Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owi...Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.展开更多
The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enh...The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enhancement of CZTSSe devices.Although the incorporation of Ag in CZTSSe can effectively suppress the SnZn-related defects and significantly improve the resulting cell performance,an excellent efficiency has not been achieved to date primarily owing to the poor electrical-conductivity and the low carrier density of the CZTSSe film induced by Ag substitution.Herein,this study exquisitely devises an Ag/H co-doping strategy in CZTSSe absorber via Ag substitution programs followed by hydrogen-plasma treatment procedure to suppress SnZn defects for achieving efficient CZTSSe devices.In-depth investigation results demonstrate that the incorporation of H in Ag-based CZTSSe absorber is expected to improve the poor electrical-conductivity and the low carrier density caused by Ag substitution.Importantly,the C=O and O-H functional groups induced by hydrogen incorporation,serving as an electron donor,can interact with under-coordinated cations in CZTSSe material,effectively passivating the SnZn-related defects.Consequently,the incorporation of an appropriate amount of Ag/H in CZTSSe mitigates carrier non-radiative recombination,prolongs minority carrier lifetime,and thus yields a champion efficiency of 14.74%,showing its promising application in kesterite-based CZTSSe devices.展开更多
Covalent organic frameworks(COFs)are considered promising catalysts for photocatalytic CO_(2)reduction reaction(pCO_(2)RR)due to facilitated regulations.However,the instability of COFs with dynamic reversible covalent...Covalent organic frameworks(COFs)are considered promising catalysts for photocatalytic CO_(2)reduction reaction(pCO_(2)RR)due to facilitated regulations.However,the instability of COFs with dynamic reversible covalent bonds and the limited modifiability of COFs with irreversible covalent bonds restricted the enhancement of the pCO_(2)RR performance.Herein,three phthalocyanine-based COFs with ether-linked,CoOP,CoPOP,and CoBOP,were successfully prepared via in situ polycondensation using modifiable bis-phthalonitrile.CoBOP achieved a record of syngas performance in pCO_(2)RR systems with photosensitizers and sacrificial agents(CO 83.7 mmol g^(-1)h^(-1)and H_254.7 mmol g^(-1)h^(-1)),surpassing most COF photocatalysts.Additionally,CoOP,CoPOP,and CoBOP exhibit stabilities in extreme environments owing to their irreversible covalent bonds.Experimental and density functional theory analyses confirm that the optimally matched the lowest unoccupied molecular orbital of the linking unit between the photosensitizer and active unit endowed Co BOP with the highest photoelectron transfer efficiency among the three catalysts,boosting its pCO_(2)RR activity.This work is highly instructive for designing COFs with structure-adjustable and irreversible covalent bonds.展开更多
Small signal equivalent circuit model and modulation properties of vertical cavity surface emitting lasers(VCSEL's) are presented.The modulation properties both in analytic equation calculation and in circuit mo...Small signal equivalent circuit model and modulation properties of vertical cavity surface emitting lasers(VCSEL's) are presented.The modulation properties both in analytic equation calculation and in circuit model simulation are studied.The analytic equation calculation of the modulation properties is calculated by using Mathcad program and the circuit model simulation is simulated by using Pspice program respectively.The results of calculation and the simulation are in good agreement with each other.Experiment is performed to testify the circuit model.展开更多
Two-dimensional(2D)nonlinear optical mediums with high and tunable light modulation capability can significantly stimulate the development of ultrathin,compact,and integrated optoelectronics devices and photonic eleme...Two-dimensional(2D)nonlinear optical mediums with high and tunable light modulation capability can significantly stimulate the development of ultrathin,compact,and integrated optoelectronics devices and photonic elements.2D carbides and nitrides of transition metals(MXenes)are a new class of 2D materials with excellent intrinsic and strong light-matter interaction characteristics.However,the current understanding of their photo-physical properties and strategies for improving optical performance is insufficient.To address this issue,we rationally designed and in situ synthesized a 2D Nb_(2)C/MoS_(2) heterostructure that outperforms pristine Nb2C in both linear and nonlinear optical performance.Excellent agreement between experimental and theoretical results demonstrated that the Nb_(2)C/MoS_(2) inherited the preponderance of Nb_(2)C and MoS_(2) in absorption at different wavelengths,resulting in the broadband enhanced optical absorption characteristics.In addition to linear optical modulation,we also achieved stronger near infrared nonlinear optical modulation,with a nonlinear absorption coefficient of Nb_(2)C/MoS_(2) being more than two times that of the pristine Nb_(2)C.These results were supported by the band alinement model which was determined by the X-ray photoelectron spectroscopy(XPS)experiment and first-principal theory calculation.The presented facile synthesis approach and robust light modulation strategy pave the way for broadband optoelectronic devices and optical modulators.展开更多
The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematica...The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.展开更多
Interlayer antiferromagnetic coupling,small magnetic anisotropy,and low air stability of the intrinsic magnetic topological insulator MnBi_(2)Te_(4)have been critical bottlenecks to the future application of the quant...Interlayer antiferromagnetic coupling,small magnetic anisotropy,and low air stability of the intrinsic magnetic topological insulator MnBi_(2)Te_(4)have been critical bottlenecks to the future application of the quantum anomalous Hall efect(QAHE)at zero magnetic feld.In this study,we propose a scheme to utilize capped sliding van der Waals materials to efectively modulate the magnetic and topological properties of MnBi_(2)Te_(4).Our results demonstrate that the h-BN/MnBi_(2)Te_(4)/h-BN heterostructure,constructed by sliding ferroelectric h-BN bilayer and MnBi_(2)Te_(4),not only realizes a transition from interlayer antiferromagnetic to ferromagnetic coupling but also signifcantly enhances the out-of-plane magnetism and air stability of MnBi_(2)Te_(4).Moreover,the above magnetic properties can be further improved by tuning the interlayer distance between h-BN and MnBi_(2)Te_(4).Additionally,the obtained band structures and topological properties clearly support that the h-BN/MnBi_(2)Te_(4)/hBN heterostructure can harbor the QAHE with a Chern number of C=1.This work provides a new and nonvolatile modulation approach to achieve high-temperature and high-precision QAHE at zero magnetic feld.展开更多
Efficient and flexible interactions require precisely converting human intentions into computer-recognizable signals,which is critical to the breakthrough development of metaverse.Interactive electronics face common d...Efficient and flexible interactions require precisely converting human intentions into computer-recognizable signals,which is critical to the breakthrough development of metaverse.Interactive electronics face common dilemmas,which realize highprecision and stable touch detection but are rigid,bulky,and thick or achieve high flexibility to wear but lose precision.Here,we construct highly bending-insensitive,unpixelated,and waterproof epidermal interfaces(BUW epidermal interfaces)and demonstrate their interactive applications of conformal human–machine integration.The BUW epidermal interface based on the addressable electrical contact structure exhibits high-precision and stable touch detection,high flexibility,rapid response time,excellent stability,and versatile“cut-and-paste”character.Regardless of whether being flat or bent,the BUW epidermal interface can be conformally attached to the human skin for real-time,comfortable,and unrestrained interactions.This research provides promising insight into the functional composite and structural design strategies for developing epidermal electronics,which offers a new technology route and may further broaden human–machine interactions toward metaverse.展开更多
Laser powder bed fusion(LPBF)combined with reaction bonding(RB)of Al particles is an effective method for preparing high-performance 3D Al_(2)O_(3) ceramic foams.However,the indistinct microstructure evolution hinders...Laser powder bed fusion(LPBF)combined with reaction bonding(RB)of Al particles is an effective method for preparing high-performance 3D Al_(2)O_(3) ceramic foams.However,the indistinct microstructure evolution hinders the regulation of pore features and the improvement of synthetic properties.Herein,the microstructure evolution of the Al_(2)O_(3) ceramic foams during the LPBF/RB process is clarified by various characterization methods,and the corresponding mechanical property modulation is realized by optimizing LPBF parameters,organic binder(E12 epoxy resin)content,heating rate,sintering time,and coral-like Al_(2)O_(3) content.The expansion from Al_(2)O_(3) outward growth and Al granule precipitation counteracts the shrinkage from E12 decomposition and Al_(2)O_(3) sintering,resulting in an ultra-low shrinkage of 0.94%–3.01%.The pore structures of particle packing pores,hollow spheres,and microporous structures allow a tunable porosity of 52.6%–73.7%.The in-situ formation of multi-scale features including hollow spheres,flaky grains,whiskers,nanofibers,and bond bridges brings about a remarkably high bending strength of 6.5–38.3 MPa.Ourfindings reveal the relationship between microstructure evolution and property optimization of high-performance ceramic foams,with potential significance for microstructure design and practical application.展开更多
Stimuli-responsive materials have shown promising applications in the areas of sensing,bioimaging,information encryption,and bioinspired camouflage.In particular,multi-stimuli-responsive materials represent a hot topi...Stimuli-responsive materials have shown promising applications in the areas of sensing,bioimaging,information encryption,and bioinspired camouflage.In particular,multi-stimuli-responsive materials represent a hot topic due to their modulated properties under multiple stimuli.Herein,we successfully developed multi-stimuli-responsive inks and a series of complex multi-stimuli-responsive 3-dimensional(3D)structures were fabricated via digital light processing 3D-printing technology.Notably,these complex 3D structures show shape memory,fast-response photochromic and thermochromic behavior,and excellent repeatability due to the combination of photochromic molecules(4-(2,2-bis(4-fluorophenyl)vinyl)benzyl methacrylate)and thermochromic pigments.Furthermore,a programmable encrypted box that changes colors and morphology by controlling temperature and ultraviolet irradiation was designed and printed,and this encrypted box exhibits strong security using OpenCV-based image recognition technology.This strategy provides a promising approach for the design of multi-stimuli-responsive materials and complex encryption systems in the future.展开更多
Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal POM.In this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_...Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal POM.In this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_(2)}{[Ni_(6)Cl(μ-OH)_(3)(H_(2)O)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))][Ni_(6)(μ-OH)_(3)(H_(2)O)_(2)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))]}Cl·27H_(2)O,(1,Dach=1,2-diaminocyclohexane)was synthesized.Compounds 1 shows excellent catalytic performance in the selective oxidation of aniline to azoxybenzene(AOB)in water.The apparently different results from that with the matrix{PW_(9)O_(34)}({PW9})suggest the successful regulation of the catalytic property of{PW9}by the introduction of the{Ni6}cluster into the skeleton.The experimental results indicate that the highlighted performance of 1 is contributed by the synergy of W and Ni sites,which are respectively responsible for the oxidation and condensation steps in the production of AOB.The good selectivity to AOB is essentially attributed to the effective modulation of the reaction rates of oxidation and condensation steps by W and Ni sites,respectively.展开更多
We propose a new approach for generating a multiple focal spot segment of subwavelength size, by tight focusing of a phase modulated radially polarized Laguerre Bessel Gaussian beam. The focusing properties are invest...We propose a new approach for generating a multiple focal spot segment of subwavelength size, by tight focusing of a phase modulated radially polarized Laguerre Bessel Gaussian beam. The focusing properties are investigated theoretically by .vector diffraction theory. We observe that the focal segment with multiple focal structures is separated with different axial distances and a super long dark channel can be generated by properly tuning the phase of the incident radially polarized Laguerre Bessel Gaussian beam. We presume that such multiple focal patterns and high intense beam may find applications in atom optics, optical manipulations and multiple optical trapping.展开更多
A numerical model of thermoelectric module （TEM） is created by academic analysis,and the impacts of the resistance ratio and thermoelement size on the output power and thermoelectric efficiency of the TEM are analyz...A numerical model of thermoelectric module （TEM） is created by academic analysis,and the impacts of the resistance ratio and thermoelement size on the output power and thermoelectric efficiency of the TEM are analyzed by the MATLAB numerical calculation.The numerical model is validated by the ANSYS thermal,electrical,and structural coupling simulation.The effects of the variable physical property parameters and contact effect on the output power and thermoelectric efficiency are evaluated,and the concept of aspect ratio optimal domain is proposed,which provides a new design approach for the TEM.展开更多
DNA hydrogels are three-dimensional polymer networks constructed using DNA as the structural building block.Due to the tight binding between hydrophilic groups on DNA chains and water molecules,they exhibit outstandin...DNA hydrogels are three-dimensional polymer networks constructed using DNA as the structural building block.Due to the tight binding between hydrophilic groups on DNA chains and water molecules,they exhibit outstanding plasticity and fluid thermodynamic properties,making them one of the best choices for mimicking natural biological tissues.By controlling the backbone building blocks,gelation conditions,and cross-linking methods of DNA hydrogels,hydrogels with different mechanical strengths can be obtained,thus expanding their applications in the field of biology.This review first introduces the relationship between the mechanical properties of DNA hydrogels and their structure,elucidates the approaches and strategies for mechanical property modulation,and focuses on the scheme of controllable design to modulate the mechanical properties of DNA hydrogels for applications in biosensing,cellular function regulation,and bone tissue engineering.Furthermore,this review outlines the future development directions and challenges faced in the mechanical property modulation of DNA hydrogels,providing useful information for the precise design of DNA hydrogels for biological research.展开更多
Instead of the L^p estimates,we study the modulation space estimates for the solution to the damped wave equation.Decay properties for both the linear and semilinear equations are obtained.The estimates in modulation ...Instead of the L^p estimates,we study the modulation space estimates for the solution to the damped wave equation.Decay properties for both the linear and semilinear equations are obtained.The estimates in modulation space differ in many aspects from those in L^p space.展开更多
Emission enhancement of gold nanoclusters protected with 6-propyl-2-thiouracil(PRT-AuNCs)is achieved through incorporating a suitable amount of Cu^(2+).Sophisticated mechanisms are involved in the modulation of emissi...Emission enhancement of gold nanoclusters protected with 6-propyl-2-thiouracil(PRT-AuNCs)is achieved through incorporating a suitable amount of Cu^(2+).Sophisticated mechanisms are involved in the modulation of emission properties of the PRT-AuNCs/Cu^(2+)system,instead of merely a metal ion induced aggregation.展开更多
High pressure as an effective strategy was employed to synthesize and modulate the electrical transport properties of(Bi,Sb)_(2)Te_(3) alloys.Intrinsic point defects could be significantly regulated via high pressure,...High pressure as an effective strategy was employed to synthesize and modulate the electrical transport properties of(Bi,Sb)_(2)Te_(3) alloys.Intrinsic point defects could be significantly regulated via high pressure,inducing a suitable donor-like effect to optimize the carrier concentration.The texture and microstructure were improved with high pressure,and a nanograin with(00l)orientation was observed in the(Bi,Sb)_(2)Te_(3) matrix,suggesting that high pressure could facilitate the recrystallization of lattice defects along the(00l)orientation.Based on the synergistic effect of high pressure on intrinsic point defects,texture,and microstructure,the carrier concentration and mobility are regularly modulated,resulting in the room-temperature power factor of the(Bi,Sb)_(2)Te_(3) alloys exhibiting a strong correlation with pressure.Hence,these important results here provide a prospective strategy in the improvement in the electrical transport properties of the Bi_(2)Te_(3)-based alloys according to the rational design of intrinsic point defects,texture,and microstructure with high pressure.展开更多
Coordination cages with a nanocavity can encapsulate various vips,which allows modulation of the physical and chemical properties of the host–vip inclusion complexes.In this work,we designed and prepared a phosph...Coordination cages with a nanocavity can encapsulate various vips,which allows modulation of the physical and chemical properties of the host–vip inclusion complexes.In this work,we designed and prepared a phosphorescence Cu_(6)L_(3)trigonal prismatic cage,which accommodates a series of aromatic vip molecules.Single crystal X-ray analysis revealed that the intermolecular Cu⋯Cu distance can be mediated by changing the volume of the vips.Moreover,the host-vip charge-transfer interactions can be also fine-tuned via tailoring the ionization potential of vips.Consequently,we have observed the vip-induced photoluminescence properties change including a gradual red shift of the maximum emission peak and a linear relationship between the quantum yield and ionization potential of vips.展开更多
The luminescence thermal quenching properties of phosphor materials have been a huge challenge for their wide application.Therefore,how to modulate the thermal quenching property of phosphor materials has become a res...The luminescence thermal quenching properties of phosphor materials have been a huge challenge for their wide application.Therefore,how to modulate the thermal quenching property of phosphor materials has become a research hotspot nowadays.The luminescence thermal quenching behavior of rare earth and transition metal ions has been widely researched in the past decades.In recent years,bismuth as a novel,nontoxic,and inexpensive activator ion has attracted much attention from researchers.However,Bi^(3+)-activated phosphors always suffer from horrible thermal quenching effects.In this contribution,many Bi^(3+)-activated phosphors with excellent antithermal quenching are summarized in detail,and four design strategies for modulating the thermal quenching properties of Bi^(3+)-activated phosphors are proposed:(1)defect engineering;(2)structural modulation;(3)lattice structure rigidity;and(4)energy transfer.In addition,the challenges and opportunities for the wide application of Bi^(3+)-activated phosphors are presented.This review provides a reference for the design and development of novel antithermal quenching Bi^(3+)-activated phosphors.展开更多
Solid solutions offer an opportunity for modulating the structural and physical properties of materials and better understanding the origin of physical phenomena as well.Herein,two salts[R-BzPy][Ni(mnt)_(2)](R-BzPy^(+...Solid solutions offer an opportunity for modulating the structural and physical properties of materials and better understanding the origin of physical phenomena as well.Herein,two salts[R-BzPy][Ni(mnt)_(2)](R-BzPy^(+)=4-R-benzylpyridinium,substituent group R=F,Cl;mnt^(2-)=maleonitriledithiolate)and their solid solutions[F_(x)Cl_(1-x)-B_(z)P_(y)][Ni(mnt)_(2)](x=0.07-0.87)were prepared and characterized by IR.展开更多
基金The authors acknowledge the micro-fabrication center of National Laboratory of Solid State Microstructures(NLSSM)for technique supportProf.Jia Zhu acknowledges the support from the XPLORER PRIZE+3 种基金This work is jointly supported by the National Key Research and Development Program of China(No.2021YFA140070)the National Natural Science Foundation of China(Nos.61735008,51925204,12022403)Excellent Research Program of Nanjing University(ZYJH005)Carbon Peaking and Carbon Neutrality Science and Technology Innovation Fund of Jiangsu Province(BK20220035).
文摘Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.
基金supported by the National Natural Science Foundation of China(51802081,62074052,and 62104061)the Natural Science Foundation of Henan Province(232300420145).
文摘The presence of SnZn-related defects in Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)absorber results in large irreversible energy loss and extra irreversible electron-hole non-radiative recombination,thus hindering the efficiency enhancement of CZTSSe devices.Although the incorporation of Ag in CZTSSe can effectively suppress the SnZn-related defects and significantly improve the resulting cell performance,an excellent efficiency has not been achieved to date primarily owing to the poor electrical-conductivity and the low carrier density of the CZTSSe film induced by Ag substitution.Herein,this study exquisitely devises an Ag/H co-doping strategy in CZTSSe absorber via Ag substitution programs followed by hydrogen-plasma treatment procedure to suppress SnZn defects for achieving efficient CZTSSe devices.In-depth investigation results demonstrate that the incorporation of H in Ag-based CZTSSe absorber is expected to improve the poor electrical-conductivity and the low carrier density caused by Ag substitution.Importantly,the C=O and O-H functional groups induced by hydrogen incorporation,serving as an electron donor,can interact with under-coordinated cations in CZTSSe material,effectively passivating the SnZn-related defects.Consequently,the incorporation of an appropriate amount of Ag/H in CZTSSe mitigates carrier non-radiative recombination,prolongs minority carrier lifetime,and thus yields a champion efficiency of 14.74%,showing its promising application in kesterite-based CZTSSe devices.
基金financially supported by the Innovation Capability Support Program of Shaanxi—Science and Technology Innovation Team Project(No.2025RS-CXTD-024)the Fundamental Research Foundation of SHCCIG New Materials Technology Research Institute Co.,Ltd(No.D5204230171)+3 种基金the Fundamental Research Funds for the Central Universities(G2025KY05240)the Natural Science Basic Research Program of Shaanxi(Program No.2024JC-YBQN-0073)the Fundamental Research Funds for the Central Universities(No.D5000250204)Young Talent Fund of Association for Science and Technology in Shaanxi(No.20230101)。
文摘Covalent organic frameworks(COFs)are considered promising catalysts for photocatalytic CO_(2)reduction reaction(pCO_(2)RR)due to facilitated regulations.However,the instability of COFs with dynamic reversible covalent bonds and the limited modifiability of COFs with irreversible covalent bonds restricted the enhancement of the pCO_(2)RR performance.Herein,three phthalocyanine-based COFs with ether-linked,CoOP,CoPOP,and CoBOP,were successfully prepared via in situ polycondensation using modifiable bis-phthalonitrile.CoBOP achieved a record of syngas performance in pCO_(2)RR systems with photosensitizers and sacrificial agents(CO 83.7 mmol g^(-1)h^(-1)and H_254.7 mmol g^(-1)h^(-1)),surpassing most COF photocatalysts.Additionally,CoOP,CoPOP,and CoBOP exhibit stabilities in extreme environments owing to their irreversible covalent bonds.Experimental and density functional theory analyses confirm that the optimally matched the lowest unoccupied molecular orbital of the linking unit between the photosensitizer and active unit endowed Co BOP with the highest photoelectron transfer efficiency among the three catalysts,boosting its pCO_(2)RR activity.This work is highly instructive for designing COFs with structure-adjustable and irreversible covalent bonds.
文摘Small signal equivalent circuit model and modulation properties of vertical cavity surface emitting lasers(VCSEL's) are presented.The modulation properties both in analytic equation calculation and in circuit model simulation are studied.The analytic equation calculation of the modulation properties is calculated by using Mathcad program and the circuit model simulation is simulated by using Pspice program respectively.The results of calculation and the simulation are in good agreement with each other.Experiment is performed to testify the circuit model.
基金financial support from the National Natural Science Foundation of China(Nos.61874141,11904239)Natural Science Foundation of Hunan Province(Grant Nos.2021JJ40709,2021JJ20080,2022JJ20080)+2 种基金Postgraduate Innovative Project of Central South University(Grant No.2021zzts0056)Open Sharing Found for the Large-scale Instruments and Equipment of Central South Universitysupported in part by the High Performance Computing Center of Central South University。
文摘Two-dimensional(2D)nonlinear optical mediums with high and tunable light modulation capability can significantly stimulate the development of ultrathin,compact,and integrated optoelectronics devices and photonic elements.2D carbides and nitrides of transition metals(MXenes)are a new class of 2D materials with excellent intrinsic and strong light-matter interaction characteristics.However,the current understanding of their photo-physical properties and strategies for improving optical performance is insufficient.To address this issue,we rationally designed and in situ synthesized a 2D Nb_(2)C/MoS_(2) heterostructure that outperforms pristine Nb2C in both linear and nonlinear optical performance.Excellent agreement between experimental and theoretical results demonstrated that the Nb_(2)C/MoS_(2) inherited the preponderance of Nb_(2)C and MoS_(2) in absorption at different wavelengths,resulting in the broadband enhanced optical absorption characteristics.In addition to linear optical modulation,we also achieved stronger near infrared nonlinear optical modulation,with a nonlinear absorption coefficient of Nb_(2)C/MoS_(2) being more than two times that of the pristine Nb_(2)C.These results were supported by the band alinement model which was determined by the X-ray photoelectron spectroscopy(XPS)experiment and first-principal theory calculation.The presented facile synthesis approach and robust light modulation strategy pave the way for broadband optoelectronic devices and optical modulators.
基金supported by the National Key Research and Development Program of China (Grant No. 2024YFB3211701)the National Natural Science Foundation of China (Grant Nos. T2222011, 62174026, and 12274234)+1 种基金the National Key Research and Development Program of China (Grant Nos. 2023YFB3611400 and 2019YFA0308000)the Fundamental Research Funds for the Central Universities (Grant No. 242023k30027)。
文摘The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.
基金supported by the National Key R&D Program of China(Grant No.2024YFA1408103)National Natural Science Foundation of China(Grants No.11974098,12474158,12234017 and 12488101)+3 种基金Innovation Program for Quantum Science and Technology(Grant No.2021ZD0302800)Natural Science Foundation of Hebei Province(Grant No.A202305017)Anhui Initiative in Quantum Information Technologies(Grant No.AHY170000)Fundamental Research Funds for the Central Universities(Grant No.WK2340000082)。
文摘Interlayer antiferromagnetic coupling,small magnetic anisotropy,and low air stability of the intrinsic magnetic topological insulator MnBi_(2)Te_(4)have been critical bottlenecks to the future application of the quantum anomalous Hall efect(QAHE)at zero magnetic feld.In this study,we propose a scheme to utilize capped sliding van der Waals materials to efectively modulate the magnetic and topological properties of MnBi_(2)Te_(4).Our results demonstrate that the h-BN/MnBi_(2)Te_(4)/h-BN heterostructure,constructed by sliding ferroelectric h-BN bilayer and MnBi_(2)Te_(4),not only realizes a transition from interlayer antiferromagnetic to ferromagnetic coupling but also signifcantly enhances the out-of-plane magnetism and air stability of MnBi_(2)Te_(4).Moreover,the above magnetic properties can be further improved by tuning the interlayer distance between h-BN and MnBi_(2)Te_(4).Additionally,the obtained band structures and topological properties clearly support that the h-BN/MnBi_(2)Te_(4)/hBN heterostructure can harbor the QAHE with a Chern number of C=1.This work provides a new and nonvolatile modulation approach to achieve high-temperature and high-precision QAHE at zero magnetic feld.
基金supported by National Natural Science Foundation of China(52202117,52232006,52072029,and 12102256)Collaborative Innovation Platform Project of Fu-Xia-Quan National Independent Innovation Demonstration Zone(3502ZCQXT2022005)+3 种基金Natural Science Foundation of Fujian Province of China(2022J01065)State Key Lab of Advanced Metals and Materials(2022-Z09)Fundamental Research Funds for the Central Universities(20720220075)the Ministry of Education,Singapore,under its MOE ARF Tier 2(MOE2019-T2-2-179).
文摘Efficient and flexible interactions require precisely converting human intentions into computer-recognizable signals,which is critical to the breakthrough development of metaverse.Interactive electronics face common dilemmas,which realize highprecision and stable touch detection but are rigid,bulky,and thick or achieve high flexibility to wear but lose precision.Here,we construct highly bending-insensitive,unpixelated,and waterproof epidermal interfaces(BUW epidermal interfaces)and demonstrate their interactive applications of conformal human–machine integration.The BUW epidermal interface based on the addressable electrical contact structure exhibits high-precision and stable touch detection,high flexibility,rapid response time,excellent stability,and versatile“cut-and-paste”character.Regardless of whether being flat or bent,the BUW epidermal interface can be conformally attached to the human skin for real-time,comfortable,and unrestrained interactions.This research provides promising insight into the functional composite and structural design strategies for developing epidermal electronics,which offers a new technology route and may further broaden human–machine interactions toward metaverse.
文摘Laser powder bed fusion(LPBF)combined with reaction bonding(RB)of Al particles is an effective method for preparing high-performance 3D Al_(2)O_(3) ceramic foams.However,the indistinct microstructure evolution hinders the regulation of pore features and the improvement of synthetic properties.Herein,the microstructure evolution of the Al_(2)O_(3) ceramic foams during the LPBF/RB process is clarified by various characterization methods,and the corresponding mechanical property modulation is realized by optimizing LPBF parameters,organic binder(E12 epoxy resin)content,heating rate,sintering time,and coral-like Al_(2)O_(3) content.The expansion from Al_(2)O_(3) outward growth and Al granule precipitation counteracts the shrinkage from E12 decomposition and Al_(2)O_(3) sintering,resulting in an ultra-low shrinkage of 0.94%–3.01%.The pore structures of particle packing pores,hollow spheres,and microporous structures allow a tunable porosity of 52.6%–73.7%.The in-situ formation of multi-scale features including hollow spheres,flaky grains,whiskers,nanofibers,and bond bridges brings about a remarkably high bending strength of 6.5–38.3 MPa.Ourfindings reveal the relationship between microstructure evolution and property optimization of high-performance ceramic foams,with potential significance for microstructure design and practical application.
基金support from the NSF of China(62275217)the Natural Science Basic Research Program of Shaanxi Province(2024JC-JCQN-51)the Fundamental Research Funds for the Central Universities.
文摘Stimuli-responsive materials have shown promising applications in the areas of sensing,bioimaging,information encryption,and bioinspired camouflage.In particular,multi-stimuli-responsive materials represent a hot topic due to their modulated properties under multiple stimuli.Herein,we successfully developed multi-stimuli-responsive inks and a series of complex multi-stimuli-responsive 3-dimensional(3D)structures were fabricated via digital light processing 3D-printing technology.Notably,these complex 3D structures show shape memory,fast-response photochromic and thermochromic behavior,and excellent repeatability due to the combination of photochromic molecules(4-(2,2-bis(4-fluorophenyl)vinyl)benzyl methacrylate)and thermochromic pigments.Furthermore,a programmable encrypted box that changes colors and morphology by controlling temperature and ultraviolet irradiation was designed and printed,and this encrypted box exhibits strong security using OpenCV-based image recognition technology.This strategy provides a promising approach for the design of multi-stimuli-responsive materials and complex encryption systems in the future.
基金supported by the National Natural Science Foundation of China(Nos.21773247,22275185,21521061,21875252)the Natural Science Foundation of Fujian Province(No.2006L2005).
文摘Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal POM.In this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_(2)}{[Ni_(6)Cl(μ-OH)_(3)(H_(2)O)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))][Ni_(6)(μ-OH)_(3)(H_(2)O)_(2)(Dach)_(3)(WO_(4))(PW9 O_(3)_(4))]}Cl·27H_(2)O,(1,Dach=1,2-diaminocyclohexane)was synthesized.Compounds 1 shows excellent catalytic performance in the selective oxidation of aniline to azoxybenzene(AOB)in water.The apparently different results from that with the matrix{PW_(9)O_(34)}({PW9})suggest the successful regulation of the catalytic property of{PW9}by the introduction of the{Ni6}cluster into the skeleton.The experimental results indicate that the highlighted performance of 1 is contributed by the synergy of W and Ni sites,which are respectively responsible for the oxidation and condensation steps in the production of AOB.The good selectivity to AOB is essentially attributed to the effective modulation of the reaction rates of oxidation and condensation steps by W and Ni sites,respectively.
文摘We propose a new approach for generating a multiple focal spot segment of subwavelength size, by tight focusing of a phase modulated radially polarized Laguerre Bessel Gaussian beam. The focusing properties are investigated theoretically by .vector diffraction theory. We observe that the focal segment with multiple focal structures is separated with different axial distances and a super long dark channel can be generated by properly tuning the phase of the incident radially polarized Laguerre Bessel Gaussian beam. We presume that such multiple focal patterns and high intense beam may find applications in atom optics, optical manipulations and multiple optical trapping.
基金Funded by Guangdong Natural Science Foundation (No.00355991220615019)
文摘A numerical model of thermoelectric module （TEM） is created by academic analysis,and the impacts of the resistance ratio and thermoelement size on the output power and thermoelectric efficiency of the TEM are analyzed by the MATLAB numerical calculation.The numerical model is validated by the ANSYS thermal,electrical,and structural coupling simulation.The effects of the variable physical property parameters and contact effect on the output power and thermoelectric efficiency are evaluated,and the concept of aspect ratio optimal domain is proposed,which provides a new design approach for the TEM.
基金supported by the National Key Research and Development Program of China(2023YFB3208204)the National Natural Science Foundation of China(12305400,12105352)+2 种基金the Natural Science Foundation of Shanghai,China(22ZR1470600)the Natural Science Foundation of Shandong Province(ZR2019MB068,ZR2022MB012,ZR2021QE167)the Xiangfu Lab Research Project(XF012022E0100).
文摘DNA hydrogels are three-dimensional polymer networks constructed using DNA as the structural building block.Due to the tight binding between hydrophilic groups on DNA chains and water molecules,they exhibit outstanding plasticity and fluid thermodynamic properties,making them one of the best choices for mimicking natural biological tissues.By controlling the backbone building blocks,gelation conditions,and cross-linking methods of DNA hydrogels,hydrogels with different mechanical strengths can be obtained,thus expanding their applications in the field of biology.This review first introduces the relationship between the mechanical properties of DNA hydrogels and their structure,elucidates the approaches and strategies for mechanical property modulation,and focuses on the scheme of controllable design to modulate the mechanical properties of DNA hydrogels for applications in biosensing,cellular function regulation,and bone tissue engineering.Furthermore,this review outlines the future development directions and challenges faced in the mechanical property modulation of DNA hydrogels,providing useful information for the precise design of DNA hydrogels for biological research.
基金supported by National Natural Science Foundation of China(Grant Nos.11201103 and 11471288)supported by the China Scholarship Council
文摘Instead of the L^p estimates,we study the modulation space estimates for the solution to the damped wave equation.Decay properties for both the linear and semilinear equations are obtained.The estimates in modulation space differ in many aspects from those in L^p space.
基金support from the National Natural Science Foundation of China(22002069&22302078)the Natural Science Foundation of Shandong Province,China(ZR2020QB062&ZR2022QB145).
文摘Emission enhancement of gold nanoclusters protected with 6-propyl-2-thiouracil(PRT-AuNCs)is achieved through incorporating a suitable amount of Cu^(2+).Sophisticated mechanisms are involved in the modulation of emission properties of the PRT-AuNCs/Cu^(2+)system,instead of merely a metal ion induced aggregation.
基金supported by the National Science Foundation of China(11464035)theChina Postdoctoral Science Foundation(2016M601397)+2 种基金the Jilin Science and Technology Development Plan(20180520012JH)the“13th Five-Year Plan”Science and Technology Research of Jilin Provincial Department of Education(JJKH20181120KJ)the Changchun University of Science and Technology(XQNJJ-2016-06).
文摘High pressure as an effective strategy was employed to synthesize and modulate the electrical transport properties of(Bi,Sb)_(2)Te_(3) alloys.Intrinsic point defects could be significantly regulated via high pressure,inducing a suitable donor-like effect to optimize the carrier concentration.The texture and microstructure were improved with high pressure,and a nanograin with(00l)orientation was observed in the(Bi,Sb)_(2)Te_(3) matrix,suggesting that high pressure could facilitate the recrystallization of lattice defects along the(00l)orientation.Based on the synergistic effect of high pressure on intrinsic point defects,texture,and microstructure,the carrier concentration and mobility are regularly modulated,resulting in the room-temperature power factor of the(Bi,Sb)_(2)Te_(3) alloys exhibiting a strong correlation with pressure.Hence,these important results here provide a prospective strategy in the improvement in the electrical transport properties of the Bi_(2)Te_(3)-based alloys according to the rational design of intrinsic point defects,texture,and microstructure with high pressure.
基金supported by the National Natural Science Foundation of China(No.21731002,21975104,21871172,and 21701049)the China Postdoctoral Science Foundation(2018M633272,2017M622894)and Jinan University+2 种基金support from Guangdong Basic and Applied Basic Research Foundation(2019B151502024)Guangdong Province Pearl River Scholar Funded Scheme(2019)the Fundamental Research Funds for the Central Universities(21619315).
文摘Coordination cages with a nanocavity can encapsulate various vips,which allows modulation of the physical and chemical properties of the host–vip inclusion complexes.In this work,we designed and prepared a phosphorescence Cu_(6)L_(3)trigonal prismatic cage,which accommodates a series of aromatic vip molecules.Single crystal X-ray analysis revealed that the intermolecular Cu⋯Cu distance can be mediated by changing the volume of the vips.Moreover,the host-vip charge-transfer interactions can be also fine-tuned via tailoring the ionization potential of vips.Consequently,we have observed the vip-induced photoluminescence properties change including a gradual red shift of the maximum emission peak and a linear relationship between the quantum yield and ionization potential of vips.
基金National Natural Science Foundation of China(grant no.21401130)Opening Research Fund of the State Key Laboratory of Rare Earth Resource Utilization,the Changchun Institute of Applied Chemistry,and the Chinese Academy of Sciences(RERU2014005)。
文摘The luminescence thermal quenching properties of phosphor materials have been a huge challenge for their wide application.Therefore,how to modulate the thermal quenching property of phosphor materials has become a research hotspot nowadays.The luminescence thermal quenching behavior of rare earth and transition metal ions has been widely researched in the past decades.In recent years,bismuth as a novel,nontoxic,and inexpensive activator ion has attracted much attention from researchers.However,Bi^(3+)-activated phosphors always suffer from horrible thermal quenching effects.In this contribution,many Bi^(3+)-activated phosphors with excellent antithermal quenching are summarized in detail,and four design strategies for modulating the thermal quenching properties of Bi^(3+)-activated phosphors are proposed:(1)defect engineering;(2)structural modulation;(3)lattice structure rigidity;and(4)energy transfer.In addition,the challenges and opportunities for the wide application of Bi^(3+)-activated phosphors are presented.This review provides a reference for the design and development of novel antithermal quenching Bi^(3+)-activated phosphors.
基金the Priority Academic Program Development of Jiangsu Higher Education Institutions and the National Natural Science Foundation of China(grant no.22073047)for financial support.
文摘Solid solutions offer an opportunity for modulating the structural and physical properties of materials and better understanding the origin of physical phenomena as well.Herein,two salts[R-BzPy][Ni(mnt)_(2)](R-BzPy^(+)=4-R-benzylpyridinium,substituent group R=F,Cl;mnt^(2-)=maleonitriledithiolate)and their solid solutions[F_(x)Cl_(1-x)-B_(z)P_(y)][Ni(mnt)_(2)](x=0.07-0.87)were prepared and characterized by IR.
