In this study, several kinds of flexible protective materials sprayed with polyurea elastomers （hereinafter referred to as polyurea elastomer protective material） were adopted to meet the abrasion resistance require...In this study, several kinds of flexible protective materials sprayed with polyurea elastomers （hereinafter referred to as polyurea elastomer protective material） were adopted to meet the abrasion resistance requirement of hydraulic structures, and their abrasion resistances against the water flow with suspended load or bed load were studied systematically through tests. Natural basalt stones were adopted as the abrasive for simulation of the abrasion effect of the water flow with bed load, and test results indicate that the basalt stone is suitable for use in the abrasion resistance test of the flexible protective material. The wear process of the polyurea elastomer protective material is stable, and the wear loss is linear with the time of abrasion. If the wear thickness is regarded as the abrasion resistance evaluation factor, the abrasion resistance of the 351 pure polyurea is about twice those of pure polyurea with a high level of hardness and aliphatic polyurea, and over five times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with suspended load. It is also about 50 times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with bed load. Overall, the abrasion resistance of pure polyurea presented a decreasing trend with increasing hardness. Pure polyurea with a Shore hardness of D30 has the best abrasion resistance, which is 60 to 70 times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with bed load, and has been recommended, among the five kinds of pure polyurea materials with different hardness, in anti-abrasion protection of hydraulic structures.展开更多
Thermal runaway(TR)is considered a significant safety hazard for lithium batteries,and thermal protection materials are crucial in mitigating this risk.However,current thermal protection materials generally suffer fro...Thermal runaway(TR)is considered a significant safety hazard for lithium batteries,and thermal protection materials are crucial in mitigating this risk.However,current thermal protection materials generally suffer from poor mechanical properties,flammability,leakage,and rigid crystallization,and they struggle to continuously block excess heat transfer and propagation once thermal saturation occurs.This study proposes a novel type of thermal protection material:an aerogel coupled composite phase change material(CPCM).The composite material consists of gelatin/sodium alginate(Ge/SA)composite biomass aerogel as an insulating component and a thermally induced flexible CPCM made from thermoplastic polyester elastomer as a heat-absorbing component.Inspired by power bank,we coupled the aerogel with CPCM through the binder,so that CPCM can continue to‘charge and store energy’for the aerogel,effectively absorbing heat,delaying the heat saturation phenomenon,and maximizing the duration of thermal insulation.The results demonstrate that the Ge/SA aerogel exhibits excellent thermal insulation(with a temperature difference of approximately 120℃ across a 1 cm thickness)and flame retardancy(achieving a V-0 flame retardant rating).The CPCM exhibits high heat storage density(811.9 J g^(−1)),good thermally induced flexibility(bendable above 40℃),and thermal stability.Furthermore,the Ge/SA-CPCM coupled composite material shows even more outstanding thermal insulation performance,with the top surface temperature remaining at 89℃ after 100 min of exposure to a high temperature of 230℃.This study provides a new direction for the development of TR protection materials for lithium batteries.展开更多
Public health events caused by viruses pose a significant risk to humans worldwide.From December 2019 till now,the rampant novel 2019 coronavirus(SAR-CoV-2)has hugely impacted China and over world.Regarding a commenda...Public health events caused by viruses pose a significant risk to humans worldwide.From December 2019 till now,the rampant novel 2019 coronavirus(SAR-CoV-2)has hugely impacted China and over world.Regarding a commendable means of protection,mask technology is relatively mature,though most of the masks cannot effectively resist the viral infections.The key material of the mask is a non-woven material,which makes the barrier of virus through filtration.Due to the lack of the ability to kill the viruses,masks are prone to cross-infection and become an additional source of infection after being discarded.If the filteration and antiviral effects can be simultaneously integrated into the mask,it will be more effcient,work for a longer time and create less difficulty in post-treatment.This mini-review presents the advances in antiviral materials,different mechanisms of their activity,and their potential applications in personal protective fabrics.Furthermore,the article addresses the future challenges and directions of mask technology.展开更多
Cu–Ni and Cu–Co–Ni superhydrophobic films were constructed on the surface of B10 copper–nickel alloy welded joints using a two-step process of electrodeposition and stearic acid modification.The chemical compositi...Cu–Ni and Cu–Co–Ni superhydrophobic films were constructed on the surface of B10 copper–nickel alloy welded joints using a two-step process of electrodeposition and stearic acid modification.The chemical composition of the film surface was determined using surface characterization techniques.The corrosion resistance of the films was characterized using electrochemical impedance spectroscopy,potentiodynamic polarization,and scanning Kelvin probe microscopy at multiple scales.The thermal stability,mechanical stability,and self-cleaning properties of the films were also characterized.It was determined that the Cu–Co–Ni superhydrophobic film exhibited the best performance,with a static water contact angle of 159.3°,a roll-off angle of 2.3°,a charge transfer resistance 3300 times higher than the substrate,a self-corrosion current density nearly three orders of magnitude lower,and a surface Kelvin potential increase of 420 mV.The film demonstrated good thermal stability,excellent mechanical stability,and outstanding self-cleaning properties.Combining with previous studies,it was found that Co elements in the film contribute to the formation of a uniform and dense film,Ni elements enhance the adhesion and corrosion resistance between the films,and the combination of Co and Ni elements promotes uniform surface potential and further improves the corrosion resistance and interfilm adhesion of the films.展开更多
The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hyperso...The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical ＆ Applied Mechanics Letters （TAML） and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.展开更多
Effect of isobutyl-triethoxy-silane penetrative protective agent on the carbonation resistance of the concrete was studied.The concrete specimens for the 28 d accelerated carbonation process were manufactured with w/c...Effect of isobutyl-triethoxy-silane penetrative protective agent on the carbonation resistance of the concrete was studied.The concrete specimens for the 28 d accelerated carbonation process were manufactured with w/c of 0.49 and 0.64,both in the presence and absence of silane and mineral admixture.The penetration of isobutyl-triethoxy-silane and the carbonation of concrete were investigated by penetration depth,carbonation depth,XRD,SEM,and pore size distribution.The results showed that concrete compactness played an important role in the silane penetration and carbonation resistance.Penetration depth of silane-treated concrete mainly depended on the compactness of the concrete,and could not remarkably change through the accelerated carbonation process.In the accelerated carbonation process,penetrative protective agent improved the carbonation resistance of the higher compactness concretes but accelerated the carbonization process of the lower compactness concretes.As penetrative protective agent penetrated along the external connectivity pores into concrete not filling the entire surface area,the inorganic film could not fully protect the Ca（OH）_2 phase from carbonation.After 28 d accelerated carbonation,fibrous hydration products disappeared and the surface holes decreased.Due to the formation of carbonized products,the porosity of the concrete surface decreased,especially in high-strength concrete.展开更多
NATO standards"AEP-2920 Procedures for the Evaluation and Classification of Personal Armor"and NIJ Standard-0101.06,indicate the method to statistically assess the resistance of personal ballistic protection...NATO standards"AEP-2920 Procedures for the Evaluation and Classification of Personal Armor"and NIJ Standard-0101.06,indicate the method to statistically assess the resistance of personal ballistic protection materials.To be validated and accepted through these procedures,a personal ballistic protection material should withstand an impact of a specific projectile with a probability of a partial penetration confidence level higher than 90%.The present study introduces an energy equilibrium method to assess the confidence level for the probability of partial penetration of ductile and brittle materials.The experiments performed in the Ballistics laboratory of the Royal Military Academy in Belgium,use a modified pendulum method that allowed the quantification of the energy balance before and after the ballistic impact.The results were then compared with the ones obtained using the method specified by the NATO standard and NIJ 0101.06,mentioned above.The outcome of this comparison shows the tendency of the values obtained by the pendulum method to faithfully follow the values obtained according to NATO and NIJ specifications.The presented method is not based on statistical estimations,but instead,an exact method,of computing the energy absorbed by the tested material.This is an advantage for the cases when the material to be evaluated is expensive or it is in the development phase and mass production is not possible.展开更多
Multi-phase flow effect generated from the combustion of aluminum based composite propellant was performed on the thermal protection material of solid rocket motor(SRM) nozzle.Injection of alumina(Al2O3) particles fro...Multi-phase flow effect generated from the combustion of aluminum based composite propellant was performed on the thermal protection material of solid rocket motor(SRM) nozzle.Injection of alumina(Al2O3) particles from 5% to 10% was tried on SRM nozzle flow field to see the influence of multiphase flow on heat transfer computations.A coupled,time resolved CFD(computational fluid dynamics) approach was adopted to solve the conjugate problem of multi-phase fluid flow and heat transfer in the solid rocket motor nozzle.The governing equations are discretized by using the finite volume method.Spalart-Allmaras(S-A) turbulence model was employed.The computation was executed on the different models selected for the analysis to validate the temperature variation in the throat inserts and baking material of SRM nozzle.Comparison for temperatures variations were also carried out at different expansion ratios of nozzle.This paper also characterized the advanced SRM nozzle composites material for their high thermo stability and their high thermo mechanical capabilities to make it more reliable simpler and lighter.展开更多
Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric an...Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric analysis (TGA),X-ray diffraction (XRD),scanning electron microscope (SEM),and mercury intrusion porosimetry (MIP) were further employed to evaluate the chemical composition and microstructure characteristics of SPM.Besides,thermodynamic modeling was adopted to simulate the changes in the phase assemblages of SPM under the carbonation process.The results showed that SPM with 1 wt% HNS could effectively enhance the carbonation resistance.The incorporation of HNS could densify the microstructure and refine the pore structure.Moreover,the thaumasite can be stable at ambient temperature with the addition of HNS,which is beneficial to maintain alkalinity under the carbonation process.展开更多
The temperature response calculation of thermal protection materials,especially ablative thermal protection materials,usually adopts the ablation model,which is complicated in process and requires a large amount of ca...The temperature response calculation of thermal protection materials,especially ablative thermal protection materials,usually adopts the ablation model,which is complicated in process and requires a large amount of calculation.Especially in the process of optimization calculation and parameter identification,the ablation model needs to be called many times,so it is necessary to construct an ablation surrogate model to improve the computational efficiency under the premise of ensuring the accuracy.In this paper,the Gaussian process model method is used to construct a thermal protection material ablation surrogate model,and the prediction accuracy of the surrogate model is improved through optimization.展开更多
The non-metallic lightning strike protection film covering carbon fiber reinforced polymers(NM-LSP covering CFRP)can reduce the weight and thus the fuel consumption of aircraft by replacing the traditional lightning s...The non-metallic lightning strike protection film covering carbon fiber reinforced polymers(NM-LSP covering CFRP)can reduce the weight and thus the fuel consumption of aircraft by replacing the traditional lightning strike protection(LSP)materials.In the present study,in order to study the environmental influence of utilizing NM-LSP covering CFRP in an aircraft elevator,a new elevator was designed and manufactured,replacing the aluminium net and glass fiber reinforced polymers(GFRP)with NM-LSP covering CFRP,with the same mechanical and LSP abilities.A comparative life cycle assessment was conducted between the two kinds of aircraft elevators,including material extraction,transportation,elevator manufacturing phase,service phase,and end-of-life procedures.Additionally,the environmental impacts of producing two LSP materials were compared by considering the environmental effects of different buy-to-fly ratios and recycling strategies on the production of aluminium net.The analysis indicates that the new elevator achieved reduction for all the environmental impact categories used,such as human toxicity potential and marine aquatic ecotoxicity potential(3.83%and 3.20%reduction).Furthermore,it is found that the service phase makes the greatest contribution to the environmental impact of the elevators under investigation.When recycling is excluded,NM-LSP covering CFRP is more environmentally friendly than the traditional material.At the same time,CFRP prepreg and electricity from the production of NM-LSP covering CFRP contribute to a higher environmental impact compared to the NM-LSP film.From the sensitivity analysis,it is believed that NM-LSP covering CFRP can reduce environmental impact compared with traditional LSP materials.展开更多
Green material was first put forward at the first International Conference on materials in 1988, and it is regarded as one of the target materials to be realized by human beings in the next century. With the awakening...Green material was first put forward at the first International Conference on materials in 1988, and it is regarded as one of the target materials to be realized by human beings in the next century. With the awakening of people's awareness of environmental protection and the increasing attention to the safety and health performance of materials, the choice of materials and design schemes will be more inclined to the direction of environmental protection and green in interior decoration design. People no longer simply pursue the aesthetic height of interior decoration personality and the decoration design schemes that win by stacking luxury materials are no longer popular with the public, but begin to attract more attention. The natural environmental protection, safety and health performance of materials should be considered. This article mainly analyzes the application of energy saving and environmental protection green decoration materials in building decoration construction, hoping to give you some inspiration.展开更多
A time-resolved numerical computational approach, involving the combustion of double-base propellant is performed on thermal protection material for SRM nozzle. An implicit Navier-Stokes Solver is selected to simulate...A time-resolved numerical computational approach, involving the combustion of double-base propellant is performed on thermal protection material for SRM nozzle. An implicit Navier-Stokes Solver is selected to simulate two-dimensional axial-symmetric unsteady turbulent flow of compressible fluid. The governing equations are discredited by using the finite Volume method. S-A turbulence model is employed. CFD scheme is implemented to investigate the temperature distribution causes at nozzle throat inserts composite material. Different parameters have been selected for the analysis to validate the temperature variation in the throat inserts and baking material of SRM nozzle. The advanced SRM nozzle composite material is also characterized for the high thermo stability and high thermo mechanical capabilities to make it more reliable, simpler and lighter.展开更多
At present, under the background of sustainable development, the construction industry must pay attention to energy conservation and consumption reduction in construction if it wants to achieve sustainable development...At present, under the background of sustainable development, the construction industry must pay attention to energy conservation and consumption reduction in construction if it wants to achieve sustainable development. At present, the application of energy-saving green building materials in construction projects is the main way to achieve energy conservation and consumption reduction, and is an important measure to achieve sustainable development of enterprises. This paper analyzes the application status of building green materials and discusses the influence of building materials control on the construction cost, hoping to provide reference for relevant personnel and improve the economic benefits of construction projects.展开更多
Under the call of building a green ecological society, all walks of life should actively fulfill their social responsibilities and effectively apply the concept of green energy saving to the specific production and li...Under the call of building a green ecological society, all walks of life should actively fulfill their social responsibilities and effectively apply the concept of green energy saving to the specific production and living activities. Especially for the building decoration construction of the material application, construction links, resource consumption of the industry, more from the implementation of technology application, material selection will be the energy saving concept in place. Through the application of energy-saving and environmental protection materials in building decoration construction to effectively reduce the environmental burden, reflect the responsibility of enterprises. This article is on the positive role of energy saving and environmental protection materials in building decoration construction and the specific application of a simple elaboration for reference.展开更多
Belt conveyor is a kind of important equipment for transporting coal mines, and is also a facility for connecting various processes. It plays a vital role in the supply of raw materials. At present, people have used b...Belt conveyor is a kind of important equipment for transporting coal mines, and is also a facility for connecting various processes. It plays a vital role in the supply of raw materials. At present, people have used belt conveyors in the mining, production, transportation and processing processes of coal mines. It not only has a large transportation volume, but also can be applied in complex working environments. The equipment has a strong carrying capacity and supports transportation by the Bureau of Parks and Roads. This paper gives an overview and analysis of the material blocking protection device of belt conveyor, looking for a proximity switch, combining with the problems encountered in the test, and based on the working principle of belt conveyor, puts forward effective improvement measures of the device, increasing the weight of the detection door in the transformation, and improving the use efficiency.展开更多
Various thermal protection materials exhibit obviously different and complicated thermal response,oxidation and ablation behavior,which are very important for the appropriate design and selection.However,the relative ...Various thermal protection materials exhibit obviously different and complicated thermal response,oxidation and ablation behavior,which are very important for the appropriate design and selection.However,the relative researches are very few currently.In this work,the thermal response,oxidation and ablation behavior of representative thermal protection materials including ultra-high temperature ceramics,C/SiC,C/C, graphite and graphite-ceramic were investigated systematically in strong heat flux,high enthalpy and low-pressure environments.Thermal response of these materials was analyzed based on experimental results and thermal energy balance that accounts for all of the heat transfer processes transporting energy into and out of the surface.Many factors were playing important roles in the thermal response including thermal conductivity,volumetric heat capacity,catalytic efficiency,emissivity and oxidation characteristics of the materials.The importance of each factor not only depends on the material characteristics such as material composition and phase content but also environment parameters including heat flux,enthalpy,pressure and testing time.The comparisons and relationships of oxidation and ablation behaviors for these materials under extreme environments were also illustrated in detail.Furthermore,thermal response and ablation behaviors of pre-oxidized material or repeated tests were also performed to evaluate the effect of pre-treatment on the performance and reusability of thermal protection materials.This work offers guiding significance for the appropriate design and selection of thermal protection materials.展开更多
The title compounds 1-（4,5-dihydro-3-phenyl pyridine-1-yl）-2-（1H-1,2,4-triazole-1-yl） ethyl ketones were studied as a corrosion inhibitor in a mild steel in 1 mol /L hydrochloric acid solution using weight loss me...The title compounds 1-（4,5-dihydro-3-phenyl pyridine-1-yl）-2-（1H-1,2,4-triazole-1-yl） ethyl ketones were studied as a corrosion inhibitor in a mild steel in 1 mol /L hydrochloric acid solution using weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy （EIS）. Results indicated that these compounds had excellent inhibition properties. Polarization curves indicated that the inhibitor behaved mainly as mixed-type inhibitor. The EIS results showed that the charge transfer controlled the corrosion process in the uninhibited and inhibited solutions. Adsorption of the inhibitor on the mild steel surface followed Langmuir＇s adsorption isotherm with negative value of the free energy of adsorption ΔGads^o. The thermodynamic parameters of adsorption were determined and discussed.展开更多
Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main conc...Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main concepts,research methods,important scientific problems,formation mechanism,structure characteristics and essence of aerogel.More applications are evolving as the scientific and engineering community,which becomes familiar with the unusual and exceptional physical properties of aerogels.In addition,we also discuss the huge development potential and prospect of polysaccharide aerogels as the research trend in the future.展开更多
The inhibition effects of sodium vanadate along with inorganic coolantinhibitors were examined on corrosion of AZ91D in ASTM D1384-80 corrosive water by polarizationmeasurements. The galvanic corrosion of AZ91D couple...The inhibition effects of sodium vanadate along with inorganic coolantinhibitors were examined on corrosion of AZ91D in ASTM D1384-80 corrosive water by polarizationmeasurements. The galvanic corrosion of AZ91D coupled to 3003, 6063, and 356 Al alloys were alsotested. An effective combination of inhibitors containing (but not limited to) sodium vanadate,silicate, and nitrate was proposed for inhibition of AZ91D and prevention of galvanic corrosion.展开更多
基金supported by the National Natural Science Foundation of China(Grants No.51109143 and 51209144)the Natural Science Foundation of Jiangsu Province(Grant No.BK2011109)the Foundation of Nanjing Hydraulic Research Institute(Grant No.Y113004)
文摘In this study, several kinds of flexible protective materials sprayed with polyurea elastomers （hereinafter referred to as polyurea elastomer protective material） were adopted to meet the abrasion resistance requirement of hydraulic structures, and their abrasion resistances against the water flow with suspended load or bed load were studied systematically through tests. Natural basalt stones were adopted as the abrasive for simulation of the abrasion effect of the water flow with bed load, and test results indicate that the basalt stone is suitable for use in the abrasion resistance test of the flexible protective material. The wear process of the polyurea elastomer protective material is stable, and the wear loss is linear with the time of abrasion. If the wear thickness is regarded as the abrasion resistance evaluation factor, the abrasion resistance of the 351 pure polyurea is about twice those of pure polyurea with a high level of hardness and aliphatic polyurea, and over five times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with suspended load. It is also about 50 times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with bed load. Overall, the abrasion resistance of pure polyurea presented a decreasing trend with increasing hardness. Pure polyurea with a Shore hardness of D30 has the best abrasion resistance, which is 60 to 70 times that of high-performance abrasion-resistant concrete under the abrasion of the water flow with bed load, and has been recommended, among the five kinds of pure polyurea materials with different hardness, in anti-abrasion protection of hydraulic structures.
基金supported by the National Key Research and Development Program of China(2022YFB3806501)the National Natural Science Foundation of China(22178050,22108026)+3 种基金the Young Elite Scientists Sponsorship Program by CAST(2021QNRC001)the Natural Science Foundation of Liaoning Province(2022-BS-091)the Dalian Science and Technology Innovation Fund Young Tech Star(2022RQ008)the Fundamental Research Funds for the Central Universities(DUT22LAB610).
文摘Thermal runaway(TR)is considered a significant safety hazard for lithium batteries,and thermal protection materials are crucial in mitigating this risk.However,current thermal protection materials generally suffer from poor mechanical properties,flammability,leakage,and rigid crystallization,and they struggle to continuously block excess heat transfer and propagation once thermal saturation occurs.This study proposes a novel type of thermal protection material:an aerogel coupled composite phase change material(CPCM).The composite material consists of gelatin/sodium alginate(Ge/SA)composite biomass aerogel as an insulating component and a thermally induced flexible CPCM made from thermoplastic polyester elastomer as a heat-absorbing component.Inspired by power bank,we coupled the aerogel with CPCM through the binder,so that CPCM can continue to‘charge and store energy’for the aerogel,effectively absorbing heat,delaying the heat saturation phenomenon,and maximizing the duration of thermal insulation.The results demonstrate that the Ge/SA aerogel exhibits excellent thermal insulation(with a temperature difference of approximately 120℃ across a 1 cm thickness)and flame retardancy(achieving a V-0 flame retardant rating).The CPCM exhibits high heat storage density(811.9 J g^(−1)),good thermally induced flexibility(bendable above 40℃),and thermal stability.Furthermore,the Ge/SA-CPCM coupled composite material shows even more outstanding thermal insulation performance,with the top surface temperature remaining at 89℃ after 100 min of exposure to a high temperature of 230℃.This study provides a new direction for the development of TR protection materials for lithium batteries.
基金This work was financially supported by the National Key Research and Development Program of China(2016YFA0201702 and 2016YFA0201700)the National Natural Science Foundation of China(51972056,51773036)+3 种基金Innovation Program of Shanghai Municipal Education Commission(2017-01-07-00-03-E00055)Shanghai Belt and Road Joint Laboratory of Advanced Fiber and Low-dimension Materials(18520750400)China Postdoctoral Science Foundation(2019M661323)the Fundamental Research Funds for the Central Universities.
文摘Public health events caused by viruses pose a significant risk to humans worldwide.From December 2019 till now,the rampant novel 2019 coronavirus(SAR-CoV-2)has hugely impacted China and over world.Regarding a commendable means of protection,mask technology is relatively mature,though most of the masks cannot effectively resist the viral infections.The key material of the mask is a non-woven material,which makes the barrier of virus through filtration.Due to the lack of the ability to kill the viruses,masks are prone to cross-infection and become an additional source of infection after being discarded.If the filteration and antiviral effects can be simultaneously integrated into the mask,it will be more effcient,work for a longer time and create less difficulty in post-treatment.This mini-review presents the advances in antiviral materials,different mechanisms of their activity,and their potential applications in personal protective fabrics.Furthermore,the article addresses the future challenges and directions of mask technology.
基金fnancial support by the National Natural Science Foundation of China(Grant No.42176209)the Natural Science Foundation of Shandong Province(Grant No.ZR2021MD064).
文摘Cu–Ni and Cu–Co–Ni superhydrophobic films were constructed on the surface of B10 copper–nickel alloy welded joints using a two-step process of electrodeposition and stearic acid modification.The chemical composition of the film surface was determined using surface characterization techniques.The corrosion resistance of the films was characterized using electrochemical impedance spectroscopy,potentiodynamic polarization,and scanning Kelvin probe microscopy at multiple scales.The thermal stability,mechanical stability,and self-cleaning properties of the films were also characterized.It was determined that the Cu–Co–Ni superhydrophobic film exhibited the best performance,with a static water contact angle of 159.3°,a roll-off angle of 2.3°,a charge transfer resistance 3300 times higher than the substrate,a self-corrosion current density nearly three orders of magnitude lower,and a surface Kelvin potential increase of 420 mV.The film demonstrated good thermal stability,excellent mechanical stability,and outstanding self-cleaning properties.Combining with previous studies,it was found that Co elements in the film contribute to the formation of a uniform and dense film,Ni elements enhance the adhesion and corrosion resistance between the films,and the combination of Co and Ni elements promotes uniform surface potential and further improves the corrosion resistance and interfilm adhesion of the films.
基金support from the Natural Science Foundation of China(91016029,91216302,and 91216301)
文摘The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical ＆ Applied Mechanics Letters （TAML） and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.
基金Funded by the National Sci-Tech Support Plan of China(No.2013BAJ10B05)Marine Interdisciplinary Research Guide Fund of Zhejiang University(No.2012HY003B)
文摘Effect of isobutyl-triethoxy-silane penetrative protective agent on the carbonation resistance of the concrete was studied.The concrete specimens for the 28 d accelerated carbonation process were manufactured with w/c of 0.49 and 0.64,both in the presence and absence of silane and mineral admixture.The penetration of isobutyl-triethoxy-silane and the carbonation of concrete were investigated by penetration depth,carbonation depth,XRD,SEM,and pore size distribution.The results showed that concrete compactness played an important role in the silane penetration and carbonation resistance.Penetration depth of silane-treated concrete mainly depended on the compactness of the concrete,and could not remarkably change through the accelerated carbonation process.In the accelerated carbonation process,penetrative protective agent improved the carbonation resistance of the higher compactness concretes but accelerated the carbonization process of the lower compactness concretes.As penetrative protective agent penetrated along the external connectivity pores into concrete not filling the entire surface area,the inorganic film could not fully protect the Ca（OH）_2 phase from carbonation.After 28 d accelerated carbonation,fibrous hydration products disappeared and the surface holes decreased.Due to the formation of carbonized products,the porosity of the concrete surface decreased,especially in high-strength concrete.
文摘NATO standards"AEP-2920 Procedures for the Evaluation and Classification of Personal Armor"and NIJ Standard-0101.06,indicate the method to statistically assess the resistance of personal ballistic protection materials.To be validated and accepted through these procedures,a personal ballistic protection material should withstand an impact of a specific projectile with a probability of a partial penetration confidence level higher than 90%.The present study introduces an energy equilibrium method to assess the confidence level for the probability of partial penetration of ductile and brittle materials.The experiments performed in the Ballistics laboratory of the Royal Military Academy in Belgium,use a modified pendulum method that allowed the quantification of the energy balance before and after the ballistic impact.The results were then compared with the ones obtained using the method specified by the NATO standard and NIJ 0101.06,mentioned above.The outcome of this comparison shows the tendency of the values obtained by the pendulum method to faithfully follow the values obtained according to NATO and NIJ specifications.The presented method is not based on statistical estimations,but instead,an exact method,of computing the energy absorbed by the tested material.This is an advantage for the cases when the material to be evaluated is expensive or it is in the development phase and mass production is not possible.
文摘Multi-phase flow effect generated from the combustion of aluminum based composite propellant was performed on the thermal protection material of solid rocket motor(SRM) nozzle.Injection of alumina(Al2O3) particles from 5% to 10% was tried on SRM nozzle flow field to see the influence of multiphase flow on heat transfer computations.A coupled,time resolved CFD(computational fluid dynamics) approach was adopted to solve the conjugate problem of multi-phase fluid flow and heat transfer in the solid rocket motor nozzle.The governing equations are discretized by using the finite volume method.Spalart-Allmaras(S-A) turbulence model was employed.The computation was executed on the different models selected for the analysis to validate the temperature variation in the throat inserts and baking material of SRM nozzle.Comparison for temperatures variations were also carried out at different expansion ratios of nozzle.This paper also characterized the advanced SRM nozzle composites material for their high thermo stability and their high thermo mechanical capabilities to make it more reliable simpler and lighter.
基金Funded by the National Natural Science Foundation of China (Nos.51808188, 52178202, 52108206)the Fundamental Research Funds for the Central Universities (No.B210201041)。
文摘Hybrid nanoSiO_(2) (HNS) modified cement pastes were explored as a kind of surface protection material (SPM).The carbonation resistance and mechanical properties of SPMs coated samples were tested.Thermogravimetric analysis (TGA),X-ray diffraction (XRD),scanning electron microscope (SEM),and mercury intrusion porosimetry (MIP) were further employed to evaluate the chemical composition and microstructure characteristics of SPM.Besides,thermodynamic modeling was adopted to simulate the changes in the phase assemblages of SPM under the carbonation process.The results showed that SPM with 1 wt% HNS could effectively enhance the carbonation resistance.The incorporation of HNS could densify the microstructure and refine the pore structure.Moreover,the thaumasite can be stable at ambient temperature with the addition of HNS,which is beneficial to maintain alkalinity under the carbonation process.
基金supported by Independent Research and Development Project of CASC(YF-ZZYF-2022-132)。
文摘The temperature response calculation of thermal protection materials,especially ablative thermal protection materials,usually adopts the ablation model,which is complicated in process and requires a large amount of calculation.Especially in the process of optimization calculation and parameter identification,the ablation model needs to be called many times,so it is necessary to construct an ablation surrogate model to improve the computational efficiency under the premise of ensuring the accuracy.In this paper,the Gaussian process model method is used to construct a thermal protection material ablation surrogate model,and the prediction accuracy of the surrogate model is improved through optimization.
基金supported by the National Key Research and Development Program of China(No.2017YFC0703007)the Chinese MIIT Special Research Plan on Civil Aircraft(No.MJ-2015-H-G-103)+1 种基金the National Natural Science Foundation of China(No.52008137)the China Postdoctoral Science Foundation(Nos.2019TQ0079 and 2019M661288)。
文摘The non-metallic lightning strike protection film covering carbon fiber reinforced polymers(NM-LSP covering CFRP)can reduce the weight and thus the fuel consumption of aircraft by replacing the traditional lightning strike protection(LSP)materials.In the present study,in order to study the environmental influence of utilizing NM-LSP covering CFRP in an aircraft elevator,a new elevator was designed and manufactured,replacing the aluminium net and glass fiber reinforced polymers(GFRP)with NM-LSP covering CFRP,with the same mechanical and LSP abilities.A comparative life cycle assessment was conducted between the two kinds of aircraft elevators,including material extraction,transportation,elevator manufacturing phase,service phase,and end-of-life procedures.Additionally,the environmental impacts of producing two LSP materials were compared by considering the environmental effects of different buy-to-fly ratios and recycling strategies on the production of aluminium net.The analysis indicates that the new elevator achieved reduction for all the environmental impact categories used,such as human toxicity potential and marine aquatic ecotoxicity potential(3.83%and 3.20%reduction).Furthermore,it is found that the service phase makes the greatest contribution to the environmental impact of the elevators under investigation.When recycling is excluded,NM-LSP covering CFRP is more environmentally friendly than the traditional material.At the same time,CFRP prepreg and electricity from the production of NM-LSP covering CFRP contribute to a higher environmental impact compared to the NM-LSP film.From the sensitivity analysis,it is believed that NM-LSP covering CFRP can reduce environmental impact compared with traditional LSP materials.
文摘Green material was first put forward at the first International Conference on materials in 1988, and it is regarded as one of the target materials to be realized by human beings in the next century. With the awakening of people's awareness of environmental protection and the increasing attention to the safety and health performance of materials, the choice of materials and design schemes will be more inclined to the direction of environmental protection and green in interior decoration design. People no longer simply pursue the aesthetic height of interior decoration personality and the decoration design schemes that win by stacking luxury materials are no longer popular with the public, but begin to attract more attention. The natural environmental protection, safety and health performance of materials should be considered. This article mainly analyzes the application of energy saving and environmental protection green decoration materials in building decoration construction, hoping to give you some inspiration.
文摘A time-resolved numerical computational approach, involving the combustion of double-base propellant is performed on thermal protection material for SRM nozzle. An implicit Navier-Stokes Solver is selected to simulate two-dimensional axial-symmetric unsteady turbulent flow of compressible fluid. The governing equations are discredited by using the finite Volume method. S-A turbulence model is employed. CFD scheme is implemented to investigate the temperature distribution causes at nozzle throat inserts composite material. Different parameters have been selected for the analysis to validate the temperature variation in the throat inserts and baking material of SRM nozzle. The advanced SRM nozzle composite material is also characterized for the high thermo stability and high thermo mechanical capabilities to make it more reliable, simpler and lighter.
文摘At present, under the background of sustainable development, the construction industry must pay attention to energy conservation and consumption reduction in construction if it wants to achieve sustainable development. At present, the application of energy-saving green building materials in construction projects is the main way to achieve energy conservation and consumption reduction, and is an important measure to achieve sustainable development of enterprises. This paper analyzes the application status of building green materials and discusses the influence of building materials control on the construction cost, hoping to provide reference for relevant personnel and improve the economic benefits of construction projects.
文摘Under the call of building a green ecological society, all walks of life should actively fulfill their social responsibilities and effectively apply the concept of green energy saving to the specific production and living activities. Especially for the building decoration construction of the material application, construction links, resource consumption of the industry, more from the implementation of technology application, material selection will be the energy saving concept in place. Through the application of energy-saving and environmental protection materials in building decoration construction to effectively reduce the environmental burden, reflect the responsibility of enterprises. This article is on the positive role of energy saving and environmental protection materials in building decoration construction and the specific application of a simple elaboration for reference.
文摘Belt conveyor is a kind of important equipment for transporting coal mines, and is also a facility for connecting various processes. It plays a vital role in the supply of raw materials. At present, people have used belt conveyors in the mining, production, transportation and processing processes of coal mines. It not only has a large transportation volume, but also can be applied in complex working environments. The equipment has a strong carrying capacity and supports transportation by the Bureau of Parks and Roads. This paper gives an overview and analysis of the material blocking protection device of belt conveyor, looking for a proximity switch, combining with the problems encountered in the test, and based on the working principle of belt conveyor, puts forward effective improvement measures of the device, increasing the weight of the detection door in the transformation, and improving the use efficiency.
基金supported by Key Program of National Natural Science Foundation of China (No. 52032003)National Natural Science for Youth Foundation of China (No. 52102093)+2 种基金National Natural Science Foundation of China (No. 51872059),National Natural Science Foundation of China (No. 51772061)China Postdoctoral Science Foundation (No. 2021M690817)Heilongjiang Provincial Postdoctoral Science Foundation (No. LBH-Z20144)。
文摘Various thermal protection materials exhibit obviously different and complicated thermal response,oxidation and ablation behavior,which are very important for the appropriate design and selection.However,the relative researches are very few currently.In this work,the thermal response,oxidation and ablation behavior of representative thermal protection materials including ultra-high temperature ceramics,C/SiC,C/C, graphite and graphite-ceramic were investigated systematically in strong heat flux,high enthalpy and low-pressure environments.Thermal response of these materials was analyzed based on experimental results and thermal energy balance that accounts for all of the heat transfer processes transporting energy into and out of the surface.Many factors were playing important roles in the thermal response including thermal conductivity,volumetric heat capacity,catalytic efficiency,emissivity and oxidation characteristics of the materials.The importance of each factor not only depends on the material characteristics such as material composition and phase content but also environment parameters including heat flux,enthalpy,pressure and testing time.The comparisons and relationships of oxidation and ablation behaviors for these materials under extreme environments were also illustrated in detail.Furthermore,thermal response and ablation behaviors of pre-oxidized material or repeated tests were also performed to evaluate the effect of pre-treatment on the performance and reusability of thermal protection materials.This work offers guiding significance for the appropriate design and selection of thermal protection materials.
基金the financial of the Knowledge Innovation Program of the Chinese Academy of Sciences as a major guiding project(KZCX2-YW-210)as well as "Eleventh Five-Year" National Scientific and Technological Support Project(2007BAB27B00)
文摘The title compounds 1-（4,5-dihydro-3-phenyl pyridine-1-yl）-2-（1H-1,2,4-triazole-1-yl） ethyl ketones were studied as a corrosion inhibitor in a mild steel in 1 mol /L hydrochloric acid solution using weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy （EIS）. Results indicated that these compounds had excellent inhibition properties. Polarization curves indicated that the inhibitor behaved mainly as mixed-type inhibitor. The EIS results showed that the charge transfer controlled the corrosion process in the uninhibited and inhibited solutions. Adsorption of the inhibitor on the mild steel surface followed Langmuir＇s adsorption isotherm with negative value of the free energy of adsorption ΔGads^o. The thermodynamic parameters of adsorption were determined and discussed.
基金supported by the National Natural Science Foundation of China(31471704 and 31271837)Major Project of the Department of Science and Technology of Fujian Province(2013N5003)
文摘Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main concepts,research methods,important scientific problems,formation mechanism,structure characteristics and essence of aerogel.More applications are evolving as the scientific and engineering community,which becomes familiar with the unusual and exceptional physical properties of aerogels.In addition,we also discuss the huge development potential and prospect of polysaccharide aerogels as the research trend in the future.
基金This work was financially supported by the National Natural Science Foundation of China (No. 50122118)
文摘The inhibition effects of sodium vanadate along with inorganic coolantinhibitors were examined on corrosion of AZ91D in ASTM D1384-80 corrosive water by polarizationmeasurements. The galvanic corrosion of AZ91D coupled to 3003, 6063, and 356 Al alloys were alsotested. An effective combination of inhibitors containing (but not limited to) sodium vanadate,silicate, and nitrate was proposed for inhibition of AZ91D and prevention of galvanic corrosion.
