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Structure of the Quarks and a New Model of Protons and Neutrons: Answer to Some Open Questions
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作者 Ágnes Cziráki 《Natural Science》 CAS 2023年第1期11-18,共8页
The described structural model tries to answer some open questions such as: Why do quarks not exist in the open state? Where are the antiparticles from the Big Bang?
关键词 Structure of Quarks New model proton Neutron Open Questions
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Proton exchange membrane fuel cells modeling based on artificial neural networks 被引量:4
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作者 YudongTian XinjianZhu GuangyiCao 《Journal of University of Science and Technology Beijing》 CSCD 2005年第1期72-77,共6页
To understand the complexity of the mathematical models of a proton exchange membrane fuel cell (PEMFC) and their shortage of practical PEMFC control, the PEMFC complex mechanism and the existing PEMFC models are anal... To understand the complexity of the mathematical models of a proton exchange membrane fuel cell (PEMFC) and their shortage of practical PEMFC control, the PEMFC complex mechanism and the existing PEMFC models are analyzed, and artificial neural networks based PEMFC modeling is advanced. The structure, algorithm, training and simulation of PEMFC modeling based on improved BP networks are given out in detail. The computer simulation and conducted experiment verify that this model is fast and accurate, and can be used as a suitable operational model for PEMFC real-time control. 展开更多
关键词 fuel cells proton exchange membrane artificial neural networks improved BP algorithm modelING
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Quantitative analysis of glutamate compounds in the swine brain following central analgesics nasal spray using proton magnetic resonance spectroscopy and linear combination model
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作者 Jianlin Wu Ting Liu +4 位作者 Yan Lin Zhiwei Shen Yanwei Miao Renhua Wu Changkai Sun 《Neural Regeneration Research》 SCIE CAS CSCD 2009年第7期508-512,共5页
BACKGROUND: In localized brain proton magnetic resonance spectroscopy (^1H-MRS), metabolite levels are often expressed as ratios, rather than absolute concentrations. Frequently, the denominator is creatine, which ... BACKGROUND: In localized brain proton magnetic resonance spectroscopy (^1H-MRS), metabolite levels are often expressed as ratios, rather than absolute concentrations. Frequently, the denominator is creatine, which is assumed to be stable in normal, as well as many pathological, states. However, in vivo creatine levels do not remain constant. Therefore, absolute metabolite measurements, which provide the precise concentrations of certain chemical compounds, are superior to metabolite ratios for determining pathological and evolutional changes. OBJECTIVE: To investigate the feasibility of quantification analysis of brain metabolite changes caused by central analgesics nasal spray using the ^1H-MRS and linear combination model (LCModel) methods. DESIGN, TIME AND SETTING: This neuroimaging, observational, animal study was performed at the Laboratory of the Department of Medical Imaging, Second Affiliated Hospital, Medical College, Shantou University, China from July to December 2007. MATERIALS: Butorphanol tartrate nasal spray, as a mixed agonist-antagonist opioid analgesic, was purchased from Shanghai Hengrui Pharmacy, China. A General Electric Signa 1.5T System (General Electric Medical Systems, Milwaukee, WI, USA) and LCModel software (Stephen Provencher, Oakville, Ontario, Canada) were used in this study. METHODS: MRS images were acquired in ten healthy swine aged 2 weeks using single-voxel point-resolved spectroscopic sequence. A region of interest (2 cm × 2 cm × 2 cm) was placed in the image centers of maximum brain parenchyma. Repeated MRS scanning was performed 15-20 minutes after intranasal administration of 1 mg of butorphanol tartrate. Three settings of repetition time/echo time were selected before and after nasal spray administration 3 000 ms/30 ms,1 500 ms/30 ms, and 3 000 ms/50 ms. Metabolite concentrations were estimated by LCModel software. MAIN OUTCOME MEASURES: ^1H-MRS spectra was obtained using various repetition time/echo time settings. Concentrations of glutamate compounds (glutamate + glutamine), N-acetyl aspartate, and choline were detected in swine brain prior to and following nasal spray treatment. RESULTS: The glutamate compounds curve was consistent with original spectra, when a repetition time/echo time of 3 000 ms/30 ms was adopted. Concentrations of glutamate compounds, N-acetyl aspartate, and choline decreased following administration. The most significant reduction was observed in glutamate compound concentrations from (9.28 ± 0.54) mmol/kg to (7.28 ± 0.54) mmol/kg (P 〈 0.05). CONCLUSION: ^1H-MRS and LCModel software were effectively utilized to quantitatively analyze and measure brain metabolites. Glutamate compounds might be an important neurotransmitter in central analgesia. 展开更多
关键词 proton magnetic resonance spectroscopy nasal spray linear combination model glutamate compounds absolute quantification
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Modeling of the Chemico-Physical Process of Protonation of Molecules Entailing Some Quantum Chemical Descriptors
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作者 Sandip K. Rajak Nazmul Islam Dulal C. Ghosh 《Journal of Quantum Information Science》 2011年第2期87-95,共9页
Relying upon the basic tenets of scientific modeling, an ansatz for the evaluation of proton affinity of mole-cules are evolved in terms of a four component model. The components of the model chosen are global de-scri... Relying upon the basic tenets of scientific modeling, an ansatz for the evaluation of proton affinity of mole-cules are evolved in terms of a four component model. The components of the model chosen are global de-scriptors like ionization energies, global softness, electronegativity and electrophilicity index. These akin quantum mechanical descriptors of atoms and molecules are linked with the charge rearrangement and polarization that occur during the physico-chemical process of protonation of molecules. The suggested ansatz is invoked to compute the protonation energy of as many as 43 compounds of diverse physico-chemical nature viz, hydrocarbons, alcohols, carbonyls, carboxylic acids, esters, aliphatic amines and aromatic amines. A detailed comparative study of theoretically evaluated protonation energies of the above mentioned molecules vis-à-vis their corresponding experimental counterparts reveals that there is a close agreement between the theory and experiment. Thus the results strongly suggest that the proposed modeling and the ansatz for computing PA, the proton affinity, of molecules for studying the physico-chemical process of protonation may be valid proposition. 展开更多
关键词 Physico-Chemical Process of protonATION proton AFFINITY Conceptual DENSITY FUNCTIONAL DESCRIPTORS Commonality between DENSITY FUNCTIONAL DESCRIPTORS and proton AFFINITY Muliti-Linear Regression model
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Discoloration Range and Shroud Image Depth Values Cannot Be Satisfied by the Same Proton Energy
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作者 Giovanni Fazio 《Open Journal of Applied Sciences》 2023年第8期1224-1232,共9页
The radiative hypothesis has been revisited showing other characteristics, produced by the protons used as dyes in total disagree with the ones of the Body Image that appears on the Shroud of Turin. Our investigations... The radiative hypothesis has been revisited showing other characteristics, produced by the protons used as dyes in total disagree with the ones of the Body Image that appears on the Shroud of Turin. Our investigations highlight that for the protons to reach 3.7 cm in air, the distance that measures the range of discoloration effects, must be emitted with an energy of about 1.5 MeV using Wilson and Brobeck’s empirical formula and 1.35 MeV using Bethe’s. This last formula provides a result closer to reality. Bethe shows that the penetration depth is greater than that calculated empirically. Such a value of proton energy (1.35 MeV) makes it possible to satisfy the discoloration effects range for the Shroud but it is incompatible with a depth of penetration in linen that is only 200 nm. Moreover, using the same subatomic particles, we obtained on the colored linen a distribution of energy represented by regression but not linear. Thus, also the possible I(z) correlation, between color intensity and body-sheet distance, which should be due to the oxidizing action of protons, does not agree with that extracted from the Shroud of Turin. 展开更多
关键词 Shroud of Turin Body Image Formation Radiative Hypothesis proton model Discoloration Effects Range
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Neural Model-Based Self-Tuning PID Strategy Applied to PEMFC 被引量:1
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作者 Cédric Damour Michel Benne +1 位作者 Brigitte Grondin-Perez Jean-Pierre Chabriat 《Engineering(科研)》 2014年第4期159-168,共10页
This paper illustrates the benefits of a self-tuning PID strategy applied to a proton exchange membrane fuel cell system. Controller parameters are updated on-line, at each sampling time, based on an instantaneous lin... This paper illustrates the benefits of a self-tuning PID strategy applied to a proton exchange membrane fuel cell system. Controller parameters are updated on-line, at each sampling time, based on an instantaneous linearization of an artificial neural network model of the process and a General Minimum Variance control law. The self-tuning PID scheme allows managing nonlinear behaviors of the system while avoiding heavy computations. The applicability, efficiency and robustness of the proposed control strategy are experimentally confirmed using varying control scenarios. In this aim, the original built-in controller is overridden and the self-tuning PID controller is implemented externally and executed on-line. Experimental results show good performance in setpoint tracking accuracy and robustness against plant/model mismatch. The proposed strategy appears to be a promising alternative to heavy computation nonlinear control strategies and not optimal linear control strategies. 展开更多
关键词 SELF-TUNING PID CONTROLLER Artificial Neural Network model proton EXCHANGE MEMBRANE Fuel Cell Real-Time Control Scheme Experimental Implementation
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Dirac Coupled Channel Analyses of Proton Inelastic Scatterings from s-d Shell Nuclei
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作者 Sugie Shim Moon-Won Kim Young-You Kim 《Journal of Applied Mathematics and Physics》 2015年第4期443-448,共6页
Proton inelastic scatterings from several s-d shell nuclei are analyzed using optical potential model and collective model in Dirac coupled channel formalism. The optical potential parameters obtained phenomenological... Proton inelastic scatterings from several s-d shell nuclei are analyzed using optical potential model and collective model in Dirac coupled channel formalism. The optical potential parameters obtained phenomenologically for the scatterings from the s-d shell nuclei are compared with each other for systematic Dirac analysis. Dirac equations are reduced to the second-order differential equations in order to obtain the Schroedinger equivalent effective central and spin-orbit optical potentials, and the surface-peaked phenomena are observed at the real effective central potentials for the scatterings from 22Ne, 20Ne and 24Mg. By analyzing the obtained effective spin-orbit potentials, it is confirmed that the spin-orbit interaction is a surface-peaked interaction. The first-order rotational collective models are used to describe the low-lying excited states of the ground state rotational bands in the s-d shell deformed nuclei, and the obtained deformation parameters are analyzed by comparing with each other, and compared with those obtained by using the nonrelativistic calculations. The obtained deformation parameters of Dirac phenomenological calculations for the s-d shell nuclei are found to agree pretty well with those of the nonrelativistic calculations using the same Woods-Saxon potential shape, even though the theoretical bases are quite different. 展开更多
关键词 DIRAC COUPLED CHANNEL ANALYSES Optical Potential model proton Inelastic Scattering Collective model
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Two-proton sequential decay from excited states of ^(18)Ne
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作者 YU Ningal MAGLIONE Enrico FERREIRA Lidia 《Nuclear Science and Techniques》 SCIE CAS CSCD 2013年第5期89-91,共3页
Two-proton radioactivity from18Ne is discussed in terms of sequential decay.The branch ratios for oneproton emission from excited states are calculated,which including spectroscopic factors,obtained from a Shellmodel ... Two-proton radioactivity from18Ne is discussed in terms of sequential decay.The branch ratios for oneproton emission from excited states are calculated,which including spectroscopic factors,obtained from a Shellmodel calculation with realistic interactions.The branch ratios show that the two-proton emission from the 1-state of 18Ne at 7.94 MeV is most likely to go through the sequential decay.The same mechanism is discussed for other excited states at higher energy by different interactions. 展开更多
关键词 质子衰变 激发态 质子发射 分支比 放射性 壳模型 衰减 计算
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Response of multi-step compound pre-equilibrium reaction cross sections for the(p,n)reactions to forms of optical model parameters 被引量:1
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作者 Felix S.Olise Oludaisi I.Oladunjoye +2 位作者 Afis Ajala Sunday D.Olorunfunmi Hezekiah B.Oianiyi 《Nuclear Science and Techniques》 SCIE CAS CSCD 2017年第10期65-70,共6页
In furtherance to improving agreement between calculated and experimental nuclear data, the nuclear reaction code GAMME was used to calculate the multistep compound(MSC) nucleus double differential cross sections(DDCs... In furtherance to improving agreement between calculated and experimental nuclear data, the nuclear reaction code GAMME was used to calculate the multistep compound(MSC) nucleus double differential cross sections(DDCs) for proton-induced neutron emission reactions using the Feshbach-Kerman-Koonin(FKK) formalism. The cross sections were obtained for reactor structural materials involving ^(52)Cr(p, n)^(52)Mn,^(56)Fe(p,n)^(56)Co, and ^(60)Ni(p, n)^(60)Cu reactions at 22.2 MeV incident energy using the zero-range reaction mechanism. Effective residual interaction strength was 28 MeV, and different optical potential parameters were used for the entrance and exit channels of the proton-neutron interactions. The calculated DDCs were fitted to experimental data at the same backward angle of 150°, where the MSC processes dominate. The calculated and experimental data agree well in the region of pre-equilibrium(MSC) reaction dominance against a weaker fit at the lower emission energies. We attribute underestimations to contributions from the other reaction channels and disagreement at higher outgoing energies to reactions to collectively excited states. Contrary to the FKK multi-step direct calculations, contributions from the higher stages to the DDCs are significant. Different sets of parameters resulted in varying levels of agreement of calculated and experimental data for the considered nuclei. 展开更多
关键词 反应截面 光学势参数 预平衡 模型参数 多步 复合 相互作用强度 实验数据
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On the Possible Structures of Electron and Proton
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作者 Wei-Xing Xu 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第4期1734-1742,共9页
In this work, the possible structures of electron and proton have been explored. Based on the potential expressions of electron and proton, we found that the electron and proton share the similar structure inside re a... In this work, the possible structures of electron and proton have been explored. Based on the potential expressions of electron and proton, we found that the electron and proton share the similar structure inside re and rn. And within re and rn, the conventional charge concept stops working, the same charge repelling force doesn’t exist anymore and as a result, the requirement of charge conservation is automatically removed. Whereas beyond re and rn, the potential expressions of electron and proton obey the point charge potentials as we normally understand. Therefore, the conventional charge concept can be applied and the requirement of charge conservation takes effect. Furthermore, a possible mechanism for the creations of electric monopole and magnetic monopole is discussed. In addition, to compare the particle size in micro-world, the balloon criterion is proposed. By this balloon criterion, the proton is determined about 10 times bigger than electron. From the physical picture about electron and proton described above, the stabilities of electron and proton can be explained quite well. 展开更多
关键词 Electromagnetic Spacetime Quantum Mechanics ELECTRON proton Standard model Particle Physics “Yin-Yang” Philosophy Electric Monopole Magnetic Monopole Charge Conservation
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Mechanistic Model versus Artificial Neural Network Model of a Single-Cell PEMFC
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作者 Brigitte Grondin-Perez Sébastien Roche +3 位作者 Carole Lebreton Michel Benne Cédric Damour Jean-Jacques Amangoua Kadjo 《Engineering(科研)》 2014年第8期418-426,共9页
Model-based controllers can significantly improve the performance of Proton Exchange Membrane Fuel Cell (PEMFC) systems. However, the complexity of these strategies constraints large scale implementation. In this work... Model-based controllers can significantly improve the performance of Proton Exchange Membrane Fuel Cell (PEMFC) systems. However, the complexity of these strategies constraints large scale implementation. In this work, with a view to reduce complexity without affecting performance, two different modeling approaches of a single-cell PEMFC are investigated. A mechanistic model, describing all internal phenomena in a single-cell, and an artificial neural network (ANN) model are tested. To perform this work, databases are measured on a pilot plant. The identification of the two models involves the optimization of the operating conditions in order to build rich databases. The two different models benefits and drawbacks are pointed out using statistical error criteria. Regarding model-based control approach, the computational time of these models is compared during the validation step. 展开更多
关键词 MECHANISTIC model Artificial Neural Network model proton Exchange Membrane Fuel Cell Real-Time Experiment
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Scaling Law of s-Wave Valence Proton Distributions
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作者 郭艳青 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第5期402-404,共3页
Inthe framework of the single-particle potential model, the root-meamsquare radii of s-wave valence proton distributions for P and S isotopes have been systematically calculated. The scaling law of s-wave valence prot... Inthe framework of the single-particle potential model, the root-meamsquare radii of s-wave valence proton distributions for P and S isotopes have been systematically calculated. The scaling law of s-wave valence proton distributions is obtained by analyzing the relation between radii and separation energies. Necessary condition for the occurrence of 2sl/2-state proton halos is deduced from the scaling law. Quantitative condition derived from this work can to some extent serve as reference for proton halo search. 展开更多
关键词 scaling law s-wave proton halo single-particle potential model
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Vehicles PEMFC Power System Mathematical Model for Integrated Design
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作者 Vincenzo Di Dio Diego La Cascia Rosario Liga Rosario Miceli 《Journal of Energy and Power Engineering》 2013年第4期746-751,共6页
In this paper, the mathematical dynamical model of a PEMFC (proton exchange membrane fuel cells) stack, integrated with an automotive synchronous electrical power drive, developed in Matlab environment, is shown. Lo... In this paper, the mathematical dynamical model of a PEMFC (proton exchange membrane fuel cells) stack, integrated with an automotive synchronous electrical power drive, developed in Matlab environment, is shown. Lots of simulations have been executed in many load conditions. In this paper, the load conditions regarding an electrical vehicle for disabled people is reported. The innovation in this field concerns the integration, in the PEMFC stack mathematical dynamic model, of a synchronous electrical power drive for automotive purposes. Goal of the simulator design has been to create an useful tool which is able to evaluate the behaviour of the whole system so as to optimize the components choose. As regards the simulations with a synchronous electrical power drive, the complete mathematical model allows to evaluate the PEMFC stack performances and electrochemical efficiency. 展开更多
关键词 proton exchange membrane fuel cells mathematical model automotive synchronous electrical power drive test cycle.
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Nuclear in-medium effects on η dynamics in proton–nucleus collisions
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作者 Jie Chen Zhao-Qing Feng Jian-Song Wang 《Nuclear Science and Techniques》 SCIE CAS CSCD 2016年第3期171-175,共5页
The dynamics of the η meson produced in proton-induced nuclear reactions via the decay of N*(1535)has been investigated within the Lanzhou quantum molecular dynamics transport model.The in-medium modifications of the... The dynamics of the η meson produced in proton-induced nuclear reactions via the decay of N*(1535)has been investigated within the Lanzhou quantum molecular dynamics transport model.The in-medium modifications of the η production in dense nuclear matter are included in the model,in which an attractive η-nucleon potential is implemented.The impact of the η optical potential on the η dynamics is investigated.It is found that the attractive potential leads to the reduction in high-momentum(kinetic energy) production from the spectra of momentum distributions and inclusive cross sections and increasing the reabsorption process by surrounding nucleons. 展开更多
关键词 量子分子动力学模型 质子 核碰撞 动量分布 吸收过程 吸引力 核反应 核物质
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Dynamic modeling and simulation test of a 60 kW PEMFC generation system 被引量:1
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作者 Ying-ying ZHANG Ji-chang SUN +2 位作者 Ying ZHANG Xi LI Ouang-yi CAO 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2011年第6期475-482,共8页
In this paper,a 60 kW proton exchange membrane fuel cell(PEMFC) generation system is modeled in order to design the system parameters and investigate the static and dynamic characteristics for control purposes.To achi... In this paper,a 60 kW proton exchange membrane fuel cell(PEMFC) generation system is modeled in order to design the system parameters and investigate the static and dynamic characteristics for control purposes.To achieve an overall system model,the system is divided into five modules:the PEMFC stack(anode and cathode flows,membrane hydration,and stack voltage and power),cathode air supply(air compressor,supply manifold,cooler,and humidifier),anode fuel supply(hydrogen valve and humidifier),cathode exhaust exit(exit manifold and water return),and power conditioning(DC/DC and DC/AC) modules.Using a combination of empirical and physical modeling techniques,the model is developed to set the operation conditions of current,temperature,and cathode and anode gas flows and pressures,which have major impacts on system performance.The current model is based on a 60 kW PEMFC power plant designed for residential applications and takes account of the electrochemical and thermal aspects of chemical reactions within the stack as well as flows of reactants across the system.The simulation tests show that the system model can represent the static and dynamic characteristics of a 60 kW PEMFC generation system,which is mathematically simple for system parameters and control designs. 展开更多
关键词 proton exchange membrane fuel cell(PEMFC) Generation system Dynamic simulation model Reactant flow
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网格化管理结合FOCUS-PDCA模式在提升PPIs临床合理用药的研究
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作者 詹剑玲 崔明 +2 位作者 欧志莲 郑小棵 曹堃 《安徽医专学报》 2025年第3期5-7,19,共4页
目的:探讨网格化管理结合焦点管理循环(FOCUS-PDCA)模式在提升质子泵抑制剂(PPIs)临床合理用药水平中的应用价值。方法:以实施网格化管理+FOCUS-PDCA为分界点,分为干预前组(2022年5月-2023年5月使用PPIs住院患者病例,该组纳入300例)和... 目的:探讨网格化管理结合焦点管理循环(FOCUS-PDCA)模式在提升质子泵抑制剂(PPIs)临床合理用药水平中的应用价值。方法:以实施网格化管理+FOCUS-PDCA为分界点,分为干预前组(2022年5月-2023年5月使用PPIs住院患者病例,该组纳入300例)和干预后组(2023年6月-2024年6月使用网格化管理+FOCUS-PDCA管理模式干预的PPIs住院患者病例,该组纳入300例)。比较两组患者PPIs用药治疗期间不合理事件发生率、PPIs使用费用情况的差异。结果:干预后组PPIs各项不合理用药事件发生率均较干预前组明显更低(P<0.05)。干预后组PPIs每月用药金额、用药频度以及DUI均较干预前组明显更低(P<0.05)。结论:网格化管理与FOCUS-PDCA模式联合应用有助于提升PPIs临床用药的合理性,可预防患者不良反应发生,还能减轻患者经济压力,值得临床推广应用。 展开更多
关键词 网格化管理 FOCUS-PDCA模式 质子泵抑制剂 临床合理用药
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车用大尺寸PEM燃料电池流场结构多目标优化设计
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作者 田韶鹏 魏运哲 肖从达 《重庆理工大学学报(自然科学)》 北大核心 2025年第8期213-221,共9页
针对大尺寸平行流场(SPFF)工质分布不均和排水效率低的问题,开发了基于曲折平行流场(WPFF)的多目标优化设计方法:通过构建二维半电池代理模型简化三维多相数值模型,结合鲸鱼优化算法(WOA)平衡电压输出与流场压降。研究表明:优化后的WPFF... 针对大尺寸平行流场(SPFF)工质分布不均和排水效率低的问题,开发了基于曲折平行流场(WPFF)的多目标优化设计方法:通过构建二维半电池代理模型简化三维多相数值模型,结合鲸鱼优化算法(WOA)平衡电压输出与流场压降。研究表明:优化后的WPFF(WPFFO)结构在催化剂用量减少7.4%的条件下,0.4 V工况下电流密度提升1.6%,净功率密度显著增加,流道内氧气分布均匀性提高,液态水积聚现象得到有效抑制。三维多物理场验证结果表明,该设计通过增强湍流效应和垂直传质效率改善了浓差极化和水管理能力,可使PEMFC更加高效、稳定地运行。 展开更多
关键词 质子交换膜燃料电池 代理模型 多目标优化 鲸鱼算法 水管理
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质子交换膜电解池阴极催化层的孔隙网络模拟
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作者 罗马吉 秦超超 +1 位作者 陈黎 陈奔 《江苏大学学报(自然科学版)》 北大核心 2025年第3期293-300,共8页
为了探究催化层内部的水气传输和电子传导现象,建立了质子交换膜电解池阴极催化层的孔隙网络模型,获取了传输参数(渗透率、扩散率)以及电化学参数(电导率、电化学活性比表面积)随催化层微观结构的变化规律.结果表明:在催化层内部,随着... 为了探究催化层内部的水气传输和电子传导现象,建立了质子交换膜电解池阴极催化层的孔隙网络模型,获取了传输参数(渗透率、扩散率)以及电化学参数(电导率、电化学活性比表面积)随催化层微观结构的变化规律.结果表明:在催化层内部,随着水饱和度的降低,催化层不同方向上的气体相对扩散率和相对渗透率均逐渐增大,且当水饱和度为0~0.61时具有较佳的水气传输特性;催化层电导率随着铂颗粒半径的增大而非线性增大,铂颗粒半径由5 nm增大到20 nm时,电导率增大了55.7%;电导率随孔隙直径的增大而逐渐减小,但变化较小;催化层电化学活性比表面积随着铂颗粒半径或者孔隙直径的增大而非线性减小,且减小程度相当. 展开更多
关键词 质子交换膜电解池 阴极催化层 孔隙网络模型 传输特性 电子传导
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船用PEM燃料电池建模与多因素仿真分析
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作者 滕宪斌 王杰 +2 位作者 葛涛 张潇 常高雷 《广州航海学院学报》 2025年第3期1-7,43,共8页
随着全球清洁能源转型的推进与船舶行业碳排放监管趋严,质子交换膜燃料电池(PEMFC)因其高效率、零排放及低噪声等优势,正成为船舶推进系统的重要发展方向。针对当前燃料电池研究中稳态分析多、动态机制揭示不足的局限,本文基于MATLAB/Si... 随着全球清洁能源转型的推进与船舶行业碳排放监管趋严,质子交换膜燃料电池(PEMFC)因其高效率、零排放及低噪声等优势,正成为船舶推进系统的重要发展方向。针对当前燃料电池研究中稳态分析多、动态机制揭示不足的局限,本文基于MATLAB/Simulink平台构建了一个集电堆电压、气体流动、水管理与热力学耦合过程于一体的多物理场动态仿真模型,重点模拟分析了工作温度、膜含水量及气体供给等参数对燃料电池性能的多因素影响机制。结果表明:当工作温度由60℃升高至80℃时,低电流密度下输出电压提升约10%;在高电流密度区域,膜水管理优化可进一步提升性能达8%。此外,通过引入双电荷层滞后机制与动态负载阶跃仿真,模型能准确反映输出电压、功率及气体分压的瞬态响应特征。 展开更多
关键词 质子交换膜燃料电池 负载扰动 动态建模 稳态特性 多因素分析
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光伏耦合组合式PEM电解槽制氢技术
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作者 王露 徐智良 +3 位作者 金浩 任宇宸 陈晓玮 齐琪 《石油与天然气化工》 北大核心 2025年第3期79-85,共7页
目的 旨在建立光伏波动条件下多质子交换膜(PEM)电解槽协同运行的动态模型,为规模化制氢系统优化提供理论依据。方法 根据电化学原理,采用Aspen Custom Modeler软件建立PEM电解槽模型,并将其作为子程序集成到Aspen Plus,在Aspen Plus中... 目的 旨在建立光伏波动条件下多质子交换膜(PEM)电解槽协同运行的动态模型,为规模化制氢系统优化提供理论依据。方法 根据电化学原理,采用Aspen Custom Modeler软件建立PEM电解槽模型,并将其作为子程序集成到Aspen Plus,在Aspen Plus中选用ELECNRTL物性计算方法及合适的单元模块,搭建了组合多个20 m^(3)/h级的PEM电解制氢工艺流程。计算中将系统电流密度设置成随着光照强度变化,以电流密度的阶跃变化来模拟可再生能源波动的场景。结果 组合2、3和4个电解槽时,系统最终平均产氢速率分别为41.03、61.55和82.07 m^(3)/h,分离与精制过程中的氢气损失均为3.9%,PEM电解槽能耗为4.504 kW·h/m^(3),与中国电力工程顾问集团某示范工程现场数据的4.509 kW·h/m^(3)对比,相对误差控制在0.1%。结论 在实际运行中,利用多个电解槽组合运用机制,若因光照较弱而导致系统输入功率下降,可停用部分PEM电解槽。研究结果可为实际光伏电解水制氢工艺提供理论参考。 展开更多
关键词 质子交换膜电解 Aspen建模 光伏制氢 动态模拟
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