采用X线衍射(X-ray diffraction,XRD)和扫描电镜(scanning electron microscope,SEM)对以电镀法制备的PbO_2/Ti阳极进行表征,以阳极氧化电流占比系数γ描述苯酚氧化与析氧反应之间的影响机制,并基于法拉第定律建立描述有机物氧化进程的...采用X线衍射(X-ray diffraction,XRD)和扫描电镜(scanning electron microscope,SEM)对以电镀法制备的PbO_2/Ti阳极进行表征,以阳极氧化电流占比系数γ描述苯酚氧化与析氧反应之间的影响机制,并基于法拉第定律建立描述有机物氧化进程的通用阶段反应动力学模型;在不同电流密度和进水流量条件下进行苯酚阳极氧化实验。研究结果表明:电极表面晶相主要为β-PbO_2,晶粒平均直径为50.23 nm,形成的团聚体粒径在5~10μm之间。PbO_2/Ti阳极析氧电位约为1.78 V;液相中苯酚的存在可抑制氧气析出,且析氧反应电阻由无苯酚情况下的148.3?增大至195.9?。回归分析和F检验结果证明理论预测值与实验数据之间具有一致性。展开更多
Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electroc...Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electrochemical decomposition was monitored by ultra-violet spectrophotometry and CODCr method. The electrochemical decomposition mechanism of imazethapyr was studied primarily by UV-VIS spectrophotometry. The effectiveness of the electrochemical pretreatment was proved by the comparative aerobic biological treatment test based on the activated sludge process.展开更多
文摘Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electrochemical decomposition was monitored by ultra-violet spectrophotometry and CODCr method. The electrochemical decomposition mechanism of imazethapyr was studied primarily by UV-VIS spectrophotometry. The effectiveness of the electrochemical pretreatment was proved by the comparative aerobic biological treatment test based on the activated sludge process.
文摘采用电沉积法镀制Ti/Sb-SnO2/β-PbO2电极,研究电沉积时间、镀液温度、pH值、NaF浓度,以及电流密度等因素对电极催化活性和稳定性的影响规律.结果表明,当电沉积时间为1 h,镀液温度为60℃,镀液pH值为1,NaF浓度为0.04 mol.L-1,组合电流密度为600/400 A.m-2(梯度电流密度)时,电极性能最佳,对苯酚降解率达91.4%,强化寿命为23 h.
