Carbonate,tight sandstone,and shale reservoirs have many pore types,and the relationship between the porosity and elastic parameters is extremely discrete due to the complex pore shape.This paper presents a method for...Carbonate,tight sandstone,and shale reservoirs have many pore types,and the relationship between the porosity and elastic parameters is extremely discrete due to the complex pore shape.This paper presents a method for predicting reservoir pore types based on pore shape substitution.The pore shape substitution allows for accurately characterizing the changes in the elastic properties of the rock with the changes in pore shape,assuming there are no changes in terms of minerals,porosity,or fl uids.By employing a multiple-porosity variable critical porosity model,the eff ective pore aspect ratio could be inverted from the velocities of the rock.To perform pore shape substitution,we could replace the eff ective pore aspect ratio with another pore aspect ratio or increase/decrease the volume content of diff erent pore shapes.The reservoir pore types could be evaluated by comparing the differences in the reservoir velocities before and after the substitution of the pore shape.The test results pertaining to the theoretical model and the well logging data indicated that the pore shape substitution method could be applied to characterize pore types in terms of separating the eff ects of the pore shapes from the eff ects of the minerals,porosity,or fl uids on the velocities.展开更多
To study the formation of layer shaped pores in TiC Fe cermet, two Ti C Fe powder compacts containing Ti powders with two size ranges (< 44μm and 135～ 154μm ) respectively were ignited in a special ignition mode...To study the formation of layer shaped pores in TiC Fe cermet, two Ti C Fe powder compacts containing Ti powders with two size ranges (< 44μm and 135～ 154μm ) respectively were ignited in a special ignition mode. The combustion temperatures of the reactions were measured, the phase constituents of the combustion synthesized products were inspected by X ray diffractometry (XRD), and the structures of the products were observed with scanning electron microscope (SEM). In the case of the finer Ti powder used, TiC Fe cermet and pore rank in an alternately laminar shape, and the shape of the pore is the same as that of the combustion wavefront, implying that the layer shaped pore results from a gather of the retained gas into the combustion wavefront. While in the case of the coarser Ti powder used, the lower combustion temperature causes the gather of the retained gas to be difficult, the pore being present in an arbitrary shape and distributing randomly.展开更多
Assuming the pores in a porous solid to be slit-shaped,according to the principle of surface chemical thermody-namics,an equation for the calculation of pore size fromthe desorption branch of the isotherm of physical ...Assuming the pores in a porous solid to be slit-shaped,according to the principle of surface chemical thermody-namics,an equation for the calculation of pore size fromthe desorption branch of the isotherm of physical adsorp-tion of nitrogen on the porous solid at liquid nitrogentemperature is derived.The calculation results obtainedby different methods,namely,the classical method,BBmethod and the method of this paper,are compared.Comparison shows that the pore sizes d_T and d_H calculat-ed by the method of this paper and BB method respec-tively are larger than the pore size d_c calculated by theclassical method in the range 0【p/p_s【1;d_T】d_Hatp/p_s【0.71 and d_H】d_T at p/p_s】0.71;The results byBB method and the method of this paper tend to be thesame as that by the classical method while p/p_s ap-proaches 1.展开更多
A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material...A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material,the paper derives the macroscopic constitutive laws for homogenous equivalent medium. By changing the shape parameter of circular particles,the effect of pore shape on macroscopic constitutive laws is explored. Yield surfaces with different pore shapes are obtained. About voids,a two-scale conception is introduced,which regards main void as macroscopic scale and secondary cavities as microscopic scale. The macroscopic potential involving main and secondary voids is achieved. The proposed macroscopic constitutive law taking microscopic features as influence factors is helpful for exploring the macroscopic mechanical properties of porous medium when numerical simulation is required.展开更多
Herein,iron-based metal–organic frameworks(MOFs),i.e.VNU-21 and VNU-22,and a new MOF termed Fe-NDC Fe_(3)O(NDC)2SO_(4)(HCO_(2))(H_(2)O)2(NDC2−=2,6-naphthalene dicarboxylate),possessing one-dimensional(1D)channels of ...Herein,iron-based metal–organic frameworks(MOFs),i.e.VNU-21 and VNU-22,and a new MOF termed Fe-NDC Fe_(3)O(NDC)2SO_(4)(HCO_(2))(H_(2)O)2(NDC2−=2,6-naphthalene dicarboxylate),possessing one-dimensional(1D)channels of different sizes and shapes in structures,were synthesized,and their methane storage capacities were measured.As a result of the structural design using mixed linkers for controlling the length and width of the rectangular 1D channels during the isoreticularly structural expanse,VNU-21,with the long-narrow 1D channels of 7.0×12.4Å^(2),exhibited the high total volumetric CH_(4)uptake of 182 cm^(3)cm^(-3)at 65 bar and 25℃,which outperformed VNU-22,Fe-NDC and traditional MOFs with large 1D channels(DUT-4 and DUT-5).Remarkably,the CH_(4)uptake of VNU-21 was comparable to those of the benchmark materials(e.g.MOF-5,MOF-177,MOF-205,MOF-210 and MOF-905-NO_(2))for methane storage at 65 bar despite the significantly lower surface area of this compound.We believe that this design strategy will inspire the synthesis of new porous frameworks such as the reticularly expanded structures of VNU-21,which have been characterized by both high surface area and a strong CH_(4)-framework interaction for enhancing the methane storage capacity.展开更多
基金the National Natural Science Foundation of China(Nos.42074136,41674130)National Key S&T Special Project of China(No.2016ZX05027-004-001)the Fundamental Research Funds for the Central University(No.18CX02061A).
文摘Carbonate,tight sandstone,and shale reservoirs have many pore types,and the relationship between the porosity and elastic parameters is extremely discrete due to the complex pore shape.This paper presents a method for predicting reservoir pore types based on pore shape substitution.The pore shape substitution allows for accurately characterizing the changes in the elastic properties of the rock with the changes in pore shape,assuming there are no changes in terms of minerals,porosity,or fl uids.By employing a multiple-porosity variable critical porosity model,the eff ective pore aspect ratio could be inverted from the velocities of the rock.To perform pore shape substitution,we could replace the eff ective pore aspect ratio with another pore aspect ratio or increase/decrease the volume content of diff erent pore shapes.The reservoir pore types could be evaluated by comparing the differences in the reservoir velocities before and after the substitution of the pore shape.The test results pertaining to the theoretical model and the well logging data indicated that the pore shape substitution method could be applied to characterize pore types in terms of separating the eff ects of the pore shapes from the eff ects of the minerals,porosity,or fl uids on the velocities.
文摘To study the formation of layer shaped pores in TiC Fe cermet, two Ti C Fe powder compacts containing Ti powders with two size ranges (< 44μm and 135～ 154μm ) respectively were ignited in a special ignition mode. The combustion temperatures of the reactions were measured, the phase constituents of the combustion synthesized products were inspected by X ray diffractometry (XRD), and the structures of the products were observed with scanning electron microscope (SEM). In the case of the finer Ti powder used, TiC Fe cermet and pore rank in an alternately laminar shape, and the shape of the pore is the same as that of the combustion wavefront, implying that the layer shaped pore results from a gather of the retained gas into the combustion wavefront. While in the case of the coarser Ti powder used, the lower combustion temperature causes the gather of the retained gas to be difficult, the pore being present in an arbitrary shape and distributing randomly.
文摘Assuming the pores in a porous solid to be slit-shaped,according to the principle of surface chemical thermody-namics,an equation for the calculation of pore size fromthe desorption branch of the isotherm of physical adsorp-tion of nitrogen on the porous solid at liquid nitrogentemperature is derived.The calculation results obtainedby different methods,namely,the classical method,BBmethod and the method of this paper,are compared.Comparison shows that the pore sizes d_T and d_H calculat-ed by the method of this paper and BB method respec-tively are larger than the pore size d_c calculated by theclassical method in the range 0【p/p_s【1;d_T】d_Hatp/p_s【0.71 and d_H】d_T at p/p_s】0.71;The results byBB method and the method of this paper tend to be thesame as that by the classical method while p/p_s ap-proaches 1.
基金Sponsored by the National Natural Science Foundation of China(Grant No.10972162)
文摘A numerical study is presented,using a homogenization technique to consider the plain strain problem of visco-plastic porous medium shaped by regularly distributed circular particles. Based on a rigid plastic material,the paper derives the macroscopic constitutive laws for homogenous equivalent medium. By changing the shape parameter of circular particles,the effect of pore shape on macroscopic constitutive laws is explored. Yield surfaces with different pore shapes are obtained. About voids,a two-scale conception is introduced,which regards main void as macroscopic scale and secondary cavities as microscopic scale. The macroscopic potential involving main and secondary voids is achieved. The proposed macroscopic constitutive law taking microscopic features as influence factors is helpful for exploring the macroscopic mechanical properties of porous medium when numerical simulation is required.
基金supported by the Vietnam National Foundation for Science and Technology Development(NAFOSTED)under the Project Code 104.05-2018.365.
文摘Herein,iron-based metal–organic frameworks(MOFs),i.e.VNU-21 and VNU-22,and a new MOF termed Fe-NDC Fe_(3)O(NDC)2SO_(4)(HCO_(2))(H_(2)O)2(NDC2−=2,6-naphthalene dicarboxylate),possessing one-dimensional(1D)channels of different sizes and shapes in structures,were synthesized,and their methane storage capacities were measured.As a result of the structural design using mixed linkers for controlling the length and width of the rectangular 1D channels during the isoreticularly structural expanse,VNU-21,with the long-narrow 1D channels of 7.0×12.4Å^(2),exhibited the high total volumetric CH_(4)uptake of 182 cm^(3)cm^(-3)at 65 bar and 25℃,which outperformed VNU-22,Fe-NDC and traditional MOFs with large 1D channels(DUT-4 and DUT-5).Remarkably,the CH_(4)uptake of VNU-21 was comparable to those of the benchmark materials(e.g.MOF-5,MOF-177,MOF-205,MOF-210 and MOF-905-NO_(2))for methane storage at 65 bar despite the significantly lower surface area of this compound.We believe that this design strategy will inspire the synthesis of new porous frameworks such as the reticularly expanded structures of VNU-21,which have been characterized by both high surface area and a strong CH_(4)-framework interaction for enhancing the methane storage capacity.
