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Seismic performance evaluation of steel frame-steel plate shear walls system based on the capacity spectrum method 被引量:3
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作者 Jian-hua SHAO Qiang GU Yong-kang SHEN 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第3期322-329,共8页
This paper presents some methods that the standard acceleration design response spectra derived from the present China code for seismic design of buildings are transformed into the seismic demand spectra, and that the... This paper presents some methods that the standard acceleration design response spectra derived from the present China code for seismic design of buildings are transformed into the seismic demand spectra, and that the base shear force-roof displacement curve of structure is converted to the capacity spectrum of an equivalent single-degree-of-freedom (SDOF) system. The capacity spectrum method (CSM) is programmed by means of MATLABT.0 computer language. A dual lateral force resisting system of 10-story steel frame-steel plate shear walls (SPSW) is designed according to the corresponding China design codes. The base shear force-roof displacement curve of structure subjected to the monotonic increasing lateral inverse triangular load is obtained by applying the equivalent strip model to stimulate SPSW and by using the finite element analysis software SAP2000 to make Pushover analysis. The seismic performance of this dual system subjected to three different conditions, i.e. the 8-intensity frequently occurred earthquake, fortification earthquake and seldom occurred earthquake, is evaluated by CSM program. The excessive safety of steel frame-SPSW system designed according to the present China design codes is pointed out and a new design method is suggested. 展开更多
关键词 Steel frame-steel plate shear walls (SPSW) system Capacity spectrum method (CSM) Seismic demand spectrum base shear force-roof displacement Seismic performance evaluation
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Effects of sol-gel method and lanthanum addition on catalytic performances of nickel-based catalysts for methane reforming with carbon dioxide 被引量:4
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作者 黎先财 胡全红 +2 位作者 杨沂凤 陈娟荣 赖志华 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第6期864-868,共5页
The nickel-based catalysts were prepared by the sol-gel method and used for the CH4 reforming with CO2. The effects of the sol-gel method on the specific surface area, catalytic activity, desorption, and reduction per... The nickel-based catalysts were prepared by the sol-gel method and used for the CH4 reforming with CO2. The effects of the sol-gel method on the specific surface area, catalytic activity, desorption, and reduction performances of catalysts were investigated with BET, TPR, and TPD. Compared with the catalyst prepared by the impregnation method, the results indicated that the catalysts prepared by the sol-gel method had larger specific surface area, showing higher catalytic activities and exhibiting perfect desorption and reduction performances. In addition, the modification effects of adding La were studied, and it was found that the 0.75NLBT catalyst constituted of 5wt.%Ni-0.75wt.%La was optimal. 展开更多
关键词 sol-gel method nickel-based catalyst REFORMING catalytic performance rare earths
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SELECTING CLUSTER MODEL IN Sn - BASED SOLDER ALLOY DESIGN WITH DV - X_α CALCULATION METHOD
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作者 C. Q. Wang and W. F. Feng National ho. of Advanced welding Technolgy, HIT, Harbin 150001,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2000年第1期84-88,共5页
Applying calculation method in alloy design should be an important tendency due to its characters of inexpensive cost, high efficiency and prediction. DOS calculations of AuSn, AsSn and SbSn Sn- based alloys have ... Applying calculation method in alloy design should be an important tendency due to its characters of inexpensive cost, high efficiency and prediction. DOS calculations of AuSn, AsSn and SbSn Sn- based alloys have been investigated by employing DV - Xa method, in which different cluster models were adopted to calculate electron structure.It is proved that some regulations must be taken into ac- count in order to carry out alloy design calculation successfully,which are described in this paper in detail. 展开更多
关键词 Cluster model Sn - based alloy design DV - X_a calculation method DOS
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Recent Advances on Preparation Method of Ti-Based Hydrogen Storage Alloy
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作者 Lina Liang Feng Wang +4 位作者 Maohua Rong Zhongmin Wang Songtao Yang Jiang Wang Huaiying Zhou 《Journal of Materials Science and Chemical Engineering》 2020年第12期18-38,共21页
Ti-based hydrogen storage alloy is one of the most common solid-state hydrogen storage materials due to its high hydrogen absorption capacity, low dehydrogenation temperature and rich resources. This paper mainly pres... Ti-based hydrogen storage alloy is one of the most common solid-state hydrogen storage materials due to its high hydrogen absorption capacity, low dehydrogenation temperature and rich resources. This paper mainly presents the influence of several different preparation methods of Ti-based hydrogen storage alloys on the hydrogen storage performance including traditional preparation methods (smelting, rapid quenching and mechanical alloying) and novel methods by plastic deformation (cold rolling, equal channel angular pressing and high-pressure torsion). The microstructure analysis and hydrogen storage properties of Ti-based alloy are summarized thoroughly corresponding with the preparation processes mentioned above. It was found that slight introduction of lattice defects including dislocation, grain boundary, sub-grain boundary and cracks by severe plastic deformation (SPD) was beneficial to improve the hydriding/dehydriding kinetic characteristic. However, the nonuniform composition and residual stress of the alloy may be caused by SPD, which is not conducive to the improvement of hydrogen storage capacity. In the future, it would be expected that new methods and technologies combined with dopant and modification are applied to Ti-based hydrogen storage alloys to make breakthroughs in practical application. 展开更多
关键词 Ti-based Alloy Preparation methods Hydrogen Storage performance Severe Plastic Deformation Lattice Defects
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A method based on diffraction theory for predicting 3D focusing performance of compound refractive X-ray lenses 被引量:5
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作者 乐孜纯 刘恺 梁静秋 《Chinese Optics Letters》 SCIE EI CAS CSCD 2005年第3期184-186,共3页
A method based on the diffraction theory for estimating the three-dimensional (3D) focusing performance of the compound refractive X-ray lenses is presented in this paper. As a special application, the 3D X-ray intens... A method based on the diffraction theory for estimating the three-dimensional (3D) focusing performance of the compound refractive X-ray lenses is presented in this paper. As a special application, the 3D X-ray intensity distribution near the focus is derived for a plano-concave compound refractive X-ray lens. Moreover, the computer codes are developed and some results of 3D focusing performance for a compound refractive X-ray lens with Si material are shown and discussed. 展开更多
关键词 A method based on diffraction theory for predicting 3D focusing performance of compound refractive X-ray lenses
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A theoretical method based on Fourier spectrum analysis for the focusing performances of the X-ray compound refractive lenses 被引量:1
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作者 叶坚 乐孜纯 +4 位作者 梁静秋 刘恺 全必胜 覃亚丽 朱广信 《Chinese Optics Letters》 SCIE EI CAS CSCD 2004年第6期367-369,共3页
It is important to predict the intensity distribution in focusing plane for designing the X-ray compound refractive lenses. On the basis of analyzing the structure of X-ray compound lenses and comparing it with Praunh... It is important to predict the intensity distribution in focusing plane for designing the X-ray compound refractive lenses. On the basis of analyzing the structure of X-ray compound lenses and comparing it with Praunhofer diffraction system, it is concluded that the X-ray focusing system can be regarded as a kind of Praunhofer diffraction system. Therefore, a method based on Fourier spectrum analysis is presented to predict the intensity distribution in the focusing plane for the X-ray lenses. A brief analysis on the relationship between the parameters of X-ray lenses and their focusing performance is also given in this paper. 展开更多
关键词 A theoretical method based on Fourier spectrum analysis for the focusing performances of the X-ray compound refractive lenses
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镁基-羟基磷灰石生物材料研究进展
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作者 张峻玮 戴景杰 +1 位作者 王阿敏 胡明 《材料保护》 2025年第11期90-98,共9页
镁及其合金由于具有独特的组织结构、力学性能、降解性能和生物相容性而备受关注,但其过快的降解速率限制了其应用。由于具有优异的生物相容性,羟基磷灰石(Hydroxyapatite, HA)在制备镁基-HA生物材料时能增强镁及其合金的生物相容性和... 镁及其合金由于具有独特的组织结构、力学性能、降解性能和生物相容性而备受关注,但其过快的降解速率限制了其应用。由于具有优异的生物相容性,羟基磷灰石(Hydroxyapatite, HA)在制备镁基-HA生物材料时能增强镁及其合金的生物相容性和耐蚀性,并具有良好的降解速率调节能力。首先详细介绍了镁基-HA生物材料的制备方法;其次,探讨了不同合金元素、金属氧化物、有机物对镁基-HA生物材料性能的影响;再者,概述了镁基-HA生物材料的力学性能、电化学腐蚀性能、体外降解性能、生物相容性能和生物活性。最后,总结了镁基-HA生物材料目前面临的主要问题,并对其未来的发展趋势进行了展望。 展开更多
关键词 羟基磷灰石 镁基生物材料 制备方法 性能测试 生物材料 综述
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PRP-Type Direct Search Methods for Unconstrained Optimization
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作者 Qunfeng Liu Wanyou Cheng 《Applied Mathematics》 2011年第6期725-731,共7页
Three PRP-type direct search methods for unconstrained optimization are presented. The methods adopt three kinds of recently developed descent conjugate gradient methods and the idea of frame-based direct search metho... Three PRP-type direct search methods for unconstrained optimization are presented. The methods adopt three kinds of recently developed descent conjugate gradient methods and the idea of frame-based direct search method. Global convergence is shown for continuously differentiable functions. Data profile and performance profile are adopted to analyze the numerical experiments and the results show that the proposed methods are effective. 展开更多
关键词 Direct Search methodS DESCENT CONJUGATE Gradient methodS Frame-based methodS Global Convergence Data PROFILE performance PROFILE
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改良式TBL教学法联合Mini-CEX在呼吸内科住培教学中的应用
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作者 阎雪 白璐 李国威 《中国继续医学教育》 2025年第4期75-79,共5页
目的探讨改良式基于团队的教学法(team-based learning,TBL)联合迷你临床演练评估(mini-clinical evaluation exercise,Mini-CEX)在呼吸内科住院医师规范化培训教学中的应用效果。方法选取2022年7月—2023年10月在锦州医科大学第一附属... 目的探讨改良式基于团队的教学法(team-based learning,TBL)联合迷你临床演练评估(mini-clinical evaluation exercise,Mini-CEX)在呼吸内科住院医师规范化培训教学中的应用效果。方法选取2022年7月—2023年10月在锦州医科大学第一附属医院呼吸内科住院医师规范化培训(简称“住培”)医师72名为研究对象。采用随机数表法将住培医师分为研究组和对照组各36名,研究组采用改良式TBL教学法联合Mini-CEX,对照组采用传统教学法,教学结束后,比较2组住培医师Mini-CEX评分、考核成绩、教学效果及教学满意度。结果教学后,研究组住培医师Mini-CEX各维度评分均高于对照组,差异有统计学意义(P<0.001);教学后,研究组住培医师的理论知识考核成绩[(88.25±8.85)分]、病例分析能力[(90.16±9.18)分]、临床操作能力[(89.46±8.26)分]得分均高于对照组[(81.26±8.67)分、(82.38±8.54)分、(80.18±8.05)分],差异有统计学意义(P<0.05);教学后,研究组住培医师的教学效果各项得分均高于对照组,差异有统计学意义(P<0.001);教学后,研究组住培医师的教学满意度(94.44%)高于对照组(75.00%),差异有统计学意义(P<0.05)。结论改良式TBL教学法配合Mini-CEX可提高呼吸内科住培医师的考核成绩、教学效果及教学满意度,为后续进一步优化住培教学方法提供依据。 展开更多
关键词 改良式基于团队的教学法 迷你临床演练评估 呼吸内科 住院医师规范化培训 教学效果 考核成绩 教学满意度
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Methods to improve the performance of the swept source at 1.0 μm based on a polygon scanner 被引量:3
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作者 JING CAO PINGHE WANG +4 位作者 YAN ZHANG GUOHUA SHI BO WU SHANGJIAN ZHANG YONG LIU 《Photonics Research》 SCIE EI 2017年第3期245-250,共6页
In this work, we investigate the methods to improve the performance of the swept source at 1.0 μm based on a polygon scanner, including in-cavity parameters and booster structures out of the cavity. The three in-cavi... In this work, we investigate the methods to improve the performance of the swept source at 1.0 μm based on a polygon scanner, including in-cavity parameters and booster structures out of the cavity. The three in-cavity parameters are the cavity length, the rotating speed of the polygon scanner, and the in-cavity energy. With the decrease of cavity length, the spectrum bandwidth becomes wider and the duty cycle becomes higher.With the increase of the rotating speed of the polygon, the spectrum bandwidth becomes narrower, and the duty cycle becomes lower but the repetition rate becomes higher. With more energy in-cavity, the spectrum bandwidth becomes wider and the duty cycle becomes higher. The booster structures include the buffered structure, secondary amplifier, and dual-semiconductor optical amplifier configuration, which are used to increase the sweep frequency to 86 kHz, the output power to 18 mW, and the tuning bandwidth to 131 nm, respectively. 展开更多
关键词 of for in is length methods to improve the performance of the swept source at 1.0 m based on a polygon scanner SOA on
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基于主亚骨架的ATB-25混合料级配研究 被引量:10
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作者 李安 游庆龙 陈成芹 《武汉理工大学学报》 CAS CSCD 北大核心 2011年第10期46-50,共5页
基于贝雷法的设计理论,对ATB-25矿料级配范围内的级配曲线进行分析,得出了在混合料中,由13.2~31.5mm粒径的颗粒形成混和料的主骨架,4.75~13.2mm粒径的颗粒形成混合料的亚骨架,在进行混合料设计时,4.75mm的通过率应控制在30%以下,13.2m... 基于贝雷法的设计理论,对ATB-25矿料级配范围内的级配曲线进行分析,得出了在混合料中,由13.2~31.5mm粒径的颗粒形成混和料的主骨架,4.75~13.2mm粒径的颗粒形成混合料的亚骨架,在进行混合料设计时,4.75mm的通过率应控制在30%以下,13.2mm的通过率控制在55%以下。通过对矿料级配贝雷法参数的计算,确定了矿料级配CA比范围一般为0.4~0.6之间,FAc和FAf的范围分别为0.4~0.6和0.3~0.6。结合重庆绕城高速公路项目,比较了ATB-25、AC-25、ATB-25#及AC-25#混合料的路用性能,表明按照该标准控制的混合料的抗水损害能力相近,但是ATB-25高温稳定性相对较好。 展开更多
关键词 ATB混合料 主骨架 亚骨架 贝雷法 成型方法 路用性能
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性态设计方法及能力-需求曲线方法的几个问题 被引量:2
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作者 李英民 杨成 赖明 《重庆建筑大学学报》 CSCD 2003年第6期26-32,共7页
简要回顾了性态设计的发展历程,明确了性态设计的相关概念及其关系,剖析了性态设计与我国现行抗震设防原则与思想间的关系,指明了我国抗震设计规范与性态设计接轨的方向,讨论了目前引起较多关注的能力-需求曲线设计方法中的结构模型、... 简要回顾了性态设计的发展历程,明确了性态设计的相关概念及其关系,剖析了性态设计与我国现行抗震设防原则与思想间的关系,指明了我国抗震设计规范与性态设计接轨的方向,讨论了目前引起较多关注的能力-需求曲线设计方法中的结构模型、水平加载模式、能力-需求曲线交角及P-Δ效应影响等问题。 展开更多
关键词 性态设计 能力一需求曲线法 抗震设计 建筑结构
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铁离子对曼尼希碱型盐酸缓蚀剂(FHS-A)缓蚀性能的影响 被引量:2
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作者 李海娟 刘志杰 +1 位作者 王家祥 邹巧育 《西安石油大学学报(自然科学版)》 CAS 北大核心 2013年第4期103-106,12,共4页
采用单因素实验,运用静态失重法考察Fe^(3+)含量对曼尼希碱型盐酸缓蚀剂(FHS-A)缓蚀性能的影响.还考察了N80钢片在具有Fe^(3+)的HCl溶液中的腐蚀速率随盐酸质量浓度和缓蚀剂质量分数的变化规律.结果表明:Fe^(3+)对曼尼希碱型盐酸缓蚀剂(... 采用单因素实验,运用静态失重法考察Fe^(3+)含量对曼尼希碱型盐酸缓蚀剂(FHS-A)缓蚀性能的影响.还考察了N80钢片在具有Fe^(3+)的HCl溶液中的腐蚀速率随盐酸质量浓度和缓蚀剂质量分数的变化规律.结果表明:Fe^(3+)对曼尼希碱型盐酸缓蚀剂(FHS-A)有一定的影响,随着Fe^(3+)含量的增大腐蚀速率增大;随着缓蚀剂质量分数的增大腐蚀速率减小;随着盐酸质量浓度的增大腐蚀速率增大.根据实验结果,初步探讨了Fe^(3+)对曼尼希碱型盐酸缓蚀剂(FHS-A)缓蚀性能的影响机理.通过电镜扫描和能谱分析,证实了Fe^(3+)对曼尼希碱型盐酸缓蚀剂(FHS-A)缓蚀性能的影响. 展开更多
关键词 曼尼希碱 缓蚀剂 缓蚀性能 FE^3+ 静态失重法
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基于性能/位移的能力-需求曲线设计方法 被引量:4
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作者 叶列平 《工程抗震与加固改造》 北大核心 2009年第3期50-55,共6页
针对能力谱法结构地震位移需求难以确定,以及在长周期下可能产生较大误差等不利问题,本文提出了能力-需求曲线法。该方法保留了能力谱法的直观图解过程,可同时确定在不同地震强度等级下的结构抗震位移需求,包括结构的损伤指标及相应的... 针对能力谱法结构地震位移需求难以确定,以及在长周期下可能产生较大误差等不利问题,本文提出了能力-需求曲线法。该方法保留了能力谱法的直观图解过程,可同时确定在不同地震强度等级下的结构抗震位移需求,包括结构的损伤指标及相应的概率。最后本文对各种需求曲线进行了比较,提出了有关建议。 展开更多
关键词 能力-需求曲线法 能力谱法 基于性能/位移设计方法 损伤指标 需求曲线
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某框架-剪力墙结构的抗震设计 被引量:2
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作者 牛金龙 《结构工程师》 北大核心 2013年第5期12-16,共5页
详细地介绍了某框架剪力墙结构的抗震设计。主体结构存在平面不规则性和竖向不规则性。在进行多遇水平地震作用分析时,采用CQC组合进行了谱分析,结果表明,各项指标均在规范允许的范围以内.根据结构各构件的重要性确定了性能化抗震设计目... 详细地介绍了某框架剪力墙结构的抗震设计。主体结构存在平面不规则性和竖向不规则性。在进行多遇水平地震作用分析时,采用CQC组合进行了谱分析,结果表明,各项指标均在规范允许的范围以内.根据结构各构件的重要性确定了性能化抗震设计目标,并通过静力弹塑性分析方法对框架梁、柱和剪力墙等重要构件的抗震性能进行了评估.结果表明。 展开更多
关键词 框架剪力墙结构 性能化抗震设计 推覆分析方法
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粘土结构和粘土-水系统辩证解析及其教学实施
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作者 严建华 崔素萍 +3 位作者 王志宏 柏晓强 韩策 徐玉茹 《教育教学论坛》 2017年第16期85-86,共2页
对粘土结构和粘土-水系统性能进行了辩证解析。基于电荷平衡的性质,结合库仑定律,从科学角度和辩证角度对粘土荷电性质进行了分析。在此基础上对粘土结构和粘土-水系统相关性质,即粘性、可塑性、悬浮性的辩证内涵进行了分析。对课程教... 对粘土结构和粘土-水系统性能进行了辩证解析。基于电荷平衡的性质,结合库仑定律,从科学角度和辩证角度对粘土荷电性质进行了分析。在此基础上对粘土结构和粘土-水系统相关性质,即粘性、可塑性、悬浮性的辩证内涵进行了分析。对课程教学中引导学生进行辩证思维以帮助学生提高学习效率的教学方法进行了探索。 展开更多
关键词 粘土结构 荷电性质 粘土-水系统性质 辩证思维 教学方法
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曼尼希碱1-苯基-3-二乙氨基-1-丙酮的合成、性能及其缓蚀机理 被引量:8
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作者 潘原 战风涛 +4 位作者 张森田 李耀武 王峥 吕志凤 赵成斌 《腐蚀与防护》 CAS 北大核心 2014年第7期715-720,共6页
以苯乙酮、二乙胺和甲醛为原料,在pH=2~3条件下合成了曼尼希碱类酸化缓蚀剂1-苯基-3-二乙氨基-1-丙酮(DEAP),并对其进行分离提纯,产率达到91.4%。用元素分析、FT-IR分析及MS分析技术对DEAP进行结构表征;采用静态失重法考察了DEAP在15%... 以苯乙酮、二乙胺和甲醛为原料,在pH=2~3条件下合成了曼尼希碱类酸化缓蚀剂1-苯基-3-二乙氨基-1-丙酮(DEAP),并对其进行分离提纯,产率达到91.4%。用元素分析、FT-IR分析及MS分析技术对DEAP进行结构表征;采用静态失重法考察了DEAP在15%盐酸和土酸(12%盐酸+3%氢氟酸)介质中对N80钢片的缓蚀性能;采用极化曲线法和扫描电子显微镜研究了DEAP在15%盐酸中的缓蚀机理,同时探讨了DEAP在N80钢片表面的吸附行为。结果表明,在15%盐酸和土酸介质中,当DEAP加剂量分别为0.6%和0.75%时,缓蚀率分别达到99.74%和99.55%;DEAP是一种混合型缓蚀剂;DEAP在N80钢片表面上主要发生化学吸附,且吸附为自发过程,吸附规律服从Langmuir吸附等温式。 展开更多
关键词 曼尼希碱 酸化缓蚀剂 静态失重法 缓蚀性能 吸附等温式
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凝固漂浮有机液滴-分散液液微萃取结合高效液相色谱法同时测定自来水中氯代多环芳烃与多环芳烃 被引量:6
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作者 熊力 王金成 《分析测试学报》 CAS CSCD 北大核心 2019年第11期1335-1339,共5页
建立了自来水中6种氯代多环芳烃和15种多环芳烃的凝固漂浮有机液滴-分散液液微萃取高效液相色谱分析方法,并探讨了萃取剂种类和用量、分散剂种类和用量、氯化钠含量及涡旋振荡时间等因素对萃取效率的影响。优化后的萃取实验条件为:10μ... 建立了自来水中6种氯代多环芳烃和15种多环芳烃的凝固漂浮有机液滴-分散液液微萃取高效液相色谱分析方法,并探讨了萃取剂种类和用量、分散剂种类和用量、氯化钠含量及涡旋振荡时间等因素对萃取效率的影响。优化后的萃取实验条件为:10μL十二醇为萃取溶剂,500μL甲醇为分散溶剂,6%NaCl,涡旋振荡时间2 min。目标化合物经多环芳烃专用柱(SUPELCOSILTMLC-PAH,150 mm×4.6 mm,5μm)分离后,外标法定量。结果表明,21种目标化合物在一定质量浓度范围内线性良好,相关系数均不低于0.999;在低、中、高3个加标水平下的回收率为70.6%~98.7%,相对标准偏差(RSD)为2.0%~10%;方法的检出限(LOD,S/N=3)为0.0007~0.009μg/L,定量下限(LOQ,S/N=10)为0.0022~0.028μg/L。可用于自来水中氯代多环芳烃和多环芳烃的分析检测。 展开更多
关键词 氯代多环芳烃和多环芳烃 凝固漂浮有机液滴-分散液液微萃取 高效液相色谱 自来水
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一种基于改进K-means算法的网络流量分类方法 被引量:13
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作者 刘纪伟 赵杨 李绍晖 《电子技术应用》 北大核心 2017年第11期86-89,94,共5页
针对网络流量分类识别系统尤其是实时识别系统对实现复杂度和分类准确率的要求,提出一种复杂度和准确率的折中方案。通过基于密度的思想对K-means算法随机选取初始聚类中心这一关键缺陷进行改进,以及引入聚类有效性判别准则函数确定最... 针对网络流量分类识别系统尤其是实时识别系统对实现复杂度和分类准确率的要求,提出一种复杂度和准确率的折中方案。通过基于密度的思想对K-means算法随机选取初始聚类中心这一关键缺陷进行改进,以及引入聚类有效性判别准则函数确定最终聚类个数实现对算法的全面优化,进而提出基于改进K-means算法的网络流量分类方法,在兼顾K-means算法简单易实现、分类快速特点的同时,提高了分类的准确率。在公开的权威网络流量数据集上的实验表明,与普通K-means方法相比,该方法在网络流量分类方面具有更高的分类准确率和更好的稳定性。 展开更多
关键词 网络流量分类 K-均值 聚类中心 基于密度
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曼尼希碱1-苯基-3-吗啉基-1-丙酮的合成及其对N80钢的缓蚀吸附行为 被引量:2
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作者 潘原 战风涛 +1 位作者 杨震 吕志凤 《材料保护》 CAS CSCD 北大核心 2015年第3期23-26,7,共4页
目前,国内对曼尼希碱类缓蚀剂的研究主要侧重于应用,而对理论方面的报道较少。以苯乙酮、吗啉和甲醛为原料,在pH=2—3条件下合成了曼尼希碱类酸化缓蚀剂1-苯基-3-吗啉基-1-丙酮(MOPP),采用元素分析仪,红外光谱仪分析MOPP的元素... 目前,国内对曼尼希碱类缓蚀剂的研究主要侧重于应用,而对理论方面的报道较少。以苯乙酮、吗啉和甲醛为原料,在pH=2—3条件下合成了曼尼希碱类酸化缓蚀剂1-苯基-3-吗啉基-1-丙酮(MOPP),采用元素分析仪,红外光谱仪分析MOPP的元素组成及结构;采用静态腐蚀失重法和电化学极化曲线法研究了MOPP在15%盐酸中对N80钢片的缓蚀性能,探讨了MOPP对N80钢片的吸附行为,并对吸附热力学和动力学参数进行了计算。结果表明:MOPP具有较高的缓蚀性能,能同时抑制N80钢的阴、阳极腐蚀反应过程,缓蚀效率随着浓度的增加而增加,随着温度的增加而降低;MOPP在N80钢片表面上主要发生化学吸附,且吸附过程是一个自发、放热、混乱程度减小的过程,吸附规律服从Langmuir吸附等温式。 展开更多
关键词 曼尼希碱类缓蚀剂 吸附行为 热力学参数 动力学行为 静态腐蚀失重 极化曲线 缓蚀性能
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