Al<sub>2</sub>O<sub>3</sub>/PVFM/Al<sub>2</sub>O<sub>3</sub> trilayer membranes are prepared by means of simple coating of PVA-Al<sub>2</sub>O<sub>3<...Al<sub>2</sub>O<sub>3</sub>/PVFM/Al<sub>2</sub>O<sub>3</sub> trilayer membranes are prepared by means of simple coating of PVA-Al<sub>2</sub>O<sub>3</sub> solution onto both sides of PVFM thin membranes, which is prepared via phase inversion method. The characteristics of the trilayer membranes and gel polymer electrolytes are investigated using FESEM, tensile testing apparatus, thermal shrinkage test, EIS and charge-discharge test. When inorganic Al<sub>2</sub>O<sub>3</sub> particles are used to coat the PVFM membrane, drawbacks associated with gel-type membranes, namely, poor mechanical strength and thermal stability are greatly improved. Lithium ion cell with the Al<sub>2</sub>O<sub>3</sub>/PVFM/Al<sub>2</sub>O<sub>3</sub> based GPE matched with LiFePO<sub>4</sub> shows excellent electrochemical performance.展开更多
文摘Al<sub>2</sub>O<sub>3</sub>/PVFM/Al<sub>2</sub>O<sub>3</sub> trilayer membranes are prepared by means of simple coating of PVA-Al<sub>2</sub>O<sub>3</sub> solution onto both sides of PVFM thin membranes, which is prepared via phase inversion method. The characteristics of the trilayer membranes and gel polymer electrolytes are investigated using FESEM, tensile testing apparatus, thermal shrinkage test, EIS and charge-discharge test. When inorganic Al<sub>2</sub>O<sub>3</sub> particles are used to coat the PVFM membrane, drawbacks associated with gel-type membranes, namely, poor mechanical strength and thermal stability are greatly improved. Lithium ion cell with the Al<sub>2</sub>O<sub>3</sub>/PVFM/Al<sub>2</sub>O<sub>3</sub> based GPE matched with LiFePO<sub>4</sub> shows excellent electrochemical performance.
