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Bioenergy recovery and carbon emissions benefits of short-term bio-thermophilic pretreatment on low organic sewage sludge anaerobic digestion:A pilot-scale study
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作者 Hui Wang Xiang Fu +5 位作者 Haozhe Huang Danni Shen Dongdong Fan Liming Zhu Xiaohu Dai Bin Dong 《Journal of Environmental Sciences》 2025年第2期321-335,共15页
Sewage sludge in cities of Yangzi River Belt,China,generally exhibits a lower organic content and higher silt contentdue to leakage of drainage system,which caused low bioenergy recovery and carbon emission benefits i... Sewage sludge in cities of Yangzi River Belt,China,generally exhibits a lower organic content and higher silt contentdue to leakage of drainage system,which caused low bioenergy recovery and carbon emission benefits in conventional anaerobic digestion(CAD).Therefore,this paper is on a pilot scale,a bio-thermophilic pretreatment anaerobic digestion(BTPAD)for low organic sludge(volatile solids(VS)of 4%)was operated with a long-term continuous flow of 200 days.The VS degradation rate and CH_(4) yield of BTPAD increased by 19.93%and 53.33%,respectively,compared to those of CAD.The analysis of organic compositions in sludge revealed that BTPAD mainly improved the hydrolysis of proteins in sludge.Further analysis of microbial community proportions by high-throughput sequencing revealed that the short-term bio-thermophilic pretreatment was enriched in Clostridiales,Coprothermobacter and Gelria,was capable of hydrolyzing acidified proteins,and provided more volatile fatty acid(VFA)for the subsequent reaction.Biome combined with fluorescence quantitative polymerase chain reaction(PCR)analysis showed that the number of bacteria with high methanogenic capacity in BTPAD was much higher than that in CAD during the medium temperature digestion stage,indicating that short-term bio-thermophilic pretreatment could provide better methanogenic conditions for BTPAD.Furthermore,the greenhouse gas emission footprint analysis showed that short-term bio-thermophilic pretreatment could reduce the carbon emission of sludge anaerobic digestion system by 19.18%. 展开更多
关键词 Sludge Anaerobic digestion Bio-thermophilic pretreatment pilot scale Molecular microbiology Carbon emissions
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Nitrogen and phosphorus removal in pilot-scale anaerobic-anoxic oxidation ditch system 被引量:35
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作者 PENG Yongzhen HOU Hongxun +2 位作者 WANG Shuying CUI Youwei Zhiguo Yuan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2008年第4期398-403,共6页
To achieve high efficiency of nitrogen and phosphorus removal and to investigate the rule of simultaneous nitrification and denitrification phosphorus removal (SNDPR), a whole course of SNDPR damage and recovery was... To achieve high efficiency of nitrogen and phosphorus removal and to investigate the rule of simultaneous nitrification and denitrification phosphorus removal (SNDPR), a whole course of SNDPR damage and recovery was studied in a pilot-scale, anaerobicanoxic oxidation ditch (OD), where the volumes of anaerobic zone, anoxic zone, and ditches zone of the OD system were 7, 21, and 280 L, respectively. The reactor was fed with municipal wastewater with a flow rate of 336 L/d. The concept of simultaneous nitrification and denitrification (SND) rate (rSND) was put forward to quantify SND. The results indicate that: (1) high nitrogen and phosphorus removal efficiencies were achieved during the stable SND phase, total nitrogen (TN) and total phosphate (TP) removal rates were 80% and 85%, respectively; (2) when the system was aerated excessively, the stability of SND was damaged, and rSND dropped from 80% to 20% or less; (3) the natural logarithm of the ratio of NOx to NH4^+ in the effluent had a linear correlation to oxidation-reduction potential (ORP); (4) when NO3^- was less than 6 mg/L, high phosphorus removal efficiency could be achieved; (5) denitrifying phosphorus removal (DNPR) could take place in the anaerobic-anoxic OD system. The major innovation was that the SND rate was devised and quantified. 展开更多
关键词 oxidation ditch biological nitrogen removal biological phosphorus removal simultaneous nitrification and denitrification (SND) pilot scale municipal wastewater
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Cells grouping scheme against pilot contamination in large scale antennas system
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作者 Zhichao Zhou Yang Xiao Dong Wang 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第3期531-540,共10页
The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems(LSAS). The former researches have confirmed... The influence of cells groupings factor to the performance of the cells groupings time-shift pilot scheme is researched for the multiple cells large scale antennas systems(LSAS). The former researches have confirmed that the cells groupings time-shift pilots scheme is effective to reduce inter-cell interference, especially pilot contamination, which results from the pilot reuse in adjacent cells. However, they have not specified reasonable cells groupings factor, which plays a critical role in the general performance of the LSAS. Therefore, this problem is researched in details. The time for reverse-link data transmission will be compressed, when the groupings factor surpasses a certain range. Thus it is not always beneficial to increase the cells groupings factor without limitation. Furthermore,a reasonable cells groupings factor is deduced from the perspective of optimization to enhance the system performance. Simulations verify the proposed cell grouping factor. 展开更多
关键词 large scale antenna system multiple cells inter-cell interference time-shift pilots scheme cells grouping factor system performance
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Feasibility and simulation model of a pilot scale membrane bioreactor for wastewater treatment and reuse from Chinese traditional medicine 被引量:5
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作者 REN Nan-qi YAN Xian-feng +3 位作者 CHEN Zhao-bo HU Dong-xue GONG Man-li GUO Wan-qian 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第2期129-134,共6页
The lack and pollution of water resource make wastewater reuse necessary. The pilot scale long-term tests for submerged membrane bioreactor were conducted to treat the effluents of anaerobic or aerobic treatment proce... The lack and pollution of water resource make wastewater reuse necessary. The pilot scale long-term tests for submerged membrane bioreactor were conducted to treat the effluents of anaerobic or aerobic treatment process for the high-strength Chinese traditional medicine wastewater. This article was focused on the feasibility of the wastewater treatment and reuse at shorter hydraulic retention time (HRT) of 5.0, 3.2 and 2.13 h. MLSS growth, membrane flux, vacuum values and chemical cleaning periods were also investigated. The experimental results of treating two-phase anaerobic treatment effluent demonstrated that the CODfilt was less than 100 mg/L when the influent COD was between 500-10000 mg/L at HRT of 5.0 h, which could satisfy the normal discharged standard in China. The experimental results to treat cross flow aerobic reactor effluent demonstrated that the average value of CODfilt was 17.28 mg/L when the average value of influent COD was 192.84 mg/L at HRT of 2.13 h during 106 d, which could completely meet the normal standard for water reuse. The maximum MLSS and MLVSS reached 24000 and 14500 mg/L at HRT of 3.2 h respectively. Membrane flux had maximal resume degrees of 94.7% at vacuum value of 0.02 MPa after cleaning. Chemical cleaning periods of membrane module were 150 d. A simulation model of operational parameters was also established based on the theory of back propagation neural network and linear regression of traditional mathematical model. The simulation model showed that the optimum operational parameters were suggested as follows: HRT was 5.0 h, SRT was 100 d, the range of COD loading rate was between 10.664-20.451 kg/(m3.d), the range of MLSS was between 7543-13694 mg/L. 展开更多
关键词 submerged membrane bioreactor (SMBR) Chinese traditional medicine wastewater hydraulic retention time (HRT) simulation model pilot scale test
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A pilot scale trickling filter with pebble gravel as media and its performance to remove chemical oxygen demand from synthetic brewery wastewater
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作者 Haimanot HABTE LEMJI Hartmut ECKST DT 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 SCIE CAS CSCD 2013年第10期924-933,共10页
Evaluating the performance of a biotrickling filter for the treatment of wastewaters produced by a company manufacturing beer was the aim of this study.A pilot scale trickling filter filled with gravel was used as the... Evaluating the performance of a biotrickling filter for the treatment of wastewaters produced by a company manufacturing beer was the aim of this study.A pilot scale trickling filter filled with gravel was used as the experimental biofilter.Pilot scale plant experiments were made to evaluate the performance of the trickling filter aerobic and anaerobic biofilm systems for removal of chemical oxygen demand(COD) and nutrients from synthetic brewery wastewater.Performance evaluation data of the trickling filter were generated under different experimental conditions.The trickling filter had an average efficiency of(86.81±6.95)% as the hydraulic loading rate increased from 4.0 to 6.4 m3/(m2·d).Various COD concentrations were used to adjust organic loading rates from 1.5 to 4.5 kg COD/(m3·d).An average COD removal efficiency of(85.10±6.40)% was achieved in all wastewater concentrations at a hydraulic loading of 6.4 m3/(m2·d).The results lead to a design organic load of 1.5 kg COD/(m3·d) to reach an effluent COD in the range of 50–120 mg/L.As can be concluded from the results of this study,organic substances in brewery wastewater can be handled in a cost-effective and environmentally friendly manner using the gravel-filled trickling filter. 展开更多
关键词 BIODEGRADATION pilot scale trickling filter Aerobic treatment Brewery wastewater Chemical oxygen demand(COD) Trickling filter performance
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SINOPEC's Success in Fixed-bed Methanol-to-Propylene Pilot Scale Tests
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《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第3期9-9,共1页
The first in China pilot tests of fixed-bed methanol-topropylene unit were successfully implemented at the Yangzi Petrochemical Company(YPC).It is told that this technology has opened up a new process for production o... The first in China pilot tests of fixed-bed methanol-topropylene unit were successfully implemented at the Yangzi Petrochemical Company(YPC).It is told that this technology has opened up a new process for production of propylene through coal gasification,and China has possessed both the fluidized-bed methanolto-propylene process(F-MTP)and the 展开更多
关键词 MTP SINOPEC’s Success in Fixed-bed Methanol-to-Propylene pilot scale Tests
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锥栗冠绵蚧在钱江源国家公园体制试点区的分布与危害
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作者 陈小南 黄羿鑫 +6 位作者 朱秀双 郑心怡 王旭 武三安 余建平 张彦周 朱朝东 《浙江林业科技》 2025年第5期94-99,共6页
2020年6月,钱江源国家公园体制试点区内原古田山国家级自然保护区常绿阔叶林发生大规模锥栗冠绵蚧Coronaproctus castanopsis危害,造成巨大损失。为全面了解试点区内锥栗冠绵蚧的危害情况,于2022年7-8月展开此次调查,共设置35条样线,覆... 2020年6月,钱江源国家公园体制试点区内原古田山国家级自然保护区常绿阔叶林发生大规模锥栗冠绵蚧Coronaproctus castanopsis危害,造成巨大损失。为全面了解试点区内锥栗冠绵蚧的危害情况,于2022年7-8月展开此次调查,共设置35条样线,覆盖试点区内各主要区域。结果表明:在35条样线中有11条出现锥栗冠绵蚧,且均分布于古田山保护区内;其中,1~2年生枝条虫口数最高的样线为样线2(宋坑-样地4号),其虫口数达6头·枝^(-1);该蚧虫寄主植物为壳斗科Fagaceae甜槠Castanopsis eyrei、米槠C.carlesii和栲C.fargesii,寄生部位为树冠1~2年生枝条。在3种寄主植物中,甜槠1~2年生枝条上的虫口数最高,锥栗冠绵蚧发生的样线数最多,是该蚧虫的主要寄生对象,米槠次之,栲最低。本次调查结果可为试点区蚧虫防治工作提供重要数据。 展开更多
关键词 国家公园体制试点区 蚧虫 寄主植物 蚧虫防治
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Experiment and Simulation for Articulated Lifting Subsystem of 1000 m Deep Sea Mining System 被引量:1
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作者 冯雅丽 张文明 +1 位作者 冯福璋 徐妍 《China Ocean Engineering》 SCIE EI 2007年第3期525-532,共8页
The experiment system of 1000 m deep sea mining system is built up with the similarity theory. Sine mechanism is used to simulate mining ship to generate lateral shock excitation by ocean wave. Simulation and experime... The experiment system of 1000 m deep sea mining system is built up with the similarity theory. Sine mechanism is used to simulate mining ship to generate lateral shock excitation by ocean wave. Simulation and experiment of spherical joint connecting deep sea mining system has been done in band six marine conditions. The results indicate that the moment of spherical joint connecting deep sea mining is smaller than that of the thread connected ones, the lifting pipe of sphelical joint is "flexible pipe". The flexural torque of the articulated lifting pipe system in pump and buffer is generally periodic variation with some irregularity, the value is stable on 60 N·S, and it is obviously smaller than that of the fixed lifting pipe system; The total displacement exhibits cyclic variation pattern, and the periodicity of them is longer than that of sea current. The results of experiment and simulation are basically consistent. And the analysis in the paper offers theoretical foundation of 1000 m deep sea mining system in China. 展开更多
关键词 articulated lifting system 1000 m deep sea mining pilot-scale system similarity theory lateral displacement
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Pilot-scale acetone-butanol-ethanol fermentation from corn stover
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作者 Changsheng Su Di Cai +7 位作者 Honggang Zhang Yilu Wu Yongjie Jiang Yicheng Liu Changwei Zhang Chunling Li Peiyong Qin Tianwei Tan 《Green Carbon》 2024年第1期81-93,共13页
Biobutanol is an advanced biofuel that can be produced from excess lignocellulose via acetone-butanol-ethanol(ABE)fermentation.Although significant technological progress has been made in this field,attempts at larges... Biobutanol is an advanced biofuel that can be produced from excess lignocellulose via acetone-butanol-ethanol(ABE)fermentation.Although significant technological progress has been made in this field,attempts at largescale lignocellulosic ABE production remain scarce.In this study,1m^(3)scale ABE fermentation was investigated using high inhibitor tolerance Clostridium acetobutylicum ABE-P1201 and steam-exploded corn stover hydrolysate(SECSH).Before expanding the fermentation scale,the detoxification process for SECSH was simplified by process engineering.Results revealed that appropriate pH management during the fed-batch cultivation could largely decrease the inhibition of the toxic components in undetoxified SECSH to the solventogenesis phase of the ABE-P1201 strains,avoiding“acid crash”.Therefore,after naturalizing the pH by Ca(OH)_(2),the undetoxified SECSH,without removal of the solid components,reached 17.68±1.30 g/L of ABE production with 0.34±0.01 g/g of yield in 1 L scale bioreactor.Based on this strategy,the fermentation scale gradually expanded from laboratory-scale apparatus to pilot-scale bioreactors.Finally,17.05±1.20 g/L of ABE titer and 0.32±0.01 g/g of ABE yield were realized in 1m3 bioreactor,corresponding to approximately 145 kg of ABE production from 1 t of dry corn stover.The pilot-scale ABE fermentation demonstrated excellent stability during repeated operations.This study provided a simplified ABE fermentation strategy and verified the feasibility of the pilot process,providing tremendous significance and a solid foundation for the future industrialization of second-generation ABE plants. 展开更多
关键词 Corn stover ABE fermentation pilot scale Steam explosion PH control
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3种方法对供水系统嗜肺军团菌、阿米巴原虫及生物膜消毒效果的比较 被引量:15
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作者 周昭彦 胡必杰 +3 位作者 于玲玲 陶黎黎 高晓东 黄声雷 《中华医院感染学杂志》 CAS CSCD 北大核心 2010年第12期1657-1660,共4页
目的评估嗜肺军团菌(LEP)在供水系统中的生长和定植,建立试水循环系统以模拟真实供水环境,比较不同消毒方法对LEP、阿米巴原虫和生物膜的清除作用。方法中试水循环系统包括4套循环管道和盲端管道系统,试验中,对3套系统分别连续施加铜/... 目的评估嗜肺军团菌(LEP)在供水系统中的生长和定植,建立试水循环系统以模拟真实供水环境,比较不同消毒方法对LEP、阿米巴原虫和生物膜的清除作用。方法中试水循环系统包括4套循环管道和盲端管道系统,试验中,对3套系统分别连续施加铜/银离子(0.4/0.04 mg/L)、二氧化氯(0.5 mg/L)和热力消毒(>55℃),持续75 d;第4套作为对照,采用培养、荧光原位杂交和LIVE/DEAD染色后共聚焦激光扫描显微镜观察等技术监测浮游和生物膜内菌群变化。结果干预前LEP高度污染中试系统(水∶3.4×103/ml和生物膜:2.4×104/cm2),二氧化氯和热力消毒对生物群体(包括LEP)的消毒效果明显好于铜银离子;铜银离子对HPC的影响不明显,也不能清除生物膜,二氧化氯可有效清除盲端管内生物群体,但干预终止后LEP很快恢复至干预前水平;终止干预后2个月,热力消毒组的循环水和管壁生物膜内均未检出LEP,铜银离子组则再次出现低浓度LEP。结论本研究中,连续加热处理是控制中试水循环系统中LEP最有效的方法 ,一旦LEP定植于环境,将其清除非常困难。 展开更多
关键词 嗜肺军团菌 消毒 阿米巴 生物膜 中试系统
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反硝化生物滤池深度脱氮中试运行效能及微生物菌群分析 被引量:7
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作者 王林 张浩浩 +1 位作者 吴兴海 李咏梅 《同济大学学报(自然科学版)》 EI CAS CSCD 北大核心 2021年第12期1727-1737,共11页
以污水处理厂二级出水为原水,开展了水力负荷、碳氮比和温度等关键参数的中试运行效能研究。中试系统中主要利用外加碳源而不是二级出水原水中的有机物进行反硝化,较优的水力负荷和碳氮比分别为5 m·h^(-1)和4,对化学需氧量(COD)和... 以污水处理厂二级出水为原水,开展了水力负荷、碳氮比和温度等关键参数的中试运行效能研究。中试系统中主要利用外加碳源而不是二级出水原水中的有机物进行反硝化,较优的水力负荷和碳氮比分别为5 m·h^(-1)和4,对化学需氧量(COD)和总氮(TN)的去除率分别为62.8%和67.3%;在温度为15~27℃时,中试系统的出水TN稳定在10.0 mg·L^(-1)以下。中试系统中,不仅Hyphomicrobium和Methyloversatilis等传统反硝化细菌的相对丰度较高(占25.12%),Methylotenera和Paracoccus等同步硝化反硝化细菌的相对丰度也较高(占33.29%),以上优势菌种的存在保证了系统的高效脱氮效果。 展开更多
关键词 反硝化 生物滤池 中试系统 微生物菌群 有机物利用
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中试循环输水管道系统中建立嗜肺军团菌生物膜 被引量:4
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作者 周昭彦 胡必杰 +3 位作者 陶黎黎 于玲玲 高晓东 黄声雷 《中华医院感染学杂志》 CAS CSCD 北大核心 2010年第10期1376-1379,共4页
目的模拟医院供水系统,建立代表上海地区自来水特征的新型中试循环输水管道系统,研究军团菌定植供水系统的能力;评估水流的停滞和层流状态对嗜肺军团菌生物膜的影响。方法采用培养技术和共聚焦激光扫描显微镜动态监测嗜肺军团菌进入生... 目的模拟医院供水系统,建立代表上海地区自来水特征的新型中试循环输水管道系统,研究军团菌定植供水系统的能力;评估水流的停滞和层流状态对嗜肺军团菌生物膜的影响。方法采用培养技术和共聚焦激光扫描显微镜动态监测嗜肺军团菌进入生物膜达到稳态的过程。结果军团菌黏附和进入生物膜后开始增殖,第5周达到稳态,95.8%的嗜肺军团菌分布在生物膜内;管壁军团菌定植数量在层流状态明显高于停滞状态,平均值为7.8×104CFU/cm2和1.5×103CFU/cm2。结论中试循环输水管道中成功建立嗜肺军团菌生物膜;生物膜在军团菌增殖中起重要作用;水流停滞不会促进军团菌增殖。 展开更多
关键词 中试管道系统 医院 嗜肺军团菌 生物膜
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热脱附与机械研磨联合作用的污染土壤修复系统 被引量:2
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作者 张磊 崔勇 +2 位作者 王坚 宁禹航 陈刚 《环境保护科学》 CAS 2019年第6期119-123,共5页
针对现有污染土壤热脱附修复存在效率低、成本高的问题,文章提出了一种热脱附与机械研磨联合作用的改进型污染土壤修复系统。该系统设计了具有独特螺旋结构的双层滚筒作为热脱附器,采用钢质载热球作为辅助载热体和土壤破碎研磨工具,并... 针对现有污染土壤热脱附修复存在效率低、成本高的问题,文章提出了一种热脱附与机械研磨联合作用的改进型污染土壤修复系统。该系统设计了具有独特螺旋结构的双层滚筒作为热脱附器,采用钢质载热球作为辅助载热体和土壤破碎研磨工具,并在滚筒内层与土壤混合,外层为热烟气通道,使土壤受到内外双层介质热作用,从而强化污染物的脱附过程。同时,热烟气与物料在滚筒内逆流,提高了能量利用率且防止了脱附气二次冷凝。此外,系统采用低温、高温两段式热脱附工艺,充分利用余热的同时增加了系统运行的灵活性。对六六六污染土壤的中试试验结果表明,系统运行的最佳球土质量比值为1.5,相较无载热球的热脱附情况,采用本系统天然气消耗量可减少30%,综合运行成本减少15%以上,验证了系统的节能性。 展开更多
关键词 污染土壤修复 热脱附 机械研磨 载热球 中试系统
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还原改性粉末活性炭的净水效果研究 被引量:4
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作者 周玉军 黄廷林 +2 位作者 赵建伟 何文杰 韩宏大 《供水技术》 2007年第3期5-7,共3页
以滦河水为对象进行了还原改性PAC的中试净水效果研究。试验结果表明:改性PAC与混凝剂投加量分别为15mg/L和10mg/L时,在预氧化1处投加改性PAC对COD_(Mn)和UV254的去除率最高,分别为52.15%和38.22%,比在混合池投加时对两者的去除率均高... 以滦河水为对象进行了还原改性PAC的中试净水效果研究。试验结果表明:改性PAC与混凝剂投加量分别为15mg/L和10mg/L时,在预氧化1处投加改性PAC对COD_(Mn)和UV254的去除率最高,分别为52.15%和38.22%,比在混合池投加时对两者的去除率均高出2%左右。于预氧化1处投加改性PAC时,其对COD_(Mn)和UV254的去除率比在相同点投加未改性PAC时分别提高5%和9%。还原改性PAC可用于处理以非极性有机物为主的高有机物污染水,提高净水效果。 展开更多
关键词 表面化学性质 还原改性 PAC 微污染水源水 中试系统
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氧化沟间歇曝气脱氮效果及控制策略的中试研究 被引量:3
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作者 王涛 岳波 +3 位作者 张妙月 扈庆 朱俊 李科 《水处理技术》 CAS CSCD 北大核心 2012年第6期78-81,85,共5页
对前置厌氧选择区的中试氧化沟系统,采用连续流间歇曝气方式进行生物脱氮的研究。试验研究表明,不同曝气-停曝时间下出水TN范围不同,其主要与曝气/停曝(时间)比有关;曝气时间过长可能导致细胞内碳源消耗过量而使反硝化因缺乏电子供体受... 对前置厌氧选择区的中试氧化沟系统,采用连续流间歇曝气方式进行生物脱氮的研究。试验研究表明,不同曝气-停曝时间下出水TN范围不同,其主要与曝气/停曝(时间)比有关;曝气时间过长可能导致细胞内碳源消耗过量而使反硝化因缺乏电子供体受影响,停曝阶段持续过长又可能使NH4+-N积累过多而超标。曝气1.5 h,停曝2 h时,出水TN和NH4+-N较好地满足一级B排放标准,该模式辅助适当的曝气控制策略可保证出水水质和节省能耗。为了研究氧化沟间歇曝气控制策略,进行了连续曝气的试验研究,结果表明,ORP与NH4+-N/NO3--N的对数有较好的线性相关性,相关系数为0.987。利用以上关系,结合NH4+-N在线传感器,提出了间歇曝气的控制流程。 展开更多
关键词 中试氧化沟 间歇曝气 曝气/停曝(时间)比 曝气过量 曝气控制策略
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热化学硫碘循环水分解制氢研究进展
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作者 王智化 曾俊杰 +2 位作者 何勇 李明阳 王晓丁 《洁净煤技术》 CAS CSCD 北大核心 2023年第11期1-24,共24页
随着化石能源日益短缺和环境污染日益严重,寻求高效、清洁、可再生能源迫在眉睫。氢能作为现代能源体系新密码,因清洁、可再生、可存储、用途广泛等优点,近年来受到广泛关注。目前制氢方式众多,但大规模、高效、低成本、绿色的制氢方式... 随着化石能源日益短缺和环境污染日益严重,寻求高效、清洁、可再生能源迫在眉睫。氢能作为现代能源体系新密码,因清洁、可再生、可存储、用途广泛等优点,近年来受到广泛关注。目前制氢方式众多,但大规模、高效、低成本、绿色的制氢方式才是未来氢能经济的基础。其中,热化学硫碘循环(也称碘硫循环)水分解制氢因具备上述优点被认为是最具发展潜力的制氢方法之一。从Bunsen反应、H2SO4分解和HI分解3方面综述了热化学硫碘循环水分解制氢的基础研究情况,对目前各国已建立的硫碘循环系统进行总结,着重介绍了核能耦合硫碘循环制氢流程的最新进展。从经济、环保和安全方面对目前核能耦合硫碘制氢进行分析讨论,以期为未来研究和发展提供新思路。针对Bunsen反应部分,寻找一种高效分离反应物的新方法至关重要;而对H2SO4分解和HI分解部分,现阶段主要研究仍集中在开发稳定、高效、低成本的催化剂。经过几十年研究,热化学硫碘循环水分解制氢技术已取得长足发展。在实际产氢中,苛刻的高温高腐蚀环境、复杂的耦合流程是限制其规模化、工业化的主要原因,开发由工业结构材料制成的耐腐蚀和耐热系统,继续对耦合流程进行优化和模拟是未来热化学硫碘循环水分解制氢技术的发展方向。 展开更多
关键词 硫碘循环 核能 制氢 热化学循环 水分解 中试系统
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间歇曝气A^2/C氧化沟工艺处理城市污水中试研究 被引量:6
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作者 侯红勋 彭永臻 +2 位作者 叶柳 王建龙 周利 《环境科学学报》 CAS CSCD 北大核心 2006年第5期740-744,共5页
为降低氧化沟工艺的运行成本,研究了连续进水间歇曝气缺氧(Anoxic)-厌氧(Anaerobic)-Carrousel氧化沟(A2/C)工艺.采用A2/C氧化沟模型运用连续进水间歇曝气模式对城市污水处理进行了研究.结果表明,增强外源反硝化是提高脱氮效率的关键.... 为降低氧化沟工艺的运行成本,研究了连续进水间歇曝气缺氧(Anoxic)-厌氧(Anaerobic)-Carrousel氧化沟(A2/C)工艺.采用A2/C氧化沟模型运用连续进水间歇曝气模式对城市污水处理进行了研究.结果表明,增强外源反硝化是提高脱氮效率的关键.在一定范围内加大回流比,能够提高间歇频率,减小各污染指标在反应系统中的积累.在曝气1h,停止曝气3h,回流污泥比200%的模式下(模式Ⅱ),出水CODCr,NH4+-N和TN分别为40~50mg·L-1、3.0~5.7mg·L-1和10.2~12.5mg·L-1.3个模式在1个周期内平均曝气量分别为连续曝气过程的66%、50%、44%.模式Ⅱ中在线监测仪表数据分析显示,曝气过程中出现NH4+-N氧化的终点———在pH曲线上表现为出现“氨谷”,若利用在线监测仪表在曝气阶段采用自动控制,则可避免过量曝气.采用实际城市污水,应用中试试验模型,能够为实际生产提供重要技术参数,为原有氧化沟工艺技术改造提供支持. 展开更多
关键词 间歇曝气 A2/C氧化沟 城市污水 生物脱氮 中试
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进水碳氮比对中试AAO-BAF系统脱氮除磷性能的影响 被引量:17
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作者 彭永臻 潘聪 +2 位作者 孙事昊 赵伟华 黄宇 《北京工业大学学报》 CAS CSCD 北大核心 2019年第9期904-910,共7页
为了研究进水碳氮比对AAO-曝气生物滤池(BAF)双污泥脱氮除磷系统的影响,以实际生活污水为处理对象,研究了一个处理量约为50m^3/d的中试规模AAO-BAF系统在碳氮比分别为3.3±0.3、4.5±0.3、6.0±0.3时长期运行的脱氮除磷特性... 为了研究进水碳氮比对AAO-曝气生物滤池(BAF)双污泥脱氮除磷系统的影响,以实际生活污水为处理对象,研究了一个处理量约为50m^3/d的中试规模AAO-BAF系统在碳氮比分别为3.3±0.3、4.5±0.3、6.0±0.3时长期运行的脱氮除磷特性.试验结果表明:在碳氮比约为3.3时,AAO-BAF工艺对COD、TN、PO4^3--P的去除率分别可达到71.4%、67.6%和85.6%.适当提高有机物浓度,当碳氮比约为4.5时,AAO-BAF工艺对COD、TN、PO4^3--P的去除率分别可达到79.7%、70.0%和93.5%,系统的脱氮除磷性能最佳,平均出水TN和PO4^3--P为12.40、0.20mg/L.但当碳氮比继续提高至约为6.0时,过量的有机物会使缺氧区内存在大量可利用有机物,反硝化菌优先利用电子受体NO3--N,削弱了反硝化除磷菌的活性.同时会有剩余的有机物进入BAF,导致异养菌的增殖,氨氮不能完全氧化,使得缺氧区的电子受体进一步减少,影响系统的脱氮除磷功能.此时,AAO-BAF工艺对COD的去除率为81.6%,TN、PO43--P的去除率分别迅速下降至55.1%和63.2%以下,系统接近崩溃. 展开更多
关键词 双污泥系统 反硝化除磷 ρ(C)/ρ(N) 中试AAO-BAF 生活污水
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无砾石微孔管地下渗滤系统处理生活污水的中试研究 被引量:2
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作者 党振华 王成端 +2 位作者 羊裔恒 邓磊 张君 《环境工程学报》 CAS CSCD 北大核心 2012年第3期922-928,共7页
进行了无砾石微孔管地下渗滤系统处理生活污水的中试研究。基于不同土壤、不同管径、不同植物的协同效应,对比研究了不同系统处理污水中有机物、氮、磷和SS的去除效果及其影响因素。结果表明,不同土壤、不同管径及不同植物组成的系统,... 进行了无砾石微孔管地下渗滤系统处理生活污水的中试研究。基于不同土壤、不同管径、不同植物的协同效应,对比研究了不同系统处理污水中有机物、氮、磷和SS的去除效果及其影响因素。结果表明,不同土壤、不同管径及不同植物组成的系统,对生活污水中有机物、氮、磷和SS的去除效果差别较大。中试系统对COD、总磷、氨氮、总氮和SS的最佳去除率分别达到86.13%、90.20%、61.24%、65.49%和97.43%,对应的出水COD、总磷、氨氮、总氮和SS的平均浓度分别为64.29、0.69、22.13、26.19和5.56 mg/L。分析表明,进水SS浓度过高、外界温度下降等共同作用是导致系统对生活污水中NH4+-N和TN的去除率相对较低的主要原因。 展开更多
关键词 地下渗滤系统 无砾石微孔管 生活污水 中试 脱氮除磷
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通风强度对市政污泥生物干化中试效果的影响 被引量:5
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作者 张喻 韩融 +4 位作者 陆文静 王洪涛 明中远 王强 夏伟 《环境科学》 EI CAS CSCD 北大核心 2015年第5期1727-1732,共6页
将污泥与树皮按照一定比例混合,利用自主研制的滚筒式污泥生物干化中试系统进行实验,通过对温度、含水率、O2和CO2浓度、挥发性固体(VS)、p H等参数的检测,研究了通风强度对市政污泥生物干化效果的影响.结果表明,通风强度对污泥生物干... 将污泥与树皮按照一定比例混合,利用自主研制的滚筒式污泥生物干化中试系统进行实验,通过对温度、含水率、O2和CO2浓度、挥发性固体(VS)、p H等参数的检测,研究了通风强度对市政污泥生物干化效果的影响.结果表明,通风强度对污泥生物干化有较大影响,通风强度(以VS计)为120 L·(h·kg)-1时,最高温度达到66℃,55℃以上高温可以维持40 h以上,111 h后污泥最终含水率可以降低至56%;生物干化过程中p H始终保持在6.5~8.5之间,不会影响微生物生命活动;滚筒式污泥生物干化反应器能够使反应器内基质均一性良好,对利用滚筒式反应器实现污泥连续流处理提供参考. 展开更多
关键词 通风强度 污泥 滚筒 生物干化 中试
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