Abstract Catalysts Pt/TiO2 and NiMo/Al2O3 are highly active and selective for the hydrodeoxygenation of guaiacol in a fixed bed reactor at 300℃ and 7.1 MPa, leading to the hydrogenation of aromatic ring, followed by ...Abstract Catalysts Pt/TiO2 and NiMo/Al2O3 are highly active and selective for the hydrodeoxygenation of guaiacol in a fixed bed reactor at 300℃ and 7.1 MPa, leading to the hydrogenation of aromatic ring, followed by demethylation and dehydroxylation to produce cyclohexane. For a complete hydrodeoxygenation of guaiacol, metal sites and acid sites are required. NiMo/Al2O3 and Pt/ Al2O3 are more active and selective for cyclohexane formation as compared with Pt/TiO2 at 285 Al2O3 and 4 MPa. However, Pt/TiO2 is stable while the other two catalysts deactivate due to the nature and amount of coke formation during the reaction.展开更多
N2O is a powerful greenhouse gas and plays an important role in destructing the ozone layer. This present work investigated the effects of Pd doping on N2O formation over Pt/BaO/Al2O3 catalyst. Three types of catalyst...N2O is a powerful greenhouse gas and plays an important role in destructing the ozone layer. This present work investigated the effects of Pd doping on N2O formation over Pt/BaO/Al2O3 catalyst. Three types of catalysts, Pt/BaO/Al2O3, Pt/Pd mechanical mixing catalyst （Pt/BaO/Al203 ＋ Pd/Al2O3） and Pt-Pd co-impregnation catalyst （Pt-Pd/BaO/Al2O3） were prepared by incipient wetness imoreenation method. These catalysts were first evaluated in NSR activity tests using H2/CO as reductants and then carefully characterized by BET, CO chemisorption, CO-DRIFTs and H2-TPR techniques. In addition, temperature programmed reactions of NO with H2/CO were conducted to obtain further information about NzO formation mechanism. Compared with Pt/BaO/Al2O3 （Pt/BaO/Al2O3 ＋ Pd/Al2O3） produced less N2O and more NH3 during NOx storage and reduction process, while an opposite trend was found over （Pt-Pd/BaO/Al2O3 ＋ Al2O3）. Temperature programmed reactions of NO with H2/CO results showed that Pd/Al2O3 component in （Pt/BaO/Al2O3 ＋ Pd/Al2O3） played an important role in NO reduction to NH3, and the formed NH3 could reduce NOx to N2 leading to a decrease in N2O formation. Most of N2O formed over （Pt-Pd/BaO/Al2O3 ＋ Al2O3） was originated from Pd/BaO/Al2O3 component. H2-TPR results indicated Pd-Ba interaction resulted in more difficult- to-reduce PdOx species over Pd/BaO/Al2O3, which inhibits the NO dissociation and thus drives the selectivity to N2O in NO reduction.展开更多
文摘Abstract Catalysts Pt/TiO2 and NiMo/Al2O3 are highly active and selective for the hydrodeoxygenation of guaiacol in a fixed bed reactor at 300℃ and 7.1 MPa, leading to the hydrogenation of aromatic ring, followed by demethylation and dehydroxylation to produce cyclohexane. For a complete hydrodeoxygenation of guaiacol, metal sites and acid sites are required. NiMo/Al2O3 and Pt/ Al2O3 are more active and selective for cyclohexane formation as compared with Pt/TiO2 at 285 Al2O3 and 4 MPa. However, Pt/TiO2 is stable while the other two catalysts deactivate due to the nature and amount of coke formation during the reaction.
基金Acknowledgements This work was financially supported by the National Key Research and Development Program （No. 2017YFC0211002） and the National Natural Science Foundation of China （Grant No. 21476170）.
文摘N2O is a powerful greenhouse gas and plays an important role in destructing the ozone layer. This present work investigated the effects of Pd doping on N2O formation over Pt/BaO/Al2O3 catalyst. Three types of catalysts, Pt/BaO/Al2O3, Pt/Pd mechanical mixing catalyst （Pt/BaO/Al203 ＋ Pd/Al2O3） and Pt-Pd co-impregnation catalyst （Pt-Pd/BaO/Al2O3） were prepared by incipient wetness imoreenation method. These catalysts were first evaluated in NSR activity tests using H2/CO as reductants and then carefully characterized by BET, CO chemisorption, CO-DRIFTs and H2-TPR techniques. In addition, temperature programmed reactions of NO with H2/CO were conducted to obtain further information about NzO formation mechanism. Compared with Pt/BaO/Al2O3 （Pt/BaO/Al2O3 ＋ Pd/Al2O3） produced less N2O and more NH3 during NOx storage and reduction process, while an opposite trend was found over （Pt-Pd/BaO/Al2O3 ＋ Al2O3）. Temperature programmed reactions of NO with H2/CO results showed that Pd/Al2O3 component in （Pt/BaO/Al2O3 ＋ Pd/Al2O3） played an important role in NO reduction to NH3, and the formed NH3 could reduce NOx to N2 leading to a decrease in N2O formation. Most of N2O formed over （Pt-Pd/BaO/Al2O3 ＋ Al2O3） was originated from Pd/BaO/Al2O3 component. H2-TPR results indicated Pd-Ba interaction resulted in more difficult- to-reduce PdOx species over Pd/BaO/Al2O3, which inhibits the NO dissociation and thus drives the selectivity to N2O in NO reduction.
