators.By the comparison between solidification structures under different conditions,it is followed that the electrode and the thermal insulator have an obvious influence on the grain refinement under an applied ECP,and further analysis demonstrates that the thermal conditions of the liquid surface play a vital role in the modification of solidification structure.Also,the results support the viewpoint that most of the equiaxed grains originate from the liquid surface subjected to an ECP.
基金Project(SELF-2011-01)supported by the Open Project of Shanghai Key Laboratory of Modern Metallurgy and Materials Processing,ChinaProjects(51204109,51035004)supported by the National Natural Science Foundation of China
文摘A mathematical model considering free nuclei was developed to reveal the migration behavior of the free nuclei. Numerical simulation results show that most of the nuclei on the top surface of the melt move downwards and distribute randomly inside the Al melt, which induces more nucleation sites resulting in grain refinement. At the same time, the effect of nuclei size on the nuclei distribution and refinement employing electric current pulse （ECP） was also investigated. The smaller nuclei migrate a short distance with the Al melt at lower speed. But for the larger nuclei, the migration downwards with higher speed benefits the refinement of interior grains of the melt. The research results help to better understand the refinement process and provide a more reasonable explanation of the grain refinement mechanism using ECP.
基金financially supported by the National Natural Science Foundation of China(U21B2082,52474410)the National Key R&D Program of China(2023YFB3709903,2020 YFA0714900)+5 种基金the Key R&D Program of Shandong Province,China(2023CXGC010406)the Scientific Research Special Project for First-Class Disciplines in Inner Mongolia Autonomous Region(YLXKZXNKD-001)the Natural Science Foundation of Inner Mongolia Autonomous Region of China(2024ZD06)the Technology Support Project for the Construction of Major Innovation Platforms in Inner Mongolia Autonomous Region(XM2024XTGXQ16)the Beijing Municipal Natural Science Foundation(2222065)the Fundamental Research Funds for the Central Universities(FRF-TP-22-02C2).
文摘The reactor pressure vessel(RPV)is susceptible to brittle fracture due to the influence of ion irradiation and high temperature,which presents a significant risk to the safe operation of nuclear reactors.It has been demonstrated that pulsed electric current can effectively address the issue of embrittlement in RPV steel.However,the relationship between pulse parameters(duty ratio,frequency,current,and time)and the effectiveness of pulse current processing has not been systematically studied.The application of machine learning methods enables autonomous exploration and learning of the relationship between data.Consequently,this study proposes a machine learning method based on the random forest model to establish the relationship between the parameters of electrical pulses and the repair effect of RPV steel.A generative adversarial network is employed to enhance data diversity and scalability,while a particle swarm optimization algorithm is utilized to optimize the initialization weights and biases of the random forest model,aiming to improve the model’s fitting ability and training performance.The results indicate that the coefficient of determination R-square(R^(2)),root mean squared error and mean absolute error values are 0.934,0.045,and 0.036,respectively,suggesting that the model has the potential to predict the performance recovery of RPV steel after pulsed electric field treatment.The prediction of the impact of pulse current parameters on the repair effect will help to enhance and optimize the repair process,thereby providing a scientific basis for pulse current repair processing.
基金supported by Heilongjiang Provincial Natural Science Foundation(Grant No.E200504)in China and the Harbin Institute of Technology Inter-disciplines Foundation(Grant No.HIT.MD2002.14).
文摘Three kinds of AI-Si piston alloys were prepared and subjected to pulse electric current treatment （PECT） at different pouring temperatures. Some aspects of the solidification microstructures were examined including the morphology and the distribution of the matrix and the secondary phases by using of optical microscopy （OM）, SEM and EDS methods. Results indicate that PECT can refine the grains of α-AI in the alloys as effectively as chemical modification by sodium salt. The processing parameters of PECT on the multi-component AI-Si alloys were then optimized through the testing of tensile strength, elongation and microhardness of the prepared alloys. A new theory was put forward to explain the mechanism of PECT.
基金Item Sponsored by National Natural Science Foundation of China(50674064,50734008)
文摘A new approach to applying the electric current pulse （ECP） with parallel electrodes to the promotion of the transition from columnar crystal to equiaxed crystal and the improvement of macrosegregation was introduced. The ECP was applied to different stages of the solidification. The results showed that the application of the ECP in both the initial stage （the thickness of solidified shell reached 2 mm approximately） and the late stage （the thickness of solidified shell reached 14 mm approximately） of solidification can promote the columnar to equiaxed transition （CET）. The analysis showed that during solidification, a large number of nuclei around the upper surface fell off due to ECP, which subsequently showered on the melt and impinged the growth front of the columnar crystal. Therefore, the CEToccurred. In addition, this method was also employed to influence the solidification process of bearing steel, and the results showed that the structure was changed from columnar crystal to equiaxed crystal, indicating that ECP can enhance the homogeneity of structure and composition of bearing steel.
基金financially supported by the National Natural Science Foundation of China(No.51304039)the Fundamental Research Funds for the Central Universities(Nos.N110402008 and N130402021)Meishan Steel Plant Research Fund
文摘In this work, low-density electric current pulse （ECP） has been applied to submerged entry nozzle （SEN） and its effect on the morphology of the inclusion buildup and the distribution of the inclusions in slab has been explored. The results reveal that under the unique effects of ECP, part of small inclusions less than 10 μm is expelled through the boundary layer along the current direction to form dense inclusion buildup. This method is of great potential to prolong the service life of SEN and improve the quality of the steel product.
基金This work was supported by the National Natural Science Foundation of China under grant No.50232020 and 50220160657.
文摘Microstructure of reaction sintering of ZnAl2O4 at 1500℃ by hot-pressing(HP) and pulse electric current was investigated. The results indicated that the existed cracks in sintered body were caused by structure mismatch. It is the evidence that periodical temperature field existed during pulse electric current sintering of nonconductive materials. The distance between high temperature areas was related to die diameter.
基金supported by the National Natural Science Foundation of China(Grant Nos.51771210,51501207,51471173 and 51271185)the China’s Manned Space Station Project(Grant No.TGJZ800-2-RW024)the Natural Science Foundation of Liaoning Province(Grant No.201501043)
文摘Continuous solidification experiments are carried out with Pb–Al alloys under the influence of the electric current pulses（ECPs）. The results demonstrate that the ECPs mainly affect the microstructure formation through changing the energy barrier for the nucleation of the minority phase droplets（MPDs） and minority phase particles（MPPs） during cooling Pb–Al alloys in the liquid–liquid and liquid–solid phase transformation temperature ranges in advance of the solidification of the matrix liquid. For Pb–Al alloys with Al-rich droplets/particles as the minority phase, the ECPs lower the energy barriers for the nucleation of the MPDs/MPPs and cause a significant increase in the nucleation rate of the MPDs/MPPs and, thus,promote the formation of Pb–Al alloys with a well-dispersed or even nanoparticles dispersed microstructure. The ECPs parameters show an important influence on the microstructure formation of Pb–Al alloys. The refinement extent of the MPDs/MPPs increases with the increase in the peak current density. For a given peak current density, the refinement extent of the MPDs/MPPs increases with the increases in the pulse frequency and pulse width first, and then level off and become asymptotic.
基金Supported by the Natural Science Foundation of China (59872024) Key Teacher Fund of National Education Ministry and Fund of State Key Lab of Plastic Forming Simulation and Die and Mould Technology(02 -11)
文摘The sintering resistance for conductive TiB2 and non-conductive A12O3 as well as empty die during pulse current sintering were investigated in this paper. Equivalent resistances were measured by current and valtage during sintering the conductive and non-conductive materials in the same conditions. It is found that the current paths for conductive are different from those for non-conductive materials. For non-conductive materials, sintering resistances are influenced by powder sizes and heating rates, which indicates that pulse current has some interaction with non-conductive powders. For conductive TiB2 , sintering resistances are influenced by heating rates and ball-milling time, which indicates the effect of powders activated by spark.
基金financially supported by National Natural Science Foundation of China(Nos.U21B2082,51874023 and U1860206)the National Key Research and Development Program of China(No.2019YFC1908403)+1 种基金the Fundamental Research Funds for the Central Universities(No.FRF-TP-20–04B)the Recruitment Program of Global Experts。
文摘Nano-scale phases can enhance or reduce the mechanical properties of materials,so it is very important to control the size of the phases.Copper-rich nanoclusters as matrix defects will significantly reduce the performance of materials for key nuclear power components,while traditional heat treatment method has a technical bottleneck for the dissolution of nanoclusters.A new method of using the inherent electrical property discrepancies between the matrix material and the nanoclusters to effectively dissolve the nanoclusters through pulsed electric current to realize the recovery of material aging degradation performance is proposed.The performance evolution of simulated steel in the aging-external field repair cycle was studied,and it was found the dislocations as the preferred nucleation sites of nanoclusters were regulated in virtue of the non-thermal effect of current,resulting in a decrease in dislocation density and entanglement release.In the subsequent thermal aging process,the embrittlement rate of the aged and tempered material trained by the electric pulse was slower than that of the untreated sample.When moving dislocations are pinned by nanoclusters under high stress,nano-scale dislocations can be induced into the clusters.The dislocations near the nanoclusters and the newly formed nano-scale dislocations in the nanoclusters act as fast diffusion channels,which can further accelerate the dissolution of the nanoclusters.
文摘Laser Wakefield plasma acceleration of electrons to energies above 10 GeV, may be possible in the new high power Laser beam facilities. The design of an Electron Spectrometer with an electro-magnet with adjustable magnetic field is proposed for the characterization of electron energy spectrum with a precision better than 10% for the entire energy range from 0.5 GeV to 38 GeV. The expected precision in the measurement of the electron energy is calculated as a function of the magnetic field, of the electron energy and of the magnet length. To outline the advantages offered by a pulsed electromagnet with high magnetic fields, the mass and the electric power lost in the coils of a 4 m long electromagnet with continuous current and Iron yoke are calculated.
基金This work was supported by the State Key Laboratory of Mechanics and Control of Mechanical Structures at NUAA[Grant number MCMS-E-0520K02]the Key Laboratory of Impact and Safety Engineering,Ministry of Education at Ningbo University[Grant number CJ201904]+1 种基金the Fundamental Research Funds for the Central Universities[Grant numbers NE2020002,NS2019007]a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).
文摘We study electric currents in a piezoelectric semiconductor fiber under a constant voltage and time-dependent axial stresses applied locally.From a nonlinear numerical analysis based on a one-dimensional phenomenological model using the commercial software COMSOL,it is found that pulse electric currents can be produced by periodic or time-harmonic stresses.The pulse currents can be tuned by the amplitude and frequency of the applied stress.The result obtained provides a new approach for the mechanical control of electric currents in piezoelectric semiconductor fibers and has potential applications in piezotronics.
