Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,tho...Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,those risks can be solved with passive solutions,which require no active cooling or heating.Thecurrentwork aims to optimize the pack design and materials of the type-NCR18650B battery based on a wide range of operation temperature.The lower limit was denoted by cold case while the maximum limit was expressed by hot case.A combined analyticalnumerical approach was developed to model the heat generation inside the battery.A thermal resistance analysis was used to determine the boundary conditions of the numerical model.The governing differential equations for the 1-D heat generation model were solved analytically.The numerical analysis was considered to determine the best battery pack design based on material parameters,number of batteries,and geometrical arrangement.The analytical results revealedthat the cold case canbe selectedas theworst case and thebestmodel wasobtainedusing thehexagonal-shaped 10-battery pack that was covered with Delrin of 1.8 mm in thickness.The numerical results showed that the best model was the hexagonal-shaped 10-battery pack with Delrin of 2 mm in thickness that achieved the largest temperature of−20.6℃ in the cold case.展开更多
Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dyn...Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies.展开更多
To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composite...To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composites using Zr_(2)Cu as the filler.The microstructure,mechanical properties,and ablation properties of the Zr_(2)Cu packed composites were analyzed.Results show that during Zr_(2)Cu impregnation,the melt efficiently fills the large pores of the composites and is converted to ZrCu due to a partial reaction of zirconium with carbon.This results in an increase in composite density from 1.91 g/cm^(3)to 2.24 g/cm^(3)and a reduction in open porosity by 27.35%.Additionally,the flexural strength of Zr_(2)Cu packed C/C-SiC-ZrC composites is improved from 122.78±8.09 MPa to 135.53±5.40 MPa.After plasma ablation for 20 s,the modified composites demonstrate superior ablative resistance compared to PIP C/C-SiC-ZrC,with mass ablation and linear ablation rates of 2.77×10^(−3)g/s and 2.60×10^(−3)mm/s,respectively.The“selftranspiration”effect of the low-melting point copper-containing phase absorbs the heat of the plasma flame,further reducing the ablation temperature and promoting the formation of refined ZrO_(2)particles within the SiO_(2)melting layer.This provides more stable erosion protection for Zr_(2)Cu packed C/C-SiC-ZrC composites.展开更多
On the morning of 23 December 2024,the Panda Pack and Bike Donation Ceremony in Cambodia under the Action Plan on Silk Road People-to-People Connectivity was held at Balaing Khang Lech Primary School in Kampong Thom P...On the morning of 23 December 2024,the Panda Pack and Bike Donation Ceremony in Cambodia under the Action Plan on Silk Road People-to-People Connectivity was held at Balaing Khang Lech Primary School in Kampong Thom Province.Over 150 participants including Kemreat Viseth,Deputy Director of the Council of Ministers of Cambodia and President of Civil Society Alliance Forum(CSAF),Nhek Ban Kheng,Deputy Governor of Kampong Thom Province.展开更多
Herein,the liquid-solid mass trans fer characteristics in micropacked bed reactors(μPBRs)operated with immiscible liquid-liquid two-phase flow is experimentally investigated.It is found that the overall volumetric li...Herein,the liquid-solid mass trans fer characteristics in micropacked bed reactors(μPBRs)operated with immiscible liquid-liquid two-phase flow is experimentally investigated.It is found that the overall volumetric liquid-solid mass transfer coefficient(k_(s)a)increases with the total flow rate and the channelto-particle diameter ratio,while decreases with the organic-to-aqueous phase flow rate ratio.A satisfactory correlation model for calculating k_(s)a of the liquid-liquid μPBRs is developed.The new knowledge obtained would be useful in guiding the design and optimization of the liquid-liquid μPBRs.展开更多
With the rapid development of the new energy automotive industry,the enhancement of lithium battery performance and production efficiency has become critical.This article explores the application of artificial intelli...With the rapid development of the new energy automotive industry,the enhancement of lithium battery performance and production efficiency has become critical.This article explores the application of artificial intelligence technology in the lithium battery module PACK line,analyzing how it optimizes the production process and improves production efficiency,and predicts future development trends.The PACK line is an important link in battery manufacturing,involving complex processes such as cell sorting,welding,assembly and testing.The application of AI technology in image recognition,data analysis and predictive maintenance provides new solutions for the intelligent upgrading of the PACK line.This article describes the process of the PACK line in detail,analyzes the challenges under current technological levels,and reviews the application cases of AI technology in the manufacturing industry.The study aims to provide theoretical and practical guidance for the intelligent development of lithium battery module PACK lines,discussing the integration of AI technology,its actual performance,technical challenges,and solutions.It is expected that AI technology will play a greater role in the PACK line,and future research will focus on improving the adaptability of models,developing efficient algorithms,and further integrating into the production line.展开更多
The large molecular weight and high hydrophilicity of chloramphenicol(CAP) residuals in wastewater led to severe degradation difficulty,which propelled the development of new wastewater degradation processes and react...The large molecular weight and high hydrophilicity of chloramphenicol(CAP) residuals in wastewater led to severe degradation difficulty,which propelled the development of new wastewater degradation processes and reactors based on process intensification.This study enhanced the CAP degradation by ozone/peroxydisulfate(PDS) advanced oxidation process in a submerged rotating packed bed(SRPB)reactor.Compared the usage of different oxidants,it was indicated that the combination of O_(3) and PDS exhibited a higher degradation efficiency than ozone and PDS alone.The more desired degradation efficiency could be achieved at the operating conditions of ascending PDS concentration,SRPB rotational speed,ozone concentration,reduced initial CAP concentration,and the water qualities of ascended pH,lower Cl^(-)and initial CO_(3)^(2-) concentrations.Under the optimized conditions of C_(CAP)=20 mg·L^(-1),C_(O3)=30 mg·L^(-1),C_(PDS)=100 mg·L^(-1),and N=400 r·min^(-1),and water qualities of pH=10,the maximum chloramphenicol degradation efficiency of 97% and kinetic constant of 0.23 min^(-1) were achieved after treating 16 min.A comparison of the results with previously reported advanced oxidation processes of CAP indicated that the enhanced O^(3)/PDS advanced oxidation system using the SRPB can significantly improve the degradation efficiency of CAP.展开更多
AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ...AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ophthalmoscopy(AOSLO)systems were utilized for retinal imaging with a large sampling window of 700μm×700μm.The study cohort included 14 emmetropic[spherical equivalent(SE)ranged+0.5 to-0.5 D],15 low myopic(SE ranged-0.5 to-3 D)and 21 moderate myopic(SE ranged-3 to-6 D)healthy young adults.Photoreceptors at 3°temporal,6°superior and inferior 6°were captured.Statistical analysis was then performed to obtain PCPD and cell spacing.RESULTS:The average age of participants was 22.54±2.86(ranged 20–30y)with no difference among 3 groups.At 3°temporal,the emmetropic group exhibited the highest PCPD of 15186.16±2050.54 cells/mm^(2),while the low and moderate myopic groups had PCPD of 14009.15±1073.01 and 13466.92±1121.71 cells/mm2,respectively.At 3°temporal,the emmetropic group also had the smallest cell spacing at 6.66±0.26 mm,compared to 6.85±0.26 and 6.91±0.28 mm for the low and moderate myopic groups,respectively.Compared to the emmetropic group,at 3°temporal,the myopic groups showed significantly reduced PCPD(low myopia:P=0.032;moderate myopia:P=0.001).At 6°inferior,the moderate myopic group exhibited a significant decrease in PCPD(P=0.013),while at 6°superior,there were no significant statistical differences in PCPD for the low and moderate myopic groups(P>0.05).In comparison to the emmetropic group,only the moderate myopic group showed significantly increased cell spacing at all three positions(temporal 3°:P=0.011,superior 6°:P=0.046,inferior 6°:P=0.013).Correlation analysis revealed a positive correlation between PCPD and axial length changes(P<0.05).CONCLUSION:Reduced PCPD and increased cell spacing strongly correlated with refractive error in mild to moderate myopic eyes,especially at 6°inferior to the fovea and the decreased PCPD in the macular region of myopic patients may be associated with increased axial lengthinduced retinal stretching.展开更多
The application of carbon capture systems on ships is technically constrained by limited onboard space and the weight of the conventional absorption tower.The rotating packed bed(RPB)has emerged as a promising alterna...The application of carbon capture systems on ships is technically constrained by limited onboard space and the weight of the conventional absorption tower.The rotating packed bed(RPB)has emerged as a promising alternative due to its small footprint and high mass transfer performance.However,despite its advantages,the structural and vibration stability of RPBs at high rotational speed remains insufficiently studied,and no international design standards currently exist for RPBs.To address this gap,this study performed a comprehensive finite element analysis(FEA)using ANSYS to investigate the structural and dynamic characteristics of an RPB.A three-dimensional model was developed to evaluate the effects of material selection(316 stainless steel,aluminum alloy,titanium alloy),bearing stiffness,and unbalanced mass on deformation,stress,and natural frequencies.In the structural analysis,316 stainless steel exhibited the highest von Mises stress and deformation.However,it was confirmed that all three materials did not exceed their yield strengths at the maximum rotating speed.Modal analysis and Campbell diagrams showed no resonance risk within the rated speed range,and increased bearing stiffness led to higher natural frequencies and improved stability.The findings provide quantitative design guidance for material selection,bearing stiffness optimization,and vibration control in high-rotational-speed RPB systems.This study contributes to establishing a foundational framework for the mechanical reliability and standardization of marine carbon capture units.展开更多
This paper introduces a kind of substitute bench testing method for vehicle application development and testing method of the test requirements,including battery fast conversion cycle test equipment,enter type incubat...This paper introduces a kind of substitute bench testing method for vehicle application development and testing method of the test requirements,including battery fast conversion cycle test equipment,enter type incubator,liquid-cooled machine and ancillary equipment composed of a set of test system,through the walk-in constant temperature box to simulate the new energy vehicles under different environmental conditions of the test requirements,Liquid-cooled machine and auxiliary parts to complete the battery thermal management system need cooling fluid conditions,the battery conversion cycle test equipment to simulate the dc fast charging way of filling pile,complete battery thermal management system test,shorten the filling fast charging time and improve battery fast charge security,for troubleshooting and data collection and analysis,Improve work efficiency,save costs,and eliminate customer anxiety about battery life and charging time.展开更多
Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is...Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is severely constrained by the absence of efficient methods for rapidly predicting crystal packing modes from molecular structures,impeding the high-throughput rational design of such materials.In this study,we employed quantified indicators,such as hydrogen bond dimension and maximum planar separation,to quickly screen 172DEM and 16 non-2DEM crystal structures from a crystal database.They were subsequently compared and analyzed,focusing on hydrogen bond donor-acceptor combinations,skeleton features,and intermolecular interactions.Our findings suggest that theπ-πpacking interaction energy is a key determinant in the formation of layered packing modes by planar energetic molecules,with its magnitude primarily influenced by the strongest dimericπ-πinteraction(π-π2max).Consequently,we have delineated a critical threshold forπ-π2max to discern layered packing modes and formulated a theoretical model for predictingπ-π2max,grounded in molecular electrostatic potential and dipole moment analysis.The predictive efficacy of this model was substantiated through external validation on a test set comprising 31 planar energetic molecular crystals,achieving an accuracy of 84%and a recall of 75%.Furthermore,the proposed model shows superior classification predictive performance compared to typical machine learning methods,such as random forest,on the external validation samples.This contribution introduces a novel methodology for the identification of crystal packing modes in 2DEMs,potentially accelerating the design and synthesis of high-energy,low-sensitivity 2DEMs.展开更多
The propylene/propane(C_(3)H_(6)/C_(3)H_(8))separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-or...The propylene/propane(C_(3)H_(6)/C_(3)H_(8))separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-organic framework(Co-aip-pyz)with customized pore environment and selective binding sites for the challenging C_(3)H_(6)/C_(3)H_(8) separation.Co-aip-pyz exhibits a good C_(3)H_(6) uptake with an ultrahigh C_(3)H_(6) packing density(931 g/L),as well as possesses a remarkable C_(3)H_(6)/C_(3)H_(8) uptake ratio with 911% and distinguished C_(3)H_(6)/C_(3)H_(8) selectivity(>10^(4))at 298 K and 1.0 bar.Furthermore,Co-aip-pyz possesses a record high C_(3)H_(6) packing density with 859 g/L at 313 K and 1.0 bar,which is unprecedented in the C_(3)H_(6)/C_(3)H_(8) separation.Its high performance for the C_(3)H_(6)/C_(3)H_(8) separation has been further confirmed by breakthrough experiments and molecular simulations.Combined with good stability,facilely synthesized procedure by low-cost precursors,record-high C_(3)H_(6) packing density,as well as good C_(3)H_(6)/C_(3)H_(8) separation performance,it highlights Co-aip-pyz as a benchmark adsorbent to address daunting challenge for industrial C_(3)H_(6)/C_(3)H_(8) separation.This work provides valuable insights into constructing top-performing MOF materials for addressing the industrial separation challenges.展开更多
针对复合材料电池包下箱体的树脂传递模塑(Resin Transfer Molding,RTM)成型进行了方案设计,基于PAM-RTM软件对其充模过程进行仿真分析及孔隙缺陷预测。首先,对比了两种方案在三种出胶口状态下充模时间,分析了注胶压力及树脂黏度对RTM...针对复合材料电池包下箱体的树脂传递模塑(Resin Transfer Molding,RTM)成型进行了方案设计,基于PAM-RTM软件对其充模过程进行仿真分析及孔隙缺陷预测。首先,对比了两种方案在三种出胶口状态下充模时间,分析了注胶压力及树脂黏度对RTM成型时间的影响规律;其次,分析了充模过程中注胶口附近位置的压力变化情况;最后,预测了宏观/微观两种尺度孔隙缺陷在构件中分布及注胶压力对孔隙含量的影响规律,并结合流速优化理论控制树脂前沿流速以降低孔隙含量。结果表明,模腔内注胶与出胶口压力差越大,成型用时越少,且受到注胶位置影响。注胶压力与充模时间呈线性关系,压力越低,充模时间缩短效果越明显,且黏度越大,充模时间越长。孔隙含量与前沿流速有关,注胶压力越大导致流速越快,宏观孔隙随之减少,微观孔隙相应增多;且流速优化方式注胶能够显著降低总体孔隙率水平,但会延长成型周期。展开更多
文摘Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,those risks can be solved with passive solutions,which require no active cooling or heating.Thecurrentwork aims to optimize the pack design and materials of the type-NCR18650B battery based on a wide range of operation temperature.The lower limit was denoted by cold case while the maximum limit was expressed by hot case.A combined analyticalnumerical approach was developed to model the heat generation inside the battery.A thermal resistance analysis was used to determine the boundary conditions of the numerical model.The governing differential equations for the 1-D heat generation model were solved analytically.The numerical analysis was considered to determine the best battery pack design based on material parameters,number of batteries,and geometrical arrangement.The analytical results revealedthat the cold case canbe selectedas theworst case and thebestmodel wasobtainedusing thehexagonal-shaped 10-battery pack that was covered with Delrin of 1.8 mm in thickness.The numerical results showed that the best model was the hexagonal-shaped 10-battery pack with Delrin of 2 mm in thickness that achieved the largest temperature of−20.6℃ in the cold case.
文摘Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies.
基金Open Fund of Zhijian Laboratory,Rocket Force University of Engineering(2024-ZJSYS-KF02-09)National Natural Science Foundation of China(51902028,52272034)+1 种基金Key Research and Development Program of Shaanxi(2023JBGS-15)Fundamental Research Funds for the Central Universities(Changan University,300102313202,300102312406)。
文摘To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composites using Zr_(2)Cu as the filler.The microstructure,mechanical properties,and ablation properties of the Zr_(2)Cu packed composites were analyzed.Results show that during Zr_(2)Cu impregnation,the melt efficiently fills the large pores of the composites and is converted to ZrCu due to a partial reaction of zirconium with carbon.This results in an increase in composite density from 1.91 g/cm^(3)to 2.24 g/cm^(3)and a reduction in open porosity by 27.35%.Additionally,the flexural strength of Zr_(2)Cu packed C/C-SiC-ZrC composites is improved from 122.78±8.09 MPa to 135.53±5.40 MPa.After plasma ablation for 20 s,the modified composites demonstrate superior ablative resistance compared to PIP C/C-SiC-ZrC,with mass ablation and linear ablation rates of 2.77×10^(−3)g/s and 2.60×10^(−3)mm/s,respectively.The“selftranspiration”effect of the low-melting point copper-containing phase absorbs the heat of the plasma flame,further reducing the ablation temperature and promoting the formation of refined ZrO_(2)particles within the SiO_(2)melting layer.This provides more stable erosion protection for Zr_(2)Cu packed C/C-SiC-ZrC composites.
文摘On the morning of 23 December 2024,the Panda Pack and Bike Donation Ceremony in Cambodia under the Action Plan on Silk Road People-to-People Connectivity was held at Balaing Khang Lech Primary School in Kampong Thom Province.Over 150 participants including Kemreat Viseth,Deputy Director of the Council of Ministers of Cambodia and President of Civil Society Alliance Forum(CSAF),Nhek Ban Kheng,Deputy Governor of Kampong Thom Province.
文摘Herein,the liquid-solid mass trans fer characteristics in micropacked bed reactors(μPBRs)operated with immiscible liquid-liquid two-phase flow is experimentally investigated.It is found that the overall volumetric liquid-solid mass transfer coefficient(k_(s)a)increases with the total flow rate and the channelto-particle diameter ratio,while decreases with the organic-to-aqueous phase flow rate ratio.A satisfactory correlation model for calculating k_(s)a of the liquid-liquid μPBRs is developed.The new knowledge obtained would be useful in guiding the design and optimization of the liquid-liquid μPBRs.
文摘With the rapid development of the new energy automotive industry,the enhancement of lithium battery performance and production efficiency has become critical.This article explores the application of artificial intelligence technology in the lithium battery module PACK line,analyzing how it optimizes the production process and improves production efficiency,and predicts future development trends.The PACK line is an important link in battery manufacturing,involving complex processes such as cell sorting,welding,assembly and testing.The application of AI technology in image recognition,data analysis and predictive maintenance provides new solutions for the intelligent upgrading of the PACK line.This article describes the process of the PACK line in detail,analyzes the challenges under current technological levels,and reviews the application cases of AI technology in the manufacturing industry.The study aims to provide theoretical and practical guidance for the intelligent development of lithium battery module PACK lines,discussing the integration of AI technology,its actual performance,technical challenges,and solutions.It is expected that AI technology will play a greater role in the PACK line,and future research will focus on improving the adaptability of models,developing efficient algorithms,and further integrating into the production line.
基金supported by the National Natural Science Foundation of China(22288102)。
文摘The large molecular weight and high hydrophilicity of chloramphenicol(CAP) residuals in wastewater led to severe degradation difficulty,which propelled the development of new wastewater degradation processes and reactors based on process intensification.This study enhanced the CAP degradation by ozone/peroxydisulfate(PDS) advanced oxidation process in a submerged rotating packed bed(SRPB)reactor.Compared the usage of different oxidants,it was indicated that the combination of O_(3) and PDS exhibited a higher degradation efficiency than ozone and PDS alone.The more desired degradation efficiency could be achieved at the operating conditions of ascending PDS concentration,SRPB rotational speed,ozone concentration,reduced initial CAP concentration,and the water qualities of ascended pH,lower Cl^(-)and initial CO_(3)^(2-) concentrations.Under the optimized conditions of C_(CAP)=20 mg·L^(-1),C_(O3)=30 mg·L^(-1),C_(PDS)=100 mg·L^(-1),and N=400 r·min^(-1),and water qualities of pH=10,the maximum chloramphenicol degradation efficiency of 97% and kinetic constant of 0.23 min^(-1) were achieved after treating 16 min.A comparison of the results with previously reported advanced oxidation processes of CAP indicated that the enhanced O^(3)/PDS advanced oxidation system using the SRPB can significantly improve the degradation efficiency of CAP.
基金Supported by National Natural Science Foundation of China(No.82271107).
文摘AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ophthalmoscopy(AOSLO)systems were utilized for retinal imaging with a large sampling window of 700μm×700μm.The study cohort included 14 emmetropic[spherical equivalent(SE)ranged+0.5 to-0.5 D],15 low myopic(SE ranged-0.5 to-3 D)and 21 moderate myopic(SE ranged-3 to-6 D)healthy young adults.Photoreceptors at 3°temporal,6°superior and inferior 6°were captured.Statistical analysis was then performed to obtain PCPD and cell spacing.RESULTS:The average age of participants was 22.54±2.86(ranged 20–30y)with no difference among 3 groups.At 3°temporal,the emmetropic group exhibited the highest PCPD of 15186.16±2050.54 cells/mm^(2),while the low and moderate myopic groups had PCPD of 14009.15±1073.01 and 13466.92±1121.71 cells/mm2,respectively.At 3°temporal,the emmetropic group also had the smallest cell spacing at 6.66±0.26 mm,compared to 6.85±0.26 and 6.91±0.28 mm for the low and moderate myopic groups,respectively.Compared to the emmetropic group,at 3°temporal,the myopic groups showed significantly reduced PCPD(low myopia:P=0.032;moderate myopia:P=0.001).At 6°inferior,the moderate myopic group exhibited a significant decrease in PCPD(P=0.013),while at 6°superior,there were no significant statistical differences in PCPD for the low and moderate myopic groups(P>0.05).In comparison to the emmetropic group,only the moderate myopic group showed significantly increased cell spacing at all three positions(temporal 3°:P=0.011,superior 6°:P=0.046,inferior 6°:P=0.013).Correlation analysis revealed a positive correlation between PCPD and axial length changes(P<0.05).CONCLUSION:Reduced PCPD and increased cell spacing strongly correlated with refractive error in mild to moderate myopic eyes,especially at 6°inferior to the fovea and the decreased PCPD in the macular region of myopic patients may be associated with increased axial lengthinduced retinal stretching.
基金support of the Korea Institute of Industrial Technology and Promotion,with the financial resources of the government(Ministry of Trade,Industry,and Energy)in 2024.(RS-2024-00424595,project to train high-quality researchers for the next generation of marine mobility industry innovation).
文摘The application of carbon capture systems on ships is technically constrained by limited onboard space and the weight of the conventional absorption tower.The rotating packed bed(RPB)has emerged as a promising alternative due to its small footprint and high mass transfer performance.However,despite its advantages,the structural and vibration stability of RPBs at high rotational speed remains insufficiently studied,and no international design standards currently exist for RPBs.To address this gap,this study performed a comprehensive finite element analysis(FEA)using ANSYS to investigate the structural and dynamic characteristics of an RPB.A three-dimensional model was developed to evaluate the effects of material selection(316 stainless steel,aluminum alloy,titanium alloy),bearing stiffness,and unbalanced mass on deformation,stress,and natural frequencies.In the structural analysis,316 stainless steel exhibited the highest von Mises stress and deformation.However,it was confirmed that all three materials did not exceed their yield strengths at the maximum rotating speed.Modal analysis and Campbell diagrams showed no resonance risk within the rated speed range,and increased bearing stiffness led to higher natural frequencies and improved stability.The findings provide quantitative design guidance for material selection,bearing stiffness optimization,and vibration control in high-rotational-speed RPB systems.This study contributes to establishing a foundational framework for the mechanical reliability and standardization of marine carbon capture units.
文摘This paper introduces a kind of substitute bench testing method for vehicle application development and testing method of the test requirements,including battery fast conversion cycle test equipment,enter type incubator,liquid-cooled machine and ancillary equipment composed of a set of test system,through the walk-in constant temperature box to simulate the new energy vehicles under different environmental conditions of the test requirements,Liquid-cooled machine and auxiliary parts to complete the battery thermal management system need cooling fluid conditions,the battery conversion cycle test equipment to simulate the dc fast charging way of filling pile,complete battery thermal management system test,shorten the filling fast charging time and improve battery fast charge security,for troubleshooting and data collection and analysis,Improve work efficiency,save costs,and eliminate customer anxiety about battery life and charging time.
基金support from National Natural Science Foundation of China(Grant Nos.22275145,22305189and 21875184)Natural Science Foundation of Shaanxi Province(Grant Nos.2022JC-10 and 2024JC-YBQN-0112).
文摘Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is severely constrained by the absence of efficient methods for rapidly predicting crystal packing modes from molecular structures,impeding the high-throughput rational design of such materials.In this study,we employed quantified indicators,such as hydrogen bond dimension and maximum planar separation,to quickly screen 172DEM and 16 non-2DEM crystal structures from a crystal database.They were subsequently compared and analyzed,focusing on hydrogen bond donor-acceptor combinations,skeleton features,and intermolecular interactions.Our findings suggest that theπ-πpacking interaction energy is a key determinant in the formation of layered packing modes by planar energetic molecules,with its magnitude primarily influenced by the strongest dimericπ-πinteraction(π-π2max).Consequently,we have delineated a critical threshold forπ-π2max to discern layered packing modes and formulated a theoretical model for predictingπ-π2max,grounded in molecular electrostatic potential and dipole moment analysis.The predictive efficacy of this model was substantiated through external validation on a test set comprising 31 planar energetic molecular crystals,achieving an accuracy of 84%and a recall of 75%.Furthermore,the proposed model shows superior classification predictive performance compared to typical machine learning methods,such as random forest,on the external validation samples.This contribution introduces a novel methodology for the identification of crystal packing modes in 2DEMs,potentially accelerating the design and synthesis of high-energy,low-sensitivity 2DEMs.
基金financially supported by the National Natural Science Foundation of China(No.22275102)NCC Fund(No.NCC2022FH01)。
文摘The propylene/propane(C_(3)H_(6)/C_(3)H_(8))separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-organic framework(Co-aip-pyz)with customized pore environment and selective binding sites for the challenging C_(3)H_(6)/C_(3)H_(8) separation.Co-aip-pyz exhibits a good C_(3)H_(6) uptake with an ultrahigh C_(3)H_(6) packing density(931 g/L),as well as possesses a remarkable C_(3)H_(6)/C_(3)H_(8) uptake ratio with 911% and distinguished C_(3)H_(6)/C_(3)H_(8) selectivity(>10^(4))at 298 K and 1.0 bar.Furthermore,Co-aip-pyz possesses a record high C_(3)H_(6) packing density with 859 g/L at 313 K and 1.0 bar,which is unprecedented in the C_(3)H_(6)/C_(3)H_(8) separation.Its high performance for the C_(3)H_(6)/C_(3)H_(8) separation has been further confirmed by breakthrough experiments and molecular simulations.Combined with good stability,facilely synthesized procedure by low-cost precursors,record-high C_(3)H_(6) packing density,as well as good C_(3)H_(6)/C_(3)H_(8) separation performance,it highlights Co-aip-pyz as a benchmark adsorbent to address daunting challenge for industrial C_(3)H_(6)/C_(3)H_(8) separation.This work provides valuable insights into constructing top-performing MOF materials for addressing the industrial separation challenges.
文摘针对复合材料电池包下箱体的树脂传递模塑(Resin Transfer Molding,RTM)成型进行了方案设计,基于PAM-RTM软件对其充模过程进行仿真分析及孔隙缺陷预测。首先,对比了两种方案在三种出胶口状态下充模时间,分析了注胶压力及树脂黏度对RTM成型时间的影响规律;其次,分析了充模过程中注胶口附近位置的压力变化情况;最后,预测了宏观/微观两种尺度孔隙缺陷在构件中分布及注胶压力对孔隙含量的影响规律,并结合流速优化理论控制树脂前沿流速以降低孔隙含量。结果表明,模腔内注胶与出胶口压力差越大,成型用时越少,且受到注胶位置影响。注胶压力与充模时间呈线性关系,压力越低,充模时间缩短效果越明显,且黏度越大,充模时间越长。孔隙含量与前沿流速有关,注胶压力越大导致流速越快,宏观孔隙随之减少,微观孔隙相应增多;且流速优化方式注胶能够显著降低总体孔隙率水平,但会延长成型周期。
