A novel photoenzyme-coupled artificial catalytic system is fabricated by immobilizing horseradish peroxidase(HRP)on the Bi_(2)WO_(6)hollow nanospheres via a facile electrostatic self-assembly process.The obtained Bi_(...A novel photoenzyme-coupled artificial catalytic system is fabricated by immobilizing horseradish peroxidase(HRP)on the Bi_(2)WO_(6)hollow nanospheres via a facile electrostatic self-assembly process.The obtained Bi_(2)WO_(6)/HRP sample not only improves the visible light harvest ability but also promotes the high-efficiency separation of charge carriers.More importantly,the photogenerated electrons and produced H2O2 on Bi_(2)WO_(6)directly take part in redox cycle reactions of HRP to induce photoenzyme synergic catalytic effect.In consequence,the degradation activity of Bi_(2)WO_(6)/HRP is significantly improved relative to Bi_(2)WO_(6)and HRP for removing bisphenol A(BPA)under the visible light irradiation.This work launches a feasible design strategy for exploiting photoenzyme-coupled artificial catalytic system with special structure to degrade organic pollutants in water efficiently.展开更多
基金supported by the NSFC-Shanxi Coal Based Low Carbon Joint Fund(No.U1810117)the National Natural Science Foundation of China(No.52072153)+3 种基金the Natural Science Foundation of Jiangsu Province(No.BK20190867)the Open Project Program of Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University)(No.2019009)the Open Project Program of Key Laboratory of Groundwater Resources and Environment(Jilin University),Ministry of Education(No.202005001KF)the Young Talent Cultivate Programme of Jiangsu University(No.4111310017)。
文摘A novel photoenzyme-coupled artificial catalytic system is fabricated by immobilizing horseradish peroxidase(HRP)on the Bi_(2)WO_(6)hollow nanospheres via a facile electrostatic self-assembly process.The obtained Bi_(2)WO_(6)/HRP sample not only improves the visible light harvest ability but also promotes the high-efficiency separation of charge carriers.More importantly,the photogenerated electrons and produced H2O2 on Bi_(2)WO_(6)directly take part in redox cycle reactions of HRP to induce photoenzyme synergic catalytic effect.In consequence,the degradation activity of Bi_(2)WO_(6)/HRP is significantly improved relative to Bi_(2)WO_(6)and HRP for removing bisphenol A(BPA)under the visible light irradiation.This work launches a feasible design strategy for exploiting photoenzyme-coupled artificial catalytic system with special structure to degrade organic pollutants in water efficiently.
