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UPLC-Q-Orbitrap HRMS测定动物源食品中烯草胺及复配除草剂残留
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作者 李亦军 荣杰峰 +5 位作者 张松艳 庄晓斌 乐有东 张志勇 杨希 陈自猷 《化学研究与应用》 北大核心 2025年第9期2725-2732,共8页
建立了快速滤过型净化结合超高效液相色谱-四极杆/静电轨道阱高分辨质谱法测定动物源食品中烯草胺及复配除草剂残留量的分析方法。样品经甲酸-乙腈溶液提取,快速滤过型固相萃取柱净化,采用平行反应监测模式监测,基质匹配外标法定量。结... 建立了快速滤过型净化结合超高效液相色谱-四极杆/静电轨道阱高分辨质谱法测定动物源食品中烯草胺及复配除草剂残留量的分析方法。样品经甲酸-乙腈溶液提取,快速滤过型固相萃取柱净化,采用平行反应监测模式监测,基质匹配外标法定量。结果表明,目标化合物在0.25~50μg/L范围内线性关系良好,相关系数均大于0.999。空白样品在1、5、20μg/kg 3个加标水平下的平均回收率为73.2%~107.2%,相对标准偏差(n=6)为2.3%~8.6%;方法定量限为1μg/kg。该方法简单、快速,具有良好的准确度和灵敏度,可实现动物源食品中烯草胺、莠去津、特丁津、异噁草酮、二甲戊灵和五氟磺草胺残留量的快速同时检测。 展开更多
关键词 烯草胺 动物源食品 快速滤过型净化 超高效液相色谱-四极杆/静电轨道阱高分辨质谱法
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Dry Bean Sensitivity to Group 15 Herbicides Applied Preemergence
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作者 Nader Soltani Christy Shropshire Peter H. Sikkema 《American Journal of Plant Sciences》 2018年第7期1414-1423,共10页
Field experiments (4 in total) were conducted in 2016 and 2017 in southwestern Ontario to compare the sensitivity of dry bean to four Group 15 herbicides applied preemergence (PRE). At 4 weeks after emergence (WAE), p... Field experiments (4 in total) were conducted in 2016 and 2017 in southwestern Ontario to compare the sensitivity of dry bean to four Group 15 herbicides applied preemergence (PRE). At 4 weeks after emergence (WAE), pethoxamid, S-metolachlor, dimethenamid-P and pyroxasulfone applied PRE at the 2X rate caused 5%, 9%, 9% and 14% visible injury in adzuki bean, 2%, 2%, 2% and 3% visible injury in kidney bean, 6%, 4%, 5% and 4% visible injury in small red Mexican (SRM) bean, and 9%, 6%, 8% and 9% visible injury in white bean, respectively. Pyroxasulfone reduced adzuki bean shoot biomass (m-1 row) 42% and height 12%. However, the other Group 15 herbicides did not reduce shoot biomass and height of adzuki bean. Kidney bean shoot biomass and height were not adversely affected by the Group 15 herbicides evaluated. S-metolachlor caused no adverse effect on SRM bean dry weight or height, but pethoxamid, dimethenamid-P and pyroxasulfone at the 2X rate reduced dry weight 26%, 28% and 28% and height 7%, 7% and 7% in SRM bean, respectively. Pethoxamid, S-metolachlor, dimethenamid-P, and pyroxasulfone applied PRE at the 2X rate reduced white bean dry weight 50%, 37%, 47% and 43% and height 16%, 10%, 16% and 15% in white bean, respectively. Pyroxasulfone (2X rate), applied PRE, reduced bean stand count and seed yield 12% and 7%, respectively. However, pethoxamid, S-metolachlor, and dimethenamid-P, applied PRE caused no decrease in stand count and seed yield of dry beans evaluated. In general, kidney and SRM bean are most tolerant, white bean is intermediate, and adzuki bean is most sensitive to Group 15 herbicides applied PRE. 展开更多
关键词 Adzuki BEAN Dimethenamid-P Kidney BEAN pethoxamid Pyroxasulfone Small Red MEXICAN BEAN S-METOLACHLOR White BEAN
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