Effects ofγ-irradiation and deformation temperature（T）on the tensile properties of Pb-2mass% Sb alloys were studied.The samples were annealed at 458 Kfor 2hin air,then water quenched after they wereγ-irradiated（t...Effects ofγ-irradiation and deformation temperature（T）on the tensile properties of Pb-2mass% Sb alloys were studied.The samples were annealed at 458 Kfor 2hin air,then water quenched after they wereγ-irradiated（the different doses were 0.5,1.0,1.5,and 2.0 MGy）.The tensile properties were performed using stress-strain measurements at a constant strain rate（1.2×10^（-3） s^（-1））and at different T（303-393K）.It was found that at constant dose,the fracture stress（σF）decreases while the fracture strain（εF）increases as Tincreases.At particular T,σFincreases whileεFdecreases with increasing dose.The strain-hardening exponent（n）,which is the slope of the relation between ln（σ）and ln（ε）of the parabolic part of the stress-strain curve,was determined and its values increase as Tincreases and decrease as the dose increases.The value of the activation energy increases as the dose increases from 0.07 eV for un-irradiated sample to 0.1eV for the 2 MGy-irradiated sample.These values are in accordance with that needed for dislocation movement and ordering process.An interpretation of the results was given,based on the creation of point and line defects due toγ-irradiation,and that results in a distribution of beta phase（Sb-phase）,leading to a difficulty in the movement of dislocations,so there is an increase in alloy hardness.展开更多
Pb?Ag?PbO2 composite anodes with different mass fractions(1%,2%,3%,4%and 5%)ofβ-PbO2 were prepared by powder-pressed(PP)method.The galvanostatic polarization curves,Tafel curves and anodic polarization curves were te...Pb?Ag?PbO2 composite anodes with different mass fractions(1%,2%,3%,4%and 5%)ofβ-PbO2 were prepared by powder-pressed(PP)method.The galvanostatic polarization curves,Tafel curves and anodic polarization curves were tested in sulfuric acid solution.The morphologies and phase compositions of the anodic layers formed after galvanostatic polarization were investigated by using scanning electron microscope(SEM)and X-ray diffractometer(XRD),respectively.The results showed thatβ-PbO2 can improve the electrocatalytic activity of anodic oxide.The anode containing 3%β-PbO2 had the lowest overpotential of oxygen evolution reaction(OER)and the best corrosion resistance.The morphologies of the anode surfaces were gradually transformed from regular crystals to amorphous ones as the content ofβ-PbO2 increased in anodes.展开更多
A zinc sulfate open framework matrix,[Zn(SO_4)(DMSO)](1),was synthesized by solvothermal evaporationusing dimethyl sulfoxide(DMSO)as the solvent.A compositeP@1,which exhibits fluorescence and room tempera-ture phospho...A zinc sulfate open framework matrix,[Zn(SO_4)(DMSO)](1),was synthesized by solvothermal evaporationusing dimethyl sulfoxide(DMSO)as the solvent.A compositeP@1,which exhibits fluorescence and room tempera-ture phosphorescence(RTP)properties,was prepared by doping 2,6-naphthalic acid(P)into matrix1at a low con-centration.P@1emitted a green RTP that was visible to the naked eye and lasted for approximately 2 s.P@1exhib-ited selective phosphorescence enhancement response towards Pb^(2+),with a detection limit of 2.52μmol·L^(-1).Themain detection mechanism is the Pb—O coordination-induced phosphorescence enhancement in the system.Inter-estingly,P@1also functioned as a dual-channel probe for the rapid detection of Fe^(3+)ions through fluorescencequenching with a detection limit of 0.038μmol·L^(-1).The recognition mechanism may be attributed to the competi-tive energy absorption betweenP@1and Fe^(3+)ions.CCDC:2388502,1.展开更多
基金Deanship of Scientific Research,Northern Border University,Arar,Kingdom of Saudi Arabia,for financial support
文摘Effects ofγ-irradiation and deformation temperature（T）on the tensile properties of Pb-2mass% Sb alloys were studied.The samples were annealed at 458 Kfor 2hin air,then water quenched after they wereγ-irradiated（the different doses were 0.5,1.0,1.5,and 2.0 MGy）.The tensile properties were performed using stress-strain measurements at a constant strain rate（1.2×10^（-3） s^（-1））and at different T（303-393K）.It was found that at constant dose,the fracture stress（σF）decreases while the fracture strain（εF）increases as Tincreases.At particular T,σFincreases whileεFdecreases with increasing dose.The strain-hardening exponent（n）,which is the slope of the relation between ln（σ）and ln（ε）of the parabolic part of the stress-strain curve,was determined and its values increase as Tincreases and decrease as the dose increases.The value of the activation energy increases as the dose increases from 0.07 eV for un-irradiated sample to 0.1eV for the 2 MGy-irradiated sample.These values are in accordance with that needed for dislocation movement and ordering process.An interpretation of the results was given,based on the creation of point and line defects due toγ-irradiation,and that results in a distribution of beta phase（Sb-phase）,leading to a difficulty in the movement of dislocations,so there is an increase in alloy hardness.
基金Project(2017YFB0305401)supported by the National Key R&D Program of ChinaProjects(51874369,51474245,51871249)supported by the National Natural Science Foundation of China+1 种基金Project(2018JJ3659)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2018RS3007)supported by Huxiang Young Talents Plan,China
文摘Pb?Ag?PbO2 composite anodes with different mass fractions(1%,2%,3%,4%and 5%)ofβ-PbO2 were prepared by powder-pressed(PP)method.The galvanostatic polarization curves,Tafel curves and anodic polarization curves were tested in sulfuric acid solution.The morphologies and phase compositions of the anodic layers formed after galvanostatic polarization were investigated by using scanning electron microscope(SEM)and X-ray diffractometer(XRD),respectively.The results showed thatβ-PbO2 can improve the electrocatalytic activity of anodic oxide.The anode containing 3%β-PbO2 had the lowest overpotential of oxygen evolution reaction(OER)and the best corrosion resistance.The morphologies of the anode surfaces were gradually transformed from regular crystals to amorphous ones as the content ofβ-PbO2 increased in anodes.
文摘A zinc sulfate open framework matrix,[Zn(SO_4)(DMSO)](1),was synthesized by solvothermal evaporationusing dimethyl sulfoxide(DMSO)as the solvent.A compositeP@1,which exhibits fluorescence and room tempera-ture phosphorescence(RTP)properties,was prepared by doping 2,6-naphthalic acid(P)into matrix1at a low con-centration.P@1emitted a green RTP that was visible to the naked eye and lasted for approximately 2 s.P@1exhib-ited selective phosphorescence enhancement response towards Pb^(2+),with a detection limit of 2.52μmol·L^(-1).Themain detection mechanism is the Pb—O coordination-induced phosphorescence enhancement in the system.Inter-estingly,P@1also functioned as a dual-channel probe for the rapid detection of Fe^(3+)ions through fluorescencequenching with a detection limit of 0.038μmol·L^(-1).The recognition mechanism may be attributed to the competi-tive energy absorption betweenP@1and Fe^(3+)ions.CCDC:2388502,1.
