Chinese medicinal materials are the material basis for the inheritance and development of traditional Chinese medicine.Intellectual property protection for the entire industrial chain of traditional Chinese medicinal ...Chinese medicinal materials are the material basis for the inheritance and development of traditional Chinese medicine.Intellectual property protection for the entire industrial chain of traditional Chinese medicinal materials promotes the inheritance and innovation of traditional Chinese medicine,and contributes to rural revitalization and the building of an agricultural power.This article provides an overview of the traditional Chinese medicinal materials in Hubei Province.It conducts a detailed investigation into the intellectual property resources of the province s traditional Chinese medicinal materials from aspects such as traditional knowledge,genetic resources,new plant varieties,patents,geographical indications,and trademarks.It analyzes the eight main problems in the protection,inheritance,and innovative development of intellectual property rights,and puts forward corresponding suggestions,such as establishing an intellectual property rights rule system for specific fields of traditional Chinese medicinal materials,promoting the"Famous Brand Action in Rural Areas",and building a"Hubei s Sixteen Superior Herbs"cluster of traditional Chinese medicinal materials.展开更多
I.INTRODUCTION Against the backdrop of profound transformations in the global energy landscape,China,as the world's largest energy producer and consumer,faces multiple challenges,including energy security,energy t...I.INTRODUCTION Against the backdrop of profound transformations in the global energy landscape,China,as the world's largest energy producer and consumer,faces multiple challenges,including energy security,energy transition,and sustainable development.To address these challenges,the Chinese government has formulated a strategic plan to build a unified national energy market and create a new framework for the energy sector.Article 42 of the Energy Law of the People's Republic of China(hereinafter referred to as the Energy Law)explicitly requires the building of a unified national energy trading market and the improvement of transaction mechanisms and rules.展开更多
Friction stir lap welding of AA2195 Al-Li alloy and Ti alloy was conducted to investigate the formation,microstructure,and mechanical properties of the joints.Results show that under different welding parameters,with ...Friction stir lap welding of AA2195 Al-Li alloy and Ti alloy was conducted to investigate the formation,microstructure,and mechanical properties of the joints.Results show that under different welding parameters,with the decrease in welding heat input,the weld surface is smoother.The Ti/Al joint interface is flat without obvious Ti and Al mixed structure,and the hook structure is not formed under optimal parameters.Due to the enhanced breaking effect of the stirring head,the hook structural defects and intermetallic compounds are more likely to form at the Ti/Al interface at high rotational speed of 1000 r/min,thereby deteriorating the mechanical properties of joints.Decreasing the heat input is beneficial to hardness enhancement of the aluminum alloy in the weld nugget zone.Under the optimal parameters of rotation speed of 800 r/min and welding speed of 120 mm/min,the maximum tensile shear strength of joint is 289 N/mm.展开更多
In this paper,the property degradation micromechanism of Al-5.10Cu-0.65 Mg-0.8Mn(wt%)alloy induced by 0.5 wt%Fe minor addition was revealed by atomic-scale scanning transmission electron microscopy and energy-dispersi...In this paper,the property degradation micromechanism of Al-5.10Cu-0.65 Mg-0.8Mn(wt%)alloy induced by 0.5 wt%Fe minor addition was revealed by atomic-scale scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy coupled with first-principles calculations.The results show that the Fe minor addition to the Al-Cu-Mg-Mn alloy leads to a slight reduction of grain size and the formation of coarse Al7Cu2Fe constituent particles.Fe tends to segregate into the T-phase dispersoids,θ'-,and S-phase precipitates by preferentially occupying Cu or Mn sites in these phase structures.The apparent Fe segregation contributes to an increase in stiffness of the T-phase and S-phase but decreased stiffness of theθ'phase.Formation of the coarse Al7Cu2Fe constituent particles and decreased stiffness of main precipitatesθ'containing Fe result in the degraded strength of the Al-Cu-Mg-Mn-Fe alloy.Further study reveals that corrosion resistance degradation of the Al-Cu-Mg-Mn-Fe alloy is associated with the increased width of precipitation free zones and consecutive grain boundary precipitates.The obtained results have significant implications for the usage of recycled Al alloys and the potential design strategies of high-performance alloys containing Fe.展开更多
Wigner-Ville distribution(WVD)is widely used in the field of signal processing due to its excellent time-frequency(TF)concentration.However,WVD is severely limited by the cross-term when working with multicomponent si...Wigner-Ville distribution(WVD)is widely used in the field of signal processing due to its excellent time-frequency(TF)concentration.However,WVD is severely limited by the cross-term when working with multicomponent signals.In this paper,we analyze the property differences between auto-term and cross-term in the one-dimensional sequence and the two-dimensional plane and approximate entropy and Rényi entropy are employed to describe them,respectively.Based on this information,we propose a new method to achieve adaptive cross-term removal by combining seeded region growing.Compared to other methods,the new method can achieve cross-term removal without decreasing the TF concentration of the auto-term.Simulation and experimental data processing results show that the method is adaptive and is not constrained by the type or distribution of signals.And it performs well in low signal-to-noise ratio environments.展开更多
Accurate prediction of molecular properties is crucial for selecting compounds with ideal properties and reducing the costs and risks of trials.Traditional methods based on manually crafted features and graph-based me...Accurate prediction of molecular properties is crucial for selecting compounds with ideal properties and reducing the costs and risks of trials.Traditional methods based on manually crafted features and graph-based methods have shown promising results in molecular property prediction.However,traditional methods rely on expert knowledge and often fail to capture the complex structures and interactions within molecules.Similarly,graph-based methods typically overlook the chemical structure and function hidden in molecular motifs and struggle to effectively integrate global and local molecular information.To address these limitations,we propose a novel fingerprint-enhanced hierarchical graph neural network(FH-GNN)for molecular property prediction that simultaneously learns information from hierarchical molecular graphs and fingerprints.The FH-GNN captures diverse hierarchical chemical information by applying directed message-passing neural networks(D-MPNN)on a hierarchical molecular graph that integrates atomic-level,motif-level,and graph-level information along with their relationships.Addi-tionally,we used an adaptive attention mechanism to balance the importance of hierarchical graphs and fingerprint features,creating a comprehensive molecular embedding that integrated hierarchical mo-lecular structures with domain knowledge.Experiments on eight benchmark datasets from MoleculeNet showed that FH-GNN outperformed the baseline models in both classification and regression tasks for molecular property prediction,validating its capability to comprehensively capture molecular informa-tion.By integrating molecular structure and chemical knowledge,FH-GNN provides a powerful tool for the accurate prediction of molecular properties and aids in the discovery of potential drug candidates.展开更多
The property IR was introduced by Friis and Rordam in 1996.They proved that any pair of almost commuting self-adjoint elements is norm close to a pair of exactly commuting self-adjoint elements in any C^(*)-algebras w...The property IR was introduced by Friis and Rordam in 1996.They proved that any pair of almost commuting self-adjoint elements is norm close to a pair of exactly commuting self-adjoint elements in any C^(*)-algebras with the property IR.In this paper,we will prove some permanence results for IR-algebras,approximate IR-algebras and local IR-algebras.Finally,we will also show that any pair of almost commuting self-adjoint elements is norm close to a pair of exactly commuting self-adjoint elements in any local IR-algebra.展开更多
Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic...Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.展开更多
With the rapid development of globalization and information technology,intellectual property has been one of the key drivers of economic growth,and the construction of intellectual property system has become an import...With the rapid development of globalization and information technology,intellectual property has been one of the key drivers of economic growth,and the construction of intellectual property system has become an important criterion for measuring the quality of business environment.This article is intended to explore the current status of intellectual property system construction in China,the challenges,and its relationship with the business environment,to propose the corresponding countermeasures and suggestions.The study finds that the legal system of intellectual property in China is gradually improving,and judicial and administrative protection are continuously strengthened.However,the challenges still remain such as frequent infringements,rights hard to protect and insufficient international cooperation.These issues not only affect the legitimate rights and interests of innovation entities,but also for the market fairness and the level of the business environment.Therefore,this article proposes that strengthening the perfection of the intellectual property legal system,enhancing intellectual property services and support capabilities,strengthening international cooperation and exchanges,and accelerating the cultivation of composite talents.It aims to provide theoretical references for the construction of intellectual property system and the optimization of the business environment,promote the high-quality development of economy and enhance the global competitiveness of the country.展开更多
This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materi...This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.展开更多
A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,el...A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,elemental analysis,IR,and magnetic properties.X-ray diffraction analysis shows that the complex exists as mononuclear molecules and Co(Ⅱ)ion is four-coordinated with two radicals and two PNB-ligands.The magnetic susceptibility study indicates the complex exhibits weak ferromagnetic interactions between cobalt(Ⅱ)and im4-py radical.The magnetic property is explained by the magnetic and structure exchange mechanism.CCDC:976028.展开更多
This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based ...This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based on the dictionary D.We establish that matrices adhering to the block D-NSP_(q)condition are both necessary and sufficient for the exact recovery of block sparse signals via l_(2)/l_(q)-synthesis.Additionally,this condition is essential for the stable recovery of signals that are block-compressible with respect to D.This D-NSP_(q)property is identified as the first complete condition for successful signal recovery using l_(2)/l_(q)-synthesis.Furthermore,we assess the theoretical efficacy of the l2/lq-synthesis method under conditions of measurement noise.展开更多
Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2...Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2)O_(3) ceramics have been fabricated at very high sintering temperatures,but their optical quality and sintering process still need further improvement.In this work,5%Yb:Sc_(2)O_(3)(in mass)nano-powders were obtained by co-precipitation,and then transparent ceramics were fabricated by vacuum pre-sintering and hot isostatic pressing(HIP)post-treatment.The cubic Yb:Sc_(2)O_(3) nano-powders with good dispersity and an average crystallite of 29 nm were obtained.Influence of pre-sintering temperatures(1500-1700℃)on densification process,microstructure changes,and optical transmittance of Yb:Sc_(2)O_(3) ceramics was detected.Experimental data revealed that all samples have a uniform microstructure,while the average grain sizes increase with the increase of the sintering temperatures.Impressively,the optimum in-line transmittance of Yb:Sc_(2)O_(3) ceramics,pre-sintered at 1550℃after HIP post-treatment,reaches 78.1%(theoretical value of 80%)at 1100 nm.Spectroscopic properties of the Yb:Sc_(2)O_(3) ceramics reveal that the minimum population inversion parameterβ2 and the luminescence decay time of 5%Yb:Sc_(2)O_(3) ceramics are 0.041 and 0.49 ms,respectively,which demonstrate that the optical quality of the Yb:Sc_(2)O_(3) has been improved.Meanwhile,their best vacuum sintering temperature can be controlled down to a lower temperature(1550℃).In conclusion,Yb:Sc_(2)O_(3) nano-powders are successfully synthesized by co-precipitation method,and good optical quality transparent ceramics are fabricated by vacuum pre-sintering at 1550℃and HIP post-treatment.展开更多
A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear r...A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear resistance,and many other critical properties.However,at present a comprehensive and robust map correlating different properties in particle-reinforced composites is much lacking.In this work,an industrial grade AZ91 magnesium alloy reinforced with hard SiC and soft fly ash particles(with 3 vol.%each),has been prepared using stir casting followed by hot extrusion at 325℃with a ratio of 21.5.Microstructure of the hybrid composite was characterized using optical and scanning electron microscopes.The composite exhibited a reduction in average grain size from 13.6 to 7.1μm,concomitantly an increase in Vickers hardness from 73 to 111 HV.The tension-compression yield asymmetry ratios of the unreinforced alloy and hybrid composite were 1.165 and 0.976,respectively indicating higher yield strength for the composite under compressive load.The composite exhibited 76%improvement in damping capacity under time sweep mode,and 28%improvement at 423 K under temperature sweep mode.The tribological characteristics of the composite under dry sliding conditions at sliding speeds and loads in the range of 0.5 to 1.5 m s^(-1)and 10 to 30 N,respectively showed higher wear resistance than the unreinforced alloy.The composite showed 23%improvement in sliding wear resistance at a load of 20 N and a speed of 1 m s^(-1).Finally,efforts have been made to understand the influence of one property on the other by developing statistical property correlation maps from the properties obtained in this study and from the literature.These maps are expected to help in the design of hybrid Metal Matrix Composites for a variety of targeted applications in different sectors.展开更多
“Some foreign scholars have proposed that the new institutional economics can unify the social sciences.”Behind the institution is property,and the dual cognition of property is the obstacle.Property dualism comes f...“Some foreign scholars have proposed that the new institutional economics can unify the social sciences.”Behind the institution is property,and the dual cognition of property is the obstacle.Property dualism comes from the thought dualism in the western rationalism tradition.The transcendence of“property dualism”has experienced the stages of“labor value”and“reasonable value”,and the new era has ushered in the opportunity of the third transcendence.In the first two stages,“abundance”and“scarcity”are the root causes of the contradiction in the transcendence of property dualism.Marx’s basic property view of production relations(property relations)unifies the property views of Locke,Hume,and Commons.The three-dimensional property system model developed on the basis of Marx’s complex property view provides a theoretical tool for the third transcendence of property dualism.We have cracked the western rationalism dualism with Marx’s historical materialism and reconciled the property dualism with three-dimensional property system model.By this,we can continue to explore the potential of“institution unifying social sciences”.展开更多
Within the context of building a community for the Chinese nation,fine traditional Chinese culture has emerged as a core competitiveness in advancing the Chinese path to modernization.However,the current absence of a ...Within the context of building a community for the Chinese nation,fine traditional Chinese culture has emerged as a core competitiveness in advancing the Chinese path to modernization.However,the current absence of a benefit-sharing mechanism for this culture,and its systemic incompatibility with the Western-dominated intellectual property system,are detrimental to building a community for the Chinese nation.Exploration reveals that,based on the Marxist labor theory of value,fine traditional Chinese culture can be justified as property;and based on Locke's labor theory of property,it should be accorded property rights.Thus,fine traditional Chinese culture can be included as the subject matter of property rights.Protecting fine traditional Chinese culture aligns with the original purpose of the intellectual property(IP)system,which should not be confined to safeguarding"knowledge innovation"but should also emphasize"knowledge transmission."Expanding the IP system to protect fine traditional Chinese culture is conducive to China's engagement in the global intellectual property landscape.A new form of intellectual property—traditional cultural property rights—should therefore be created.Traditional cultural property rights refer to the direct and exclusive rights held by rights holders,defined as the communities in specific regions,over specific traditional cultural expressions according to law.The protectable subject matter would encompass cultural traditions characterized by their intergenerational continuity,communal identity,and intrinsic value.The scope of these rights would include control over use,authorization of use,and the right to benefit from such use.The construction of a protection system for traditional cultural property rights should establish the principles of perpetual protection,collective protection,and regional protection.展开更多
Creep is one of the most typical failure modes for the turbine blades of an aero-engine.The microstructure of the turbine blades after long-term service can be adjusted by rejuvenation heat treatment(RHT)to restore it...Creep is one of the most typical failure modes for the turbine blades of an aero-engine.The microstructure of the turbine blades after long-term service can be adjusted by rejuvenation heat treatment(RHT)to restore its creep properties.In this work,a series of RHT experiments were carried out on a directionally solidified(DS)nickel-based superalloy under different solution temperatures and primary aging temperatures based on the standard heat treatment(SHT)process parameters to investigate the mechanism of temperature influence on DS's microstructure after RHT.It is indicated that a more uniform microstructure can be obtained under higher solution temperatures and lower primary aging temperatures compared to the SHT process.Furthermore,by employing the image processing methods to quantify microstructural parameters,a comprehensive indicator parameter for the RHT effect(marked as Prej)was proposed to characterize the effects of RHT on DS superalloy's microstructure and creep property combined with the entropy weight method.Based on this,a regression model to describe the relationship between RHT process parameters and Prej was constructed by using the response surface methodology(RSM).It is revealed that the optimal solution temperature and primary aging temperature for this DS superalloy are 1283°C and 1095°C,respectively.Then the conclusion was validated through complete creep experiments on the DS superalloy,which showed the creep life after RHT reaches 95.5%of the SHT specimen,and the total life has increased by 20.6%.展开更多
Multifunctional semiconductors play an important role in developing advanced photoelectric technologies.In this work,based on an octahedral replacement strategy in chalcogenides,a new selenide semiconductor NaMn_(3)Ga...Multifunctional semiconductors play an important role in developing advanced photoelectric technologies.In this work,based on an octahedral replacement strategy in chalcogenides,a new selenide semiconductor NaMn_(3)Ga_(3)Se_(8)was rationally designed,and synthesized by the flux method.The compound crystallizes in the noncentrosymmetric(NCS)P_(6)space group,and is composed of unique prismatic[NaSe_(6)],octahedral[MnSe_(6)]and tetrahedral[GaSe_(4)]motifs,inheriting the stable three-dimensional framework built by the octahedral and tetrahedral units in the A^(Ⅰ)Mg_(3)^(Ⅱ)C_(3)^(Ⅲ)Q_(8)^(Ⅵ)family.NaMn_(3)Ga_(3)Se_(8)shows the largest known secondary nonlinear optical(NLO)response of~2.1×AgGaS_(2)(AGS)in the A^(Ⅰ)Mg_(3)^(Ⅱ)C_(3)^(Ⅲ)Q_(8)^(Ⅵ)family,and a high laser-induced damage threshold of~3.0×AGS.Meanwhile,the introduction of Mn2t with unpaired 3d electrons induces a strong red emission band(685–805 nm)under the excitation source of 496 nm,as well as a paramagnetic to antiferromagnetic(AFM)transition at 7.3 K.The results confirm that NaMn_(3)Ga_(3)Se_(8)possesses multifunctional features including significant NLO response,fluorescence emission and AFM properties,and illustrate that replacing octahedral units with approaching size and geometry(like[MgSe_(6)]and[MnSe_(6)])could be a feasible way to develop multifunctional chalcogenides.展开更多
NiTi alloy has been widely used as orthopedic implant materials due to its unique shape memory properties and superelasticity.However,implantation failure often occurs because of the poor antibacterial ability,antioxi...NiTi alloy has been widely used as orthopedic implant materials due to its unique shape memory properties and superelasticity.However,implantation failure often occurs because of the poor antibacterial ability,antioxidation property and corrosion resistance of the NiTi alloy.In order to overcome the above problems,we constructed Zn/polydopamine(PDA)/Chitosan-Catechol(CS-C)composite coating on the surface of NiTi alloy in this paper.The surface morphology and wettability of the coating were characterized by scanning electron microscopy(SEM)and optical contact angle measuring instrument,respectively.The results showed that the Zn/CS-C coating was successfully prepared,and exhibited good hydrophilic property,especially the sample Zn/PDA/CS-C-24 h.In addition,the corrosion resistance,antioxidation property and biological properties of the coating were systematically analyzed.The results indicated that the Zn/PDA/CS-C composite coating exhibited good corrosion resistance and antibacterial property,antioxidant property and osteogenic activity,especially sample Zn/PDA/CS-C-24 h.The sample Zn/PDA/CS-C-24 h could effectively protect osteoblasts from reactive oxygen species(ROS)damage and promote cell proliferation and osteoblast differentiation.This study provides a feasible and effective strategy for the surface modification of orthopedic implant.展开更多
Conventional natural rubber(NR)fillers pose several environmental concerns.This study presents the sustain-able development of NR composites incorporating sugarcane leaf(SCL)-derived alkali lignin and commercial alkal...Conventional natural rubber(NR)fillers pose several environmental concerns.This study presents the sustain-able development of NR composites incorporating sugarcane leaf(SCL)-derived alkali lignin and commercial alkali lignin as functional fillers.The primary objective was to evaluate the mechanical properties,aging resistance,thermal stability,and antimicrobial activity of the NR composites.Various NR composites were prepared by different filler types,including KOH-extracted SCL lignin,commercial alkali lignin,and butylated hydroxytoluene(BHT).The results show that NR composites containing KOH-extracted SCL lignin exhibited superior mechanical properties(crosslink density 126 mol/m^(3)),improved aging resistance(aging coefficient 80.08%),and enhanced thermal stability(the thermal degradation with 50%weight loss(T50)and the highest degradation rate occurs(Td)of 394 and 383℃,respectively)compared to all other samples.NR composites with commercial lignin demonstrated the highest reduction in Staphylococcus aureus populations(56.25%).The NR composites with KOH-extracted SCL lignin displayed limited antimicrobial efficacy(37.78%),suggesting that its primary contribution lies in mechanical and thermal reinforcement rather than microbial inhibition.These findings highlight the potential of eco-friendly lignin from SCL biomass as a sustainable bio-based filler for NR composites.展开更多
基金Supported by the Project of National Social Science Fund of China(22CMZ015).
文摘Chinese medicinal materials are the material basis for the inheritance and development of traditional Chinese medicine.Intellectual property protection for the entire industrial chain of traditional Chinese medicinal materials promotes the inheritance and innovation of traditional Chinese medicine,and contributes to rural revitalization and the building of an agricultural power.This article provides an overview of the traditional Chinese medicinal materials in Hubei Province.It conducts a detailed investigation into the intellectual property resources of the province s traditional Chinese medicinal materials from aspects such as traditional knowledge,genetic resources,new plant varieties,patents,geographical indications,and trademarks.It analyzes the eight main problems in the protection,inheritance,and innovative development of intellectual property rights,and puts forward corresponding suggestions,such as establishing an intellectual property rights rule system for specific fields of traditional Chinese medicinal materials,promoting the"Famous Brand Action in Rural Areas",and building a"Hubei s Sixteen Superior Herbs"cluster of traditional Chinese medicinal materials.
基金research result of the Chongqing Social Science Fund Project,entitled Legal Pathways for the Governance Optimization of Financial Holding Companies(No.21SKJD036).
文摘I.INTRODUCTION Against the backdrop of profound transformations in the global energy landscape,China,as the world's largest energy producer and consumer,faces multiple challenges,including energy security,energy transition,and sustainable development.To address these challenges,the Chinese government has formulated a strategic plan to build a unified national energy market and create a new framework for the energy sector.Article 42 of the Energy Law of the People's Republic of China(hereinafter referred to as the Energy Law)explicitly requires the building of a unified national energy trading market and the improvement of transaction mechanisms and rules.
基金National Natural Science Foundation of China(52275349)Key Research and Development Program of Shandong Province(2021ZLGX01)。
文摘Friction stir lap welding of AA2195 Al-Li alloy and Ti alloy was conducted to investigate the formation,microstructure,and mechanical properties of the joints.Results show that under different welding parameters,with the decrease in welding heat input,the weld surface is smoother.The Ti/Al joint interface is flat without obvious Ti and Al mixed structure,and the hook structure is not formed under optimal parameters.Due to the enhanced breaking effect of the stirring head,the hook structural defects and intermetallic compounds are more likely to form at the Ti/Al interface at high rotational speed of 1000 r/min,thereby deteriorating the mechanical properties of joints.Decreasing the heat input is beneficial to hardness enhancement of the aluminum alloy in the weld nugget zone.Under the optimal parameters of rotation speed of 800 r/min and welding speed of 120 mm/min,the maximum tensile shear strength of joint is 289 N/mm.
基金supported by the National Natural Science Foundation of China(Nos.U20A20274 and 52061003)the Natural Science Foundation of Yunnan Province(No.202301AT070209)the Science and Technology Major Project of Yunnan Province(No.202102AG050017).
文摘In this paper,the property degradation micromechanism of Al-5.10Cu-0.65 Mg-0.8Mn(wt%)alloy induced by 0.5 wt%Fe minor addition was revealed by atomic-scale scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy coupled with first-principles calculations.The results show that the Fe minor addition to the Al-Cu-Mg-Mn alloy leads to a slight reduction of grain size and the formation of coarse Al7Cu2Fe constituent particles.Fe tends to segregate into the T-phase dispersoids,θ'-,and S-phase precipitates by preferentially occupying Cu or Mn sites in these phase structures.The apparent Fe segregation contributes to an increase in stiffness of the T-phase and S-phase but decreased stiffness of theθ'phase.Formation of the coarse Al7Cu2Fe constituent particles and decreased stiffness of main precipitatesθ'containing Fe result in the degraded strength of the Al-Cu-Mg-Mn-Fe alloy.Further study reveals that corrosion resistance degradation of the Al-Cu-Mg-Mn-Fe alloy is associated with the increased width of precipitation free zones and consecutive grain boundary precipitates.The obtained results have significant implications for the usage of recycled Al alloys and the potential design strategies of high-performance alloys containing Fe.
基金Supported by the National Natural Science Foundation of China(62201171).
文摘Wigner-Ville distribution(WVD)is widely used in the field of signal processing due to its excellent time-frequency(TF)concentration.However,WVD is severely limited by the cross-term when working with multicomponent signals.In this paper,we analyze the property differences between auto-term and cross-term in the one-dimensional sequence and the two-dimensional plane and approximate entropy and Rényi entropy are employed to describe them,respectively.Based on this information,we propose a new method to achieve adaptive cross-term removal by combining seeded region growing.Compared to other methods,the new method can achieve cross-term removal without decreasing the TF concentration of the auto-term.Simulation and experimental data processing results show that the method is adaptive and is not constrained by the type or distribution of signals.And it performs well in low signal-to-noise ratio environments.
基金supported by Macao Science and Technology Development Fund,Macao SAR,China(Grant No.:0043/2023/AFJ)the National Natural Science Foundation of China(Grant No.:22173038)Macao Polytechnic University,Macao SAR,China(Grant No.:RP/FCA-01/2022).
文摘Accurate prediction of molecular properties is crucial for selecting compounds with ideal properties and reducing the costs and risks of trials.Traditional methods based on manually crafted features and graph-based methods have shown promising results in molecular property prediction.However,traditional methods rely on expert knowledge and often fail to capture the complex structures and interactions within molecules.Similarly,graph-based methods typically overlook the chemical structure and function hidden in molecular motifs and struggle to effectively integrate global and local molecular information.To address these limitations,we propose a novel fingerprint-enhanced hierarchical graph neural network(FH-GNN)for molecular property prediction that simultaneously learns information from hierarchical molecular graphs and fingerprints.The FH-GNN captures diverse hierarchical chemical information by applying directed message-passing neural networks(D-MPNN)on a hierarchical molecular graph that integrates atomic-level,motif-level,and graph-level information along with their relationships.Addi-tionally,we used an adaptive attention mechanism to balance the importance of hierarchical graphs and fingerprint features,creating a comprehensive molecular embedding that integrated hierarchical mo-lecular structures with domain knowledge.Experiments on eight benchmark datasets from MoleculeNet showed that FH-GNN outperformed the baseline models in both classification and regression tasks for molecular property prediction,validating its capability to comprehensively capture molecular informa-tion.By integrating molecular structure and chemical knowledge,FH-GNN provides a powerful tool for the accurate prediction of molecular properties and aids in the discovery of potential drug candidates.
基金Supported by NSFC(No.11401256)Scientific Research Fund of Zhejiang Provincial Education Department(No.Y202249575)Zhejiang Provincial NSF(No.LQ13A010016).
文摘The property IR was introduced by Friis and Rordam in 1996.They proved that any pair of almost commuting self-adjoint elements is norm close to a pair of exactly commuting self-adjoint elements in any C^(*)-algebras with the property IR.In this paper,we will prove some permanence results for IR-algebras,approximate IR-algebras and local IR-algebras.Finally,we will also show that any pair of almost commuting self-adjoint elements is norm close to a pair of exactly commuting self-adjoint elements in any local IR-algebra.
文摘Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.
基金Guizhou Provincial University Humanities and Social Sciences Research Project in 2024"Enhancing the Development of New Productive Forces through University Technological Innovation and Intellectual Property Management"(2024RW256)Guizhou University of Commerce Research Project in 2022"Study on the Ideas and Pathways to Drive Agricultural Powerhouse through Digital Economy"(2022XJZX315)。
文摘With the rapid development of globalization and information technology,intellectual property has been one of the key drivers of economic growth,and the construction of intellectual property system has become an important criterion for measuring the quality of business environment.This article is intended to explore the current status of intellectual property system construction in China,the challenges,and its relationship with the business environment,to propose the corresponding countermeasures and suggestions.The study finds that the legal system of intellectual property in China is gradually improving,and judicial and administrative protection are continuously strengthened.However,the challenges still remain such as frequent infringements,rights hard to protect and insufficient international cooperation.These issues not only affect the legitimate rights and interests of innovation entities,but also for the market fairness and the level of the business environment.Therefore,this article proposes that strengthening the perfection of the intellectual property legal system,enhancing intellectual property services and support capabilities,strengthening international cooperation and exchanges,and accelerating the cultivation of composite talents.It aims to provide theoretical references for the construction of intellectual property system and the optimization of the business environment,promote the high-quality development of economy and enhance the global competitiveness of the country.
文摘This paper delves into the theoretical mechanisms of the electronic structure and optical properties of aluminum-based semiconductors(AlX,X=N,P,As,Sb)and indium-based semiconductors(InX,X=N,P,As,Sb)as potential materials for optical devices.Band structure calculations reveal that,except for InSb,all other compounds are direct bandgap semiconductors,with AlN exhibiting a bandgap of 3.245 eV.The valence band maximum of these eight compounds primarily stems from the p-orbitals of Al/In and X.In contrast,the conduction band minimum is influenced by all orbitals,with a predominant contribution from the p-orbitals.The static dielectric constant increased with the expansion of the unit cell volume.Compared to AlX and InX with larger X atoms,AlN and InN showed broader absorption spectra in the near-ultraviolet region and higher photoelectric conductance.Regarding mechanical properties,AlN and InN displayed greater shear and bulk modulus than the other compounds.Moreover,among these eight crystal types,a higher modulus was associated with a lower light loss function value,indicating that AlN and InN have superior transmission efficiency and a wider spectral range in optoelectronic material applications.
文摘A new cobalt(Ⅱ)-radical complex:[Co(im4-py)_(2)(PNB)_(2)](im4-py=2-(4'-pyridyl)-4,4,5,5-tetramethylimidazole-1-oxyl,HPNB=p-nitrobenzoic acid)has been synthesized and characterized by X-ray diffraction analysis,elemental analysis,IR,and magnetic properties.X-ray diffraction analysis shows that the complex exists as mononuclear molecules and Co(Ⅱ)ion is four-coordinated with two radicals and two PNB-ligands.The magnetic susceptibility study indicates the complex exhibits weak ferromagnetic interactions between cobalt(Ⅱ)and im4-py radical.The magnetic property is explained by the magnetic and structure exchange mechanism.CCDC:976028.
基金Supported by The Featured Innovation Projects of the General University of Guangdong Province(2023KTSCX096)The Special Projects in Key Areas of Guangdong Province(ZDZX1088)Research Team Project of Guangdong University of Education(2024KYCXTD018)。
文摘This paper explores the recovery of block sparse signals in frame-based settings using the l_(2)/l_(q)-synthesis technique(0<q≤1).We propose a new null space property,referred to as block D-NSP_(q),which is based on the dictionary D.We establish that matrices adhering to the block D-NSP_(q)condition are both necessary and sufficient for the exact recovery of block sparse signals via l_(2)/l_(q)-synthesis.Additionally,this condition is essential for the stable recovery of signals that are block-compressible with respect to D.This D-NSP_(q)property is identified as the first complete condition for successful signal recovery using l_(2)/l_(q)-synthesis.Furthermore,we assess the theoretical efficacy of the l2/lq-synthesis method under conditions of measurement noise.
基金National Key R&D Program of China(2023YFE3812005)International Partnership Program of Chinese Academy of Sciences(121631KYSB20200039)+1 种基金National Center for Research and Development(WPC2/1/SCAPOL/2021)Chinese Academy of Sciences President’s International Fellowship Initiative(2024VEA0005,2024VEA0014)。
文摘Sc_(2)O_(3),as a host for solid-state laser gain materials,has advantage of high thermal conductivity and easy matching with activating ions,which is promising in high-power laser applications.Currently,Yb-doped Sc_(2)O_(3) ceramics have been fabricated at very high sintering temperatures,but their optical quality and sintering process still need further improvement.In this work,5%Yb:Sc_(2)O_(3)(in mass)nano-powders were obtained by co-precipitation,and then transparent ceramics were fabricated by vacuum pre-sintering and hot isostatic pressing(HIP)post-treatment.The cubic Yb:Sc_(2)O_(3) nano-powders with good dispersity and an average crystallite of 29 nm were obtained.Influence of pre-sintering temperatures(1500-1700℃)on densification process,microstructure changes,and optical transmittance of Yb:Sc_(2)O_(3) ceramics was detected.Experimental data revealed that all samples have a uniform microstructure,while the average grain sizes increase with the increase of the sintering temperatures.Impressively,the optimum in-line transmittance of Yb:Sc_(2)O_(3) ceramics,pre-sintered at 1550℃after HIP post-treatment,reaches 78.1%(theoretical value of 80%)at 1100 nm.Spectroscopic properties of the Yb:Sc_(2)O_(3) ceramics reveal that the minimum population inversion parameterβ2 and the luminescence decay time of 5%Yb:Sc_(2)O_(3) ceramics are 0.041 and 0.49 ms,respectively,which demonstrate that the optical quality of the Yb:Sc_(2)O_(3) has been improved.Meanwhile,their best vacuum sintering temperature can be controlled down to a lower temperature(1550℃).In conclusion,Yb:Sc_(2)O_(3) nano-powders are successfully synthesized by co-precipitation method,and good optical quality transparent ceramics are fabricated by vacuum pre-sintering at 1550℃and HIP post-treatment.
文摘A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear resistance,and many other critical properties.However,at present a comprehensive and robust map correlating different properties in particle-reinforced composites is much lacking.In this work,an industrial grade AZ91 magnesium alloy reinforced with hard SiC and soft fly ash particles(with 3 vol.%each),has been prepared using stir casting followed by hot extrusion at 325℃with a ratio of 21.5.Microstructure of the hybrid composite was characterized using optical and scanning electron microscopes.The composite exhibited a reduction in average grain size from 13.6 to 7.1μm,concomitantly an increase in Vickers hardness from 73 to 111 HV.The tension-compression yield asymmetry ratios of the unreinforced alloy and hybrid composite were 1.165 and 0.976,respectively indicating higher yield strength for the composite under compressive load.The composite exhibited 76%improvement in damping capacity under time sweep mode,and 28%improvement at 423 K under temperature sweep mode.The tribological characteristics of the composite under dry sliding conditions at sliding speeds and loads in the range of 0.5 to 1.5 m s^(-1)and 10 to 30 N,respectively showed higher wear resistance than the unreinforced alloy.The composite showed 23%improvement in sliding wear resistance at a load of 20 N and a speed of 1 m s^(-1).Finally,efforts have been made to understand the influence of one property on the other by developing statistical property correlation maps from the properties obtained in this study and from the literature.These maps are expected to help in the design of hybrid Metal Matrix Composites for a variety of targeted applications in different sectors.
基金supported by the National Social Science Fund of China:“Research on the Philosophy of Property System of Modernization of China’s National Governance System and Governance Capacity”(Project Number:20BZX025).
文摘“Some foreign scholars have proposed that the new institutional economics can unify the social sciences.”Behind the institution is property,and the dual cognition of property is the obstacle.Property dualism comes from the thought dualism in the western rationalism tradition.The transcendence of“property dualism”has experienced the stages of“labor value”and“reasonable value”,and the new era has ushered in the opportunity of the third transcendence.In the first two stages,“abundance”and“scarcity”are the root causes of the contradiction in the transcendence of property dualism.Marx’s basic property view of production relations(property relations)unifies the property views of Locke,Hume,and Commons.The three-dimensional property system model developed on the basis of Marx’s complex property view provides a theoretical tool for the third transcendence of property dualism.We have cracked the western rationalism dualism with Marx’s historical materialism and reconciled the property dualism with three-dimensional property system model.By this,we can continue to explore the potential of“institution unifying social sciences”.
文摘Within the context of building a community for the Chinese nation,fine traditional Chinese culture has emerged as a core competitiveness in advancing the Chinese path to modernization.However,the current absence of a benefit-sharing mechanism for this culture,and its systemic incompatibility with the Western-dominated intellectual property system,are detrimental to building a community for the Chinese nation.Exploration reveals that,based on the Marxist labor theory of value,fine traditional Chinese culture can be justified as property;and based on Locke's labor theory of property,it should be accorded property rights.Thus,fine traditional Chinese culture can be included as the subject matter of property rights.Protecting fine traditional Chinese culture aligns with the original purpose of the intellectual property(IP)system,which should not be confined to safeguarding"knowledge innovation"but should also emphasize"knowledge transmission."Expanding the IP system to protect fine traditional Chinese culture is conducive to China's engagement in the global intellectual property landscape.A new form of intellectual property—traditional cultural property rights—should therefore be created.Traditional cultural property rights refer to the direct and exclusive rights held by rights holders,defined as the communities in specific regions,over specific traditional cultural expressions according to law.The protectable subject matter would encompass cultural traditions characterized by their intergenerational continuity,communal identity,and intrinsic value.The scope of these rights would include control over use,authorization of use,and the right to benefit from such use.The construction of a protection system for traditional cultural property rights should establish the principles of perpetual protection,collective protection,and regional protection.
基金Supported by National Natural Science Foundation of China(Grant No.52275142)Science Center for Gas Turbine Project(Grant Nos.P2022-AIII-003-001,P2022-B-III-005-001)+1 种基金National Science and Technology Major Project(Grant Nos.J2019-IV-0009-0077,Y2022-IV-0002-0019,J2019-IV-0008-0076)National Basic Scientific Research Project(Grant No.JCKY2021601B204)。
文摘Creep is one of the most typical failure modes for the turbine blades of an aero-engine.The microstructure of the turbine blades after long-term service can be adjusted by rejuvenation heat treatment(RHT)to restore its creep properties.In this work,a series of RHT experiments were carried out on a directionally solidified(DS)nickel-based superalloy under different solution temperatures and primary aging temperatures based on the standard heat treatment(SHT)process parameters to investigate the mechanism of temperature influence on DS's microstructure after RHT.It is indicated that a more uniform microstructure can be obtained under higher solution temperatures and lower primary aging temperatures compared to the SHT process.Furthermore,by employing the image processing methods to quantify microstructural parameters,a comprehensive indicator parameter for the RHT effect(marked as Prej)was proposed to characterize the effects of RHT on DS superalloy's microstructure and creep property combined with the entropy weight method.Based on this,a regression model to describe the relationship between RHT process parameters and Prej was constructed by using the response surface methodology(RSM).It is revealed that the optimal solution temperature and primary aging temperature for this DS superalloy are 1283°C and 1095°C,respectively.Then the conclusion was validated through complete creep experiments on the DS superalloy,which showed the creep life after RHT reaches 95.5%of the SHT specimen,and the total life has increased by 20.6%.
基金supported by the Natural Science Foundation of the Xinjiang Uygur Autonomous Region(2024D01E30)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0880000)+1 种基金the Open Fund of the Anhui Key Laboratory of Photonic Materials and Devices(AHKL2024KF02)the National Natural Science Foundation of China(22475234,22335007,22193044 and 22361132544).
文摘Multifunctional semiconductors play an important role in developing advanced photoelectric technologies.In this work,based on an octahedral replacement strategy in chalcogenides,a new selenide semiconductor NaMn_(3)Ga_(3)Se_(8)was rationally designed,and synthesized by the flux method.The compound crystallizes in the noncentrosymmetric(NCS)P_(6)space group,and is composed of unique prismatic[NaSe_(6)],octahedral[MnSe_(6)]and tetrahedral[GaSe_(4)]motifs,inheriting the stable three-dimensional framework built by the octahedral and tetrahedral units in the A^(Ⅰ)Mg_(3)^(Ⅱ)C_(3)^(Ⅲ)Q_(8)^(Ⅵ)family.NaMn_(3)Ga_(3)Se_(8)shows the largest known secondary nonlinear optical(NLO)response of~2.1×AgGaS_(2)(AGS)in the A^(Ⅰ)Mg_(3)^(Ⅱ)C_(3)^(Ⅲ)Q_(8)^(Ⅵ)family,and a high laser-induced damage threshold of~3.0×AGS.Meanwhile,the introduction of Mn2t with unpaired 3d electrons induces a strong red emission band(685–805 nm)under the excitation source of 496 nm,as well as a paramagnetic to antiferromagnetic(AFM)transition at 7.3 K.The results confirm that NaMn_(3)Ga_(3)Se_(8)possesses multifunctional features including significant NLO response,fluorescence emission and AFM properties,and illustrate that replacing octahedral units with approaching size and geometry(like[MgSe_(6)]and[MnSe_(6)])could be a feasible way to develop multifunctional chalcogenides.
基金jointly supported by the Natural Science Foundation of Shanxi Province(Nos.202203021222127,202403021212109).
文摘NiTi alloy has been widely used as orthopedic implant materials due to its unique shape memory properties and superelasticity.However,implantation failure often occurs because of the poor antibacterial ability,antioxidation property and corrosion resistance of the NiTi alloy.In order to overcome the above problems,we constructed Zn/polydopamine(PDA)/Chitosan-Catechol(CS-C)composite coating on the surface of NiTi alloy in this paper.The surface morphology and wettability of the coating were characterized by scanning electron microscopy(SEM)and optical contact angle measuring instrument,respectively.The results showed that the Zn/CS-C coating was successfully prepared,and exhibited good hydrophilic property,especially the sample Zn/PDA/CS-C-24 h.In addition,the corrosion resistance,antioxidation property and biological properties of the coating were systematically analyzed.The results indicated that the Zn/PDA/CS-C composite coating exhibited good corrosion resistance and antibacterial property,antioxidant property and osteogenic activity,especially sample Zn/PDA/CS-C-24 h.The sample Zn/PDA/CS-C-24 h could effectively protect osteoblasts from reactive oxygen species(ROS)damage and promote cell proliferation and osteoblast differentiation.This study provides a feasible and effective strategy for the surface modification of orthopedic implant.
基金This research project(Grant No FF-112/2566)is supported by Mahidol University(Basic Research Fund:fiscal year 2023 by National Science Research and Innovation Fund(NSRF)).
文摘Conventional natural rubber(NR)fillers pose several environmental concerns.This study presents the sustain-able development of NR composites incorporating sugarcane leaf(SCL)-derived alkali lignin and commercial alkali lignin as functional fillers.The primary objective was to evaluate the mechanical properties,aging resistance,thermal stability,and antimicrobial activity of the NR composites.Various NR composites were prepared by different filler types,including KOH-extracted SCL lignin,commercial alkali lignin,and butylated hydroxytoluene(BHT).The results show that NR composites containing KOH-extracted SCL lignin exhibited superior mechanical properties(crosslink density 126 mol/m^(3)),improved aging resistance(aging coefficient 80.08%),and enhanced thermal stability(the thermal degradation with 50%weight loss(T50)and the highest degradation rate occurs(Td)of 394 and 383℃,respectively)compared to all other samples.NR composites with commercial lignin demonstrated the highest reduction in Staphylococcus aureus populations(56.25%).The NR composites with KOH-extracted SCL lignin displayed limited antimicrobial efficacy(37.78%),suggesting that its primary contribution lies in mechanical and thermal reinforcement rather than microbial inhibition.These findings highlight the potential of eco-friendly lignin from SCL biomass as a sustainable bio-based filler for NR composites.
