Based on comprehensive petrological, geochronological, and geochemical studies, this study analyzed the relationships between the Beiya gold-polymetallic skarn deposit and quartz syenite porphyries, and discussed the ...Based on comprehensive petrological, geochronological, and geochemical studies, this study analyzed the relationships between the Beiya gold-polymetallic skarn deposit and quartz syenite porphyries, and discussed the source（s） and evolution of magmas. Our results suggest that syenite porphyries（i.e. the Wandongshan, the Dashadi, and the Hongnitang porphyries）, which formed between the Eocene and the early Oligocene epochs, are the sources for the gold-polymetallic ores at the Beiya deposit. Carbonate rocks（T2 b） of the Triassic Beiya Formation in the ore district provide favorable host space for deposit formation. Fold and fault structures collectively play an important role in ore formation. The contact zone between the porphyries and carbonates, the structurally fractured zone of carbonate and clastic rocks, and the zone with well-developed fractures are the ideal locations for ore bodies. Four types of mineralization have been recognized： 1） porphyry-style stockwork gold–iron（copper） ore, 2） skarn-style gold-iron（copper and lead） ore in the near contact zone, 3） strata-bound, lense-type lead–silver–gold ore in the outer contact zone, and 4） distal vein-type gold–lead–silver ore. Supergene processes led to the formation of oxide ore, such as the weathered and accumulated gold–iron ore, the strata-bound fracture oxide ore, and the structure-controlled vein-type ore. Most of these ore deposits are distributed along the axis of the depressed basin, with the hypogene ore controlling the shape and characteristics of the oxide ore. This study provides critical geology understanding for mineral prospecting scenarios.展开更多
The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Abla...The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Ablation-Inductively Coupled Plasma Mass Spectrometry（LA-ICP-MS） U-Pb zircon dating of two granodiorite intrusions（Xiaohekou and Lengshuigou deposits）was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8 to 152.6±1.2 Ma,averaging 150.5 Ma,accompanied by a younger disturbance age of 144.3±1.7 Ma in the Lengshuigou intrusion,which is in excellent agreement with published sensitive high resolution ion micro-probe（SHRIMP）zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit.Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry,yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma.These mineralization ages overlap rock-forming ages of the host intrusions within the error range.This implies that the mineralization occurred in the Late Jurassic,which belongs to the tectonic phase B event of the Yanshan Movement,not Cretaceous as previously thought.Therefore,the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period,the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates,perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.展开更多
The Shimensi deposit is a recently discovered W-Cu-Mo polymetallic deposit located in the Jiangnan porphyry-skarn W belt in South China.The deposit has a resource of 0.74×10^(6)t of WO_(3)accompanied by 0.4×...The Shimensi deposit is a recently discovered W-Cu-Mo polymetallic deposit located in the Jiangnan porphyry-skarn W belt in South China.The deposit has a resource of 0.74×10^(6)t of WO_(3)accompanied by 0.4×10^(6)t Cu and 28000 t Mo and other useful components like Ga,making it one of the largest W deposits in the world.This paper is aimed to reveal the ore-controlling mechanisms of the Shimensi deposit,involving the role of the ore-related granites,the tectonic background for its formation,and the metallogenesis model.The systematic geological survey suggests multi-types of alteration are developed in the deposit,mainly including greisenization,potassic-alteration,sericitization,chloritization,and silicification.Drilling engineering data and mining works indicate that the Shimensi deposit consists of two main orebodies of I and II.Therein,the W resource has reached a supergiant scale,and the accompanied Cu,Mo,Au,Bi,Ga,and some other useful components are also of economic significance.The main ore-minerals consist of scheelite,wolframite and chalcopyrite.Disseminated mineralization is the dominant type of the W-Cu-Mo polymetallic orebodies,and mainly distributes in the inner and external contact zone that between the Neoproterozoic biotite granodiorite and the Yanshanian granites.The main orebody occurs at the external contact zone,and the pegmatoid crust near the inner contact zone is an important prospecting marker of the W mineralization.Of them,the disseminated W ores within the wall rock of the Neoproterozoic biotite granodiorite is a new mineralization type identified in this paper.Combining previous geochronological and isotopic data,we propose that the mineralization of the Shimensi deposit is closely related to the intruding of the Yanshanian porphyritic biotite granite and granite porphyry.Geochemical data suggest that the biotite granodiorite is rich in Ca and had provided a large amount of Ca for the precipitation of scheelite in this area.Thus,it is a favorable wall rock type for W mineralization.The Shimensi deposit belongs to granitic-type W polymetallic deposit related to post-magmatic hydrothermal,and the ore-forming fluid was initially derived from the Yanshanian magmas.展开更多
The Beiya porphyry-skarn gold-polymetallic deposit is one of the largest gold deposits in China and it also contains significant amounts of silver and base metals.The ore-bearing monzonitic granite porphyry occurs as ...The Beiya porphyry-skarn gold-polymetallic deposit is one of the largest gold deposits in China and it also contains significant amounts of silver and base metals.The ore-bearing monzonitic granite porphyry occurs as a stock,of which the skarn type gold-copper-iron ore bodies are controlled by the contact zone between alkali-rich monzonitic granite porphyry and the limestone,and the gold-silver polymetallic mineralization is controlled by interlayer structure.Alteration and mineralization occur around the intrusion and exterior of monzonitic granite porphyry.Ore mineral formation sequence is as follows:skarn minerals→magnetite→pyrite→chalcopyrite/bornite+pyrite+gold→pyrite+galena+gold(silver).Petrographic studies of fluid inclusions indicate that the following types of inclusions exist in the pre-mineralization quartz-pyrite stage:gas-liquid two-phase inclusions(L-type),three-phase inclusions with daughter minerals(D-type)and gas-rich inclusions(V-type).The colorless transparent quartz in the main gold-chalcopyrite-pyrite stage mainly consists of L-type and V-type inclusions,whereas the inclusions in the late gold-silver-galena stage are mainly L-type.The evolution of ore-forming fluids shows a trend from high temperature,high salinity to medium-low temperature and low salinity.Medium-low density fluids play a dominant role in mineral component migration and transportation.Fluid cooling and boiling are the main mechanisms of gold-copper precipitation,while the involvement of atmospheric water and pH reduction are the main mechanisms of gold-silver polymetallic precipitation.The fluids in the quartz-pyrite stage before mineralization and the main gold-chalcopyrite-pyrite stage are dominated by magmatic water,while in the gold-silver-galena stage the fluids are dominated by atmospheric water.Isotope tracers show that S and Pb are mainly derived from monzonitic granite porphyry,not from limestone of the Beiya Formation.展开更多
Most giant porphyry-skarn Cu-Au ore systems are associated with either the metasomatic mantle wedge,formed by the dehydration of subducting oceanic crust,or the melting of Cu-rich juvenile lower crust.The ore-forming ...Most giant porphyry-skarn Cu-Au ore systems are associated with either the metasomatic mantle wedge,formed by the dehydration of subducting oceanic crust,or the melting of Cu-rich juvenile lower crust.The ore-forming parent rocks are typically depleted adakites.In contrast,parent rocks in intracontinental Cu-Au ore systems exhibit enriched isotopic compositions,yet their formation mechanisms and deep processes remain unclear.To address this,our study focuses on the central Yangtze River ore belt(CYROB)and adjacent areas.By compiling regional petrological and chronological data,we conducted multi-isotope tracing and Hf isotope mapping,integrated with regional seismic velocity tomography and magnetotelluric detection results,to reconstruct the lithospheric architecture and its evolutionary processes.Our findings indicate that the CYROB underwent significant crustal accretion during the Meso-and Neo-proterozoic,forming a juvenile crust.In the Late Mesozoic,the crust experienced polygenetic reworking,through two distinct periods(156–136 Ma and 136–120 Ma).During the transition from the Late Jurassic to the Early Cretaceous(156–140 Ma),in the area near and north of the Gaotan fault,lithospheric delamination in an extensional setting facilitated mantle convection and partial melting of enriched lithospheric mantle.This process modified the pre-existing juvenile lower crust,leading to the formation of adakites with slightly negativeεHf values(-5 to 0)and associated porphyry-skarn Cu-Au deposits.Concurrently,ascent of adakitic magma occasionally incorporated W-rich middle-to-upper crustal materials,enriching the melts in W and forming localized small-to medium-sized skarn W deposits.During 140–136 Ma,with the continued relaxation of lithospheric stress,a more intense modification of the lower crust by enriched mantle occurred west of Anqing and north of Qingyang.This led to the formation of adakic magmas with strongly negativeεHfvalues(-24 to-8)and related skarn Cu-Fe deposits.To the south of the Jiangnan fault,where the crust was deeper,mantle convection induced the remelting of Proterozoic reworked crust,releasing W and Mo into crust-derived melts,ultimately forming a series of large-and medium-sized porphyry-skarn W-Mo deposits.During the late period(136–120 Ma),progressive lithospheric extension triggered large-scale lithospheric delamination and oblique asthenospheric upwelling from the southeast to the northwest,further modifying the lower crust.The remelting of reworked crust with input from depleted mantle materials,led to the formation of extensive alkali-rich granitic batholiths.This study demonstrates that,under the extensional regime of the Late Mesozoic,the polygenic reworking of juvenile crust and the remelting of previously reworked crust—driven by ongoing lithosphere-scale delamination and asthenospheric upwelling—played a key role in controlling the temporal and spatial distribution of metal ore systems in the CYROB and adjacent areas.展开更多
基金jointly financially supported by “Yunling Scholars” Research Project from Yunnan Province,China Geological Survey Project(No.DD20160124 and 12120114013501)the National Natural Science Foundation of China(grant No.41602103)the “Study on metallogenic regularities and metallogenic series of gold-polymetallic deposits,Northwestern Yunnan Province” research project(E1107)from Yunnan Gold&Mining Group Co.,Ltd
文摘Based on comprehensive petrological, geochronological, and geochemical studies, this study analyzed the relationships between the Beiya gold-polymetallic skarn deposit and quartz syenite porphyries, and discussed the source（s） and evolution of magmas. Our results suggest that syenite porphyries（i.e. the Wandongshan, the Dashadi, and the Hongnitang porphyries）, which formed between the Eocene and the early Oligocene epochs, are the sources for the gold-polymetallic ores at the Beiya deposit. Carbonate rocks（T2 b） of the Triassic Beiya Formation in the ore district provide favorable host space for deposit formation. Fold and fault structures collectively play an important role in ore formation. The contact zone between the porphyries and carbonates, the structurally fractured zone of carbonate and clastic rocks, and the zone with well-developed fractures are the ideal locations for ore bodies. Four types of mineralization have been recognized： 1） porphyry-style stockwork gold–iron（copper） ore, 2） skarn-style gold-iron（copper and lead） ore in the near contact zone, 3） strata-bound, lense-type lead–silver–gold ore in the outer contact zone, and 4） distal vein-type gold–lead–silver ore. Supergene processes led to the formation of oxide ore, such as the weathered and accumulated gold–iron ore, the strata-bound fracture oxide ore, and the structure-controlled vein-type ore. Most of these ore deposits are distributed along the axis of the depressed basin, with the hypogene ore controlling the shape and characteristics of the oxide ore. This study provides critical geology understanding for mineral prospecting scenarios.
基金supported by the NSFC project(Grant No41072169 and 40972150)the Ministry of Science and Technology of People's Republic of China(Grant No2006BAB01All)a China Postdoctoral Science Foundation Grant
文摘The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Ablation-Inductively Coupled Plasma Mass Spectrometry（LA-ICP-MS） U-Pb zircon dating of two granodiorite intrusions（Xiaohekou and Lengshuigou deposits）was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8 to 152.6±1.2 Ma,averaging 150.5 Ma,accompanied by a younger disturbance age of 144.3±1.7 Ma in the Lengshuigou intrusion,which is in excellent agreement with published sensitive high resolution ion micro-probe（SHRIMP）zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit.Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry,yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma.These mineralization ages overlap rock-forming ages of the host intrusions within the error range.This implies that the mineralization occurred in the Late Jurassic,which belongs to the tectonic phase B event of the Yanshan Movement,not Cretaceous as previously thought.Therefore,the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period,the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates,perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.
基金supported financially by the National Natural Science Foundation of China(No.41772069)projects of the China Geological Survey(1212011220737,121201004000150015,DD20190570).
文摘The Shimensi deposit is a recently discovered W-Cu-Mo polymetallic deposit located in the Jiangnan porphyry-skarn W belt in South China.The deposit has a resource of 0.74×10^(6)t of WO_(3)accompanied by 0.4×10^(6)t Cu and 28000 t Mo and other useful components like Ga,making it one of the largest W deposits in the world.This paper is aimed to reveal the ore-controlling mechanisms of the Shimensi deposit,involving the role of the ore-related granites,the tectonic background for its formation,and the metallogenesis model.The systematic geological survey suggests multi-types of alteration are developed in the deposit,mainly including greisenization,potassic-alteration,sericitization,chloritization,and silicification.Drilling engineering data and mining works indicate that the Shimensi deposit consists of two main orebodies of I and II.Therein,the W resource has reached a supergiant scale,and the accompanied Cu,Mo,Au,Bi,Ga,and some other useful components are also of economic significance.The main ore-minerals consist of scheelite,wolframite and chalcopyrite.Disseminated mineralization is the dominant type of the W-Cu-Mo polymetallic orebodies,and mainly distributes in the inner and external contact zone that between the Neoproterozoic biotite granodiorite and the Yanshanian granites.The main orebody occurs at the external contact zone,and the pegmatoid crust near the inner contact zone is an important prospecting marker of the W mineralization.Of them,the disseminated W ores within the wall rock of the Neoproterozoic biotite granodiorite is a new mineralization type identified in this paper.Combining previous geochronological and isotopic data,we propose that the mineralization of the Shimensi deposit is closely related to the intruding of the Yanshanian porphyritic biotite granite and granite porphyry.Geochemical data suggest that the biotite granodiorite is rich in Ca and had provided a large amount of Ca for the precipitation of scheelite in this area.Thus,it is a favorable wall rock type for W mineralization.The Shimensi deposit belongs to granitic-type W polymetallic deposit related to post-magmatic hydrothermal,and the ore-forming fluid was initially derived from the Yanshanian magmas.
基金Supported by Project of China Geological Survey(No.1212011085485).
文摘The Beiya porphyry-skarn gold-polymetallic deposit is one of the largest gold deposits in China and it also contains significant amounts of silver and base metals.The ore-bearing monzonitic granite porphyry occurs as a stock,of which the skarn type gold-copper-iron ore bodies are controlled by the contact zone between alkali-rich monzonitic granite porphyry and the limestone,and the gold-silver polymetallic mineralization is controlled by interlayer structure.Alteration and mineralization occur around the intrusion and exterior of monzonitic granite porphyry.Ore mineral formation sequence is as follows:skarn minerals→magnetite→pyrite→chalcopyrite/bornite+pyrite+gold→pyrite+galena+gold(silver).Petrographic studies of fluid inclusions indicate that the following types of inclusions exist in the pre-mineralization quartz-pyrite stage:gas-liquid two-phase inclusions(L-type),three-phase inclusions with daughter minerals(D-type)and gas-rich inclusions(V-type).The colorless transparent quartz in the main gold-chalcopyrite-pyrite stage mainly consists of L-type and V-type inclusions,whereas the inclusions in the late gold-silver-galena stage are mainly L-type.The evolution of ore-forming fluids shows a trend from high temperature,high salinity to medium-low temperature and low salinity.Medium-low density fluids play a dominant role in mineral component migration and transportation.Fluid cooling and boiling are the main mechanisms of gold-copper precipitation,while the involvement of atmospheric water and pH reduction are the main mechanisms of gold-silver polymetallic precipitation.The fluids in the quartz-pyrite stage before mineralization and the main gold-chalcopyrite-pyrite stage are dominated by magmatic water,while in the gold-silver-galena stage the fluids are dominated by atmospheric water.Isotope tracers show that S and Pb are mainly derived from monzonitic granite porphyry,not from limestone of the Beiya Formation.
基金jointly funded by the National Key Technologies Research and Development Program(Grant Nos.2019YFA0708603,2023YFF0804203)the China Geological Survey(Grant No.DD20243510)+2 种基金the Scientific Research Fund Project of BGRIMM Technology Group(Grant No.JTKY202427822)the National Natural Science Foundation of China(Grant No.42073042)the Basic Scientific Research Fund of the Institute of Geology,Chinese Academy of Geological Sciences(Grant No.J2402)。
文摘Most giant porphyry-skarn Cu-Au ore systems are associated with either the metasomatic mantle wedge,formed by the dehydration of subducting oceanic crust,or the melting of Cu-rich juvenile lower crust.The ore-forming parent rocks are typically depleted adakites.In contrast,parent rocks in intracontinental Cu-Au ore systems exhibit enriched isotopic compositions,yet their formation mechanisms and deep processes remain unclear.To address this,our study focuses on the central Yangtze River ore belt(CYROB)and adjacent areas.By compiling regional petrological and chronological data,we conducted multi-isotope tracing and Hf isotope mapping,integrated with regional seismic velocity tomography and magnetotelluric detection results,to reconstruct the lithospheric architecture and its evolutionary processes.Our findings indicate that the CYROB underwent significant crustal accretion during the Meso-and Neo-proterozoic,forming a juvenile crust.In the Late Mesozoic,the crust experienced polygenetic reworking,through two distinct periods(156–136 Ma and 136–120 Ma).During the transition from the Late Jurassic to the Early Cretaceous(156–140 Ma),in the area near and north of the Gaotan fault,lithospheric delamination in an extensional setting facilitated mantle convection and partial melting of enriched lithospheric mantle.This process modified the pre-existing juvenile lower crust,leading to the formation of adakites with slightly negativeεHf values(-5 to 0)and associated porphyry-skarn Cu-Au deposits.Concurrently,ascent of adakitic magma occasionally incorporated W-rich middle-to-upper crustal materials,enriching the melts in W and forming localized small-to medium-sized skarn W deposits.During 140–136 Ma,with the continued relaxation of lithospheric stress,a more intense modification of the lower crust by enriched mantle occurred west of Anqing and north of Qingyang.This led to the formation of adakic magmas with strongly negativeεHfvalues(-24 to-8)and related skarn Cu-Fe deposits.To the south of the Jiangnan fault,where the crust was deeper,mantle convection induced the remelting of Proterozoic reworked crust,releasing W and Mo into crust-derived melts,ultimately forming a series of large-and medium-sized porphyry-skarn W-Mo deposits.During the late period(136–120 Ma),progressive lithospheric extension triggered large-scale lithospheric delamination and oblique asthenospheric upwelling from the southeast to the northwest,further modifying the lower crust.The remelting of reworked crust with input from depleted mantle materials,led to the formation of extensive alkali-rich granitic batholiths.This study demonstrates that,under the extensional regime of the Late Mesozoic,the polygenic reworking of juvenile crust and the remelting of previously reworked crust—driven by ongoing lithosphere-scale delamination and asthenospheric upwelling—played a key role in controlling the temporal and spatial distribution of metal ore systems in the CYROB and adjacent areas.
