Photocatalysis is considered as the promising energy conversion way to resolve the issues of energy crisis and environmental pollution.As the key point of the photocatalysis,the photocatalyst determines the final conv...Photocatalysis is considered as the promising energy conversion way to resolve the issues of energy crisis and environmental pollution.As the key point of the photocatalysis,the photocatalyst determines the final conversion efficiency from solar,therefore,the composition and photoelectronic nature of which deserve to be valued.Halogen often affects immensely the intrinsic electron configuration of the matrix because of electrophilic property,and thus its topic has attracted lots of attention for photocatalytic application.In this review,halogencontained organic porous semiconductors are discussed in detailed.Firstly,the role of halogens in photocatalysis based on organic porous semiconductors are categorized.Then,the way to introduce the halogens into organic porous semiconductors and their applications in photocatalysis are reviewed.At last,the outlooks are given at the end of this paper.This review would bring new insights into the non-metal doping engineering for improving the photocatalytic performance of organic semiconductors.展开更多
基金The National Natural Science Foundation of China(NO.22205124 and NO.52172206)Natural Science Foundation of Shandong province(No.ZR2021QB070)+1 种基金Special Fund for Taishan Scholars Project and Basic Research Projects for the Pilot Project of Integrating Science and Education and Industry of Qilu University of Technology(Shandong Academy of Sciences)(2023PY024 and 2023PX008)the Development Plan of Youth Innovation Team in Colleges and Universities of Shandong Province provide the powerful financial support.
文摘Photocatalysis is considered as the promising energy conversion way to resolve the issues of energy crisis and environmental pollution.As the key point of the photocatalysis,the photocatalyst determines the final conversion efficiency from solar,therefore,the composition and photoelectronic nature of which deserve to be valued.Halogen often affects immensely the intrinsic electron configuration of the matrix because of electrophilic property,and thus its topic has attracted lots of attention for photocatalytic application.In this review,halogencontained organic porous semiconductors are discussed in detailed.Firstly,the role of halogens in photocatalysis based on organic porous semiconductors are categorized.Then,the way to introduce the halogens into organic porous semiconductors and their applications in photocatalysis are reviewed.At last,the outlooks are given at the end of this paper.This review would bring new insights into the non-metal doping engineering for improving the photocatalytic performance of organic semiconductors.
