Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeratio...Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeration characteristics of siderite particles after argon(Ar)plasma surface modification through settling tests,flocs size measurements,and fractal dimension calculations.Ar plasma surface modification promotes the agglomeration of siderite particles,as evidenced by increased floc size and density.The agglomeration mechanism induced by Ar plasma surface modification is evaluated using a theoretical model combining the surface element integration(SEI)approach,differential geometry,and the composite Simpson's rule.Changes in surface roughness,wettability,and charge are considered in this model.Compared to the unpretreated siderite particles,the energy barrier for interaction of the 30-min Ar plasma-pretreated siderite particles decreases from 2.3×10-^(17)J to 1.6×10^(-17)J.This reduction provides strong evidence for the agglomeration behavior of siderite particles.Furthermore,flotation experiments confirm that Ar plasma surface modification is conducive to the aggregation flotation of siderite.These findings offer crucial insights into particle aggregation and dispersion behaviors,with notable application in mineral flotation.展开更多
In this study, the influence of fluid cracking catalyst(FCC) on the fluidization behavior of ZnO-CuO binary nanoparticles was systematically investigated by varying FCC size. High-speed camera was employed to analyze ...In this study, the influence of fluid cracking catalyst(FCC) on the fluidization behavior of ZnO-CuO binary nanoparticles was systematically investigated by varying FCC size. High-speed camera was employed to analyze the collision and fragmentation process of agglomerates with adding FCC coarse particles. It can be found from photographs by the camera that fluidization performance improved by the agglomerate variation that is bound to be shaped a compact and spherical structure. Furthermore, the result of agglomeration composition analysis showed that uniform mixing of nanoparticles remarkably affected the fluidization behavior of ZnO-CuO binary system. Finally, the improvement of fluidization performance can be justified by the analysis of inter-cohesive force between the two agglomerates with sharp reduction of the newly-formed agglomerates.展开更多
Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturin...Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturing operations.The commonly used TPA mainly includes hard particles,fibers,gels,and composite systems.However,current particles have many limitations in applications,such as insufficient plugging strength and slow degradation rate.In this paper,a degradable pre-formed particle gel(DPPG)was developed.Experimental results show that the DPPG has an excellent static swelling effect and self-degradation performance.With a decrease in the concentration of total monomers or cross-linker,the swelling volume of the synthesized DPPG gradually increases.However,the entire self-degradation time gradually decreases.The increase in 2-acrylamide-2-methylpropanesulfonic acid(AMPS)in the DPPG composition can significantly increase its swelling ratio and shorten the self-degradation time.Moreover,DPPG has excellent high-temperature resistance(150°C)and high-salinity resistance(200,000 mg/L NaCl).Core displacement results show that the DPPG has a perfect plugging effect in the porous media(the plugging pressure gradient was as high as 21.12 MPa),and the damage to the formation after degradation is incredibly minor.Therefore,the DPPG can be used as an up-and-coming TPA in oil fields.展开更多
The Williamson-Hall and uniaxial compression methods were used to study the variations of the micro-strain and stress-strain relations in WC powders after jet milling and ball milling, respectively. The rupture behavi...The Williamson-Hall and uniaxial compression methods were used to study the variations of the micro-strain and stress-strain relations in WC powders after jet milling and ball milling, respectively. The rupture behavior of agglomerates in WC powders was investigated. Meanwhile, the as-obtained WC powders treated by different milling methods were used to fabricate WC-10%Co cemented carbides, followed by the performance assessment of cemented carbides. The results show that the micro-strain of the jet-milled WC powders decreases significantly compared with that of the ball-milled WC powders, and that the cemented carbides prepared by jet-milled WC powders exhibit excellent properties with a transverse-rupture strength of 4260 MPa, due to the elimination of agglomerates and the reduction of lattice strain.展开更多
The cohesive solids in liquid flows are featured by the dynamic growth and breakage of agglomerates, and the difficulties in the development, design and optimization of these systems are related to this significant fe...The cohesive solids in liquid flows are featured by the dynamic growth and breakage of agglomerates, and the difficulties in the development, design and optimization of these systems are related to this significant feature.In this paper, discrete particle method is used to simulate a solid–liquid flow system including millions of cohesive particles, the growth rate and breakage rate of agglomerates are then systematically investigated. It was found that the most probable size of the agglomerates is determined by the balance of growth and breakage of the agglomerates the cross point of the lines of growth rate and breakage rate as a function of the particle numbers in an agglomerate, marks the most stable agglomerate size. The finding here provides a feasible way to quantify the dynamic behaviors of growth and breakage of agglomerates, and therefore offers the possibility of quantifying the effects of agglomerates on the hydrodynamics of fluid flows with cohesive particles.展开更多
Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,...Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,the evolution behavior and mechanism of different reactive ICA under simulated BF smelting conditions were studied.The results show that the existence of more sillimanite and aluminosilicate and less active sites of metallic iron will weaken gasification reaction and carburization ability of ICA-1(containing 10%iron ore).It weakens the promoting effect of ICA-1 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron.The aluminosilicate with a high melting point decreases,the low melting point slag phase and Fe–Si alloy increase,and many active sites of metallic iron exist,which strengthen the gasification reaction and carburization ability of ICA-2(containing 30%iron ore).The promoting effect of ICA-2 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron is significantly improved.The gasification reaction capacity of ICA-3(containing 35%iron ore)is reduced,and the improvement in ICA-3 on the softening–melting performance of mixed burdens is reduced.The appropriate proportion of iron ore in ICA is about 30%.展开更多
The flow pattern and hydrodynamics of a heterogeneous permeable agglomerate in a uniform upward flow at intermediate Reynolds numbers(1–40)are analyzed from three-dimensional(3 D)computational fluid dynamics simulati...The flow pattern and hydrodynamics of a heterogeneous permeable agglomerate in a uniform upward flow at intermediate Reynolds numbers(1–40)are analyzed from three-dimensional(3 D)computational fluid dynamics simulations.Different from the homogeneous or stepwise-varying permeability models used in previous papers,a continuously radially varying permeability model is used in the present study.The effects of two dimensionless parameters,the Reynolds number and the permeability ratio,on the flow field and the hydrodynamics were investigated in detail.The results reveal that unlike the solid sphere,a small recirculating wake initially forms inside the agglomerate.The critical Reynolds number for the formation of the recirculating wake is lower than that of the solid sphere and it decreases with the increase of permeability ratio.A correlation of drag coefficient as a function of the Reynolds number and permeability ratio is proposed.Comparisons of drag coefficients obtained by different permeability models show that at intermediate Reynolds numbers(1–40),the effect of radially varying permeability on the drag coefficient must be considered.展开更多
An intensive study of the particle size distribution of four commercial ultrafine alumina powders to obtain information about the powder agglomeration and relate them to the compactibility and the sinterability has be...An intensive study of the particle size distribution of four commercial ultrafine alumina powders to obtain information about the powder agglomeration and relate them to the compactibility and the sinterability has been made.展开更多
The density of black regranulate (BR) of cork and of black agglomerate (BA) and composite agglomerate (CA) prepared fromsuch a waste by different methods was investigated. The preparation of the agglomerates was under...The density of black regranulate (BR) of cork and of black agglomerate (BA) and composite agglomerate (CA) prepared fromsuch a waste by different methods was investigated. The preparation of the agglomerates was undertaken by controlling thespecimen thickness for BA and the particle size for BR and the binder dosage for CA. The mass changes produced in theoven-drying treatment at 376.15 K of the agglomerates and in their subsequent stabilization under ambient conditions werealso analyzed. The density was determined by standard methods. For BR, the bulk density first decreased and then increasedwith decreasing particle size. It was much lower than the apparent density of the agglomeration products of cork. Although toa lesser extent, the density was also lower for BA than for CA. It was higher for the smaller thickness specimens of BA. In thecase of CA, the density followed the same variation trends as for BR. Furthermore it increased significantly with the increasein resin dosage. This resulted in a noticeable increase in the weight loss during the oven-drying and in a significant decreasein the degree of moisture adsorption during the stabilization period of the agglomerate.展开更多
Agglomerates formed in the fluidized bed were studied in this paper using the TEB atomization nozzle. The multi-sieving method was adopted to distinguish the size of original particles, nucleation agglomerates, cohere...Agglomerates formed in the fluidized bed were studied in this paper using the TEB atomization nozzle. The multi-sieving method was adopted to distinguish the size of original particles, nucleation agglomerates, coherence agglomerates, and paste agglomerates in order to successfully identify the different growth stages and select the region for coexistence of most stable heterogeneous agglomerates as the research object. A multi-channel conductance electrical circuit experimental device was developed in this study to measure the conductance signal, which was found to have a liner relationship with the moisture content inside the fluidized bed. By adjusting the sieve mesh openings to achieve the layered isolation of heterogeneous agglomerates, the conductance signal recovered slowly as a result of the agglomerates' fracture during the continuous fluidization process, so that particles and agglomerates moisture distribution measurements could be implemented. The device was used to measure the particles and agglomerates moisture distribution state in the heterogeneous coexistence region, when they were injected with liquid mass within the range of w i=2.8 kg to 4.4 kg. The results indicated that with the increase of liquid mass flow, the moisture content of coherence agglomerates also increased, but the moisture content of nucleation agglomerates was decreased, and that of the original particles was maintained at a relatively low level. When the experimental injection amount reached 4.4 kg, the moisture contained in coherence agglomerates could amount to 87.3%, accounting for a big percentage of moisture in the fluidized bed.展开更多
Based on the theoretical analyses, the adhesion process of fine gold particles to oil-carbon agglomerates in a dynamic system was quantitatively investigated in terms of the relationship between the attachment probabi...Based on the theoretical analyses, the adhesion process of fine gold particles to oil-carbon agglomerates in a dynamic system was quantitatively investigated in terms of the relationship between the attachment probability and the surface energy. The proposed way to establish this relationship is to firstly theoretically derive the formula to （evaluate） the surface energy change of the system by analyzing the adhesion process of a gold particle on an oil-carbon agglomerate in a mathematic and thermodynamic way. The obtained formula of the maximum energy change of unit surface area is, (Δw′max=12σhw（cos θ-1）,) which involves two measurable elements: interfacial tension and contact angle. In a well-quantified system, based on the related model it is also possible to calculate the complicated concept, namely, the attachment probability by transferring other measurable indices. In this way, after some adhesion experiments and measurements of relevant parameters, the empirical relationship between the attachment probability and the surface energy change was established in an exponential function, Pa=Aexp(-ΔGsurf/k).展开更多
Nanoscale medicine confers passive and active targeting potential.The development of nanomedicine is however met with processing,handling and administration hurdles.Excessive solid nanoparticle aggregation and caking ...Nanoscale medicine confers passive and active targeting potential.The development of nanomedicine is however met with processing,handling and administration hurdles.Excessive solid nanoparticle aggregation and caking result in lowproduct yield,poor particle flowability and inefficient drug administration.These are overcome by converting the nanoparticles into a microscale dosage form via agglomeration or compaction techniques.Agglomeration and compaction nonetheless predispose the nanoparticles to risks of losing their nanogeometry,surface composition or chemistry being altered and negating biological performance.This study reviews risk factors faced during agglomeration and compaction that could result in these changes to nanoparticles.The potential risk factors pertain to materials choice in nanoparticle and microscale dosage form development,and their interplay effects with process temperature,physical forces and environmental stresses.To render the physicochemical and biological behaviour of the nanoparticles unaffected by agglomeration or compaction,modes to modulate the interplay effects of material and formulation with processing and environment variables are discussed.展开更多
The deformation and failure mechanism of cylindrical shells and square plate with pre-formed holes under blast loading were investigated numerically by employing the Ansys 17.0 and Ls-Dyna 971.To calibrate the numeric...The deformation and failure mechanism of cylindrical shells and square plate with pre-formed holes under blast loading were investigated numerically by employing the Ansys 17.0 and Ls-Dyna 971.To calibrate the numerical model,the experiments of square plates with pre-formed circle holes were modeled and the numerical results have a good agreement with the experiment data.The calibrated numerical model was used to study the deformation and failure mechanism of cylindrical shells with pre-formed circle holes subjected to blast loading.The structure response and stress field changing process has been divided into four specific stages and the deformation mechanism has been discussed systematically.The local and global deformation curves,degree of damage,change of stress status and failure modes of cylindrical shell and square plate with pre-formed circular holes are obtained,compared and analyzed,it can be concluded as:(1)The transition of tensile stress fields is due to the geometrical characteristic of pre-formed holes and cylindrical shell with arch configuration;(2)The existence of preformed holes not only lead to the increasing of stress concentration around the holes,but also release the stress concentration during whole response process;(3)There are three and two kinds of failure modes for square plate and cylindrical shell with pre-formed holes,respectively.and the standoff distance has a key influence on the forming location of the crack initiating point and the locus of crack propagation;(4)The square plate with pre-formed holes has a better performance than cylindrical shell on blast-resistant capability at a smaller standoff distance,while the influence of pre-formed holes on the reduction of blast-resistant capability of square plate is bigger than that of cylindrical shell.展开更多
Rare earth resources are relatively scarce worldwide, but their global consumption is increasing year-by-year. At present, China has about 36% of the global rare earth reserves, but provides 90% of the world＇s supply...Rare earth resources are relatively scarce worldwide, but their global consumption is increasing year-by-year. At present, China has about 36% of the global rare earth reserves, but provides 90% of the world＇s supply, which has generally met world demand and promoted the development of the world economy. In order to continuously and stably supply rare earths to international markets, the Chinese Government has financially supported the Institute of Multipurpose Utilization of Mineral Resources within the China Geological Survey to study the utilization of low-grade rare earth ores. Following many years of experimental research, the project has developed a new technology entitled ＂Flotation to Form Agglomerates and then Magnetic Separation＂, which will bring a technological revolution to the world＇s light rare earth ore dressing.展开更多
Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful l...Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful land resource management plan is the evaluation of Land Use Land Cover(LULC).Over the past 20 years,our planet’s land cover resources have undergone substantial changes due to rapid development.The Land Use Land Cover(LULC)categories of the Patna Urban Agglomeration(PUA),including water bodies,agricultural land,barren land,built-up areas,and vegetation,were identified using Geographic Information System(GIS)techniques.Three multi-temporal images were analyzed and classified through supervised classification using the maximum likelihood method.By comparing three separately created LULC categorized maps from 1990 and 2024,temporal changes were analyzed.In order to update land cover or manage natural resources,it is vital to use change detection as a tool to identify changes in LULC over time in PUA,Patna between 1990,2010 and 2024.According to their respective Kappa coefficients,the accuracy rates for 1990,2010 and 2024 LULC are 91.66 and 94.93,respectively.An accuracy evaluation was conducted to determine the correctness of the classification system and to determine the efficacy of the LULC classification maps.One hundred reference test pixels were identified.There have been found significant changes in the LULC were built up area has increased doubled in last thirty-four years of timeline.展开更多
The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm wa...The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm was achieved. The crushing strength of the agglomerates was determined for good handling of fine （coal-liquid mixture） to improve fugitive dust control, decrease in transportation losses, reduce risk of coal freezing, lower risk of spontaneous combustion, etc. in iron and steel industries, railway corporations and coal corporations. Kerosene （paraffin oil） was used as a binder and the agglomerated coal oil mixture was pelletized using balling technique （disc）. Mechanical and physical tests like compressive strength test, etc. were carried out. The relationship between the bridging liquid surface tension and specific surface area on strength factor of coal agglomerates showed that there is considerable variation in these parameters in the coal powder systems.展开更多
Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Si...Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Sichuan Province and Chongqing Municipality for the years 2000 to 2019 to estimate their statistical carbon emissions.We then employed nighttime light data to downscale and infer the spatial distribution of carbon emissions at the county level within the Chengdu-Chongqing urban agglomeration.Furthermore,we analyzed the spatial pattern of carbon emissions at the county level using the coefficient of variation and spatial autocorrelation,and we used the Geographically and Temporally Weighted Regression(GTWR)model to analyze the influencing factors of carbon emissions at this scale.The results of this study are as follows:(1)from 2000 to 2019,the overall carbon emissions in the Chengdu-Chongqing urban agglomeration showed an increasing trend followed by a decrease,with an average annual growth rate of 4.24%.However,in recent years,it has stabilized,and 2012 was the peak year for carbon emissions in the Chengdu-Chongqing urban agglomeration;(2)carbon emissions exhibited significant spatial clustering,with high-high clustering observed in the core urban areas of Chengdu and Chongqing and low-low clustering in the southern counties of the Chengdu-Chongqing urban agglomeration;(3)factors such as GDP,population(Pop),urbanization rate(Ur),and industrialization structure(Ic)all showed a significant influence on carbon emissions;(4)the spatial heterogeneity of each influencing factor was evident.展开更多
This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking an...This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality goals.This research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration nodes.The goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand scenarios.The results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in 2000.High-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were identified.The carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and Guangdong.The number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to 18.In the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon sinks.Under the Human-based sustainable restoration scenario,the carbon sink area will decrease from 607.00×10^(4) t C/yr in 2030 to 596.39×10^(4) t C/yr in 2060,with carbon sink areas frag-menting and positive carbon flow corridors becoming less dense.4)On the basis of the current and predicted CMSSPs,this study ex-plores spatial ecological restoration strategies for high-carbon storage areas in bay urban agglomerations at four levels:the land control region,urban agglomeration structure system,carbon sink structure and bay structure control region.展开更多
Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.Howe...Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.However,the overall spatial distribution and driving mechanisms of farmland transfer at the county scale has been less quantified.In this study,we evaluated farmland transfer and its spatial pattern in Central Yunnan Urban Agglomeration(CYUA)of China by using statistical data at the county scale in 2020.A so-cial-ecological indicator system,comprising natural endowment,social indicators,economic indicators,and landscape patterns,was es-tablished to explore the relationship between farmland transfer and its driving factors.Additionally,a heuristic structural equation mod-el(SEM)was employed to disentangle direct and indirect drivers of farmland transfer.The results indicated that significant spatial clusters of farmland transfer,with high transfer rates concentrated in highly urbanized areas and low transfer rates prevalent in tradition-al ethnic minority regions.Farmland transfer is primarily driven by soil quality,landscape patterns,terrain,and social-economic rurality.Specifically,higher soil quality and improved landscape connectivity facilitate farmland transfer directly,while gentler slopes promote farmland transfer indirectly by supporting better educational opportunities and fewer minority population.Improving rural vocational training and optimizing landscape patterns through land consolidation and redistribution are important in the mountainous areas.This study can provide valuable analytical framework for farmland management for other mountainous regions.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52204284)the China Postdoctoral Science Foundation(No.2025MD784125)+2 种基金the Natural Science Foundation of Shaanxi Province,China(No.2024JC-YBQN-0365)the Shaanxi Province Postdoctoral Science Foundation,China(No.2025BSHSDZZ363)Outstanding Youth Science Fund of Xi’an University of Science and Technology,China(No.202308)。
文摘Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeration characteristics of siderite particles after argon(Ar)plasma surface modification through settling tests,flocs size measurements,and fractal dimension calculations.Ar plasma surface modification promotes the agglomeration of siderite particles,as evidenced by increased floc size and density.The agglomeration mechanism induced by Ar plasma surface modification is evaluated using a theoretical model combining the surface element integration(SEI)approach,differential geometry,and the composite Simpson's rule.Changes in surface roughness,wettability,and charge are considered in this model.Compared to the unpretreated siderite particles,the energy barrier for interaction of the 30-min Ar plasma-pretreated siderite particles decreases from 2.3×10-^(17)J to 1.6×10^(-17)J.This reduction provides strong evidence for the agglomeration behavior of siderite particles.Furthermore,flotation experiments confirm that Ar plasma surface modification is conducive to the aggregation flotation of siderite.These findings offer crucial insights into particle aggregation and dispersion behaviors,with notable application in mineral flotation.
基金Supported by the National Natural Science Foundation of China(21376269)the Hunan Provincial Science and Technology Plan Project,China(2016TP1007)
文摘In this study, the influence of fluid cracking catalyst(FCC) on the fluidization behavior of ZnO-CuO binary nanoparticles was systematically investigated by varying FCC size. High-speed camera was employed to analyze the collision and fragmentation process of agglomerates with adding FCC coarse particles. It can be found from photographs by the camera that fluidization performance improved by the agglomerate variation that is bound to be shaped a compact and spherical structure. Furthermore, the result of agglomeration composition analysis showed that uniform mixing of nanoparticles remarkably affected the fluidization behavior of ZnO-CuO binary system. Finally, the improvement of fluidization performance can be justified by the analysis of inter-cohesive force between the two agglomerates with sharp reduction of the newly-formed agglomerates.
基金This work was supported by the Research Foundation of China University of Petroleum-Beijing at Karamay(No.XQZX20200010)the Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2019D01B57)+3 种基金the University Scientific Research Project of Xinjiang Uygur Autonomous Region(No.XJEDU2019Y067)the Xinjiang Uygur Autonomous Region Innovation Environment Construction Project(No.2019Q025)the Sichuan Province Regional Innovation Cooperation Project(No.2020YFQ0036)the CNPC Strategic Cooperation Science and Technology Project(ZLZX2020-01-04-04)。
文摘Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturing operations.The commonly used TPA mainly includes hard particles,fibers,gels,and composite systems.However,current particles have many limitations in applications,such as insufficient plugging strength and slow degradation rate.In this paper,a degradable pre-formed particle gel(DPPG)was developed.Experimental results show that the DPPG has an excellent static swelling effect and self-degradation performance.With a decrease in the concentration of total monomers or cross-linker,the swelling volume of the synthesized DPPG gradually increases.However,the entire self-degradation time gradually decreases.The increase in 2-acrylamide-2-methylpropanesulfonic acid(AMPS)in the DPPG composition can significantly increase its swelling ratio and shorten the self-degradation time.Moreover,DPPG has excellent high-temperature resistance(150°C)and high-salinity resistance(200,000 mg/L NaCl).Core displacement results show that the DPPG has a perfect plugging effect in the porous media(the plugging pressure gradient was as high as 21.12 MPa),and the damage to the formation after degradation is incredibly minor.Therefore,the DPPG can be used as an up-and-coming TPA in oil fields.
基金Project(2016GZ0290) supported by the Key Technology R&D Program of Sichuan Province,ChinaProject(2019CDXYCL0031) supported by the Fundamental Research Funds for the Central Universities,China
文摘The Williamson-Hall and uniaxial compression methods were used to study the variations of the micro-strain and stress-strain relations in WC powders after jet milling and ball milling, respectively. The rupture behavior of agglomerates in WC powders was investigated. Meanwhile, the as-obtained WC powders treated by different milling methods were used to fabricate WC-10%Co cemented carbides, followed by the performance assessment of cemented carbides. The results show that the micro-strain of the jet-milled WC powders decreases significantly compared with that of the ball-milled WC powders, and that the cemented carbides prepared by jet-milled WC powders exhibit excellent properties with a transverse-rupture strength of 4260 MPa, due to the elimination of agglomerates and the reduction of lattice strain.
基金Supported by TOTAL(DS-2885)the National Natural Science Foundation of China(91434201,21422608)the “Strategic Priority Research Program” of the Chinese Academy of Sciences(XDA07080000)
文摘The cohesive solids in liquid flows are featured by the dynamic growth and breakage of agglomerates, and the difficulties in the development, design and optimization of these systems are related to this significant feature.In this paper, discrete particle method is used to simulate a solid–liquid flow system including millions of cohesive particles, the growth rate and breakage rate of agglomerates are then systematically investigated. It was found that the most probable size of the agglomerates is determined by the balance of growth and breakage of the agglomerates the cross point of the lines of growth rate and breakage rate as a function of the particle numbers in an agglomerate, marks the most stable agglomerate size. The finding here provides a feasible way to quantify the dynamic behaviors of growth and breakage of agglomerates, and therefore offers the possibility of quantifying the effects of agglomerates on the hydrodynamics of fluid flows with cohesive particles.
基金This work was financially supported by the National Natural Science Foundation of China-Liaoning Joint Funds(U1808212)National Natural Science Foundation of China(52074080)Xingliao Talent Plan(XLYC1902118).
文摘Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,the evolution behavior and mechanism of different reactive ICA under simulated BF smelting conditions were studied.The results show that the existence of more sillimanite and aluminosilicate and less active sites of metallic iron will weaken gasification reaction and carburization ability of ICA-1(containing 10%iron ore).It weakens the promoting effect of ICA-1 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron.The aluminosilicate with a high melting point decreases,the low melting point slag phase and Fe–Si alloy increase,and many active sites of metallic iron exist,which strengthen the gasification reaction and carburization ability of ICA-2(containing 30%iron ore).The promoting effect of ICA-2 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron is significantly improved.The gasification reaction capacity of ICA-3(containing 35%iron ore)is reduced,and the improvement in ICA-3 on the softening–melting performance of mixed burdens is reduced.The appropriate proportion of iron ore in ICA is about 30%.
基金financial support of the Natural Science Foundation of Heilongjiang Province of China(E2018031)。
文摘The flow pattern and hydrodynamics of a heterogeneous permeable agglomerate in a uniform upward flow at intermediate Reynolds numbers(1–40)are analyzed from three-dimensional(3 D)computational fluid dynamics simulations.Different from the homogeneous or stepwise-varying permeability models used in previous papers,a continuously radially varying permeability model is used in the present study.The effects of two dimensionless parameters,the Reynolds number and the permeability ratio,on the flow field and the hydrodynamics were investigated in detail.The results reveal that unlike the solid sphere,a small recirculating wake initially forms inside the agglomerate.The critical Reynolds number for the formation of the recirculating wake is lower than that of the solid sphere and it decreases with the increase of permeability ratio.A correlation of drag coefficient as a function of the Reynolds number and permeability ratio is proposed.Comparisons of drag coefficients obtained by different permeability models show that at intermediate Reynolds numbers(1–40),the effect of radially varying permeability on the drag coefficient must be considered.
文摘An intensive study of the particle size distribution of four commercial ultrafine alumina powders to obtain information about the powder agglomeration and relate them to the compactibility and the sinterability has been made.
文摘The density of black regranulate (BR) of cork and of black agglomerate (BA) and composite agglomerate (CA) prepared fromsuch a waste by different methods was investigated. The preparation of the agglomerates was undertaken by controlling thespecimen thickness for BA and the particle size for BR and the binder dosage for CA. The mass changes produced in theoven-drying treatment at 376.15 K of the agglomerates and in their subsequent stabilization under ambient conditions werealso analyzed. The density was determined by standard methods. For BR, the bulk density first decreased and then increasedwith decreasing particle size. It was much lower than the apparent density of the agglomeration products of cork. Although toa lesser extent, the density was also lower for BA than for CA. It was higher for the smaller thickness specimens of BA. In thecase of CA, the density followed the same variation trends as for BR. Furthermore it increased significantly with the increasein resin dosage. This resulted in a noticeable increase in the weight loss during the oven-drying and in a significant decreasein the degree of moisture adsorption during the stabilization period of the agglomerate.
基金supported by the National Natural Science Foundation of China(No.51276033)
文摘Agglomerates formed in the fluidized bed were studied in this paper using the TEB atomization nozzle. The multi-sieving method was adopted to distinguish the size of original particles, nucleation agglomerates, coherence agglomerates, and paste agglomerates in order to successfully identify the different growth stages and select the region for coexistence of most stable heterogeneous agglomerates as the research object. A multi-channel conductance electrical circuit experimental device was developed in this study to measure the conductance signal, which was found to have a liner relationship with the moisture content inside the fluidized bed. By adjusting the sieve mesh openings to achieve the layered isolation of heterogeneous agglomerates, the conductance signal recovered slowly as a result of the agglomerates' fracture during the continuous fluidization process, so that particles and agglomerates moisture distribution measurements could be implemented. The device was used to measure the particles and agglomerates moisture distribution state in the heterogeneous coexistence region, when they were injected with liquid mass within the range of w i=2.8 kg to 4.4 kg. The results indicated that with the increase of liquid mass flow, the moisture content of coherence agglomerates also increased, but the moisture content of nucleation agglomerates was decreased, and that of the original particles was maintained at a relatively low level. When the experimental injection amount reached 4.4 kg, the moisture contained in coherence agglomerates could amount to 87.3%, accounting for a big percentage of moisture in the fluidized bed.
文摘Based on the theoretical analyses, the adhesion process of fine gold particles to oil-carbon agglomerates in a dynamic system was quantitatively investigated in terms of the relationship between the attachment probability and the surface energy. The proposed way to establish this relationship is to firstly theoretically derive the formula to （evaluate） the surface energy change of the system by analyzing the adhesion process of a gold particle on an oil-carbon agglomerate in a mathematic and thermodynamic way. The obtained formula of the maximum energy change of unit surface area is, (Δw′max=12σhw（cos θ-1）,) which involves two measurable elements: interfacial tension and contact angle. In a well-quantified system, based on the related model it is also possible to calculate the complicated concept, namely, the attachment probability by transferring other measurable indices. In this way, after some adhesion experiments and measurements of relevant parameters, the empirical relationship between the attachment probability and the surface energy change was established in an exponential function, Pa=Aexp(-ΔGsurf/k).
文摘Nanoscale medicine confers passive and active targeting potential.The development of nanomedicine is however met with processing,handling and administration hurdles.Excessive solid nanoparticle aggregation and caking result in lowproduct yield,poor particle flowability and inefficient drug administration.These are overcome by converting the nanoparticles into a microscale dosage form via agglomeration or compaction techniques.Agglomeration and compaction nonetheless predispose the nanoparticles to risks of losing their nanogeometry,surface composition or chemistry being altered and negating biological performance.This study reviews risk factors faced during agglomeration and compaction that could result in these changes to nanoparticles.The potential risk factors pertain to materials choice in nanoparticle and microscale dosage form development,and their interplay effects with process temperature,physical forces and environmental stresses.To render the physicochemical and biological behaviour of the nanoparticles unaffected by agglomeration or compaction,modes to modulate the interplay effects of material and formulation with processing and environment variables are discussed.
基金The reported research is financially supported by The National Natural Science Foundation of China under Grant No.11902310 and No.11802292.
文摘The deformation and failure mechanism of cylindrical shells and square plate with pre-formed holes under blast loading were investigated numerically by employing the Ansys 17.0 and Ls-Dyna 971.To calibrate the numerical model,the experiments of square plates with pre-formed circle holes were modeled and the numerical results have a good agreement with the experiment data.The calibrated numerical model was used to study the deformation and failure mechanism of cylindrical shells with pre-formed circle holes subjected to blast loading.The structure response and stress field changing process has been divided into four specific stages and the deformation mechanism has been discussed systematically.The local and global deformation curves,degree of damage,change of stress status and failure modes of cylindrical shell and square plate with pre-formed circular holes are obtained,compared and analyzed,it can be concluded as:(1)The transition of tensile stress fields is due to the geometrical characteristic of pre-formed holes and cylindrical shell with arch configuration;(2)The existence of preformed holes not only lead to the increasing of stress concentration around the holes,but also release the stress concentration during whole response process;(3)There are three and two kinds of failure modes for square plate and cylindrical shell with pre-formed holes,respectively.and the standoff distance has a key influence on the forming location of the crack initiating point and the locus of crack propagation;(4)The square plate with pre-formed holes has a better performance than cylindrical shell on blast-resistant capability at a smaller standoff distance,while the influence of pre-formed holes on the reduction of blast-resistant capability of square plate is bigger than that of cylindrical shell.
文摘Rare earth resources are relatively scarce worldwide, but their global consumption is increasing year-by-year. At present, China has about 36% of the global rare earth reserves, but provides 90% of the world＇s supply, which has generally met world demand and promoted the development of the world economy. In order to continuously and stably supply rare earths to international markets, the Chinese Government has financially supported the Institute of Multipurpose Utilization of Mineral Resources within the China Geological Survey to study the utilization of low-grade rare earth ores. Following many years of experimental research, the project has developed a new technology entitled ＂Flotation to Form Agglomerates and then Magnetic Separation＂, which will bring a technological revolution to the world＇s light rare earth ore dressing.
文摘Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful land resource management plan is the evaluation of Land Use Land Cover(LULC).Over the past 20 years,our planet’s land cover resources have undergone substantial changes due to rapid development.The Land Use Land Cover(LULC)categories of the Patna Urban Agglomeration(PUA),including water bodies,agricultural land,barren land,built-up areas,and vegetation,were identified using Geographic Information System(GIS)techniques.Three multi-temporal images were analyzed and classified through supervised classification using the maximum likelihood method.By comparing three separately created LULC categorized maps from 1990 and 2024,temporal changes were analyzed.In order to update land cover or manage natural resources,it is vital to use change detection as a tool to identify changes in LULC over time in PUA,Patna between 1990,2010 and 2024.According to their respective Kappa coefficients,the accuracy rates for 1990,2010 and 2024 LULC are 91.66 and 94.93,respectively.An accuracy evaluation was conducted to determine the correctness of the classification system and to determine the efficacy of the LULC classification maps.One hundred reference test pixels were identified.There have been found significant changes in the LULC were built up area has increased doubled in last thirty-four years of timeline.
文摘The aim of this research is to determine the effect of bridging liquid surface tension and specific surface area on strength factor of coal agglomerates. The production of coal agglomerates of the range 15-27.51 mm was achieved. The crushing strength of the agglomerates was determined for good handling of fine （coal-liquid mixture） to improve fugitive dust control, decrease in transportation losses, reduce risk of coal freezing, lower risk of spontaneous combustion, etc. in iron and steel industries, railway corporations and coal corporations. Kerosene （paraffin oil） was used as a binder and the agglomerated coal oil mixture was pelletized using balling technique （disc）. Mechanical and physical tests like compressive strength test, etc. were carried out. The relationship between the bridging liquid surface tension and specific surface area on strength factor of coal agglomerates showed that there is considerable variation in these parameters in the coal powder systems.
基金supported by the Humanities and Social Sciences Project of the Ministry of Education of the Peoples Republic(No.21YJCZH099)the National Natural Science Foundation of China(Nos.41401089 and 41741014)the Science and Technology Project of Sichuan Province(No.2023NSFSC1979).
文摘Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Sichuan Province and Chongqing Municipality for the years 2000 to 2019 to estimate their statistical carbon emissions.We then employed nighttime light data to downscale and infer the spatial distribution of carbon emissions at the county level within the Chengdu-Chongqing urban agglomeration.Furthermore,we analyzed the spatial pattern of carbon emissions at the county level using the coefficient of variation and spatial autocorrelation,and we used the Geographically and Temporally Weighted Regression(GTWR)model to analyze the influencing factors of carbon emissions at this scale.The results of this study are as follows:(1)from 2000 to 2019,the overall carbon emissions in the Chengdu-Chongqing urban agglomeration showed an increasing trend followed by a decrease,with an average annual growth rate of 4.24%.However,in recent years,it has stabilized,and 2012 was the peak year for carbon emissions in the Chengdu-Chongqing urban agglomeration;(2)carbon emissions exhibited significant spatial clustering,with high-high clustering observed in the core urban areas of Chengdu and Chongqing and low-low clustering in the southern counties of the Chengdu-Chongqing urban agglomeration;(3)factors such as GDP,population(Pop),urbanization rate(Ur),and industrialization structure(Ic)all showed a significant influence on carbon emissions;(4)the spatial heterogeneity of each influencing factor was evident.
基金Under the auspices of the National Natural Science Foundation of China(No.52268008)。
文摘This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality goals.This research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration nodes.The goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand scenarios.The results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in 2000.High-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were identified.The carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and Guangdong.The number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to 18.In the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon sinks.Under the Human-based sustainable restoration scenario,the carbon sink area will decrease from 607.00×10^(4) t C/yr in 2030 to 596.39×10^(4) t C/yr in 2060,with carbon sink areas frag-menting and positive carbon flow corridors becoming less dense.4)On the basis of the current and predicted CMSSPs,this study ex-plores spatial ecological restoration strategies for high-carbon storage areas in bay urban agglomerations at four levels:the land control region,urban agglomeration structure system,carbon sink structure and bay structure control region.
基金Under the auspices of Yunnan Provincial Science and Technology Project at Southwest United Graduate School(No.202302AO370012)National Natural Science Foundation of China(No.42201290)+1 种基金Talent Introduction Fund of Yunnan University(No.CZ22623101)the Fourteenth Program of Research Innovation Fund for Graduate Students of Yunnan University(No.KC-22221099)。
文摘Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.However,the overall spatial distribution and driving mechanisms of farmland transfer at the county scale has been less quantified.In this study,we evaluated farmland transfer and its spatial pattern in Central Yunnan Urban Agglomeration(CYUA)of China by using statistical data at the county scale in 2020.A so-cial-ecological indicator system,comprising natural endowment,social indicators,economic indicators,and landscape patterns,was es-tablished to explore the relationship between farmland transfer and its driving factors.Additionally,a heuristic structural equation mod-el(SEM)was employed to disentangle direct and indirect drivers of farmland transfer.The results indicated that significant spatial clusters of farmland transfer,with high transfer rates concentrated in highly urbanized areas and low transfer rates prevalent in tradition-al ethnic minority regions.Farmland transfer is primarily driven by soil quality,landscape patterns,terrain,and social-economic rurality.Specifically,higher soil quality and improved landscape connectivity facilitate farmland transfer directly,while gentler slopes promote farmland transfer indirectly by supporting better educational opportunities and fewer minority population.Improving rural vocational training and optimizing landscape patterns through land consolidation and redistribution are important in the mountainous areas.This study can provide valuable analytical framework for farmland management for other mountainous regions.
