Cyclic voltammetry and chronoamperometry were used to investigate theelectrochemical behavior of Pr^(3+) ions in a system of 0.01 mol centre dot dm^(-3) Pr(CH_3SO_3)_3 +0.01 mol centre dot dm^(-3) FeCl_2 + 3.0 mol cen...Cyclic voltammetry and chronoamperometry were used to investigate theelectrochemical behavior of Pr^(3+) ions in a system of 0.01 mol centre dot dm^(-3) Pr(CH_3SO_3)_3 +0.01 mol centre dot dm^(-3) FeCl_2 + 3.0 mol centre dot dm^(-3) urea + DMSO on a R electrode. Someelectrochemical parameters were measured. Potentiostatic depositions between -1.6 and -2.4 V wereapplied to deposit Pr-Fe films in urea-DMSO mixed solution. The Pr content in the alloy films was inthe range of 34.89 wt. percent to 37.15 wt. percent. The Pr-Fe alloy films are proven to beamorphous by XRD (X-ray diffraction).展开更多
The effects of Zr on crystallization kinetics of Pr Fe B amorphous alloys have been investigated by DTA and XRD methods. It was found that for Pr 8Fe 86- x Zr x B 6 ( x =0, 1, 2) amorphous alloys, the final crystalliz...The effects of Zr on crystallization kinetics of Pr Fe B amorphous alloys have been investigated by DTA and XRD methods. It was found that for Pr 8Fe 86- x Zr x B 6 ( x =0, 1, 2) amorphous alloys, the final crystallized mixture is α Fe and Pr 2Fe 14 B, and the metastable Pr 2Fe 23 B 3 phase occurs during crystallization of Pr 8Fe 86 B 6 amorphous alloy, not during crystallization of Pr 8Fe 86- x Zr x B 6( x =1, 2) amorphous alloys. By analyzing the activation energy of crystallization, the formation of an α Fe/Pr 2Fe 14 B composite microstructure with a coarse grain size in annealed Pr 8Fe 86 B 6 alloy, is attributed to a difficult nucleation and an easy growth for both the α Fe and Pr 2Fe 14 B in the alloy. The addition of Zr can be used to change the crystallization behavior of the α Fe phase in Pr Fe B amorphous alloy, which is helpful to reduce the grain size for the α Fe phase.展开更多
Characteristics of magnetic hardening in cast-hot pressed magnet Pr_(19)Fe_(74.5)B_5Cu_(1.5)were stu- died.The microstructure features and virgin magnetization curve reveal a nucleation control- led coercivity mechani...Characteristics of magnetic hardening in cast-hot pressed magnet Pr_(19)Fe_(74.5)B_5Cu_(1.5)were stu- died.The microstructure features and virgin magnetization curve reveal a nucleation control- led coercivity mechanism.Regression analysis shows that the intrinsic coercivity varies inversely as the logarithm of the average grain size: _iH_c(MA/m)=1.7312-0.48161nd(μm) which confirms the randomness of nucleation of reversed domains and the statistical nature of coercivity,indicating that the decrease of grain size would reduce the average number of de- fects on its surface and lower the probability of magnetization reversal of a grain and the cu- mulative fraction of the grains that have reversed their magnetization.Coercivity is thus en- hanced.展开更多
The hot deformation process of cast Pr_(19)Fe_(74.5)B_5Cu_(1.5) magnets were studied.It is found that the easy-axes are aligned parallel to the compressive strain direction in vari- ous hot deformation process.During ...The hot deformation process of cast Pr_(19)Fe_(74.5)B_5Cu_(1.5) magnets were studied.It is found that the easy-axes are aligned parallel to the compressive strain direction in vari- ous hot deformation process.During hot deformation,the crushing of Pr_2Fe_(14)B matrix grains and the relative slip and rotation between the grains take place and the Pr-rich melt is squeezed out of the magnet,leading to a fine,dense and well-aligned microstruc- ture in the fully-deformed magnets.Magnetic properties of B_r=990 mT,_iH_c=880 kA/m and(BH)_m=191 kJ/m^3are obtained.The increase of coercivity is attributed to the fine Pr_2Fe_(14)B grains and the thin Pr-rich phase layer continuously distributed at the grain boundaries.The increasing remanence is resulted primarily from the develop- ment of the easy-axis alignment as well as from the densification of the Pr_2Fe_(14)B matrix. The easy-axis alignment is developed by the relative slip and rotation of the crushed Pr_2Fe_(14)B grains.A full and slow hot deformation is necessary for the good easy-axis alighnment and high magnetic properties.展开更多
With the aid of 3-dimensional topological analysis methodology,relationships among phage regions on the isothermal section of the Nd-Fe-B phase diagram at 1000℃ and those on vertical sections of the Pr-Fe-B phase dia...With the aid of 3-dimensional topological analysis methodology,relationships among phage regions on the isothermal section of the Nd-Fe-B phase diagram at 1000℃ and those on vertical sections of the Pr-Fe-B phase diagram passing through Pr_2 Fe_(14)B point have been re-discussed and modified.展开更多
文摘Cyclic voltammetry and chronoamperometry were used to investigate theelectrochemical behavior of Pr^(3+) ions in a system of 0.01 mol centre dot dm^(-3) Pr(CH_3SO_3)_3 +0.01 mol centre dot dm^(-3) FeCl_2 + 3.0 mol centre dot dm^(-3) urea + DMSO on a R electrode. Someelectrochemical parameters were measured. Potentiostatic depositions between -1.6 and -2.4 V wereapplied to deposit Pr-Fe films in urea-DMSO mixed solution. The Pr content in the alloy films was inthe range of 34.89 wt. percent to 37.15 wt. percent. The Pr-Fe alloy films are proven to beamorphous by XRD (X-ray diffraction).
文摘The effects of Zr on crystallization kinetics of Pr Fe B amorphous alloys have been investigated by DTA and XRD methods. It was found that for Pr 8Fe 86- x Zr x B 6 ( x =0, 1, 2) amorphous alloys, the final crystallized mixture is α Fe and Pr 2Fe 14 B, and the metastable Pr 2Fe 23 B 3 phase occurs during crystallization of Pr 8Fe 86 B 6 amorphous alloy, not during crystallization of Pr 8Fe 86- x Zr x B 6( x =1, 2) amorphous alloys. By analyzing the activation energy of crystallization, the formation of an α Fe/Pr 2Fe 14 B composite microstructure with a coarse grain size in annealed Pr 8Fe 86 B 6 alloy, is attributed to a difficult nucleation and an easy growth for both the α Fe and Pr 2Fe 14 B in the alloy. The addition of Zr can be used to change the crystallization behavior of the α Fe phase in Pr Fe B amorphous alloy, which is helpful to reduce the grain size for the α Fe phase.
文摘Characteristics of magnetic hardening in cast-hot pressed magnet Pr_(19)Fe_(74.5)B_5Cu_(1.5)were stu- died.The microstructure features and virgin magnetization curve reveal a nucleation control- led coercivity mechanism.Regression analysis shows that the intrinsic coercivity varies inversely as the logarithm of the average grain size: _iH_c(MA/m)=1.7312-0.48161nd(μm) which confirms the randomness of nucleation of reversed domains and the statistical nature of coercivity,indicating that the decrease of grain size would reduce the average number of de- fects on its surface and lower the probability of magnetization reversal of a grain and the cu- mulative fraction of the grains that have reversed their magnetization.Coercivity is thus en- hanced.
文摘The hot deformation process of cast Pr_(19)Fe_(74.5)B_5Cu_(1.5) magnets were studied.It is found that the easy-axes are aligned parallel to the compressive strain direction in vari- ous hot deformation process.During hot deformation,the crushing of Pr_2Fe_(14)B matrix grains and the relative slip and rotation between the grains take place and the Pr-rich melt is squeezed out of the magnet,leading to a fine,dense and well-aligned microstruc- ture in the fully-deformed magnets.Magnetic properties of B_r=990 mT,_iH_c=880 kA/m and(BH)_m=191 kJ/m^3are obtained.The increase of coercivity is attributed to the fine Pr_2Fe_(14)B grains and the thin Pr-rich phase layer continuously distributed at the grain boundaries.The increasing remanence is resulted primarily from the develop- ment of the easy-axis alignment as well as from the densification of the Pr_2Fe_(14)B matrix. The easy-axis alignment is developed by the relative slip and rotation of the crushed Pr_2Fe_(14)B grains.A full and slow hot deformation is necessary for the good easy-axis alighnment and high magnetic properties.
文摘With the aid of 3-dimensional topological analysis methodology,relationships among phage regions on the isothermal section of the Nd-Fe-B phase diagram at 1000℃ and those on vertical sections of the Pr-Fe-B phase diagram passing through Pr_2 Fe_(14)B point have been re-discussed and modified.
基金National Natural Science Foundation of China(51361007)Guangxi Natural Science Foundation(2014GXNSFAA118317,2013GXNSFAA019295)+1 种基金Scientific Research Project of Guangxi Education Department(YB2014139)Guangxi Key Laboratory of Information Materials(131010-Z)
