CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voir...CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voirs.However,the use of these gels in high-temperature CCUS applications is limited due to their rever-sible swelling behavior at elevated temperatures.In this study,a novel dispersed particle gel(DPG)suspension is developed for high-temperature profile control in CCUS applications.First,we synthesize a double-network hydrogel consisting of a crosslinked polyacrylamide(PAAm)network and a crosslinked sodium alginate(SA)network.The hydrogel is then sheared in water to form a pre-prepared DPG suspen-sion.To enhance its performance,the gel particles are modified by introducing potassium methylsilan-etriolate(PMS)upon CO_(2) exposure.Comparing the particle size distributions of the modified and pre-prepared DPG suspension reveals a significant swelling of gel particles,over twice their original size.Moreover,subjecting the new DPG suspension to a 100℃ environment for 24 h demonstrates that its gel particle sizes do not decrease,confirming irreversible swelling,which is a significant advantage over the traditional CO_(2)-responsive gels.Thermogravimetric analysis further indicates improved thermal sta-bility compared to the pre-prepared DPG particles.Core flooding experiments show that the new DPG suspension achieves a high plugging efficiency of 95.3%in plugging an ultra-high permeability sandpack,whereas the pre-prepared DPG suspension achieves only 82.8%.With its high swelling ratio,irreversible swelling at high temperatures,enhanced thermal stability,and superior plugging performance,the newly developed DPG suspension in this work presents a highly promising solution for profile control in high-temperature CCUS applications.展开更多
A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional ...A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional polymers (such as polyacrylamide) used in profile control, profile performance improvement and EOR operations in the Zhongyuan Oilfield, Sinopec. This system has been developed on the basis of the specific molecular structure and the better properties of high temperature resistance, high salinity resistance and strong shearing resistance of the new type of AP-P4 association polymer. Acidity modifying agents and cross-linking agents (MZ-YL, MZ-BE, MZ-XS), compatible with the new polymer system, are selected. Results of performance tests have shown that the new polymer system has excellent thickening, high temperature, high salinity and shearing resistance and anti-dehydrating properties. In 2003, it underwent its first pilot test in 26 wells in China, with remarkable effects in increasing oil production and decreasing water production. The newly developed polymer system and its application technology described in this paper may play a guiding role in polymer profile control operations in the oil reservoirs of high temperature and high salinity.展开更多
The precision of profile and thickness is the most important target for wide strip rolling,but the coupling of profile control and thickness control is ignored in rolling schedule,which holds down the simultaneous qua...The precision of profile and thickness is the most important target for wide strip rolling,but the coupling of profile control and thickness control is ignored in rolling schedule,which holds down the simultaneous quality improvement of profile and thickness.A cross-coupled process control model for combined shape and gauge control was developed on the basis of the fact that both controls for profile and thickness are realized by controlling the rolling gap.A dynamic decoupling controller was then proposed to decouple the model.Both the simulation results and the online production data are valid and ensure the quality of the decoupling controller.展开更多
Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatn...Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatness control models are developed for hot strip mills on the basis of large amount of finite element calculation. These models include shape setup control model in process control system, bending force feedforward control model, crown feedback control model and flatness feedback control model in basis automation system. Such a profile and flatness control system with full functions is applied in 1 700 mm industrial hot strip mills of Ansteel. Large amount of production data shows that the crown precision with the tolerance of±18 μm is over 90%, the strip percentage which the actual flatness is within ±25 I-unit surpasses 96%, and general roll consume is reduced by 28% by using the profile and fiatness control system. In addition, schedule-free rolling is realized.展开更多
Thermal-force driving of roll profile electromagnetic control technology(RPECT),which can be used to adjust the roll profile,can be affected by the sequential temperature rise between the electromagnetic stick(ES)and ...Thermal-force driving of roll profile electromagnetic control technology(RPECT),which can be used to adjust the roll profile,can be affected by the sequential temperature rise between the electromagnetic stick(ES)and electromagnetic control roll.Due to the limited space of ES and induction coil,the cross-sectional area of induction coil can be inevitably affected by changing the size of the ES induction zone,which can further change the energy input under the same electromagnetic parameters,the temperature rising effect and the bulging ability.To investigate this phenomenon,the effects of the radius of the induction zone on the thermal-force contribution ratio,the heating ability of ES and the temperature distribution were analyzed through an electromagnetic-thermal-structural finite element model.To ensure that the results are applicable to RPECT,the thermal energy conversion ability and thermal-force roll crown control ability under different lengths of the induction zone were analyzed.It was found that whether the current density regulation mode or the current frequency regulation mode is adopted,the cases with 20 or 25 mm radius of the induction zone have the great thermal energy conversion ability and the good thermal-force roll crown control ability.The reasonable adjustment of the length of the induction zone can reduce the radius required for the maximum energy efficiency regulation.Combined with the results of the simulation analysis,the optimization of ES based on the control ability maximization requirement is achieved,which provides the base for the design and configuration of ES in RPECT.展开更多
Affected by reservoir heterogeneity, there is often a serious problem of water channeling in the late stage of water injection oilfield development. Conventional water injection adjustment is difficult to further impr...Affected by reservoir heterogeneity, there is often a serious problem of water channeling in the late stage of water injection oilfield development. Conventional water injection adjustment is difficult to further improve water drive recovery. It is necessary to adopt deep profile control and displacement technology to block water channeling channel and improve water drive efficiency.Based on the analysis of deep profile control and flooding mechanism, this paper analyzes the composition, technical indexes and adaptive conditions of seven types of profile control and flooding agent formula system, and takes block J as an example to analyze the deep adjustment effect in detail, including profile control and flooding agent system, injection volume and changes of various indexes after profile control and flooding. The effect of increasing oil and controlling water is remarkable, with an efficiency of 36.148 million yuan and an input-output ratio of 1:2.81,To achieve the purpose of cost reduction and efficiency increase under low oil prices, the achievements and understanding can provide reference experience for peers.展开更多
To achieve stable rolling,the influence of a tension mechanism of a large diameter ratio roll system on the rolling process of a strip flatness electromagnetic control rolling mill is studied.Through the analysis of t...To achieve stable rolling,the influence of a tension mechanism of a large diameter ratio roll system on the rolling process of a strip flatness electromagnetic control rolling mill is studied.Through the analysis of the rolling deformation zone,the deformation zone composition form of a large diameter ratio roll system and a calculation formula of neutral angle under tension are proposed.To analyze the effect of front and post tensions on the rolling characteristic and the strip flatness control characteristic,a three-dimensional rolling finite element(FE)model of a large diameter ratio roll system with the function of roll profile electromagnetic control is established by FE software and verified by a strip flatness electromagnetic control rolling mill.Based on the model,the strip thickness characteristic,metal transverse flow,strip flatness state,and adjustment range of the loaded roll gap are analyzed for different front and post tensions setting values.The results show that changing the front or post tension setting values can improve the single-pass reduction rate of a large diameter ratio roll system and have little effect on the flatness control ability of the strip flatness electromagnetic control rolling mill.展开更多
Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings signifi...Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings significant challenges for existing profile control agents.WMEG particles were developed to address this problem.WMEG particles were synthesized via intercalation with ultrasound irradiation and chemical oxidation.The critical expansion temperature of WMEG particles is 130℃,and these particles can effectively expand 3-8 times under high temperature and high salinity water.The core flow experiments show that WMEG particles exhibit a good plugging capacity,profile control capacity,and a better-enhanced oil recovery(EOR)capacity in deep carbonate reservoirs.WMEG particles can be expanded in the formation and form larger particles that bridge the upper and lower end faces of the fracture.Then the high-permeability zones are effectively plugged,and the heterogeneity is improved,resulting in an obvious increase in oil recovery.This research provides a novel insight into future applications of profile control agents for in-depth profile control treatment in carbonate reservoirs.展开更多
Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthro...Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthrough, preferential flow channels were formed in narrow sand packs and most residual oil left in these channels was immobile. This shortened the steam breakthrough time of follow-up steam flooding and decreased the increment of oil recovery efficiency. Steam breakthrough occurred easily for a smaller producer-injector spacing, and a bigger difference in physical properties between fluids and rock. Steam breakthrough is more likely to occur at a larger formation permeability （k）, greater steam displacement velocity （u） and smaller producer-injector spacing （L）. Steam breakthrough time is a function of the parameter group （uk/L）, i.e. tb=3.2151 （uk/L）^-0.5142. A non piston-like displacement model was built based on steam breakthrough observation for a steam stimulated well in the Jinglou Oilfield, Henan Oilfield Company. The steam volume swept in different directions could be obtained from inter-well permeability capacity and breakthrough angle, and the steam swept pore volume （SSPV） was also determined. Numerical simulation showed that steam sweep efficiency reached its peak value when a slug of profile control agent （slug size 10%-15% SSPV） was set at one half of the inter-well spacing. Field test with 12.5% SSPV of profile control agents in the Jinglou Oilfield achieved success in sealing breakthrough channels and good production performance of adjacent producers.展开更多
The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and...The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and analyzed by the developed finite element models of different typical roll contours configurations.A rather smooth local work roll contour near strip edges and an increase in rolled length can be obtained by application of long stroke work roll shifting system with conventional work roll contours that is incapable of the crown control.In comparison with the conventional backup and work roll contours configuration,the crown control range by the roll bending force enhances by 12.79% and the roll gap stiffness increases by 25.26% with the developed asymmetry self-compensating work rolls(ASR) and varying contact backup rolls(VCR).A better strip profile and flatness quality,an increase in coil numbers within the rolling campaign and a significant alleviated effect of severe work roll wear contours on performance of edge drop control are achieved by the application of ASR with crown control and wear control ability in downstream stand F5 and VCR in all stands of 1 700 mm hot strip mill.展开更多
Profile requirements of silicon steel strip are extremely high and the thickness difference of cold-rolled products is usually less than 7μm,and the profile quality of hot-rolled strip is the key to ensure the thickn...Profile requirements of silicon steel strip are extremely high and the thickness difference of cold-rolled products is usually less than 7μm,and the profile quality of hot-rolled strip is the key to ensure the thickness difference of cold-rolled products.In order to produce the silicon steel strip with high-precision shape,the concept of quasi-rectangular rolling during hot continuous rolling was put forward;the equipment configuration and technical method of approximate rectangular section control were studied.Through the roughing multi-target load distribution technology and the roll configuration technology for uniform wear of a 4-high rolling mill,the strip crown of transfer bar was reduced and the profile control stability was guaranteed.Configuring variable contact back-up roll technology on all stands in the finishing rolling process,equipped with symmetry variable taper work roll and long-stroke intelligent shifting strategy in the downstream stands,and using side rolling lubrication technology can make the roll wear more uniform,reduce the edge drop of silicon steel strip,improve the profile quality,and make the strip section of finishing exit"quasi-rectangular".In addition,induction furnace and side heater were also equipped to guarantee the temperature uniformity of the strip,so as to improve the stability of profile control.The whole control technology is based on the 1580-mm hot continuous rolling production line,designed,and developed according to the characteristics of equipment and products,and has been successfully applied,which can obtain the approximate rectangular strip section satisfying the flatness quality,and improve the strip section precision of silicon steel and other products.展开更多
Donghua steel continuous casting-rolling(DSCCR)production line is an endless rolling production line independently integrated and developed by a Chinese enterprise.To solve the problem of out-of-control shape caused b...Donghua steel continuous casting-rolling(DSCCR)production line is an endless rolling production line independently integrated and developed by a Chinese enterprise.To solve the problem of out-of-control shape caused by insufficient adjustment ability of work roll bending force of DSCCR finishing mills,the backup roll contours of the finishing mill were optimized considering multi-objectives,and varying contact length backup roll(VCR)contours matching the concave work rolls were designed based on the rapid rolls-strip deformation calculation model,which integrated the elastic deformation of the rolls and the fast plastic deformation of the rolled strip.The simulation results showed that VCR configuration can significantly enhance the control efficiency of the work roll bending force and increase the transverse stiffness of rolling mill compared with the conventional roll configuration.In addition,VCR backup roll can improve the contact state between backup roll and work roll.The industrial production showed that the bending force setup value was more reasonable and the strip crown control accuracy was improved.展开更多
The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary ...The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary to treat ECR and ES surfaces.According to the heterogeneous characteristics of surface treatments,the roll profile electromagnetic control characteristics were analyzed for different parameters.An electromagnetic-thermal-force coupled axisymmetric finite element model was built to explore the differences in performance as a result of several treatment strategies,and the model was verified by experimental results measured with a roll profile electromagnetic control experimental platform.This model was used to analyze the influence of the heterogeneity of ECR inner hole and ES on the roll crown,the roll profile,the average contact pressure,and the stress state during RPECT process.The results indicate that the heterogeneous layer at ECR inner hole has a restrictive effect on RPECT and that the heterogeneous layer of ES can enhance the profile control ability of RPECT.A reasonable configuration scheme between the heterogeneity of ECR inner hole and the ES can increase the life of ECR and maintain the control ability of RPECT.展开更多
The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with ...The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with an delayed organic acid crosslinker which contains lactic acid/propionic acid/ethanoic acid and ethylene glycol. After research of the influence factors, such as pH, temperature, salinity and the dosage of delayed crosslinker, the optimum condition(pH 5.2, temperature 55℃, salinity < 7g/L) was found. Gelation time (12-144h) can be controlled by adjusting the dosage of the delayed crosslinker. Deep profile control experiments are carried out on heterogeneous models, which contains three serial high permeable and low permeable cores arranged in a parallel. After water flooding (total recovery, 24.3%), the first, second and third high-permeable cores each are sealed in turn by the profile control agent, and the total displacement recovery increases to 46.8%, 62.2% and 69.1% respectively. So, the greater the sealed depth, the larger the enhancing recovery will be. Finally, the oil displacement mechanisms of deep profile control are discussed.展开更多
Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced con...Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced conformance efficiency and affected de-velopment response.Therefore,the research on profile control and water shut-off agents becomes increasingly important for thermal recovery wells.The requirements on the performances of profile control and water shut-off agents are discussed in conjunction with the physical properties of heavy oil reservoirs and the technical conditions of steam injection in China.Based on the mechanism of action,research progress and application status,5 agents are summarized including polymer gel,solid particles plugging agent,foam,water-in-oil emulsion and salt precipitation.Problems in each agent are mentioned,and optimization solutions are put for-ward.At last,the development trend of future profile control and water shut-off agents is put forward,i.e.synthesizing agents of low cost and high-temperature resistance,intensifying mechanism research,developing composite system,and researching on new technologies that are less harmful and environmental friendly.展开更多
Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control...Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control and flooding measures).Therefore,in this study,a novel method based on“plugging,profile control,and flooding”being implemented at the same time is proposed.To assess the performances of this approach,physical simulations,computer tomography,and nuclear magnetic resonance are used.The results show that the combination of a gel plugging agent,a polymer microsphere flooding agent,and a high-efficiency oil displacement agent leads to better results in terms of oil recovery with respect to the situation in which these approaches are used separately(the oil recovery is increased by 15.37%).Computer tomography scan results show that with the combined approach,a larger sweep volume and higher oil washing efficiency are obtained.The remaining oil in the cluster form can be recovered in the middle and low permeability layer,increasing the proportion of the columnar and blind end states of the oil.The nuclear magnetic resonance test results show that the combined“plugging,profile control,and flooding”treatment can also be used to control more effectively the dominant channels of the high permeability layer and further expand the recovery degree of the remaining oil in the pores of different sizes in the middle and low permeability layers.However,for the low permeability layer(permeability difference of 20),the benefits in terms of oil recovery are limited.展开更多
Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recov...Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recovery and is already present in production fluids. In order to detect polyacrylamide microspheres in the reservoir pro- duced fluid, fluorescent polyacrylamide microspheres P（AM-BA-AMCO）, which fluoresce under ultraviolet irradiation, were synthesized via an inverse suspension polymerization. In order to keep the particle size distribu- tion in a narrow range, the synthesis conditions of the polymerization were studied, including the stirring speed and the concentrations of initiator, NaaCO3, and dispersant. The bonding characteristics of microspheres were deter- mined by Fourier transform infrared spectroscopy. The surface morphology of these microspheres was observed under ultraviolet irradiation with an inverse fluorescence microscope. A laboratory evaluation test showed that the fluorescent polymer microspheres had good water swelling capability, thus they had the ability to plug and migrate in a sand pack. The plugging rate was 99.8 % and the residual resistance coefficient was 800 after microsphere treatment in the sand pack. Furthermore, the fluorescent microspheres and their fragments were accurately detected under ultra- violet irradiation in the produced fluid, even though theyhad experienced extrusion and deformation in the sand pack.展开更多
Profile control is utilized to redirect the injection water to low permeability region where a large amount of crude oil lies.Performed gel particles are the commonly used agent for redistributing water by blocking th...Profile control is utilized to redirect the injection water to low permeability region where a large amount of crude oil lies.Performed gel particles are the commonly used agent for redistributing water by blocking the pores in high permeability region.But the capability of deep penetration of performed gel particles is poor.Here,we formulate nanoparticle stabilized emulsion(NSE).The stability and the effect of NSE on the fluid redirection in a three-dimensional porous medium were investigated.By usingμ-PIV(particle image velocimetry),it was found that the velocity gradient of continuous fluid close to the nanoparticle stabilized droplets is much higher than that close to surfactant stabilized droplets.NSE behaves as solid particle in preferential seepage channels,which will decrease effectively the permeability,thereby redirecting the subsequent injection water.Furthermore,NSE shows high stability compared with emulsion stabilized by surfactant in static and dynamic tests.In addition,water flooding tests also confirm that the NSE can significantly reduce the permeability of porous media and redirect the fluid flow.Our results demonstrate NSE owns high potential to act as profile control agent in deep formation.展开更多
A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a de...A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a density of 1.08 g/cm^3, and mainly contains over 65% of light CaCO3, MgCO3, CaSO4, Fe2S3 and Ca（OH）2. This paper ascertains the effect of water treatment residue on core permeability and its application in oilfields. Coreflooding tests in laboratory were conducted in two artificial cores and one natural core. Core changes were evaluated by cast model image analysis, mercury injection method and scanning electron microscopy （SEM）. Fresh water was injected into another natural core, which was plugged with water treatment residue, to determine the effective life. The results indicate that the water treatment residue has a strongly plugging capability, a resistance to erosion and a long effective life, and thus it can be used as a cheap raw material for profile control. In the past 8 years, a total of 60,164 m^3 of water treatment residue has been used for profile control of 151 well treatments, with a success ratio of 98% and an effective ratio of 83.2%. In the field tests, the profile control agent increased both starting pressure and injection pressure of injectors, and decreased the apparent water injectivity coefficient, significantly improving intake profiles and lengthening average service life of injectors. 28,381 tons of additional oil were recovered from these corresponding oil wells, with economic benefits of ￥3,069.55×10^4 （RMB） and a remarkable input-output ratio of 8.6：1.展开更多
After steam discharge in heavy oil reservoirs,the distribution of temperature,pressure,and permeability in different wells becomes irregular.Flow channels can easily be produced,which affect the sweep efficiency of th...After steam discharge in heavy oil reservoirs,the distribution of temperature,pressure,and permeability in different wells becomes irregular.Flow channels can easily be produced,which affect the sweep efficiency of the oil displacement.Previous studies have shown that the salting-out plugging method can effectively block these channels in high-temperature reservoirs,improve the suction profile,and increase oil production.In the present study,the optimal dosage of the plugging agent is determined taking into account connection transmissibility and inter-well volumes.Together with the connectivity model,a water flooding simulation model is introduced.Moreover,a non-gradient stochastic disturbance algorithm is used to obtain the optimal plugging agent dosage,which provides the basis for the high-temperature salting-out plugging agent adjustment in the field.展开更多
基金Lin Du acknowledges the financial support provided by China Scholarship Council(CSC)via a Ph.D.Scholarship(202008510128)supported by Core Technology Project of China National Petroleum Corporation(CNPC)"Research on Thermal Miscible Flooding Technology"(2023ZG18)。
文摘CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voirs.However,the use of these gels in high-temperature CCUS applications is limited due to their rever-sible swelling behavior at elevated temperatures.In this study,a novel dispersed particle gel(DPG)suspension is developed for high-temperature profile control in CCUS applications.First,we synthesize a double-network hydrogel consisting of a crosslinked polyacrylamide(PAAm)network and a crosslinked sodium alginate(SA)network.The hydrogel is then sheared in water to form a pre-prepared DPG suspen-sion.To enhance its performance,the gel particles are modified by introducing potassium methylsilan-etriolate(PMS)upon CO_(2) exposure.Comparing the particle size distributions of the modified and pre-prepared DPG suspension reveals a significant swelling of gel particles,over twice their original size.Moreover,subjecting the new DPG suspension to a 100℃ environment for 24 h demonstrates that its gel particle sizes do not decrease,confirming irreversible swelling,which is a significant advantage over the traditional CO_(2)-responsive gels.Thermogravimetric analysis further indicates improved thermal sta-bility compared to the pre-prepared DPG particles.Core flooding experiments show that the new DPG suspension achieves a high plugging efficiency of 95.3%in plugging an ultra-high permeability sandpack,whereas the pre-prepared DPG suspension achieves only 82.8%.With its high swelling ratio,irreversible swelling at high temperatures,enhanced thermal stability,and superior plugging performance,the newly developed DPG suspension in this work presents a highly promising solution for profile control in high-temperature CCUS applications.
文摘A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional polymers (such as polyacrylamide) used in profile control, profile performance improvement and EOR operations in the Zhongyuan Oilfield, Sinopec. This system has been developed on the basis of the specific molecular structure and the better properties of high temperature resistance, high salinity resistance and strong shearing resistance of the new type of AP-P4 association polymer. Acidity modifying agents and cross-linking agents (MZ-YL, MZ-BE, MZ-XS), compatible with the new polymer system, are selected. Results of performance tests have shown that the new polymer system has excellent thickening, high temperature, high salinity and shearing resistance and anti-dehydrating properties. In 2003, it underwent its first pilot test in 26 wells in China, with remarkable effects in increasing oil production and decreasing water production. The newly developed polymer system and its application technology described in this paper may play a guiding role in polymer profile control operations in the oil reservoirs of high temperature and high salinity.
基金Item Sponsored by National Significant Technical Equipment Research and Development Project of 10th Five-Year-Plan of China(ZZ02-13B-03-03)
文摘The precision of profile and thickness is the most important target for wide strip rolling,but the coupling of profile control and thickness control is ignored in rolling schedule,which holds down the simultaneous quality improvement of profile and thickness.A cross-coupled process control model for combined shape and gauge control was developed on the basis of the fact that both controls for profile and thickness are realized by controlling the rolling gap.A dynamic decoupling controller was then proposed to decouple the model.Both the simulation results and the online production data are valid and ensure the quality of the decoupling controller.
基金National Key Scientific Technological Project of the Ninth Five-year of China(No.97-316-01-01)
文摘Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatness control models are developed for hot strip mills on the basis of large amount of finite element calculation. These models include shape setup control model in process control system, bending force feedforward control model, crown feedback control model and flatness feedback control model in basis automation system. Such a profile and flatness control system with full functions is applied in 1 700 mm industrial hot strip mills of Ansteel. Large amount of production data shows that the crown precision with the tolerance of±18 μm is over 90%, the strip percentage which the actual flatness is within ±25 I-unit surpasses 96%, and general roll consume is reduced by 28% by using the profile and fiatness control system. In addition, schedule-free rolling is realized.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.U1560206 and 51975510)the Natural Science Foundation of China in Hebei Province(Grant No.E2021203129).
文摘Thermal-force driving of roll profile electromagnetic control technology(RPECT),which can be used to adjust the roll profile,can be affected by the sequential temperature rise between the electromagnetic stick(ES)and electromagnetic control roll.Due to the limited space of ES and induction coil,the cross-sectional area of induction coil can be inevitably affected by changing the size of the ES induction zone,which can further change the energy input under the same electromagnetic parameters,the temperature rising effect and the bulging ability.To investigate this phenomenon,the effects of the radius of the induction zone on the thermal-force contribution ratio,the heating ability of ES and the temperature distribution were analyzed through an electromagnetic-thermal-structural finite element model.To ensure that the results are applicable to RPECT,the thermal energy conversion ability and thermal-force roll crown control ability under different lengths of the induction zone were analyzed.It was found that whether the current density regulation mode or the current frequency regulation mode is adopted,the cases with 20 or 25 mm radius of the induction zone have the great thermal energy conversion ability and the good thermal-force roll crown control ability.The reasonable adjustment of the length of the induction zone can reduce the radius required for the maximum energy efficiency regulation.Combined with the results of the simulation analysis,the optimization of ES based on the control ability maximization requirement is achieved,which provides the base for the design and configuration of ES in RPECT.
文摘Affected by reservoir heterogeneity, there is often a serious problem of water channeling in the late stage of water injection oilfield development. Conventional water injection adjustment is difficult to further improve water drive recovery. It is necessary to adopt deep profile control and displacement technology to block water channeling channel and improve water drive efficiency.Based on the analysis of deep profile control and flooding mechanism, this paper analyzes the composition, technical indexes and adaptive conditions of seven types of profile control and flooding agent formula system, and takes block J as an example to analyze the deep adjustment effect in detail, including profile control and flooding agent system, injection volume and changes of various indexes after profile control and flooding. The effect of increasing oil and controlling water is remarkable, with an efficiency of 36.148 million yuan and an input-output ratio of 1:2.81,To achieve the purpose of cost reduction and efficiency increase under low oil prices, the achievements and understanding can provide reference experience for peers.
基金supported by the Natural Science Foundation of Hebei Province of China(Grant No.E2021203129).
文摘To achieve stable rolling,the influence of a tension mechanism of a large diameter ratio roll system on the rolling process of a strip flatness electromagnetic control rolling mill is studied.Through the analysis of the rolling deformation zone,the deformation zone composition form of a large diameter ratio roll system and a calculation formula of neutral angle under tension are proposed.To analyze the effect of front and post tensions on the rolling characteristic and the strip flatness control characteristic,a three-dimensional rolling finite element(FE)model of a large diameter ratio roll system with the function of roll profile electromagnetic control is established by FE software and verified by a strip flatness electromagnetic control rolling mill.Based on the model,the strip thickness characteristic,metal transverse flow,strip flatness state,and adjustment range of the loaded roll gap are analyzed for different front and post tensions setting values.The results show that changing the front or post tension setting values can improve the single-pass reduction rate of a large diameter ratio roll system and have little effect on the flatness control ability of the strip flatness electromagnetic control rolling mill.
基金financially supported by the National Natural Science Foundation of China(No.52074335)China University of Petroleum(East China)Independent Innovation Research Program:Oilfield Chemistry and Enhanced Oil Recovery(27RA2302015)+1 种基金Innovation Fund Project for Graduate Student of China University of Petroleum(East China)the Fundamental Research Funds for the Central Universities(No.24CX04003A)。
文摘Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings significant challenges for existing profile control agents.WMEG particles were developed to address this problem.WMEG particles were synthesized via intercalation with ultrasound irradiation and chemical oxidation.The critical expansion temperature of WMEG particles is 130℃,and these particles can effectively expand 3-8 times under high temperature and high salinity water.The core flow experiments show that WMEG particles exhibit a good plugging capacity,profile control capacity,and a better-enhanced oil recovery(EOR)capacity in deep carbonate reservoirs.WMEG particles can be expanded in the formation and form larger particles that bridge the upper and lower end faces of the fracture.Then the high-permeability zones are effectively plugged,and the heterogeneity is improved,resulting in an obvious increase in oil recovery.This research provides a novel insight into future applications of profile control agents for in-depth profile control treatment in carbonate reservoirs.
文摘Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthrough, preferential flow channels were formed in narrow sand packs and most residual oil left in these channels was immobile. This shortened the steam breakthrough time of follow-up steam flooding and decreased the increment of oil recovery efficiency. Steam breakthrough occurred easily for a smaller producer-injector spacing, and a bigger difference in physical properties between fluids and rock. Steam breakthrough is more likely to occur at a larger formation permeability （k）, greater steam displacement velocity （u） and smaller producer-injector spacing （L）. Steam breakthrough time is a function of the parameter group （uk/L）, i.e. tb=3.2151 （uk/L）^-0.5142. A non piston-like displacement model was built based on steam breakthrough observation for a steam stimulated well in the Jinglou Oilfield, Henan Oilfield Company. The steam volume swept in different directions could be obtained from inter-well permeability capacity and breakthrough angle, and the steam swept pore volume （SSPV） was also determined. Numerical simulation showed that steam sweep efficiency reached its peak value when a slug of profile control agent （slug size 10%-15% SSPV） was set at one half of the inter-well spacing. Field test with 12.5% SSPV of profile control agents in the Jinglou Oilfield achieved success in sealing breakthrough channels and good production performance of adjacent producers.
基金Project(20040311890) supported by the Science and Technology Development Foundation of University of Science and Technology Beijing
文摘The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and analyzed by the developed finite element models of different typical roll contours configurations.A rather smooth local work roll contour near strip edges and an increase in rolled length can be obtained by application of long stroke work roll shifting system with conventional work roll contours that is incapable of the crown control.In comparison with the conventional backup and work roll contours configuration,the crown control range by the roll bending force enhances by 12.79% and the roll gap stiffness increases by 25.26% with the developed asymmetry self-compensating work rolls(ASR) and varying contact backup rolls(VCR).A better strip profile and flatness quality,an increase in coil numbers within the rolling campaign and a significant alleviated effect of severe work roll wear contours on performance of edge drop control are achieved by the application of ASR with crown control and wear control ability in downstream stand F5 and VCR in all stands of 1 700 mm hot strip mill.
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.51975043)Fundamental Research Funds for the Central Universities(Grant No.FRF-TP-19-002A3)Beijing Natural Science Foundation(3182026)for the support to this research.
文摘Profile requirements of silicon steel strip are extremely high and the thickness difference of cold-rolled products is usually less than 7μm,and the profile quality of hot-rolled strip is the key to ensure the thickness difference of cold-rolled products.In order to produce the silicon steel strip with high-precision shape,the concept of quasi-rectangular rolling during hot continuous rolling was put forward;the equipment configuration and technical method of approximate rectangular section control were studied.Through the roughing multi-target load distribution technology and the roll configuration technology for uniform wear of a 4-high rolling mill,the strip crown of transfer bar was reduced and the profile control stability was guaranteed.Configuring variable contact back-up roll technology on all stands in the finishing rolling process,equipped with symmetry variable taper work roll and long-stroke intelligent shifting strategy in the downstream stands,and using side rolling lubrication technology can make the roll wear more uniform,reduce the edge drop of silicon steel strip,improve the profile quality,and make the strip section of finishing exit"quasi-rectangular".In addition,induction furnace and side heater were also equipped to guarantee the temperature uniformity of the strip,so as to improve the stability of profile control.The whole control technology is based on the 1580-mm hot continuous rolling production line,designed,and developed according to the characteristics of equipment and products,and has been successfully applied,which can obtain the approximate rectangular strip section satisfying the flatness quality,and improve the strip section precision of silicon steel and other products.
基金This work was financially supported by the National Natural Science Foundation of China(51774139)the Natural Science Foundation of Hebei Province(E2020209014).
文摘Donghua steel continuous casting-rolling(DSCCR)production line is an endless rolling production line independently integrated and developed by a Chinese enterprise.To solve the problem of out-of-control shape caused by insufficient adjustment ability of work roll bending force of DSCCR finishing mills,the backup roll contours of the finishing mill were optimized considering multi-objectives,and varying contact length backup roll(VCR)contours matching the concave work rolls were designed based on the rapid rolls-strip deformation calculation model,which integrated the elastic deformation of the rolls and the fast plastic deformation of the rolled strip.The simulation results showed that VCR configuration can significantly enhance the control efficiency of the work roll bending force and increase the transverse stiffness of rolling mill compared with the conventional roll configuration.In addition,VCR backup roll can improve the contact state between backup roll and work roll.The industrial production showed that the bending force setup value was more reasonable and the strip crown control accuracy was improved.
基金This project is supported by the National Natural Science Foundation of China(Grant Nos.U1560206 and 51975510).
文摘The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary to treat ECR and ES surfaces.According to the heterogeneous characteristics of surface treatments,the roll profile electromagnetic control characteristics were analyzed for different parameters.An electromagnetic-thermal-force coupled axisymmetric finite element model was built to explore the differences in performance as a result of several treatment strategies,and the model was verified by experimental results measured with a roll profile electromagnetic control experimental platform.This model was used to analyze the influence of the heterogeneity of ECR inner hole and ES on the roll crown,the roll profile,the average contact pressure,and the stress state during RPECT process.The results indicate that the heterogeneous layer at ECR inner hole has a restrictive effect on RPECT and that the heterogeneous layer of ES can enhance the profile control ability of RPECT.A reasonable configuration scheme between the heterogeneity of ECR inner hole and the ES can increase the life of ECR and maintain the control ability of RPECT.
文摘The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with an delayed organic acid crosslinker which contains lactic acid/propionic acid/ethanoic acid and ethylene glycol. After research of the influence factors, such as pH, temperature, salinity and the dosage of delayed crosslinker, the optimum condition(pH 5.2, temperature 55℃, salinity < 7g/L) was found. Gelation time (12-144h) can be controlled by adjusting the dosage of the delayed crosslinker. Deep profile control experiments are carried out on heterogeneous models, which contains three serial high permeable and low permeable cores arranged in a parallel. After water flooding (total recovery, 24.3%), the first, second and third high-permeable cores each are sealed in turn by the profile control agent, and the total displacement recovery increases to 46.8%, 62.2% and 69.1% respectively. So, the greater the sealed depth, the larger the enhancing recovery will be. Finally, the oil displacement mechanisms of deep profile control are discussed.
文摘Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced conformance efficiency and affected de-velopment response.Therefore,the research on profile control and water shut-off agents becomes increasingly important for thermal recovery wells.The requirements on the performances of profile control and water shut-off agents are discussed in conjunction with the physical properties of heavy oil reservoirs and the technical conditions of steam injection in China.Based on the mechanism of action,research progress and application status,5 agents are summarized including polymer gel,solid particles plugging agent,foam,water-in-oil emulsion and salt precipitation.Problems in each agent are mentioned,and optimization solutions are put for-ward.At last,the development trend of future profile control and water shut-off agents is put forward,i.e.synthesizing agents of low cost and high-temperature resistance,intensifying mechanism research,developing composite system,and researching on new technologies that are less harmful and environmental friendly.
基金The authors gratefully acknowledge the financial support from the National Science and Technology Major Special Project(2016ZX05058-003).
文摘Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control and flooding measures).Therefore,in this study,a novel method based on“plugging,profile control,and flooding”being implemented at the same time is proposed.To assess the performances of this approach,physical simulations,computer tomography,and nuclear magnetic resonance are used.The results show that the combination of a gel plugging agent,a polymer microsphere flooding agent,and a high-efficiency oil displacement agent leads to better results in terms of oil recovery with respect to the situation in which these approaches are used separately(the oil recovery is increased by 15.37%).Computer tomography scan results show that with the combined approach,a larger sweep volume and higher oil washing efficiency are obtained.The remaining oil in the cluster form can be recovered in the middle and low permeability layer,increasing the proportion of the columnar and blind end states of the oil.The nuclear magnetic resonance test results show that the combined“plugging,profile control,and flooding”treatment can also be used to control more effectively the dominant channels of the high permeability layer and further expand the recovery degree of the remaining oil in the pores of different sizes in the middle and low permeability layers.However,for the low permeability layer(permeability difference of 20),the benefits in terms of oil recovery are limited.
基金supported by the National Natural Science Foundation of China (No.21273286)Doctoral Program Foundation of the Education Ministry (No.20130133110005)
文摘Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recovery and is already present in production fluids. In order to detect polyacrylamide microspheres in the reservoir pro- duced fluid, fluorescent polyacrylamide microspheres P（AM-BA-AMCO）, which fluoresce under ultraviolet irradiation, were synthesized via an inverse suspension polymerization. In order to keep the particle size distribu- tion in a narrow range, the synthesis conditions of the polymerization were studied, including the stirring speed and the concentrations of initiator, NaaCO3, and dispersant. The bonding characteristics of microspheres were deter- mined by Fourier transform infrared spectroscopy. The surface morphology of these microspheres was observed under ultraviolet irradiation with an inverse fluorescence microscope. A laboratory evaluation test showed that the fluorescent polymer microspheres had good water swelling capability, thus they had the ability to plug and migrate in a sand pack. The plugging rate was 99.8 % and the residual resistance coefficient was 800 after microsphere treatment in the sand pack. Furthermore, the fluorescent microspheres and their fragments were accurately detected under ultra- violet irradiation in the produced fluid, even though theyhad experienced extrusion and deformation in the sand pack.
基金supported by the National Natural Science Foundation of China(U1663206,51704313)the Taishan Scholar Climbing Program in Shandong Province(tspd20161004)the Fundamental Research Funds for the Central Universities(18CX02028A)
文摘Profile control is utilized to redirect the injection water to low permeability region where a large amount of crude oil lies.Performed gel particles are the commonly used agent for redistributing water by blocking the pores in high permeability region.But the capability of deep penetration of performed gel particles is poor.Here,we formulate nanoparticle stabilized emulsion(NSE).The stability and the effect of NSE on the fluid redirection in a three-dimensional porous medium were investigated.By usingμ-PIV(particle image velocimetry),it was found that the velocity gradient of continuous fluid close to the nanoparticle stabilized droplets is much higher than that close to surfactant stabilized droplets.NSE behaves as solid particle in preferential seepage channels,which will decrease effectively the permeability,thereby redirecting the subsequent injection water.Furthermore,NSE shows high stability compared with emulsion stabilized by surfactant in static and dynamic tests.In addition,water flooding tests also confirm that the NSE can significantly reduce the permeability of porous media and redirect the fluid flow.Our results demonstrate NSE owns high potential to act as profile control agent in deep formation.
文摘A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a density of 1.08 g/cm^3, and mainly contains over 65% of light CaCO3, MgCO3, CaSO4, Fe2S3 and Ca（OH）2. This paper ascertains the effect of water treatment residue on core permeability and its application in oilfields. Coreflooding tests in laboratory were conducted in two artificial cores and one natural core. Core changes were evaluated by cast model image analysis, mercury injection method and scanning electron microscopy （SEM）. Fresh water was injected into another natural core, which was plugged with water treatment residue, to determine the effective life. The results indicate that the water treatment residue has a strongly plugging capability, a resistance to erosion and a long effective life, and thus it can be used as a cheap raw material for profile control. In the past 8 years, a total of 60,164 m^3 of water treatment residue has been used for profile control of 151 well treatments, with a success ratio of 98% and an effective ratio of 83.2%. In the field tests, the profile control agent increased both starting pressure and injection pressure of injectors, and decreased the apparent water injectivity coefficient, significantly improving intake profiles and lengthening average service life of injectors. 28,381 tons of additional oil were recovered from these corresponding oil wells, with economic benefits of ￥3,069.55×10^4 （RMB） and a remarkable input-output ratio of 8.6：1.
基金supported by China Postdoctoral Science Foundation(No.2021M702304)Shandong Provincial Natural Science Foundation Youth Fund(No.ZR2021QE260).
文摘After steam discharge in heavy oil reservoirs,the distribution of temperature,pressure,and permeability in different wells becomes irregular.Flow channels can easily be produced,which affect the sweep efficiency of the oil displacement.Previous studies have shown that the salting-out plugging method can effectively block these channels in high-temperature reservoirs,improve the suction profile,and increase oil production.In the present study,the optimal dosage of the plugging agent is determined taking into account connection transmissibility and inter-well volumes.Together with the connectivity model,a water flooding simulation model is introduced.Moreover,a non-gradient stochastic disturbance algorithm is used to obtain the optimal plugging agent dosage,which provides the basis for the high-temperature salting-out plugging agent adjustment in the field.
