Two kinds of tough ductile heatresisting thermoplastic, namely bisphenol A polysulfone (PSF) and polyethersulfone (PES) were used to toughen thermoset epoxy resin. A systematic study on the relationship between the mo...Two kinds of tough ductile heatresisting thermoplastic, namely bisphenol A polysulfone (PSF) and polyethersulfone (PES) were used to toughen thermoset epoxy resin. A systematic study on the relationship between the molecular weight and the terminal group of the thermoplastic modifier and the fracture toughness of the modified resin was carried out. The morphology of PSF modified epoxy resin was surveyed. With the same kind of PSF the structure of the epoxy resin and the toughening effect of PSF was also investigated. The fractography of PSF, particle modified epoxy was examined in detail with SEM. The contribution of every possible energy absorption process has been discussed. Crack pinning mechanism seems to be the most important toughening mechanism for tough ductile thermoplastic PSF particle modified epoxy system.展开更多
The particulate toughening behaviour of epoxy resins modified by ductile thermoplastics is elucidated here by various bridging models. The experimental data for three different epoxy/PSF sys- tems are presented to ill...The particulate toughening behaviour of epoxy resins modified by ductile thermoplastics is elucidated here by various bridging models. The experimental data for three different epoxy/PSF sys- tems are presented to illustrate the trend of the toughening characteristics. The conventional continuous bridging model is shown to have underestimated the effect of the particulate toughening. A joint appli- cation of the discrete bridging model and the multiple bridging model, however, shows promising result for modified epoxy systems such as AG80/DDS/PSF and E51/DDS/PSF. These models also provide quantitative descriptions for the crack pinning phenomenon previously observed by Fu and Sun in AG80/DDS/PSF.展开更多
基金Sponsored by the National Natural Science Foundation of China
文摘Two kinds of tough ductile heatresisting thermoplastic, namely bisphenol A polysulfone (PSF) and polyethersulfone (PES) were used to toughen thermoset epoxy resin. A systematic study on the relationship between the molecular weight and the terminal group of the thermoplastic modifier and the fracture toughness of the modified resin was carried out. The morphology of PSF modified epoxy resin was surveyed. With the same kind of PSF the structure of the epoxy resin and the toughening effect of PSF was also investigated. The fractography of PSF, particle modified epoxy was examined in detail with SEM. The contribution of every possible energy absorption process has been discussed. Crack pinning mechanism seems to be the most important toughening mechanism for tough ductile thermoplastic PSF particle modified epoxy system.
基金The project sponsored by the National Natural Science Foundation of China under the Grant 5870134.
文摘The particulate toughening behaviour of epoxy resins modified by ductile thermoplastics is elucidated here by various bridging models. The experimental data for three different epoxy/PSF sys- tems are presented to illustrate the trend of the toughening characteristics. The conventional continuous bridging model is shown to have underestimated the effect of the particulate toughening. A joint appli- cation of the discrete bridging model and the multiple bridging model, however, shows promising result for modified epoxy systems such as AG80/DDS/PSF and E51/DDS/PSF. These models also provide quantitative descriptions for the crack pinning phenomenon previously observed by Fu and Sun in AG80/DDS/PSF.
