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Verification of Beam Models for Ionic Polymer-Metal Composite Actuator 被引量:4
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作者 Hoon Cheol Park Quoc Viet Nguyen +1 位作者 Jang Woo Lee Young Tai Yoo 《Journal of Bionic Engineering》 SCIE EI CSCD 2009年第3期232-238,共7页
Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify ... Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify the equivalent beam and equivalent bimorph beam models.The blocking force and tip displacement of the IPMC actuator were measured with a DC power supply and Young's modulus of the IPMC strip was measured by bending and tensile tests respectively.The calculated maximum tip displacement and the Young's modulus by the equivalent beam model were almost identical to the corresponding measured data.Finite element analysis with thermal analogy technique was utilized in the equivalent bimorph beam model to numerically reproduce the force-displacement relationship of the IPMC actuator.The results by the equivalent bimorph beam model agreed well with the force-displacement relationship acquired by the measured data.It is confirmed that the equivalent beam and equivalent bimorph beam models are practically and effectively suitable for predicting the tip displacement,blocking force and Young's modulus of IPMC actuators with different thickness and different composite of ionic polymer membrane. 展开更多
关键词 jonic polymer-metal composite BEAM model DISPLACEMENT FORCE
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Constitutive relationship of ionic polymer-metal composite and static response character of its cantilever setup to voltage 被引量:1
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作者 唐华平 聂拓 +3 位作者 唐运军 殷陈峰 唐春喜 王桥医 《Journal of Central South University of Technology》 EI 2008年第3期387-391,共5页
As a new ionic polymer-metal composite(IPMC) for artificial muscle,the mechanical performance parameters and the relationship between the deformation and the electrical parameters of the IPMC were studied. With the di... As a new ionic polymer-metal composite(IPMC) for artificial muscle,the mechanical performance parameters and the relationship between the deformation and the electrical parameters of the IPMC were studied. With the digital speckle correlation method,the constitutive relationship of the IPMC was confirmed. With non-contact photography measurement,a cantilever setup was designed to confirm the relationship between the deformation of the IPMC film and the applied voltage. The relationship curve of tip displacement of the IPMC cantilever setup vs the voltage was achieved. The results indicate that the IPMC is isotropic,its elastic modulus is 232 MPa and Poisson ratio is 0.163. The curve achieved from the test of the tip displacement of the IPMC cantilever setup shows that the tip displacement reaches the maximum when the stimulated voltage is 5 V. And the tip displacement descends largely when the frequency of the applied voltage is between 30 mHz and 100 mHz. 展开更多
关键词 constitutive relationship ionic polymer-metal composite(IPMC) cantilever setup static response
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Soft actuator based on ion-exchange polymer-metal composite
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作者 罗玉元 金健 +1 位作者 张国贤 李朝东 《Journal of Shanghai University(English Edition)》 CAS 2007年第1期88-90,共3页
Ion-exchange polymer-metal composite (IPMC) is a new electroactive material. It has large deformation and high force weight ratio in the presence of low voltage (〈1.5 V). In this study a soft actuator known as ar... Ion-exchange polymer-metal composite (IPMC) is a new electroactive material. It has large deformation and high force weight ratio in the presence of low voltage (〈1.5 V). In this study a soft actuator known as artificial muscle based on IPMC was prepared. The IPMC actuator is composed of a perfluorinated ion-exchange membrane and platinum plated on both sides of the membrane by chemical means. Experiences and some key points are introduced in preparation of the IPMC. Electromechanical behaviors of the actuator are investigated, Factors related to the actuator performance are discussed. 展开更多
关键词 ion-exchange polymer-metal composite (IPMC) ACTUATOR artificial muscle
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Neural Network Approach to Modelling the Behaviour of Ionic Polymer-Metal Composites in Dry Environments
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作者 Andrés Díaz Lantada Pilar Lafont Morgado +2 位作者 José Luis Munoz Sanz Juan Manuel Munoz Guijosa Javier Echávarri Otero 《Journal of Signal and Information Processing》 2012年第2期137-145,共9页
Ionic polymer-metal composites (IPMCs) are especially interesting electroactive polymers because they show large a deformation in the presence of a very low driving voltage (around 1 - 2 V) and several applications ha... Ionic polymer-metal composites (IPMCs) are especially interesting electroactive polymers because they show large a deformation in the presence of a very low driving voltage (around 1 - 2 V) and several applications have recently been proposed. Normally a humid environment is required for the best operation, although some IPMCs can operate in a dry environment, after proper encapsulation or if a solid electrolyte is used in the manufacturing process. However, such solutions usually lead to increasing mechanical stiffness and to a reduction of actuation capabilities. In this study we focus on the behaviour of non-encapsulated IPMCs as actuators in dry environments, in order to obtain relevant information for design tasks linked to the development of active devices based on this kind of smart material. The non-linear response obtained in the characterisation tests is especially well-suited to modelling these actuators with the help of artificial neural networks (ANNs). Once trained with the help of characterisation data, such neural networks prove to be a precise simulation tool for describing IPMC response in dry environments. 展开更多
关键词 IONIC polymer-metal Composites (IPMCs) Artificial NEURAL Networks (ANNs) Smart Materials MODELLING and Simulation
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On the thrust performance of an ionic polymer-metal composite actuated robotic fish: Modeling and experimental investigation 被引量:5
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作者 WANG TianMiao SHEN Qi +1 位作者 WEN Li LIANG JianHong 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第12期3359-3369,共11页
In this paper, we theoretically predict and experimentally measure the thrust efficiency of a biomimetic robotic fish, which is propelled by an ionic polymer-metal composite (IPMC) actuator. A physics-based model th... In this paper, we theoretically predict and experimentally measure the thrust efficiency of a biomimetic robotic fish, which is propelled by an ionic polymer-metal composite (IPMC) actuator. A physics-based model that consists of IPMC dynamics and hydrodynamics was proposed, and simulation was conducted. In order to test the thrust performance of the robotic fish, a novel experimental apparatus was developed for hydrodynamic experiments. Under a servo towing system, the IPMC fish swam at a self-propelled speed where external force is averagely zero. Experimental results demonstrated that the theoretical model can well predict the thrust efficiency of the robotic fish. A maximum thrust efficiency of 2.3x10-3 at 1 Hz was recorded experi- mentally, the maximum thrust force was 0.0253 N, recorded at 1.2 Hz, while the maximum speed was 0.021 m/s, recorded at 1.5 Hz, and a peak power of 0.36 W was recorded at 2.6 Hz. Additionally, the optimal actuation frequency for the thrust efficiency was also recorded at the maximum self-propelled speed. The present method of examining the thrust efficiency may also be applied to the studies of other types of smart material actuated underwater robots. 展开更多
关键词 biomimetic robotic fish hydrodynamic modeling thrust efficiency measurement ionic polymer-metal composites
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Bio-inspired robotic manta ray powered by ionic polymer-metal composite artificial muscles 被引量:4
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作者 Zheng Chen Tae I.Um Hilary Bart-Smith 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期296-308,共13页
The manta ray(Manta birostris)is the largest species of rays that demonstrates excellent swimming capabilities via large-amplitude flapping of its pectoral fins.In this article,we present a bio-inspired robotic manta ... The manta ray(Manta birostris)is the largest species of rays that demonstrates excellent swimming capabilities via large-amplitude flapping of its pectoral fins.In this article,we present a bio-inspired robotic manta ray using ionic polymer–metal composite(IPMC)as artificial muscles to mimic the swimming behavior of the manta ray.The robot utilizes two artificial pectoral fins to generate undulatory flapping motions,which produce thrust for the robot.Each pectoral fin consists of an IPMC muscle in the leading edge and a passive polydimethylsiloxane membrane in the trailing edge.When the IPMC is actuated,the passive polydimethylsiloxane membrane follows the bending of the leading edge with a phase delay,which leads to an undulatory flapping motion on the fin.Characterization of the pectoral fin has shown that the fin can generate flapping motions with up to 100%tip deflection and 40◦twist angle.To test the free-swimming performance of the robot,a light and compact on-board control unit with a lithium ion polymer battery has been developed.The experimental results have shown that the robot can swim at 0.067 BL/s with portable power consumption of under 2.5 W. 展开更多
关键词 ionic polymer-metal composite artificial muscle bio-inspired robot
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Novel Strategies for Preparation and Characterization of Functional Polymer-metal Nanocomposites for Electrochemical Applications
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作者 D.N.Muraviev 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期630-631,共2页
1 Introduction The synthesis and characterization of Metal NanoParticles (MNPs) has attracted great interest of scientists and technologists within the last years due their unique physical and chemical properties,whic... 1 Introduction The synthesis and characterization of Metal NanoParticles (MNPs) has attracted great interest of scientists and technologists within the last years due their unique physical and chemical properties,which substantially differ from those of both bulk material and single atoms.These properties provide various practical applications of MNPs including catalysis-and electrocatalysis-based processes,which occur in,for example,fuel cells of different types or in various sensing devices (e.g.amper... 展开更多
关键词 novel strategies polymer-metal NANOCOMPOSITES
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Wireless actuation and control of ionic polymer-metal composite actuator using a microwave link
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作者 J.S.Lee W.Yim +1 位作者 C.Bae K.J.Kim 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期244-262,共19页
The ionic polymer–metal composite(IPMC),a type of electroactive polymer(EAP)actuator,has created a unique opportunity to design robots that mimic the motion of biological systems due to its soft structure and operati... The ionic polymer–metal composite(IPMC),a type of electroactive polymer(EAP)actuator,has created a unique opportunity to design robots that mimic the motion of biological systems due to its soft structure and operation at a low voltage.Although this polymer actuator has strong potential for a next-generation artificial muscle actuator,it has been observed by many researchers that supplying actuation voltages in multiple locations is challenging.In robotic applications,a tethered operation is prohibited and the battery weight can be critical for actual implementation.In this research,the remote unit can provide necessary power and control signals to the target mobile robot units actuated by IPMCs.This research addresses a novel approach of using a wireless power link between the IPMC and a remote unit using microstrip patch antennas designed on the electrode surface of the IPMC for transmitting the power.Frequency modulation of the microwave is proposed to selectively actuate a particular portion of the IPMC where the matching patch antenna pattern is located.This approach can be especially useful for long-term operation of small-scale locomotion units and avoids problems caused by complex internal wiring often observed in various types of biologically inspired robots. 展开更多
关键词 ionic polymer-metal composite actuator microwave link wireless actuation robotic application biomimetic robot
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Ionic polymer-metal composite mechanoelectric transduction:effect of impedance
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作者 Rashi Tiwari 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期275-295,共21页
Ionic polymer–metal composites(IPMCs)are commonly used as soft actuators due to their electromechanical response.However,the reverse phenomenon,i.e.IPMC’s ability to generate charge on application of mechanical stra... Ionic polymer–metal composites(IPMCs)are commonly used as soft actuators due to their electromechanical response.However,the reverse phenomenon,i.e.IPMC’s ability to generate charge on application of mechanical strain(mechanoelectric response),is not very well understood.The concept of mechanoelectric transduction and its dependence on complex IPMC architecture comprising of electrode,polymer and composite layer is illustrated with a phenomenological model.The impedance model takes into account the charge transport inside the polymer and layer properties in terms of their impedances.The model lucidly indicates the significance of capacitance in IPMC transduction.The impedance model is used for studying IPMC step and frequency response and the effect of IPMC capacitance on its application as energy harvester. 展开更多
关键词 ionic polymer-metal composite CAPACITANCE IMPEDANCE mechanoelectric response
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Development of an ionic polymer-metal composite stepper motor using a novel actuator model
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作者 A.J.McDaid K.C.Aw +2 位作者 K.Patel S.Q.Xie E.Haemmerle 《International Journal of Smart and Nano Materials》 SCIE EI 2010年第4期261-277,共17页
A novel ionic polymer–metal composite(IPMC)actuated stepper motor was developed in order to demonstrate an innovative design process for complete IPMC systems.The motor was developed by utilizing a novel model for IP... A novel ionic polymer–metal composite(IPMC)actuated stepper motor was developed in order to demonstrate an innovative design process for complete IPMC systems.The motor was developed by utilizing a novel model for IPMC actuators integrated with the complete mechanical model of the motor.The dynamic,nonlinear IPMC model can accurately predict the displacement and force actuation in air for a large range of input voltages as well as accounting for interactions with mechanical systems and external loads.By integrating this geometrically scalable IPMC model with a mechanical model of the motor mechanism an appropriate size IPMC strip has been chosen to achieve the required motor specifications.The entire integrated system has been simulated and its performance verified.The system has been built and the experimental results validated to show that the motor works as simulated and can indeed achieve continuous 360rotation,similar to conventional motors.This has proven that the model is an indispensable design tool for integrated IPMC actuators into real systems.This newly developed system has demonstrated the complete design process for smart material actuator systems,representing a large step forward and aiding in the progression of IPMCs towards wide acceptance as replacements for traditional actuators. 展开更多
关键词 ionic polymer-metal composite(IPMC) stepper motor mechanical design model application
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Modeling Ionic Polymer-Metal Composites with Space-Time Adaptive Multimesh hp-FEM
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作者 David Pugal Pavel Solin +1 位作者 Kwang J.Kim Alvo Aabloo 《Communications in Computational Physics》 SCIE 2012年第1期249-270,共22页
We are concerned with a model of ionic polymer-metal composite(IPMC)materials that consists of a coupled system of the Poisson and Nernst-Planck equations,discretized by means of the finite element method(FEM).We show... We are concerned with a model of ionic polymer-metal composite(IPMC)materials that consists of a coupled system of the Poisson and Nernst-Planck equations,discretized by means of the finite element method(FEM).We show that due to the transient character of the problem it is efficient to use adaptive algorithms that are capable of changing the mesh dynamically in time.We also show that due to large qualitative and quantitative differences between the two solution components,it is efficient to approximate them on different meshes using a novel adaptive multimesh hp-FEM.The study is accompanied with numerous computations and comparisons of the adaptive multimesh hp-FEMwith several other adaptive FEM algorithms. 展开更多
关键词 Ionic polymer-metal composites IPMC Nernst-Planck equation Poisson equation finite element method FEM adaptive multi-mesh hp-FEM
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不同金属盐离子对乳清分离蛋白纤维聚合物形成的影响 被引量:1
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作者 董世鹏 刘美艳 +3 位作者 邹霈怡 刘丹 陈鑫 李然红 《食品工业科技》 北大核心 2025年第11期124-131,共8页
本研究旨在探究不同金属离子(NaCl、KCl、CaCl_(2)、AlCl_(3)和FeCl_(3))对乳清分离蛋白(whey protein isolate,WPI)纤维聚合物聚合动力学、形态和结构的影响。结果表明,不同金属离子影响了WPI纤维聚合物的最终结构和特征。NaCl、KCl和C... 本研究旨在探究不同金属离子(NaCl、KCl、CaCl_(2)、AlCl_(3)和FeCl_(3))对乳清分离蛋白(whey protein isolate,WPI)纤维聚合物聚合动力学、形态和结构的影响。结果表明,不同金属离子影响了WPI纤维聚合物的最终结构和特征。NaCl、KCl和CaCl_(2)对WPI的聚集影响较小,增加了溶液pH和电导率,而AlCl_(3)和FeCl_(3)加速了WPI的聚集,降低了溶液pH,增加了溶液电导率;与原始WPI纤维聚合物硫黄素T(Th T)荧光强度(388.92)相比,NaCl、KCl和CaCl_(2)增加Th T荧光强度分别至465.39、433.37和486.83,增加了WPI纤维聚合物的生成量,AlCl_(3)和FeCl_(3)降低Th T荧光强度分别至228.81和90.24,降低了WPI纤维聚合物的生成量;不同金属离子均改变了WPI聚合动力学,降低了(df/dt)_(max)值,并改变了滞后时间;NaCl、KCl和CaCl_(2)对WPI纤维聚合物的形态影响较小,AlCl_(3)和FeCl_(3)使WPI纤维聚合物更团簇、粗而杂乱;傅里叶红外光谱结果表明,NaCl、KCl和CaCl_(2)促进β-折叠结构生成,而AlCl_(3)和FeCl_(3)抑制了β-折叠生成,不同金属离子的加入均改变了纤维中β-链间的特征距离。这些结果为利用WPI制备不同聚集形态的纤维聚合物提供了科学依据。 展开更多
关键词 乳清分离蛋白 聚合动力学 金属离子 纤维聚合物 电导率 硫黄素T
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Performance Enhancement of Aquivion-based Ionic Polymer Metal Composites for Cylindrical Actuators 被引量:1
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作者 Xiaojie Tong Min Yu +3 位作者 Guoxiao Yin Yuwei Wu Chengbo Tian Gengying Wang 《Journal of Bionic Engineering》 2025年第1期1-11,共11页
As a kind of ionic artificial muscle material,Ionic Polymer-Metal Composites(IPMCs)have the advantages of a low drive current,light weight,and significant flexibility.IPMCs are widely used in the fields of biomedicine... As a kind of ionic artificial muscle material,Ionic Polymer-Metal Composites(IPMCs)have the advantages of a low drive current,light weight,and significant flexibility.IPMCs are widely used in the fields of biomedicine,soft robots,etc.However,the displacement and blocking force of the traditional sheet-type Nafion-IPMC need to be improved,and it has the limitation of unidirectional actuation.In this paper,a new type of short side chain Aquivion material is used as the polymer in the IPMC.The cylindrical IPMC is prepared by extrusion technology to improve its actuation performance and realize multi-degree-of-freedom motion.In comparison to the traditional Nafion-IPMC,the ion exchange capacity,specific capacitance,and conductivity of Aquivion-IPMC are improved by 28%,27%,and 32%,respectively,and the displacement and blocking force are improved by 57%and 25%,respectively.The cylindrical actuators can be deflected in eight directions.This indicates that Aquivion,as a polymer membrane for IPMC,holds significant application potential.By designing a cylindrical IPMC electrode distribution,the multi-degree-of-freedom deflection of IPMC can be realized. 展开更多
关键词 Ionic polymer-metal composite Equivalent weight Aquivion NAFION Actuation performance
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原位聚合制备聚合物电解质用于锂金属电池的研究进展 被引量:1
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作者 谢清水 张世禹 +2 位作者 张成锟 胡欣超 彭栋梁 《厦门大学学报(自然科学版)》 北大核心 2025年第1期1-14,62,共15页
[背景]聚合物电解质(PE)由于其良好的热稳定性、高柔韧性以及可加工性,成为固态电解质理想材料之一.原位聚合技术能增强电极-电解质的界面相容性,革新传统PE的制备方法,已广泛应用于PE的制备.[进展]本文阐述了原位聚合制备PE的最新研究... [背景]聚合物电解质(PE)由于其良好的热稳定性、高柔韧性以及可加工性,成为固态电解质理想材料之一.原位聚合技术能增强电极-电解质的界面相容性,革新传统PE的制备方法,已广泛应用于PE的制备.[进展]本文阐述了原位聚合制备PE的最新研究进展,探讨了不同原位聚合工艺制备PE的优缺点,比较了不同单体通过原位聚合制备PE的差异,综述了原位聚合设计PE在离子电导率、机械性能、高电压稳定性和阻燃性能等方面的改性方法.[展望]基于上述研究进展,总结了原位聚合制备的PE在锂金属电池应用中所面临的问题和发展方向.由于各类电解质固有的局限性,研究者需要更深入地思考如何选择合适的方案对PE进行改性,为高能量密度固态锂金属电池的研发提供指导. 展开更多
关键词 聚合物电解质 原位聚合 锂金属电池 电化学性能
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可控自由基聚合在MOFs及其功能化中的应用研究进展
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作者 赵敏坚 陈强 《化工新型材料》 北大核心 2025年第11期61-68,共8页
金属有机框架材料(MOFs)通过金属-有机配体的精准组装,实现结构与功能的原子级调控。而可控自由基聚合基于单体反应活性和链动力学的动态调控,优化分子量分布与机械性能。尽管两者在反应机理、应用场景等方面存在本质差异,但均表现出分... 金属有机框架材料(MOFs)通过金属-有机配体的精准组装,实现结构与功能的原子级调控。而可控自由基聚合基于单体反应活性和链动力学的动态调控,优化分子量分布与机械性能。尽管两者在反应机理、应用场景等方面存在本质差异,但均表现出分子层面的设计灵活性与动态响应能力,这使其在交叉应用中能够突破单一体系的固有局限。MOFs利用其孔道结构和金属节点调控可控自由基聚合反应过程,而可控自由基聚合在MOFs框架聚合功能高分子层保护其活性位点或优化其性能。聚焦MOFs与可控自由基聚合的交叉融合应用研究,系统综述了二者协同作用的最新进展,总结“MOF结构设计-可控自由基聚合策略”的双驱协同模式,加深理解无机-有机界面相互作用机制,为新型功能材料(如兼具高催化活性、动态响应性及功能可设计性等)的开发提供一定的参考。 展开更多
关键词 可控自由基聚合 金属-有机框架 聚合物 复合物
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脱氢聚合制备极性高分子材料研究进展
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作者 陈丽 李琳 +3 位作者 饶艺伟 杨维冉 简忠保 姚昌广 《高分子学报》 北大核心 2025年第4期551-563,共13页
随着环保意识的提高,人们越来越注重材料制备过程的原子经济性和步骤经济性.聚酰胺、聚酯和聚脲作为合成高分子材料,具有优异的力学性能、化学稳定性和热稳定性,能满足不同领域的使用需求.脱氢偶联能将伯醇转化为醛中间体,它进一步与胺... 随着环保意识的提高,人们越来越注重材料制备过程的原子经济性和步骤经济性.聚酰胺、聚酯和聚脲作为合成高分子材料,具有优异的力学性能、化学稳定性和热稳定性,能满足不同领域的使用需求.脱氢偶联能将伯醇转化为醛中间体,它进一步与胺和醇反应生成酰胺、酯和脲等化合物;该反应避免了繁琐的底物合成和羧酸及其衍生物的使用,具有反应条件温和、选择性高和原子经济性等优点,在有机合成方面已经取得显著进展.然而,将醇的脱氢偶联应用到高分子制备方面的研究还相对较少.本文系统介绍了近年来脱氢聚合在聚酰胺、聚酯和聚脲制备方面的研究进展.首先简述了这三类聚合物的独特性能及其在工业生产和日常生活中的广泛应用,并指出了传统制备方法的局限性;通过对比分析,突显了脱氢聚合在制备极性高分子材料方面的显著优势.其次,详细讨论了用于脱氢聚合的各种催化剂及其反应机理.最后,对脱氢聚合技术在极性高分子材料制备领域的发展趋势进行了展望. 展开更多
关键词 脱氢聚合 聚酰胺 聚酯 聚脲 金属配合物
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生物基9-癸烯酸甲酯/乙烯共聚物的制备 被引量:2
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作者 程键 李世文 +2 位作者 李倩 马占芳 李化毅 《生物质化学工程》 2025年第2期48-52,共5页
生物基9-癸烯酸甲酯是生物基油酸甲酯与乙烯的交叉复分解产物,乙烯与9-癸烯酸甲酯的共聚反应可能会开辟新的生物基聚烯烃合成路线。本研究采用配位聚合的方法,成功将生物基9-癸烯酸甲酯与乙烯进行共聚,经过工艺条件探索,得到非茂后过渡... 生物基9-癸烯酸甲酯是生物基油酸甲酯与乙烯的交叉复分解产物,乙烯与9-癸烯酸甲酯的共聚反应可能会开辟新的生物基聚烯烃合成路线。本研究采用配位聚合的方法,成功将生物基9-癸烯酸甲酯与乙烯进行共聚,经过工艺条件探索,得到非茂后过渡金属催化剂(Ni-N-Br)-甲基铝氧烷(MAO)催化体系是适合该反应的最佳催化路线;温度30℃、乙烯压力0.05 MPa、反应时间30 min、甲苯溶剂100 mL、Ni-N-Br用量5μmol、MAO用量2 mL和生物基9-癸烯酸甲酯浓度0.1 mol/L时,得到的生物基9-癸烯酸甲酯/乙烯共聚物,其熔融温度125.44℃、产率1.02 g、结晶温度114.42℃、重均相对分子质量(M_(w))2.63×10^(4)、相对分子质量分布1.6。通过红外光谱、核磁共振氢谱、DSC等证实了生物基9-癸烯酸甲酯/乙烯共聚物成功合成,为生物基极性单体与乙烯共聚提供了可行性路径。 展开更多
关键词 生物基9-癸烯酸甲酯 配位聚合 非茂后过渡金属催化剂 生物基极性单体
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具有双重交联结构的低成本高性能降滤失剂
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作者 王志永 周新宇 +1 位作者 李怀科 耿铁 《油田化学》 北大核心 2025年第2期198-205,214,共9页
人工合成聚合物作为水基钻井液降滤失剂仅通过改变共聚物官能团的类型和比例已很难满足钻井工程的需要,尤其是在超高温高盐度条件下通过加大功能单体的用量会增加其成本。通过调整交联剂,在主单体丙烯酰胺(AM)中添加抗盐单体2-丙烯酰胺... 人工合成聚合物作为水基钻井液降滤失剂仅通过改变共聚物官能团的类型和比例已很难满足钻井工程的需要,尤其是在超高温高盐度条件下通过加大功能单体的用量会增加其成本。通过调整交联剂,在主单体丙烯酰胺(AM)中添加抗盐单体2-丙烯酰胺-2-甲基丙磺酸(AMPS)和耐温单体N-乙烯基吡咯烷酮(NVP),同时采用极少量的有机交联剂N,N'-亚甲基双丙烯酰胺(MBA)和金属交联剂柠檬酸锆(MC),制备具有双重交联结构的降滤失剂。以聚合物的高温降滤失效果为考察指标,采用单因素实验优化合成条件,并利用激光粒度分析仪、傅里叶变换红外光谱、扫描电子显微镜和热重分析仪分析了共聚物的粒径分布、微观结构、表面形貌、耐热性能和抗温机理等。结果表明,降滤失剂的最佳制备条件为:AM、AMPS、NVP单体质量比为18∶1∶1,MBA与MC的质量比为1∶3,引发剂用量为1.0%,搅拌速度400 r/min,反应温度65℃。具有双重交联结构降滤失剂的平均粒径为16.48μm,耐温高达350℃。含有5000 mg/L降滤失剂的基浆在210℃下热滚16 h后的高温高压滤失量和API滤失量分别由77.6、18.8 mL降至31.4、6.8 m L。具有双重交联结构降滤失剂的抗高温机理为:水解后的聚合物分子链与金属交联剂进行二次交联,保护了水解的聚合物分子链不会快速降解,从而形成更加致密复杂的三维网络结构,使得聚合物降滤失剂表现出优异的耐温抗盐降滤失性能。 展开更多
关键词 反相悬浮聚合法 金属交联剂 有机交联剂 双重交联 降滤失剂
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金属配合物催化合成二氧化碳基聚碳酸酯研究进展
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作者 寻志伟 顾永正 +4 位作者 李歌 魏书洲 黄杰 沈伯雄 赵忠 《洁净煤技术》 北大核心 2025年第S1期132-145,共14页
随着全球对环境保护和可持续发展的日益关注,二氧化碳(CO_(2))的资源化利用已逐渐成为化学工程领域的重要研究课题。通过催化CO_(2)与环氧化物的共聚反应,可以合成含有碳酸酯基团的聚合物,为绿色、可持续的聚合物制备提供了新的途径。因... 随着全球对环境保护和可持续发展的日益关注,二氧化碳(CO_(2))的资源化利用已逐渐成为化学工程领域的重要研究课题。通过催化CO_(2)与环氧化物的共聚反应,可以合成含有碳酸酯基团的聚合物,为绿色、可持续的聚合物制备提供了新的途径。因此,催化剂的设计与优化也逐步成为该领域的核心研究方向。综述近年来CO_(2)合成聚碳酸酯的研究进展,系统总结催化剂的研究现状,重点讨论Salen金属配合物的结构特征、活性中心、催化机制及产物性能等方面的最新成果。此外,展望多核催化剂体系在CO_(2)聚合反应中的应用前景,提出了该领域在催化剂设计、反应体系优化及催化剂可回收性等方面的挑战与机遇。 展开更多
关键词 聚碳酸酯 二氧化碳 固相催化剂 Salen金属配合物 聚合反应
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螺环-salen配合物催化开环聚合制备立构规整、功能化聚羟基脂肪酸酯
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作者 黄皓毅 谢敏 +3 位作者 黄玉婷 崔嘉豪 蔡中正 朱剑波 《化学学报》 北大核心 2025年第8期810-815,共6页
聚羟基脂肪酸酯(polyhydroxyalkanoates,PHAs)作为一类由细菌发酵制备的生物可降解材料,因其性能可媲美商业聚烯烃,被视为传统塑料的潜在替代品.然而,高昂的生产成本严重制约了其规模化应用.尽管天然细菌发酵PHAs呈现丰富的结构多样性,... 聚羟基脂肪酸酯(polyhydroxyalkanoates,PHAs)作为一类由细菌发酵制备的生物可降解材料,因其性能可媲美商业聚烯烃,被视为传统塑料的潜在替代品.然而,高昂的生产成本严重制约了其规模化应用.尽管天然细菌发酵PHAs呈现丰富的结构多样性,但产物多局限于烷基侧基取代衍生物.本研究通过开发外消旋杂原子取代四元环内酯单体的立体选择性聚合体系,成功合成了具有高间同立构结构的PHAs(P_(r)>0.95),其分子结构显著区别于微生物合成PHAs,突破了传统发酵法在结构调控上的局限性,拓展了PHAs的结构多样性及潜在应用范围. 展开更多
关键词 开环聚合 聚羟基脂肪酸酯 立体选择性聚合 可持续聚合物 金属配合物
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